2008 Chemistry Times With Answer

134 SOALAN ULANGKAJI SPM 2008
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is
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2008 Chemistry Mata
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Analysis of Chemistry
( 2004 - 2007 )
JAWAPAN boleh didapati di laman web http://www.times.my
YEAR PAPER 1 PAPER 2 PAPER 3
TOPICS 04 05 06 07 04 05 06 07 04 05 06 07
Form 4
Introduction to chemistry
The structure of the atom 7 6 4 6 1 1 1 1 1 1
Chemical formulae and questions 4 6 6 6 1 1
Periodic table of elements 2 3 3 3 1 1
Chemical bonds 2 1 2 1 1 1
Electrochemistry 3 3 5 3 1 1 1 1
Acids and bases 5 4 3 4 1
Salts 1 - 2 - 1 1 1
Manufactured substances in industry 4 3 4 3 1 1 1
Form 5
Rate of reaction 4 5 4 4 1 1 1
Carbon compounds 6 7 6 7 1 1 1 1
Oxidation and reduction 6 7 4 6 1 1 1 1
Thermo chemistry 4 4 5 5 1 2 1
Chemical for consumer 2 1 2 2 1 1 1 1
SOALAN ULANGKAJI SPM 2008 135
SULIT
TIMES HIGHER EDUCATION

SOALAN ULANGKAJI SPM 2008

CHEMISTRY
Paper 1
Nov./Dis

DO NOT OPEN UNTILL INTSRUCTED TO
1. Answer all the questions
2. Think thoroughly before answering any of the questions. If you need to change your
answer, erase the answer properly and thoroughly before remarking the question sheet.
This question paper contains 7 printed pages and 0 non printed pages
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Instruction : For Question 1 to 50, each question is followed by four options, A, B, C and D. Choose one correct answer for each
question and blacken the corresponding space in your objective answer sheet.
1. Diagram 1 shows the set-up of the apparatus for electrolysis 5. Which of the following is a strong alkali ?
A Magnesium hydroxide
B Calcium hydroxide
C Aqueous ammonia
D Potassium hydroxide
6. Diagram2 shows the formation of ammonia through the

Haber process
Diagram 1 Hyrogen Nitrogen

Which of the following compounds could be used as an
electrolyte ?
A Ethanol C Naphthalene
B Kerosene D Ethanoic acid Catalyst X
Temperature Y
Pressure Z
2. Which of the following is true about acids.

A Acids react with metal to produce salt and water Ammonia
B Acids react with bases to produce salt and hydrogen gas
Diagram 2
C Acids react with metal oxide to produce salt, water, and
hydrogen gas Which of the following represent catalyst X, temperature Y
D Acids react with carbonates of metals to produce salt, and pressure Z?
water, and carbon dioxide gas.
3. Which of the following substance is a non electrolyte? Catalyst X Temperature Pressure

A Molten lead (ii) oxide Y, C Z/atm
B Aqueous silver nitrate A Vanadium(V) oxide 550 200
C Molten nanphthalene B Nickel 300 100
D Ammonia in water C Iron 200 450
D Iron 450 300
4. Glacial ethanoic acid is put into four test tubes A, B, C and
D. In which test tube does a reaction occur? 7. X Y Z
SO2 SO3 H2S2O H2SO4
The figure above represents the manufacture of sulphuric
acid by the Contact Process. What do the letters X, Y and Z
represent ?
X Y Z
A Oxygen Concentrated Water
sulfuric acid
B Oxygen concentrated Catalyst
sulphuric acid
C Oxygen Water Concentrated
sulfuric acid
Calcium
D Catalyst Oxygen Concentrated
sulfuric acid
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8. Which of the following substances can be used to 14. Which of these chemicals equation is not balanced?
compare the chemical properties of hexane and hexene? I 2Pb3O4 6PbO + O2
I Lime water II Mg + Fe2O3 MgO + 2Fe
II Liquid Bromine III H2 + S H2S
III Dilute sulphuric acid IV H2SO4 + NaHCO3 Na2SO4 + H2O + CO2
IV Acidified potassium manganate (VII)
A IV only C II and IV only
A I and III only C II, III and IV only B I and III only D I, II, III and IV
B II and IV only D I, II, III and IV 15. 10.4g of a sample of chloride of metal M contains 6.85g
of metal M. Determine the formula of the metal M chloride.
9. Ethanol undergoes complete combustion when it burns in
(Relative atomic mass : m,137;cl,35.5

