ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI

IIT JEE: 2015 CRASH COURSE (C-4) DATE:

TOPIC: CHEMICAL EQUILIBRIUM, IONIC EQILIBRIUM

SECTIONI (Multiple Choice Questions)

This section contains 05 multiple choice questions. Each question has 4 choices (a),
(b), (c) and (d) for its answer, out which ONLY ONE is correct.

1. If equilibrium constant for the reaction between a week acid HA and NaOH is 1010 , then what should
be the percentage of hydrolysis of a 102 M NaA solution?

(a) 104 (b) 102 (c) 103 (d) 101

2. The equilibrium constants K p1 and K p2 for the reactions X P + Q , respectively

2Y and Z
are in the ratio of 1 : 9. If degree of dissociation of X and Z be equal then the ratio of total pressure at
these equilibria is
(a) 1 : 9 (b) 1 : 36 (c) 1 : 1 (d) 1 : 3

2
3. H 2S is bubbled into 0.2 M NaCN solution which is 0.02 M in each Cd ( CN )4 and Ag ( CN )2
The H 2S produces 1109 M sulphite in the solution.
11050 M 3 ; K sp CdS =
(Given K sp Ag 2S = 7.1 1028 M 2
2
K inst Ag ( CN )2 =
11020 M 2 K inst Cd ( CN )4 =
7.8 1018 M 4 ),
Identify the correct statement.
(a) Ag 2S precipitates first from the solution
(b) CdS precipitates first from the solution
(c) None of them precipitates under the given conditions
(d) Ag 2S precipitates at a sulphide concentration of 11015 M

X 3 ( x =
X 2 + X iodine )

4.
This reaction is set up in aqueous medium. We start with 1 mol of X 2 and 0.5 mol of X in 1L
flask. After equilibrium is reached, excess of AgNO3 gave 0.25 mol of yellow ppt. equilibrium
constant is
(a) 1.33 (b) 2.66 (c) 2.00 (d) 3.00

5. An ammonia ammonium chloride buffer has a pH value of 9 with [ NH 3 ] = 0.25 . What will be the
new pH if 500 mL 0.1 M KOH is added to 200 mL buffer solution ( K b = 2 105 ) [ log 2 = 0.3]
(a) 8.4 (b) 9.6 (c) 5.6 (d) 4.4

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 SECTION-II (Multiple Choice Questions)
This section contains 3 multiple choice questions. Each question has 4 choices (a),
(b), (c) and (d) for its answer, out which ONE OR MORE is/are correct.

M O(s) + CO 2 (g) the equilibrium pressure of CO 2 at 127 C and 147 C are 0.14
M CO3 (s) o o
6.
and 0.35 bar respectively
(a) the enthylpy of the reaction is nearly + 64 kJ/mol
(b) increases in temperature decreases the yield of CO 2 gas at equilibrium
(c) it is endothermic reaction
(d) on addition of MCO3 at equilibrium, the equilibrium shifts towards right

7. A gaseous substance AB2 ( g ) converts to AB ( g ) in presence of solid A ( s ) as

AB2 ( g ) + A ( s ) 12AB ( g )
The initial pressure and equilibrium pressure are 0.7 and 0.95 bar. Now the equilibrium mixture is
expanded reversibly and isothermally till the gas pressure falls to 0.4 bar. Then what is correct?
(a) Volume per cent of AB ( g ) at final equilibrium is nearly 27%
(b) Volume per cent of AB2 ( g ) at final equilibrium is nearly 32.5%
5
(c) K p for the equilibrium is
9
(d) Ratio of equilibrium pressure of AB2 ( g ) at initial and final equilibrium is more than 2 but less
than 3.

8. A 1L solution of pH = 1 , is diluted upto 10 times. What volume of a solution with pH = 2 is to be

added in diluted solution so that pH does not change?
(a) 10 L (b) 100 L (c) 1 L (d) 25 L

SECTION III (Integer Answer Type)

This section contains 5 questions. The answer to each of the questions is a single
digit integer, ranging from 0 to 9. The correct digit below the question number in
the ORS is be bubbled.

9. PCl5 dissociates into PCl3 and Cl2 . At equilibrium pressure of 3 atm, all three gases were found to
have equal number of moles in a vessel. In another vessel, equimolar mixture of PCl5 , PCl3 and Cl2
are taken at the same temperature but at an initial pressure of 9 atm then find the partial pressure of
Cl2 (in atm) at equilibrium in second vessel.

