OPERATING MANUAL

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PLANT NAME: CDU II
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FEED AND PRODUCT CHARACTERISTICS

FEED AND PRODUCT CHARACTERISTICS

4.1 FEED SPECIFICATIONS AND INLET BATTERY LIMIT CONDITIONS

4.1.1 Feed Characteristics:

The Crude Distillation Column has been designed to process 3 MMTPA of Basrah crude for
both Kerosene (SKO) and Aviation Turbine Fuel (ATF) operations. Modifications, under the
BH Conversion Project, have been done in the plant to process 3 MMTPA of Bombay High
crude also.

Property Basrah Bombay high

SP.GR 0.848 0.8284
API @ 16 C 35.4 39.2
RVP@38 0C psi 5.8 5.5
Pour point , 0C -15 +30
Wax Content % Wt 6.0 14.7
Total Sulfur % Wt 1.9 0.15
Salt content (ptb) 3.0 5.0
Viscosity 9.0 cst @ 20C 2.876 KV @ 40 C
5.9 cst @ 37.8C 2.404 KV @ 50 C
Asphaltenes (wt %) 1.0 0.05
Total light ends (wt%) 5.02 2.62

4.1.2 Feed at battery limit Conditions:

Feed Stocks Pressure Temperature Source

Crude oil 1.0 Kg/cm2 Ambient (300C) Storage tank

4.1.3 TBP Distillation:

Temperature, C Basrah (wt%) BH (wt%)

IBP-150 19.0 24.5
150-250 16.7 19.6
250-370 19.8 23.2
370 Plus 45.5 32.7
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PLANT NAME: CDU II
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FEED AND PRODUCT CHARACTERISTICS

4.1.4 Metal content weight ppm:

Metal Basrah Bombay high

Vanadium 18.0 4.24
Iron 1.0 7.14
Nickel 5.4 6.2
Sodium - -

4.2 PRODUCT SPECIFICATIONS AND OUTLET BATTERY LIMIT CONDITIONS:

4.2.1 Products TBP at ranges for crude and vacuum unit are as follows:

Product PG Case (0C) BH Case (0C)

Overheads IBP-130 IBP-110
Heavy Naphtha 130-160 110-140
ATF/KERO 160-230/160-270 140-240 /140-270
Diesel 230-380/270-380 240-380/270-380
LVGO 380-400 IBP-410
HVGO 400-530 400-510
Slop 530-550 510-550
Short Residue (VR) 550+ 550+

4.2.2 Liquefied Petroleum Gas (LPG) (As per IS-4576 standards)

Property Basrah Bombay High

Yield tones/annum 68075 62100
Sp. Gravity at 15/4 C 0.554 0.549
Vapor Pressure at 65 0C 16.87 Kg\Cm2 16.88
Sulphur wt% <0.003 -
H2S Wt% 0.45* -
Dryness no free entrained water no free entrained water
Volatility: evaporation 2 2
Weathering 95% Vaporization by volume 95% Vaporization by volume
at 760 mm HG pressure at 760 mm HG pressure
* LPG for further treatment.
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Chapter No: 4
PLANT NAME: CDU II
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FEED AND PRODUCT CHARACTERISTICS

4.2.3 Stabilized Naphtha (SRN):

Property Basrah Bombay High

Rate tones/annum 401423 356950
Pour point C 0.69 -
Sulfur mercaptans, PPM 10 27
Sp.Gravity@400C NA 0.726
RVP (max) Psi 10 7.0
E.O.N clear 53.4
Paraffins vol % 77.8 60.9
Naphthenes, vol % 16.9 29.2
Aromatics, vol % 5.3 9.9
ASTM-distillation Temperature
IBP - 49
10% 51.5 70
30% 65.5 83
50% 84 94
70 % 96 105
90% 111.5 120
FBP 118 138

4.2.4 Heavy Naphtha (HN) Product:

Property Basrah Bombay High

Rate tones/annum 153000 192600
Sp.Gravity@150C 0.7723 0.747
ASTM D-86(Vol. %) Temperature 0C
IBP 118 126
10% 136 138
30% 141 143
50% 144 149
70% 148 153
90% 156 161
FBP 177 177
Viscosity 20C CST NA NA
Sulfur wt% 0.016 48 ppm
Paraffins vol % 65.8 52.7
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FEED AND PRODUCT CHARACTERISTICS

Naphthenes, vol % 19.5 30.0

Aromatics, vol % 14.7 17.2
Flash point C 20 20

4.2.5 Kerosene Product:

Property Basrah Bombay high

Flash point 0C 45 48
Smoke point mm. 25
Rate tones/annum 549600 770400
Sp.Gravity@150C 0.8104 0.803
Sulfur Wt % 0.158 0.25
Viscosity Cst @ 20 C 2.2 1.32
Viscosity Cst @37.8 C 1.5 1.30
Diesel index 68.7 33
ASTM D-86(VOL %) Temperature 0C
IBP 148 143
10% 175 177
30% 192.2 195
50% 206 208
70% 221 222
90% 251 241
FBP 291.9 260

