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R,/N\/\ii/~i'~N'R,
\/\//\//
I
R~=CsHs, R~=CsHs, 1I
R,=CH~--CeHs, R4=CH2--CHz--C6H6)"
\/
The s p e c t r a of all the investigated compounds showed a band in the region 33,000-34,000 cm -1 (energy 4.20-
4.27 eV). T h i s band can be attributed to i n t r a m o l e c u l a r c h a r g e t r a n s f e r (ICT). In this e a s e the m o l a r ab-
s o r p t i o n coefficient of this band ( q C T ) in the different rhodamine d e r i v a t i v e s will depend on the ionization
potential of the e l e c t r o n - d o n o r group. Such a relationship is shown in Fig. 1. The ionization potentials
for the NH2, NHC2H5, N(C2Hs)2, and NHC6H 5 groups a r e taken f r o m the l i t e r a t u r e [2]. As Fig. 1 shows, the
r e l a t i o n s h i p between q C T and the ionization potential I is c l e a r l y l i n e a r . T h i s g r a p h could be used to de-
t e r m i n e the ionization potentials of substituents for which t h e r e a r e no published data.
The a b s o r p t i o n band in the visible region of the s p e c t r u m can be r e g a r d e d as the r e s u l t of i n t e r a c t i o n
of the i n t r a m o l e e u l a r c h a r g e - t r a n s f e r s t a t e with the state L~. In this case, as in the c a s e of c o m p l e x e s
9 I97j Consultants Bureau, a division of Plenum Publishing Corporation, 227 West 17th Street, New York,
N. Y. 10011. All rights reserved. This article cannot be reproduced for any purpose whatsoever without
permission of the publisher. A copy of this article is available from the publisher for $15.00.
798
max
'Y abs. e.tO "4
9 i0 -4
IC
ol
6 fgOOO ro
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4
f&OOO
8, 9 Io 11 I , e g ? 8 9 I0 l't I, eVI2
Fig. 1 Fig. 2
Fig. 1o Plot of elC T against ionization potential of donor group of rho-
damine d e r i v a t i v e s .
Fig. 2. P l o t s of positio n of long-wave absorption band (1) and e of
long-wave absorption band (2) against ionization potential of donor group
of rhodamine derivatives.
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O2
0.5
O 9
, , , , , , m
LITERATURE CITED
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