excess air to produce
A Water and carbon dioxide gas
Which of these following statement is true?
B Water, carbon and carbon dioxide gas
A MCl
C Water, carbon monoxide gas and carbon dioxide gas
B MCl2
D Water, carbon, carbon monoxide gas and carbon dioxide
C M2Cl
gas
D M2Cl3
10. Diagram 3 shows the change of the state of matter
16. Which of the following correctly matches the type of glass
and its composition ?
Glass Main composition

Diagram 3
I Lead glass Lead(II) oxide
II Borosilicate glass Boron oxide
Which of the following is process Y?
III Fused glass Sodium oxide
A Sublimation C Freezing
IV Soda-lime glass Aluminium oxide
B Boiling D Condensation
11. Which of the following has the same number of molecules A I and II only C II and IV only
as 80 g of magnesium oxide? B I, II and III only D II, III and IV only
A 44 g carbon dioxide gas
B 4 g hydrogen gas 17. Soap is produced in the saporification reaction by
C 6 g helium gas
D 58.5 g sodium chloride A heating carboxylic acid with ethanol
B heating ethanol with acidic potassium dichromate(VI)
12. Which of the following contains 6.02 x 1023 molecules? C heating animal oil with sodium hydroxide solution
[Relative atomic mass : H,1; N, 14; O, 16, Avogadro D heating palm oil with hydrochloric acid
constant: 6.02 x 1023]
I 1.5 g of hydrogen gas 18. Diagram 4 shows the atomic symbol of element X.
II 1.8 g of water
III 32 g of oxygen gas 7
IV 17 g of ammonia gas X
3
A I and II only C II, III and IV only
B III and IV only D I, II, III and IV Duagram 4
13. What is the meaning of heat of reaction? Which of the following is true about the sub-atomic
A The change in the energy needed to break the chemical particles of element X?
bond
Proton Number of Number of
B The change in the energy contained in the products and
Number Neutron electron
in the reactants
C The energy needed to start a reaction A 7 7 10
D The energy involved when the change of state of the B 7 7 7
matter happens C 3 4 3
D 3 4 2
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19. Chlorine and bromine are in the same Group in the Periodic 23.
Table because 30kJ
V+W
A their physical properties are the same
150kJ
B Both of them are gases at room temperature
C Both of them have 7 valence electrons
D Both of them dissolve in water at the same rate
20. Diagram 5 shows three different alkali metals burning at X+Y
different rates in bromine gas.
Diagram 7

Bromine vapour Diagram 7 shows energy level of reaction which is
represented by
Gas jar spoon
Gas jar cover V + W X + Y H = P kJ mol-1
Gas jar
R - Reddish
S - Bright Yellowish R S T Calculate the value of the heat of reaction
T - Very bright purplish Diagram 5
By observing the brightness and colour of the flames, which A + 120 kJ mol-1 C - 120 kJ mol-1
metals are present in gas jars R, S and T respectively? B + 150 kJ mol-1 D -150 kJ mol-1
R S T 24. When excess zinc powder is put into 50 cm3 1.0 mol dm-3
copper (II) sulphate solution, the temperature of the mixture
A Potassium Lithium Sodium rises by T C. What is the displacement heat for one mole
B Sodium Potassium Lithium copper displaced ? [ Relative formula mass: CuS04 , 160;
C Lithium Sodium Potassium Specific heat capacity of solution, c: 4.2 J g -1 oC -1 ]
D Sodium Potassium Lithium A 50 x T x 4.2
kJ mol-1
1000
21. The sub-atomic particles that are present in an atom are
I electron III neutron B 50 x T x 4.2 x 160
II proton IV nucleon kJ mol-1
0.5 x 1000
A 1, II and IV only B 1, II and III only C 50 x T x 4.2 x 1

