VOC emissions from atmospheric

storage tanks and driving

mechanisms
Relevant international standards
Calculating and reporting VOC tank
emissions as per API Chapter 19
Measuring VOC tank emissions

Gert van Meijeren,

Managing Director, CTS
 API Chapter 19
API 2567 landing emissions
IPPC BREF Storage tanks 2005
EPA Tank 4.0.9 emission software
 Various Basic Types of API 650
Atmospheric Storage Tank Designs

Steel External Floating Roof (EFR) Fixed Aluminum Dome Roof with IFR

Fixed Steel Cone Fixed Steel Cone Roof Fixed Aluminum or Steel
Roof with IFR (no IFR) Dome Roof (no IFR)
External Floating Roof Tank (EFRT)
External Floating Roof Tank (EFRT),
pontoon type
External Floating Roof Tank (EFRT),
double deck type
Wind and solar radiation drive emissions
Cone Roof Tank (CRT)
Fixed Steel Cone Roof (no IFR), this tank type generates
highest emissions and product loss
Steel cone roof tank with light weight
internal floating roof (IFRT)
Possible emissions for external floating
roof tanks
Possible emissions for fixed roof tanks
Tank emissions, filling loss
Emission aspects ExxonMobil Benzene tanks:
Detailed calculations available, Rotterdam, 12
turn overs per annum
Emission
per Emission
annum reduction
Description: (kg/year): (%):
Emission for standard atmospheric
storage tank 20.513 0
Emission for external floating roof tank,
double seal 1.708 91,67
Emission for internal floating roof tank,
double seal 184 99,10
25.000
Emission
20.000
table
Exxon
15.000
Mobil
Emission per annum:

10.000
Benzene
tanks
5.000

0
Emission for standard Emission for external Emission for internal
atmospheric storage tank floating roof tank, double floating roof tank, double
seal seal

Emission reduction is significant

Tank emissions, landing and filling loss
Tank emissions, tank filling losses (IR
registration)
Tank emissions, breathing losses on
EFR tank (IR registration)
Tank emissions, breathing losses on
IFR tank (IR registration)
Tank emissions, possible reductions
Tank emissions, possible reductions,
tank colour
Tank emissions, possible reductions,
tank configuration
External floating roof tanks are part of the
focus in reducing emissions
Rule 1178 South Coast US
AQMD legislation, BAT:
Converting EFR Tanks is mandatory in California
as per Rule 1178 by the South Coast Air Quality
Management District (AQMD):
- As the true vapor pressure of the stored product
3 psia (20 kPa) than the following is required
1/3 of the EFRT converted per 1-1-2004
2/3 of the EFRT converted per 1-1-2006
All EFR tanks converted per 1-1-2008
Fitting an
aluminium dome
offers other major
benefits.
Picture shows a
converted EFR
tank where the
rolling ladder is
suspended from
the dome and still
gives access to
the (now internal)
floating roof.

Domes eliminate rainwater ingress

and reduce maintenance!
More and more terminals will start to
look like this!
Replacing an external floating roof
by an aluminium dome roof with
internal floating roof (IFR)
CTS40 double
compression
plate seal in
BP tank 130
(BP
Netherlands)
Leg seals for external floating roof
support legs
Leg seals
prevent leg
emissions,
product boil
over and
watering in of
leg sleeves
and therefore
reduce
corrosion
Leg seals will
also prevent
leg sleeve
corrosion,
and as such
reduce
maintenance
costs
BP Tank 130, Guide pole cover and
Leg seals (The Netherlands)
BP Tank 130,
Guide pole
cover and
Leg seals
(The
Netherlands)
Guide pole sleeves in service
Tank emissions, possible reductions,
vapour recovery, treatment and balancing
Summary VRU options
Tank emissions, possible reductions
Storage tanks, risk matrix of emissions
(BREF EIPPC 2005)
Possible emissions for external floating
roof tanks
Possible emissions for fixed roof tanks
ECM (Emission Control Method)
compatibility
Possible Emission Control Method per
type of storage tank
ECM Card
operational
vapour
emissions for
external
floating roof
tanks

ECM =
Emission
Control
Method
ECM Card
operational
vapour
emissions for
fixed roof
tanks

ECM =
Emission
Control
Method
Assessment method BREF:
A) Emission reduction potential
B) Operability
C) Applicability
D) Safety
E) Waste, energy, cross-media
Operational score OS = A * (B+C+D+E)

Financial score:
Capex = Capital Expenditure (F)
Opex = Operational Expenditure (H)
Cn=F * H
Overall score = OS * Cn
Case study, new EFRT for Crude Oil
North Europe, 90 m. diameter double deck
Case study, new FRT for ACN
North Europe, cone roof, 12.5 m. diameter
Emission
measurement, IR
camera (low
costs, not
quantifiable)
Emission measurement, DIAL
measurements (high costs, quantifiable)
Emission measurement, SOF (Solar
Occultation Flux) measurements (high
costs, quantifiable)