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DOI 10.1007/s11998-013-9506-2
American Coatings Association & Oil and Colour Chemists Association 2013
stabilizes the coating process and delays the onset of volume flow rate through a negative gap of a forward
ribbing instability.7,8 roll coater with deformable rolls exists to date. So, the
Coyle9 was among the first researchers to give present work aims at predicting the application weight
theoretical model for forward roll coating with deform- by analytical methods based on lubrication theory and
able rolls. He investigated a 1D elastohydrodynamic using a Hookean model for the solid. The results
model for positive gaps, i.e., no contact or intersection should contribute to the understanding of the funda-
of rolls, and negative gaps, i.e., only deformation of a mental influence factors for deformable roll coating.
rubber-like layer of the roll prevents it from intersect-
ing. For modeling the elastic behavior, the validity of
Hookes law for the solid and infinitesimal strains was Governing equations and calculation model
assumed. The resulting nonlinear ordinary differential
equation was solved by numerical methods and so, Basic equations
among others, pressure distribution and gap passing
flow rate could be predicted. Based on Coyles calcu- The aspired analytical solution for forward roll coating
lations, Carvalho and Scriven extended the analysis with deformable rolls and for negative gaps is based on
with a 1D neo-Hookean model and a 2D Hookean the well known and frequently used lubrication approx-
plain-strain model for the solid body. The fluid flow imation. Lubrication approximation is a simplification of
was in both cases modeled similar to Coyle with the NavierStokes equation for thin laminar films where
lubrication approximation. The work showed a inertia is assumed to be comparably negligible and
remarkable difference between 1D and 2D models results in a quasi 1D approach.21 Several authors used it
while the latter seemed to be more accurate to the for analytical solutions for rigid roll coating, as well as for
authors. They also stated that their theories are not numerically solved solutions for deformable roll coat-
able to calculate the coating weight on each roll as the ing.1,2,9,10 Integration of the lubrication approximation
theory does not cover film splitting.10 leads to the velocity profile in main flow direction x. It
Later, the same authors compared a spring and depends on the viscosity g of the Newtonian fluid, and
plain-strain model using the 2D NavierStokes equa- the pressure gradient p. The two apparently unknown
tions for both. The obtained results are mostly similar. integration constants C1 and C2 can be determined using
Major differences appeared only for the velocity boundary conditions for the velocities of the rolls.
distribution along the deformable roll.11 Further mod- The description of the behavior of rubber covered
ifications of the calculation procedure involve the pressure rolls is based on the contact theory of Hertz.22
consideration of viscoelastic behavior of the material.12 Parish23 presented in his research work a resulting
Unlike Carvalho and Scriven, Gostling et al. 13 used equation (1) for the nip width, i.e., length between the
a finite-strip model for the solid coupled with lubrica- beginning and the end of the deformed region, 2h0
tion theory to especially treat the case of incompress- between one hard and one elastic roller depending on
ible compliant layers. A comparison with experimental the applied load per unit length of the rollers W, the
results of Cohu and Magnin14 for the resulting film Poisson ratio m, the Youngs modulus of the elastic
thickness shows a difference of a factor of two, but it roller E, and the roll diameters D1 and D2.
was assumed that viscoelastic effects of the deformable
cover might have caused the difference.12 2WD1 D2 1 m2
2
Recently, the effect of fluid absorption during h0 : 1
pED1 D2
forward roll coating process with deformable rolls has
been studied.15
Since many of the fluids being coated show non- His calculations use plane strain theory24 and are based
Newtonian flow behavior, efforts are made to describe on the work of Thomas and Hoersch25 for homogenous
the performance of these fluids also in the case of rollers and on the calculations of Hannah26 for thin
deformable roll coating. For the description of the elastic covers. For thin rubber covers an additional
rheological behavior different models are used. Research parameter, the cover thickness b, has to be considered
work considering power-law fluids,16 Carreau and Car- in equation (1). The resulting nip width 2h is then
reauGillespie fluids,17 or fluids with elastic behavior smaller than 2h0.27
described with a Boger18 approach has been performed. For the analytical solution in the following sections
The fluid rheology also influences the occurrence of flow the use of equation (1) corrected with Hannahs theory
instabilities like ribbing.19 Today, available high speed for incompressible layers seems to be suitable as Parish23
video systems also allow a level of knowledge concerning showed within his experiments the validity of her theory
misting in deformable roll coating.20 for ratios of 2h/b approximately smaller than 3/2.