C I, III and IV only D I, II, III and IV kJ mol-1
0.05 x 1000
22. Diagram 6 shows a simple voltaic cell. P and Q are D 50 x T x 4.2 x 0.05
kJ mol
-1
electrodes of the an hour for the reaction to occur 1000
V
Za Voltmeter
Cu 25. Below is the half-equation of a reaction.
P Q
Cu2+ + 2e Cu
What is meant by reduction reaction based on the equation ?
A Electrons are received by copper
B Electrons are donated by copper
C Electrons are received by copper (II) ions
Copper (II)
Zinc sulphate solution D Electrons are donated by copper (II) ions
sulphate solution
Diagram 6
26. Which of the following cannot be prepared by double
Which of the following is/are true about the cell? decomposition method?
I Porous pot is used to capture electrons I Silver bromide
II Electrode Q becomes thicker II Calcium carbonate
III Electrons flow from Q to P III Lead(II) nitrate
IV Oxidation process occurs at P IV Lead(II) chloride
A I and IV only C II and III only

B II and IV only D I, II and IV only
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26. Which of the following cannot be prepared by double Which of the following set is suitable to make the process
decomposition method? work?
I Silver bromide Anode Cathode Electrolyte
II Calcium carbonate
A Impure copper Pure copper Dilute hydrochloric
III Lead(II) nitrate
acid
IV Lead(II) chloride
B Impure copper Pure copper Copper (II) Chloride
27. Sodium hydroxide solution is added in excess to a solution solution
containing lead ion, magnesium ion, iron(II)ion and C Impure copper Carbon Dilute hydrochloric
aluminium ion in four separate test tubes and shaken. Which acid
of the following is the correct observation? D Impure copper Carbon Copper (II) Chloride

Catalyst X Observation solution
A Aluminium White precipitate. Does not 30. The following represents the structural formula of a carbon
dilute in excess NaOH compound
B Magnesium White precipitate. Does not 0
dilute in excess NaOH ||
C Lead White precipitate. Does not CH3 C 0 CH2 CH2 CH3
dilute in excess NaOH
The compound is produced by the reaction between
D Iron (II) Brown precipitate. Does not A ethanol and propanoic acid
dilute in excess NaOH B ethanol and butanoic acid
C propanol and ethanoic acid
28. Diagram 8 shows the electron arrangement of a compound
D butanol and ethanoic acid
formed between atoms P and Q .
31.
2+ 2-
P Q Diagram 10
Diagram 8 Based on diagram 10, what is observation after 10
Which of the following statements is true about the minutes?
compound?
A Gas bubbles are released
A There is a strong intermolecular force between particles B Grey precipitate is formed
P and Q C Blue colour solution turns colourless
B The compound is formed by sharing the electrons D The concentration of copper ion decreases
C The compound conducts electricity in molten state
32. The tables shows the heat of combustion of three alcohols.
D It is a covalent compound
29. Diagram 9 shows the set-up of the apparatus used to purify Alcohol Heat of combustion/kJ mol-1
impure copper Stripe. CH3OH -710
C2H5OH -1370
A C4H9OH -2670
+
Which of the following factors increases the heat of

combustion of alcohols?
Diagram 9 A Size of molecules decreases

B Number of carbon atoms per molecule increases
C Number of oxygen atoms per molecule increases
D Number of hydrogen atoms per molecule decreases
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33. Which of the following compounds is an isomer of 39. When sodium metal is left exposed to the air, the grey metal
heptane? turns white. What inference can be made from this
A 2-methyl pentane C 2,3-dimethyl pentane observation?
B 2-methyl heptane D 3,3-dimethye hexane A Sodium does not rust
34. Protein is a polymer that is made up of many units of B Sodium undergoes oxidation by receiving electrons
A glycerols C amino acids C Sodium resistant to corrosion
B fatty acids D monosaccharides D Sodium corrodes and gets tarnished
40. Diaram 12 shows the change of ethanol through step I, II
and III. Step III
35. Diagram 11 shows information about two types of particle. C2H4 C2H6
_______________________________________________
Particle Proton Electron Step II

