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ABSTRACT: Pasteurization or sterilization of food and bioproducts is mostly performed using heat exchangers
in countercurrent flow. The lack of appropriate analytic solutions for temperature profiles in the heating and
cooling sections of such processes is most likely the main reason for the traditional cautious approach of
disregarding the contribution of these stages in the total thermal history calculation. This approach leads to
excessive thermal abuse of the product. The current manuscript describes the derivation and validation of an
analytic solution for the temperature profiles within a double-pipe heat exchanger with countercurrent turbulent
flow of Newtonian fluids, at any possible flow rate and not necessarily assuming an isothermal heating medium
or coolant. The presented solution is based on application of the heat exchanger effectiveness concept in a
partial heat exchanger, and can be easily solved and plotted using a spreadsheet. An interactive ExcelTM workbook
was developed for fast prediction of temperature profiles and used in a simulated case study to demonstrate the
2004 Institute of Food Technologists Vol. 69, Nr. 8, 2004JOURNAL OF FOOD SCIENCE E433
Further reproduction without permission is prohibited Published on Web 10/28/2004
Temperature profiles within a counter . . .
of flow parameters on the thiamine retention. However, numerical coefficient; and A is heat exchange area. In the case of a double-pipe
solutions are unlikely to be used by the food industry because of heat exchanger it is
the mathematical complexity and the substantial programming
skills required. Recently, Abdelghani and Idrissi (2002a) applied a A = D1L (3)
differential approach to determine an exponential factor that can
be used to relate temperatures to a flow-length variable in a where L is flow distance. In the following derivation L was defined
steady-state countercurrent double-pipe heat exchanger. This fac- as starting (L = 0) at the hot inlet. D1 is inside diameter of the inner
tor is strongly dependent on convective heat transfer coefficients pipe (if the difference between the inside and outside diameters is
and requires previous knowledge of these values, rather than us- not negligible, then U should be calculated based on the inside di-
ing the overall heat transfer coefficient. They further used this ameter using Eq. 24). For example, AT = D1LT, where AT is overall
method to investigate the transient response of a flow-rate step heat transfer area and LT is the total pipe length.
change (Abdelghani and Idrissi 2002b). A differential approach was The effectiveness is used to calculate the heat transfer rate (Q)
also applied by Kiesner and Reuter (1984) to simulate temperature for the whole heat exchanger, according to (Incropera and DeWitt
profiles within heat exchangers during countercurrent flow to study 1985):
the effect of temperature profiles on the resulting F-values in ultra-
high temperature (UHT) plants. Simpson and Williams (1974) mod- (4)
eled inactivation of microorganisms and nutrient retention in a tu-
bular sterilizer at laminar flow of Newtonian and non-Newtonian Thi is hot stream inlet temperature and Tci is cold stream inlet
foods. They have used their model to demonstrate the effect of temperature.
tube radius, wall temperature, and the pseudoplastic index of the Similarly, when considering a partial heat exchanger (Figure 1),
food on inactivation of Clostridium botulinum spores and retention the latter equation should be written as:
of thiamin. However, their model assumed constant wall tempera-
ture and heat transfer accounted for conduction only, which makes (5)
it inapplicable for a general countercurrent turbulent flow.
In the current paper, we present an analytic solution for temper- Thi is hot stream inlet temperature and TcL is cold stream inlet
E: Food Engineering & Physical Properties
ature profiles within a double-pipe heat exchanger with counter- temperature at distance L. Q could be also calculated according to
current turbulent flow, at any possible flow rate. Note that the re-
quirement for turbulence limits the applicability of this solution to
(6)
low-viscosity Newtonian foods, such as water, milk, and juices with
viscosities of less than about 5 mPa/s. The presented solution is
or
based on application of the heat exchanger effectiveness concept
in a partial heat exchanger. An interactive Excel workbook was de-
veloped for fast prediction of temperature profiles and used in a (7)
simulated case study to demonstrate the influence of operating
conditions on the temperature profile and thermal history of a pas- where TcL and ThL are the cold stream temperature and the hot
teurized liquid product. stream temperature (correspondingly) at flow distance L.
From Eq. 2, 3, 5, and 7 we obtain
Solution derivation
The solution is divided into 2 general different cases: (1)
m ccpc m hcph and (2) m ccpc = mhcph.
Solution for m ccpc m
hcph. The Heat Exchanger Effectiveness
() is defined as the ratio between the heat transferred in the actu-
al exchanger and theoretical maximum heat transfer (that is, if the
same system were used but with an infinite length of heat ex-
changer).