The understanding of the self-metered roll coating
and its influence factors is high and, based on analysis
of the experimental and numerical data, various Set-up of the calculation model
correlations for the influence factors of application
weight exist.911,14 Nevertheless, according to the The treated set-up for the calculation is shown in
authors, no analytical description for the resulting Fig. 1. The roll pair consists of a rigid roll with radius
J. Coat. Technol. Res.
Deformable
layer Fluid
R
Rigid
core
R1 and a deformable roll with radius R2. For the feed Fig. 2: Model of deformable roll coating used for the
system a flooded inlet with constant filling level and prediction of the volume flow rate by analytical methods
including the negative gap region with an assumed
constant ambient pressure p0 at the top of the feed
constant height hmin
pool is assumed.
The figure shows the case of a negative gap, which is
analyzed in the following sections. The case of negative
gap is given when the intersection of rolls is only Calculation procedure and result
avoided by deformation of the rubber-like material of
the deformable roll and is in contrast to deformable Starting with the lubrication approximation the two
roll coating with positive gaps, where a small initial gap integration constants are fixed setting the velocity of
is increased by deformation of the cover. The geomet- the lower roll at y = 0, to u1, and the velocity of the
rical setup is transferred into a model, which simplifies upper roll at y = h, to u2 (see also Table 1). Integrating
the geometry and hence enables the analytical predic- the velocity profile results in the volume flow per unit
tion. For the model the rollroll geometry is trans- width Q (equation (4)).
ferred in a plateroll model with equivalent radius R
Zh
following literature.2,9 The corresponding radius can be 1 @p u 2 u1
calculated following equation (2). Q h xy y2 y u1 dy: 4
2g @x h x
0
1 1 1 1
: 2
R 2 R1 R2 Depending on the region, h(x) has been substituted by
hmin in the negative gap region or with equation (2)
Also based on literature2,9 the curvature h of the roll elsewhere. As the resulting equations still contain the a
with equivalent radius is assumed to be describable as priori unknown hmin as well as the unknown pressure
the quadratic function (3). gradient further boundary conditions are necessary.
The following steps have to be performed.
x2
h x hmin : 3 (i) Equation (4) for the volume flow is valid for all
2R three different calculation regions. The results for
inflow and outflow regions only slightly differ if
Within the equation hmin is the minimal gap distance the function h(x) is substituted due to the applied
between the roll surfaces while fluid flows through the overall coordinate system, which has its origin at
gap and therefore is a priori unknown. the plate at the beginning of negative gap region
For predicting the system by analytical methods, in (see also Fig. 2). However, in both cases, the
contrast to the existing literature, a further assumption quadratic function (3) adjusted to the overall
is necessary. coordinate system is used. For the negative gap
Hence the calculation area is split into three parts: region function h(x) is assumed as a constant. The
the inflow region, the negative gap region, and the equation (4) can be solved in a general way for the
outflow region, as illustrated in Fig. 2. While in inflow still unknown pressure gradient p/x using h(x)
and outflow region, the curvature of the roll is expected (see equation (5)).
to be undeformed; in the negative gap region a
deformation resulting in the constant height hmin is @p dp 2Q u1 u2 hx
assumed. This assumption was based on the numerical 6g : 5
@x dx hx3
results of Gostling et al.13 and enables the prediction
by analytical methods. But as other anterior models8
show different behavior, the results of the analytical (ii) As the further known boundary conditions are
model have to be carefully validated. pressure ones, the indefinite integral of equation (5)
J. Coat. Technol. Res.
Table 1: Overview about used boundary conditions deformed region, which is given as the operation
during calculation procedure parameter or can be calculated (see Basic equations
section) and the radius R. The still unknown
Velocity profile Pressure profile Volume flow dimensionless minimal gap distance hmin can finally
be determined by integrating the pressure profile along
u(y = 0) = u1 p(x = R) = p0 p(x = xs) = pCa
the negative gap region. The resulting implicit form of
u(y = h(x)) = u2
the conditional equation for hmin , which is the ratio of
hmin to the radius R, is given in equation (7).
is calculated to get the pressure distribution. In p
this step three different equations are obtained, q p 3 2pL2
due to different functions h(x) in the three hmin
16L hmin 3 2phmin : 7
W
calculation areas. While for inflow and outflow
region the results only slightly differ, in the Within the equation, the variable W* is the dimen-
negative gap region the result is comparably sionless load, which is either directly measurable or
simple as the height does not vary with x. can be calculated with a given footprint following
(iii) At first the occurring integration constant in the equation (1).
inflow region is determined (see also Table 1). It
is assumed that the pressure far upstream is
equal to ambient pressure. In the presented case
the relative pressure at x = R is set to 0. This is Results and discussion
a valid assumption for a gap feed system, as
shown in Fig. 1, and is used for different feed Validation for thick rubber covers
situations in references (1), (2), (9), and (28).