Step I
Number configuration C2H5OH CH3COOH
_______________________________________________ Diagram 12
X 9 2.8
Which of the following processes are applicable for step I,
Y 17 2.8.8
II and III?
_______________________________________________
R S T
Diagram 11 A Oxidation Dehydration Hydrogenation
B Reduction Hydration Hydrogenation
Based on the information in the table, both particles X and
Y are C Esterification Dehydration Hydration
A inert gases D Dehydration Oxidation Reduction
B negative ions 41. The following chemical equation shows the reaction
C atoms of metals between stearate ions, CH3(CH2)16COO- and alkyl sulphate
D isotopes of the same element ions, ROSO3- with calcium ions, Ca2+ in hard water. R
36. Which of the following are uses of an alloy? represents the hydrocarbon long chain.
I To make ornaments
II To produce superconductors 2CH3( CH2 )16COO ( aq ) + Ca ( aq )
- 2+
III To build the bodies of aircrafts
A I and II only C II and III only [ CH3( CH2 )16COO]2Ca( s )

B I and III only D I, II and III
ROSO3 Na (aq) + Ca (aq)
- + 2+
37. What is the number of molecules in 12 dm-3 of oxygen gas,

O2 ? [1 mole of gas occupies 24 dm-3 at room temperature ( ROSO3 )2 Ca ( aq ) + 2Na ( aq )
- 2+ 2+
and pressure; Avogadro constant 6.0 x 10 particles]

23
A 1.5 x 10 molecules
22
What is the effect of the addition of calcium ion on the
B 1.5 x 10 molecules
23
concentration of stearate ion or alkyl sulphate ion?
C 3 x 10 molecules
23
A The concentration of stearate ion increases
D 3x 1022 molecules B The concentration of stearate ion decreases
C The concentration of alkyl sulphate ion increases
38. The equation shows the reaction between sulphuric acid and
D The concentration of alkyl sulphate ion decreases
sodium hydroxide.
H2SO4 + 2NaOH Na2SO4 + 2H2O 42. Diagram 13 shows the set up of the apparatus to plate an
What is the volume of 1.0 mol dm-3 sodium hydroxide iron spoon with silver.
solution which can neutralize 50 cm3 of 0.5 mol dm-3
sulphuric acid ?
A 25 cm3 B 30 cm3
C 50 cm D 75 cm3
3
Iron spoon
Silver rod Silver nitrate
solution
Diagram 13
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After 30 minute it was found that no plating took place on 47. What is the structure of the product of reaction when
the iron spoon. What should be done ? propane is passed into liquid bromine?
A Increase the cell voltage A CH3-CH2-CH2Br solution

B Interchange the terminals in the cell B CH2=CH-CH2-CH2Br
C Rub the ion spoon with sand paper C CH3-CH2-CHBr-CH2Br
D Use iron(II) sulphate solution as the electrolyte D CH3- CHBr-CH2Br
43. A dibasic acid, H2J has the concentration of 0.5 mol dm-3.
Letter J is not the actual symbol of the element. What is the
volume of potassium hydroxide, KOH, 1.0 mol dm that
-3 48. Diagram 15 shows the experiment to study the effect of
different metals on the rusting of iron when in contact with

can neutralize 25.0 cm of the H2J acid solution?
3
iron.
A 6.25 cm3 C 25.00 cm3
B 12.50 cm3 D 50.00 cm3 Zinc Iron Lead Iron
Beaker I Beaker II
44. Energy Nace solution

Copper Iron Tin
T1
Beaker III Beaker IV
A+B
Diagram 15
T2 The iron bar in which beaker will not rust?
C+D
Diagram 14 A Beaker IV C Beaker II

Diagram 14 shows the energy level for a neutralization B Beaker III D Beaker I
reaction. Which of the following statements is correct?
A Reaction between A and B is an endothermic reaction. 49. Which of the following has the lowest pH?
B T2 is the total heat energy released
C The temperature of this reaction decreases A 0.01 mol dm-3 of ammonia solution
D T1 is the Heat of reaction B 0.01 mol dm-3 of sulphuric acid solution
C 0.001 mol dm-3 of ethanoic acid solution
D 0.001 mol dm of ammonia solution
-3
45. In an experiment, 25 cm of ethanoic acid was added to
3
20 cm of aqueous ammonia. The temperature of mixture

3
50. Diagram 16 shows the graph obtained when an experiment

increased by 5 C. How much was the heat energy released?
o
was repeated with the change of one variable.