(1)
(2)
E434 JOURNAL OF FOOD SCIENCEVol. 69, Nr. 9, 2004 URLs and E-mail addresses are active links at www.ift.org
Temperature profiles within a counter . . .
section area of the hot stream flow. The expression for the individ-
ual cross-section areas should correspond to the flow configuration.
For example, if the inner liquid is the cold one, the following will be
calculated:
(13)
(8)
(15)
(10)
Thi Tco = ThL TcL = Tho Tci = Tconstant. (16)
and .
(18)
Finally, the value of TcL is calculated using Eq. 9.
If time-temperature data are required (for example, to calculate By applying the specific flow conditions to Eq. 9, the cold stream
thermal history values), the time scales should be calculated differ- temperature is calculated as
ently for each of the streams.
For the hot stream, the time is calculated by: (19)
(12) because the L direction was defined from the hot stream inlet. The
time values for the hot and the cold streams are calculated using
Eq. 12 and 15, respectively.
where velh is the hot stream velocity (assuming Plug-flow) and is
Similar solutions for other configurations, such as cocurrent flow
equal to the hot stream volumetric flow rate divided by the cross-
or plate and frame heat exchangers, are possible by accounting for
URLs and E-mail addresses are active links at www.ift.org Vol. 69, Nr. 9, 2004JOURNAL OF FOOD SCIENCE E435
Temperature profiles within a counter . . .
the appropriate expression for effectiveness, volumes, and areas. automatically in a 3rd worksheet, dividing the range into 100 data
The solution described above is not applicable if the heating medi- points.
um is condensing vapor. However, this case is much simpler to Another useful feature in our workbook is reaction rate calcula-
solve, and a good approximation can be achieved by applying a tion. Inserting the rate constant at reference temperature (kTref) and
very high cph value (> 106 J/kgK). the energy of activation (Ea) allows the workbook to integrate the
The assumptions used in the described derivation are as follows: thermal effect of the specific process on a specific reaction using
(1) Turbulent flow in both streams. Thus we can assume perfect the following equation:
mixing (that is, plug flow, and there are no temperature profiles in
the radial axis of each fluid cross section). (2) The whole system is
in steady state. (3) Physical properties remain constant throughout
the whole process. For example, if important viscosity changes were (20)
taking place due to temperature change, it would affect the U value
along the flow. If the relation of U to temperature is known (a math-
ematical correlation), it could be applied in Eq. 10; then the param- where N and N0 are the respective outlet and inlet concentrations
eter G in Eq. 11 is not to be considered constant. of the ingredient or microbe of interest. tj is the time difference of
2 consecutive data points at increment j. n is the number of incre-
Excel workbook general description ments (in our workbook n = 99). R is the universal gas constant. Tref
We used an Excel workbook as a framework to execute fast sim- is the reference temperature and Tav,j is the average of 2 consecutive
ulations of any double-pipe heat exchanger in countercurrent tur- temperature points at increment j (absolute temperatures).
bulent flow. The Excel workbook can be obtained online at http:// The latter equation assumes that the reaction of interest obeys
fscn.che.umn.edu/Ted_Labuza/tpl-Research.html (Scroll down to the Arrhenius relation and follows apparent 1st-order kinetics.
sub-category F). Nevertheless, the obtained value could be used for different reac-
Our workbook can be used in 2 modes: (1) Existing System: To tion orders, by accounting for the appropriate units. For example,
calculate and plot the temperature profiles of an existing configura- the right side of Eq. 20 will be equal to N N0 for a zero-order reac-
tion, when the inlet temperatures and 1 outlet temperature are tion or 1/N0 1/N for a 2nd-order reaction. The same calculation can
be used for a formation reaction by replacing N with N0.
E: Food Engineering & Physical Properties
known. (2) New System Design: To calculate and plot the tempera-
ture profiles of a new configuration, or when only inlet temperatures Alternatively, the rate of a 1st-order reaction can be evaluated
are known. This feature is a very powerful utility for optimization of using D and z kinetic values by applying the equation:
the effectiveness and efficiency of the heat exchanger and optimiza-
tion of reaction kinetics of interest taking place in the exchanger.