(iv) Based on the obtained pressure distribution in The validity of the derived analytical relation for the
the inflow region, the integration constant in the volume flow rate of a deformable roll coater with
pressure distribution equation of the negative negative gaps was proven using experimental data of
gap region can be obtained as at the boundary of Cohu and Magnin.14 They distinguished their results in
both the pressure should be equal. With the same data for thick and thin rubber covers. For the thick
procedure also the pressure distribution in the cover with a thickness b = 25 mm the half contact
outflow region can be calculated. length h0, calculated using deflection measurements
lies between 27.7 and 5 mm.14 Following Hooke,32
Since two unknowns, the volume flow per unit width Cohu and Magnin14 expected the rubber cover to have
Q and the resulting gap height in negative gap region a little influence. This agrees also with the classification
hmin, are present in the pressure distribution, further of Carvalho,12 who specified a value of 0.1 for the ratio
boundary conditions are necessary to predict the of cover thickness and radius as border for negligible
volume flow. The often-used condition1,2,28 of Capil- influence. So for the conducted validation in the case of
lary pressure at the film splitting point is suitable to thick rubber covers, it is assumed, that the resulting
present one of the missing boundary conditions. As the length of contact 2h equals approximately the calcu-
exact prediction of film-splitting location is still under lated width 2h0 (see equation (1)).
investigation,29,30 it is assumed that the outflow region Following the data of Cohu and Magnin, for the
is negligibly small, i.e., the x-coordinate of the splitting elastic modulus and the roll radius values of 2.2 MPa
point xs is near by the end of the deformed region, and 118 mm are assumed. All experiments were
following Ascanio and Ruiz.31 performed with equal roll speed and so symmetrical
The volume flow can be obtained through equalizing film splitting between pick-up and applicator roll is
the pressure distribution at the rim of the deformed assumed. As the derived analytical equations (6) and
region with the capillary pressure. Rearranging the (7) do not include any film splitting behavior, in the
equation and introducing dimensionless footprint L present case, the resulting volume flow (see equation
and minimal height hmin the volume flow per unit width (5)) is hence halved. The validation in the case of thick
can be calculated. rubber covers is performed for parameter setups with
Equation (6) shows the result for the dimensionless different roll velocities, namely 0.17 and 0.77 m/s and
volume flow Q+, which is scaled with the flow rate of different Newtonian viscosities, 0.15 and 0.36 Pa s.
pure shear flow, with the assumption of negligible Figure 3 shows the resulting film thickness of the
surface tension, i.e., pCa 0. applicator roll depending on different loads W for
p p the experimental data of Cohu and Magnin and the
8L hmin 2 2phmin corresponding prediction by the derived analytical
Q p p hmin : 6
16L hmin 3 2phmin equations (6) and (7) using the correlation (1) for
length of contact and the appearing inaccuracies as
The dimensionless footprint L within the equation is shaded areas. The film thickness e on the applicator
the ratio of the length 2h0, respectively, 2h of the roll is calculated following equation (8).
J. Coat. Technol. Res.
20 2.5101
12
1.0101
8
5.0100
2. Savage, MD, Mathematical Models for Coating Processes. with a Deformable Roll: Application to Non-Newtonian
J. Fluid Mech., 117 443455 (1982) Industrial Formulations. Comput. Chem. Eng., 33
3. Benkreira, H, Edwards, MF, Wilkinson, WL, A Semi- 14271437 (2009)
empirical Model of the Forward Roll Coating Flow of 18. Kang, Y-T, Lee, K-Y, Liu, T-J, The Effect of Polymer
Newtonian Fluids. Chem. Eng. Sci., 36 423427 (1981) Additives on the Performance of a Two-Roll Coater.
4. Benkreira, H, Edwards, MF, Wilkinson, WL, Roll Coating J. Appl. Polym. Sci., 43 11871195 (1991)
of Purely Viscous Liquids. Chem. Eng. Sci., 36 429434 19. Lee, JH, Han, SK, Jung, HW, Hyun, JC, Ribbing Instability
(1981) in Rigid and Deformable Forward Roll Coating Flows,
5. Mmbaga, JP, Hayes, RE, Bertrand, FH, Tanguy, PA, Flow Ribbing Instability in Rigid and Deformable Forward Roll
Simulation in the Nip of a Rigid Forward Roll Coater. Int. Coating Flows. Korea-Aust. Rheol. J., 22 7580 (2010)
J. Numer. Meth. Fluids, 48 10411066 (2005) 20. Ascanio, G, Carreau, PJ, Brito-de la Fuente, E, Tamguy, PA,
6. Han, SK, Shin, DM, Park, HY, Jung, HW, Hyun, JC, Effect Forward Deformable Roll Coating at High Speed with
of Viscoelasticity on Dynamics and Stability in Roll Coat- Newtonian fluids. Trans. IChemE, Part A Chem. Eng. Res.