4.2.6 ATF product:

Property Basrah Bombay high

Flash point 0C 43
Smoke point mm. 25
Rate tones/annum 350700 578400
Sp.Gravity@150C 0.7886 0.791
Sulfur Wt % 0.098 0.013
Viscosity Cst @ 20 C 1.6 0.93
Viscosity Cst @37.8 C 1.2 0.95
Freezing point, C -50 -47
Diesel index 71
ASTM D-86(VOL %) Temperature 0C
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IBP 150 110

10% 170 149
30% 182 161
50% 190 171
70% 199 183
90% 218 202
FBP 249.6 240

4.2.7 Diesel (DSL):

Property Basrah Bombay high

Flash point 0C 115
Smoke point mm. NA
Rate tones/annum 539099 639000
Sp.Gravity@150C 0.8527 0.855
Sulfur Wt % 1.6 0.129
Viscosity Cst 8.7
Viscosity Cst @37.8 0C 5.2
N2 NA 52 mg/l
ASTM D-86(VOL %) Temperature 0C
IBP 236.9 241
10% 272 269
30% 293 284
50% 307 300
70% 323 322
90% <366 366

4.2.8 Diesel (DSL): (during ATF regulation)

Property Basrah Bombay high

Flash point 0C 94
Smoke point mm. NA
Rate tones/annum 737999 831000
Sp.Gravity@150C 0.8525 0.852
Sulfur Wt % 1.32 0.129
Viscosity Cst @ 20 C NA 3.74
Viscosity Cst @37.8 0C 4.0 3.2
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ASTM D-86(VOL %) Temperature 0C

IBP 213.5 175
10% 246 224
30% 270.5 246
50% 289.5 264
70% 311.5 289
90% <366 348

4.2.9 Light Vacuum Gas Oil (LVGO):

Property Basrah Bombay high

Flash point 0C 79
Rate tones/yr 93309 125830
Sp.Gravity@150C 0.891 0.861
Sulfur Wt % 2.45 0.174
Viscosity Cst @ 20 C 34 17.3
Viscosity Cst @ 37.8 C 16 12.5

Metal Content NA
96% distillate 400 467

4.2.10 FCCU FEED : (LVGO + HVGO)

Property Basrah Bombay high

Pour point 0C +48 +30
Sulfur Wt % 3.5 0.19
Rate Kg/hr 50980
Sp.Gravity@150C 0.933 0.90
Viscosity Cp 1.12@2460C NA
0.77@314.20C NA
Metal Content NA
ASTM D-86 (VOL %) Temperature 0C
5% 410.1 379
10% 422.0 395
30% 444.7 425
50% 462.0 442
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70% 480.0 467

90% 511.4 512
95% 529.2 538

4.2.12 Slop Distillate:

Property Basrah Bombay high

Flash point 0C NA
Pour point 0C +55 +34
Rate Kg/hr 4831 9950
Sp.Gravity@150C 0.961 0.93
Sulfur Wt % 6.0 0.35
Viscosity Cp 0.9@378.70C NA
Metal Content NA
ASTM D-86(VOL %) Temperature 0C
5% 469.1 425
10% 486.7 448
30% 511.3 505
50% 525.3 549
70% 546.4 -
90% 573.8 -
95% 599.0 -

4.2.13 Vacuum Residue (VR/SR):

Property Basrah Bombay high

Pour point 0C +60 NA
Rate Kg/hr 91931
Sp.Gravity@150C 10.56 0.99
Sulfur Wt % 5.50 0.68
Viscosity Cp 3.0@3820C NA
37.2@2200C NA
Metal Content NA
ASTM D-86(VOL %) Temperature 0C
5% 513.1 464
10% 526.5 520
30% 574.8 601
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50% 616.2 641

70% 661.2 702
90% 711.5 794
95% 713.7 819

4.3 PRODUCTS BATTERY LIMIT CONDITIONS:

Products Pressure Kg/cm2 Temperature 0C Destination

Stabilizer off 8.1 35 FCCU-2/FG header
Gas
LPG 16.0 40 MEROX
Light Naphtha 5.5 40 storage tank
Heavy Naphtha 5.5 40 into Diesel
Kerosene/ATF 5.5 44 storage tank
Diesel(DSL) 5.5 44 storage tank
VGO 7.0 70/140 Storage tank/FCCU
Vacuum Residue 9.0 90/250/160 Storage
tank/BBU/VBU/FO