The main reason for using 2 different calculation modes was that (21)
in the 1st mode the actual U value is calculated from the inlet and
outlet temperatures, while in the 2nd one, an estimated U value
should be given (for example, using experimental correlations) to where DTref is the heating time at constant reference temperature
calculate outlet temperatures. that is required to decrease the concentration by 1 order of magni-
The raw data for the equipment and fluids are inserted in the tude, and z is the temperature increase required to decrease D by
1st worksheet, and the mode of calculation is chosen by clicking on 1 order of magnitude, assuming a logarithmic relationship.
the corresponding button (Figure 3). In a different worksheet, in-
termediate parameters are calculated, and finally columns of tem- Materials and Methods
perature versus flow distance and time from inlet are produced
The experimental system for validation
Validation of temperature profile simulations using the derived
equation and our Excel workbook was realized using water flowing
E436 JOURNAL OF FOOD SCIENCEVol. 69, Nr. 9, 2004 URLs and E-mail addresses are active links at www.ift.org
Temperature profiles within a counter . . .
Table 1Flow conditions applied for temperature profile simulations and validations
Run no. 1 2 3 4 5 6 7 8 9
Inner pipe V (L/min) 11.4 3.8 20.1 20.1 11.4 20.1 3.8 20.1 3.8
Inlet temperature (C) 64.5 64.7 63.6 65.1 64.6 65.6 65.3 13.5 16.9
Outer pipe V (L/min) 11.4 11.4 11.4 3.8 3.8 11.4 20.1 3.8 20.1
Inlet temperature (C) 14.5 14.4 14.6 16.9 17.0 13.7 13.7 63.0 64.8
on both sides of the system, described in Figure 3. Type-T thermo- the measured temperatures were expected to be found on 2 paral-
couples were localized at inlet, outlet, 1/3 length, and 2/3 length of lel linear curves.
each pipe, in the center of flow cross-section. Data acquisition was
performed using an OMB-DAQ-56 module (Omega, Stamford, Evaluating U values for simulation
Conn., U.S.A.) connected to a computer with Personal DaqView 1.9 Outlet temperatures were measured with equal flow rates on
software (Omega). For every run, temperature data were acquired both liquids, namely: 3.4, 6.4, 11.2, 15.5, and 18.9 L/min, with hot
during 2 min at 5-s intervals, and the average temperature was liquid in the inner pipe entering at about 60 C and cold liquid in
used (maximum standard deviation was less than 0.1 C). Pipe di- the outer pipe at about 14 C. U in values were calculated by the
mensions and average physical property values that were used are developed Excel workbook using the equation:
presented in Figure 4. The physical properties represent average
values for liquid saturated water (Incropera and De-Witt 1985) (22)
within an approximated range of temperatures (285 to 310 K for the
cold stream and 310 to 335 K for the hot stream). Flow rates were
The individual convective heat transfer coefficient at the inner
measured in triplicate by weighing the amount of water filling a
surface (hin) of the heat exchanging pipe (the inner pipe) was cal-
bucket during 60 s.
culated by the experimental correlation known as Dittus-Boelter
(24)
where Ain is the internal heat transfer surface area, and Aout is the
external heat transfer surface area of the inner pipe.
The individual hout values were then used to derive a specific
correlation versus flow rate. This correlation and Eq. 23 were used
to approximate the expected h values in simulated temperature
profiles with the flow rates presented in Table 1 (only runs 1 to 7,
where the hot stream was in the inner pipe). Finally, Uin values
were calculated using Eq. 24.
URLs and E-mail addresses are active links at www.ift.org Vol. 69, Nr. 9, 2004JOURNAL OF FOOD SCIENCE E437
Temperature profiles within a counter . . .
that the intermediate temperature data points (that is, in 1/3 and Results and Discussion
2/3 length) fall on the plotted lines. The experimental Uin value is
determined by the Excel workbook using the relation (Incropera
and De-Witt 1985):
F igure 5 presents the internal and external convective heat trans-
fer coefficients that were calculated and correlated to flow rate
and used for temperature profile prediction in the New System De-
sign mode.
The temperature values measured by the experimental system
inside the heat exchanger pipes were very closely predicted by the
present solution using the Excel spreadsheet. This was true,
whether the heating medium flows in the inner or outer pipe and
whether its flow rate is higher or lower than that of the cold stream
(25) (Figure 6).
Simulation of the temperature profile using the inlet tempera-
tures and approximated values of the overall heat transfer coef-
from which the 2nd outlet temperature is calculated by comparing ficient also was very satisfactory (Figure 7), although a slight di-
the right and the middle parts of the equation, and then Uin is de- gression from predicted values was found at the highest ratio of
rived from the comparison of the left part to 1 of the other 2. cold to hot stream flow rate, where the largest temperature chang-
In addition, temperature profiles for the conditions of runs 1 to es took place. This minor discordance is most likely the conse-
7 were simulated in the New System Design mode. In the latter, quence of temperature dependence of physical properties, which
only inlet temperatures were given and Uin was approximated as was neglected in the prediction of heat transfer coefficients. Of
described above. Thus, in this case the outlet temperatures are also major importance is the effect of temperature on the viscosity,
to be compared. which changes up to 3 fold within the applied range of tempera-
tures.
