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Solution: Let fNi be the atomic fraction of nickel; 1 2 fNi is then the atomic fraction
of cobalt. The numbers of Bohr magnetons per cubic meter due to nickel
and to cobalt atoms are:
Ni: 14 atoms/cell2 12 magnetons/atom2 fNi / 13.544 3 10210 m2 3
5 0.1797 3 1030fNi
Co: 14 atoms/cell213 magnetons/atom2 11 2 fNi 2 / 13.544 3 10210 m2 3
5 0.2696 3 1030 11 2 fNi 2
M 5 3 10.1797 3 1030 2 fNi 1 10.2696 3 1030 2 11 2 fNi 2 4 19.27 3 10224 2
M 5 20.833 3 106fNi 1 2.499 3 106 5 2 3 106
fNi 5 0.60 fCo 5 0.40
1912 Estimate the magnetization that might be produced in an alloy containing nickel and
70 at% copper, assuming that no interaction occurs.
Solution: We can estimate the lattice parameter of the alloy from those of the pure
nickel and copper and their atomic fractions:
ao 5 10.3213.2942 1 10.72 13.61512 5 3.52
If the copper does not provide magnetic moments that influence magneti-
zation, then
14 atoms/cell2 10.3 fraction Ni2 12 magnetons/Ni atom2 19.27 3 10224 2
M5
13.52 3 10210 m2 3
M 5 0.51 3 106 A /m 5 6410 oersted