ings. Eur. Phys. J. Special Top., 166 107110 (2009) Des., 82 390397 (2004)
7. Szczurek, E, Dubar, M, Deltombe, R, Dubois, A, Dubar, L, 21. Durst, F, Grundlagen der StromungsmechanikEine Ein-
New Approach to the Evaluation of the Free Surface fuhrung in die Theorie der Stromungen von Fluiden. Spring-
Position in Roll Coating. J. Mater. Proc. Technol., 209 er, Berlin (2006)
31873197 (2009) 22. Hertz, H, U ber die Beruhrung fester elastischer Korper.
8. Carvalho, MS, Scriven, LE, Three-Dimensional Stability J. Reine Angew. Math., 92 156171 (1881)
Analysis of Free Surface Flows: Application to Forward 23. Parish, GJ, Measurements of Pressure Distribution Be-
Deformable Roll Coating. J. Comput. Phys., 151 534562 (1999) tween Metal and Rubber Covered Rollers. Br. J. Appl.
9. Coyle, DJ, Forward Roll Coating with Deformable Rolls: A Phys., 9 158161 (1958)
Simple One-Dimensional Elastohydrodynamic Model. 24. Parish, GJ, Apparent Slip Between Metal and Rubber-
Chem. Eng. Sci., 43 26732684 (1988) Covered Pressure Rollers. Br. J. Appl. Phys., 9 428433
10. Carvalho, MS, Scriven, LE, Effect of Deformable Roll (1958)
Cover on Roll Coating. Tappi J., 77 201208 (1994) 25. Thomas, HR, Hoersch, VA, Stresses Due to the Pressure of
11. Carvalho, MS, Scriven, LE, Flows in Forward Deformable Roll One Elastic Solid Upon Another, One Elastic Solid Upon
Coating Gasp: Comparison between Spring and Plane-Strain Another. University of Illinois, Engineering Experimental
Models of Roll Cover. J. Comput. Phys., 138 449479 (1997) Station, Bulletin no. 212, pp. 66-99 (1930)
12. Carvalho, MS, Effect of Thickness and Viscoelastic Prop- 26. Hannah, M, Contact Stress and Deformation in a Thin
erties of Roll Cover on Deformable Roll Coating Flows. Elastic Layer. Q. J. Mech. Appl. Math., 3 94105 (1950)
Chem. Eng. Sci., 58 43234333 (2003) 27. Parish, GJ, Calculation of the Behaviour of Rubber-
13. Gostling, MJ, Savage, MD, Young, AE, Gaskell, PH, A Covered Pressure Rollers. Br. J. Appl. Phys., 12 333336
Model for Deformable Roll Coating with Negative Gaps and (1961)
Incompressible Compliant Layers. J. Fluid. Mech., 489 28. Coyle, DJ, Macosko, CW, Scriven, LE, Film-Splitting Flows
155184 (2003) in Forward Roll Coating. J. Fluid Mech., 171 183207
14. Cohu, O, Magnin, A, Forward Roll Coating of Newtonian (1986)
Fluids with Deformable Rolls: An Experimental Investiga- 29. Decre, M, Gailly, E, Buchlin, JM, Meniscus Shape Exper-
tion. Chem. Eng. Sci., 52 13391347 (1997) iments in Forward Roll Coating. Phys. Fluids, 7 458467
15. Devisetti, SK, Bousfield, DW, Fluid Absorption During (1995)
Forward Roll Coating of Porous Webs. Chem. Eng. Sci., 65 30. Becerra, MZ, Oldrich, JR, Azevedo, LFA, Carvalho, MS,
35283537 (2010) Measuring the Velocity Field in Film-Splitting Flows of
16. Bohan, MFJ, Fox, IJ, Claypole, TC, Gethin, DT, Numerical Newtonian Liquids. AIChE J., 53 281289 (2007)
Modelling of Elastohydrodynamic Lubrication in Soft Con- 31. Ascanio, G, Ruiz, G, Measurement of Pressure Distribution
tacts Using Non-Newtonian Fluids. Int. J. Numer. Methods in a Deformable Nip of Counter-Rotating Rolls. Mess. Sci.
Heat Fluid Flow, 12 494511 (2002) Technol., 17 24302436 (2006)
17. Lecuyer, HA, Mmbaga, JP, Hayes, RE, Bertrand, FH, 32. Hooke, CJ, The Elastohydrodynamic Lubrication of a
Tanguy, PS, Modelling of Forward Roll Coating Flows Cylinder on an Elastomeric Layer. Wear, 111 8399 (1986)