Simulation of a final heating stage for pasteurization Although the come-up time in the heat exchanger is usually
The programmed Excel workbook was used to evaluate the influ- not considered when a pasteurization process is designed, it is dem-
ence of the heating fluid flow-rate and temperature on the death of onstrated in Figure 8 that the heating stage, prior to holding, can
Listeria monocytogenes at the final heating stage for pasteurization cause a remarkable thermal effect, which is highly influenced by
E: Food Engineering & Physical Properties
of a beverage (from 64 C to 72 C), assuming physical properties the heating medium conditions.
similar to those of water. The simulation was run for a 10-m long In the simulated conditions, the concentration of L. monocyto-
double-pipe heat exchanger with identical diameters as the one genes within the heat exchanger decreased by 4 to 9 orders of mag-
used in the validation. The heating fluid flow rate was in the range nitude (Figure 8) by applying a hot liquid flow rate in the range of
of 3 to 20.5 L/min (the validated range) and the inlet temperature 3 to 20.5 L/min, correspondingly, although the inlet and outlet
was adjusted to obtain a product (cold liquid) outlet temperature product temperatures were kept constant by adjusting the hot
of 72 C. The Uin values were approximated using the same corre- liquid inlet temperature. Approximating the temperature profile
lations described previously. Thermal death of L. monocytogenes of the product stream to a linear (straight) curve connecting the
was assumed to obey 1st-order kinetics and the Arrhenius relation. inlet and outlet temperatures would have resulted in 2107 re-
The applied energy of activation (Ea = 386 kJ/mol) and rate constant
at 63.3 C (k63.3 = 0.12/s; average value) were reported in literature
for L. monocytogenes death in milk processing (ICMSF 1996).
E438 JOURNAL OF FOOD SCIENCEVol. 69, Nr. 9, 2004 URLs and E-mail addresses are active links at www.ift.org
Temperature profiles within a counter . . .
duction from initial concentration (Figure 8, dashed line). Thus, temperatures (Figure 8, T hi). In certain delicate products, it may
the simulation of temperature profiles indicate that a remarkable result in increased fouling formation or even sedimentation of
difference in product quality can be obtained by only changing charred or denatured particles into the product. Moreover, Figure
the heating medium conditions. However, if minimizing the ther- 8 implies that taking the heat stage contribution to thermal histo-
mal effect in the heat exchanger is desired, doing that by reduc- ry into consideration by assuming a linear profile can sometimes
ing the hot liquid flow rate may require a much better control of be a safety hazard.
the operating conditions (flow rates and inlet temperatures), be- The thermal history of a heated product, within the heat ex-
cause the temperature profile close to the product outlet is much changer, is becoming less negligible as we decrease the product flow
steeper (Figure 8, [dTc/dL]LT). Therefore, in such conditions, the rate and increase the heating medium flow rate. For example, sim-
cold outlet temperature (which determines the temperature in ulation with 3 L/min and 20 L/min for the cold and hot stream flow
the holding tube) is more influenced by changes in operating con- rates, respectively, in the original length heat exchanger (3.78 m)
ditions. Another concern is that reducing the hot liquid flow rate, and the same cold inlet and outlet temperatures (64 C to 72 C),
while aiming for the same outlet product temperature, requires reduced the concentration of L. monocytogenes by 21012. When
higher hot liquid inlet temperatures, thus creating higher surface applying 20 L/min and 3 L/min for the cold and hot stream flow
rates, respectively, the bacteria concentration was reduced by only
101. This dramatic change in death rate is the result of the combi-
nation of a longer residence time and the curve form of the product
temperature profile (convex versus concave). Although a reduction
of the product flow rate requires a reduction of the holding tube
anyway (lower velocity in the holding tube), the latter comparison
implies that the holding tube length can be reduced much further,
when taking the temperature profile into consideration appropri-
ately.
Conclusions
URLs and E-mail addresses are active links at www.ift.org Vol. 69, Nr. 9, 2004JOURNAL OF FOOD SCIENCE E439
Temperature profiles within a counter . . .
E440 JOURNAL OF FOOD SCIENCEVol. 69, Nr. 9, 2004 URLs and E-mail addresses are active links at www.ift.org