Well I try to explain what you need to mail a smartform.

Here is a part of the function call:

data: g_mail_rec_obj type SWOTOBJID,

g_mail_sen_obj type SWOTOBJID,
g_mail_app_obj type SWOTOBJID,
folder TYPE SWC_OBJECT,
BEGIN OF SOFMFOL_KEY,
FOLDERTYPE LIKE SOFM-FOLTP,
FOLDERYEAR LIKE SOFM-FOLYR,
FOLDERNUMBER LIKE SOFM-FOLNO,
TYPE LIKE SOFM-DOCTP,
YEAR LIKE SOFM-DOCYR,
NUMBER LIKE SOFM-DOCNO,
FORWARDER LIKE SOUB-USRNAM,
END OF SOFMFOL_KEY,
bor_key LIKE SWOTOBJID-OBJKEY.

g_cont_par-device = 'MAIL'.

* Get BOR-Objects for Recipient, Sender und Applikation

PERFORM mail_recipient_object CHANGING g_mail_rec_obj.
PERFORM mail_sender_object CHANGING g_mail_sen_obj.
PERFORM mail_appl_object CHANGING g_mail_app_obj.

* Calling Smartform
CALL FUNCTION fm_name
EXPORTING
* ARCHIVE_INDEX =
* ARCHIVE_INDEX_TAB =
* ARCHIVE_PARAMETERS =
control_parameters = g_cont_par
mail_appl_obj = g_mail_app_obj
mail_recipient = g_mail_rec_obj
mail_sender = g_mail_sen_obj
output_options = g_output
user_settings = ' '
IMPORTING
... rest of function ...

COMMIT WORK.

Here are the Forms:

*&---------------------------------------------------------------------*
*& Form mail_recipient_object
*&---------------------------------------------------------------------*
* text
*----------------------------------------------------------------------*
* <--P_G_MAIL_REC_OBJ text
*----------------------------------------------------------------------*
FORM mail_recipient_object CHANGING p_mail_rec_obj.
CALL FUNCTION 'CREATE_RECIPIENT_OBJ_PPF'
EXPORTING
* IP_COUNTRY =
* IP_FAXNO =
ip_mailaddr = g_mail "g_mail type
" SO_NAME.
ip_type_id = g_rectype " 'U'
IMPORTING
ep_recipient_id = p_mail_rec_obj
* EP_ADDRESS =
* ET_RECIPIENT =
EXCEPTIONS
invalid_recipient = 1
OTHERS = 2.

IF sy-subrc <> 0.
MESSAGE ID sy-msgid TYPE sy-msgty NUMBER sy-msgno
WITH sy-msgv1 sy-msgv2 sy-msgv3 sy-msgv4.
ENDIF.

ENDFORM. " mail_recipient_object

*&---------------------------------------------------------------------*
*& Form mail_sender_object
*&---------------------------------------------------------------------*
* text
*----------------------------------------------------------------------*
* <--P_G_MAIL_SEN_OBJ text
*----------------------------------------------------------------------*
FORM mail_sender_object CHANGING p_mail_sen_obj.

CALL FUNCTION 'CREATE_SENDER_OBJECT_PPF'

EXPORTING
ip_sender = sy-uname
IMPORTING
ep_sender_id = p_mail_sen_obj
EXCEPTIONS
invalid_sender = 1
OTHERS = 2.

IF sy-subrc <> 0.
MESSAGE ID sy-msgid TYPE sy-msgty NUMBER sy-msgno
WITH sy-msgv1 sy-msgv2 sy-msgv3 sy-msgv4.
ENDIF.

ENDFORM. " mail_sender_object

*&---------------------------------------------------------------------*
*& Form mail_appl_object
*&---------------------------------------------------------------------*
* text
*----------------------------------------------------------------------*
* <--P_G_MAIL_APP_OBJ text
*----------------------------------------------------------------------*
FORM mail_appl_object CHANGING p_mail_app_obj.

SELECT * FROM soud WHERE sapnam LIKE sy-uname AND deleted = ' '.
ENDSELECT.

IF sy-subrc NE 0.

CALL FUNCTION 'SO_USER_AUTOMATIC_INSERT'

EXPORTING
sapname = sy-uname
EXCEPTIONS
no_insert = 1
sap_name_exist = 2
x_error = 3
OTHERS = 4.
IF sy-subrc NE 0.
CLEAR soud.
ELSE.
SELECT * FROM soud WHERE sapnam LIKE sy-uname AND deleted = ' '.
ENDSELECT.
ENDIF.
ENDIF.

CLEAR sofmfol_key.
sofmfol_key-type = 'FOL'.
sofmfol_key-year = soud-inbyr.
sofmfol_key-number = soud-inbno.
bor_key = sofmfol_key.
IF NOT bor_key IS INITIAL.
swc_create_object folder 'SOFMFOL' bor_key.
IF sy-subrc = 0.
swc_object_to_persistent folder p_mail_app_obj.
IF sy-subrc NE 0.
CLEAR p_mail_app_obj.
ENDIF.
ENDIF.
ELSE.
CLEAR p_mail_app_obj.
ENDIF.

ENDFORM. " mail_appl_object

Please also search for "email" in this forum concerning the connection from SAP to a mailsystem.
If everything works you can check the mailtraffic in TA SOST.
Hope this helps you a bit further