10. Glutamic acid, H 2 N CH ( CH 2 CH 2 COOH ) COOH has pK a1 ( COOH ) = 2.2 ,

+

pK a 2 N H 3 =9.8 and pK a3 ( R group COOH ) = 4.3 .

Find the isoelectric point of glutamic acid to its nearest integer.

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11. A weak acid HA ( 50.0 mL ) was titrated against 0.1 M NaOH . The pH values when 20 mL and 40
mL base have been added are found to be 4.898 and 5.324 respectively. Calculate the pH of the
=
solution at equivalence point. (Given, =
log 8 3 0.426, log 2 0.301 , log15 = 1.176 )

12. In Mohrs method, solution of Cl is titrated against standard AgNO3 . During the titration, a small
quantity of K 2 CrO 4 solution is added as an indicator. As AgCl is less soluble than Ag 2 CrO 4 , the
added Ag + reacts first with Cl than with CrO 24 . At the equivalence point, when Cl is precipitated
quantitatively as AgCl , the slight excess of Ag + reacts with CrO 24 to given intensely red precipitate
of Ag 2 CrO 4 .50.0 mL of 0.1 MCl solution is titrated against 0.1 M standard AgNO3 . What must be
the theoretical molar concentration of CrO 24 in the solution so that Ag 2 CrO 4 will start precipitating
at the equivalence point?
Given, K sp ( AgCl )= 1010 M 2 ; K sp ( Ag 2 CrO 4 )= 4 1012 M 3
[Fill your answer by multiplying it with 102 .]

13. An NH +4 NH 3 buffer is supposed to keep the pH of the solution constant during the following
reaction within the safe limit
CH 3COOCH 3 ( aq ) + 2H 2 O ( ) CH 3COO ( aq ) + H 3O + ( aq ) + CH 3OH ( aq )
If this buffer solution had these initial conditions,
[CH3COOCH3 ]0 = 0.020 M ,
NH +4 = 0.100M
0

[ NH3 ]0 = 0.06M
What would be the difference in initial pH & final pH after the completion of reaction.
( pK b = =
of NH 3 4.74;log =
2 0.3, log 3 0.48 )

SECTION IV (Paragraph Type)

This section contains 2 multiple choice questions relating to 1 paragraph. Each
question has four choices (a), (b), (c) and (d) out of which ONLY ONE is correct.

Acetic acid tends to form dimer due to the formation of intermolecular hydrogen bonding.

The equilibrium constant for this reaction is 1.5 102 M 1 in benzene solution and 3.6 102 M 1 in
water. In benzene, monomer does not dissociate but in water, monomer dissociates simultaneously
with acid dissociation constant 2.0 105 M .

Dimer does not dissociate in benzene as well as in water.

[Given, log 2 = 0.3]

14. The molar ratio of dimer to monomer for 0.1 M acetic acid in water (neglecting the dissociation of
acetic acid in water) is equal to
(a) 250 : 1 (b) 1 : 250 (c) 9 : 2500 (d) 2500 : 9

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15. The pH of 0.1 M acetic acid solution in water, considering the simultaneous dimerisation of acid is
(a) 1 (b) 2.85 (c) 5.7 (d) 3.42

SECTION - IV (Matrix Match Type)

This section 1 Question. Each question has four statements Given in Column - I and
four statements in Column II. Any given statement in Column I can have correct
matching with one or more statement (s) given in column II.

16. Match the following

Column I Column II
(A) For the equilibrium (p) Forward shift
NH 4 I ( S) NH 3 ( g ) + HI ( g ) , if pressure is
increased at equilibrium
(B) For the equilibrium N 2 + 3H 2 2NH 3 at (q) No change
equilibrium volume is increased at equilibrium
(C) For the equilibrium (r) Backward shift
(D) For the equilibrium PCl5 PCl3 + Cl2 Cl2 is (s) Final pressure is more that
removed at equilibrium initial pressure

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 ANDHERI / BORIVALI / DADAR / CHEMBUR / THANE / MULUND/ NERUL / POWAI
TOPIC: CHEMICAL EQUILIBRIUM, IONIC EQILIBRIUM
(ANSWER KEY) C-4

1 [b] 2 [b] 3 [b] 4 [a] 5 [b] 6 [ac] 7 [bcd]

8 [abcd] 9 [2] 10 [3] 11 [9] 12 [4] 13 [0.26]

14 [c] 15 [b] 16 [ ( A ) r; ( B ) r; ( C ) q; ( D ) p,s ]

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