[The specific heat capacity of mixture=4.2 Jg C ;
-1o -1
density of mixture = 1 gcm ]

-3
Volume of Experiment I
carbon dioxide
A 840 J B 900 J
(cm3) Experiment II
C 945 J D 1000 J
46. Which of the following chemical reactions are representing Time (s)
a redox reaction? Diagram 16
I H2SO4 + 2NaOH Na2SO4 + 2H2O
Which of the following statements is true to describe the
11 Cu + 2AgN03 Cu(N03)2 + 2Ag
above graph?
III Pb(NO3)2 + Na2CO3 PbCO3 + 2NaNO3

IV 2Al + Fe203 Al203 + 2Fe
A The rate of reaction of Experiment I is higher than
A I and II only C III and IV only
experiment II
B I,II and IV only D II and IV only
B The rate of reaction of Experiment II is higher because
catalyst was used in Experiment II
C The difference in temperatures is not the factor affecting
the rate of reaction of Experiment I and II
D The time taken for reaction in Experiment I to stop is
shorter than reaction in Experiment II
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CHEMISTRY
Paper 2
Nov./Dis
1 hour 30 minutes
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Paper 2
Section A (60 marks)
Answer all questions in this Section. You are advised to spend 90 minutes on this section
1. Diagram below shows the set-up of apparatus to investigate the redox reaction in a chemical cell.
A
A B
Silver Rod Zinc Rod
Silver Zinc
nitrate Sulphate
solution solution
Potassium
nitrate

solution
Diagram 1
(a) What is the energy change that occurrs in the experiment?
(1 mark)
(b) What is the function of potassium nitrate solution in the above experiment?
(1 mark)
(c) State one observation that can be made in the above experiment. Explain why.
(2 marks)
(d) (i) Name the process that occurrs in electrode A.

(ii) Write an ionic equation for the reaction that occurrs in electrode A. (1 mark)
( 1 mark)
(e) State the negative terminal for this cell. Explain your answer.
(2 marks)
(f) Write a complete ionic equation for the reaction that occurrs in this experiment.
(2 marks)
Switch Voltmeter
2. V
Zinc Copper plate
Porous pot
Zinc nitrate
solution Copper (II)
Diagram 2 sulphate solution
Diagram 2 shows a chemical cell.

(a) Write the formula of zinc nitrate
[1 mark]
(b) Write the half ionic equation for reactions at

(i) negative terminal
(ii) positive terminal [2 marks]
(c) Name the reaction that occurs at

(i) negative terminal
(ii) positive terminal [2 marks]
(d) State one observation in the experiment [1 mark]
(e) (i) Shows the direction of electron flow in Diagram 2 [1 mark]

(ii) State the change in energy in this experiment [1 mark]
(f) State the change in oxidation number for copper in this reaction [1 mark]
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3. Glucose
Yeast Distillation
Heat
Liquid A Gas D
Porcelain chips
Acidified K2Cr2O7 solution
Liquid A + Catalyst Y
Liquid B Liquid C
Reflux
Diagram 3
Diagram 3 shows a series of changes involving glucose.

(a) Liquid A has a structural formula of C2H6O and the functional group OH. Draw the structural formula for liquid A.
_____________________________________________________________________________________________
[1 mark]
(b) Liquid B produces carbon dioxide gas when it reacts with sodium carbonate.
(i) What is liquid B?
_____________________________________________________________________________________________
[1 mark]
(ii) Write the molecular formula for liquid B

_____________________________________________________________________________________________
[1 mark]

(c) Liquid C has a sweet, fruity smell
(i) Name catalyst Y.
_____________________________________________________________________________________________
[1 mark]
(ii) Name the homologous series for liquid C.

_____________________________________________________________________________________________
[1 mark]
(d) When gas D is passed through bromine water, the brown colour of bromine water is decolourised
(i) Name gas D.

_____________________________________________________________________________________________
[1 mark]
(ii) Write down the molecular formula for the compound that is produced when gas D reacts with bromine water.
_____________________________________________________________________________________________
[1 mark]
(e) i) Write the equation for the reaction involving the combustion of liquid A.
_____________________________________________________________________________________________
[1 mark]
(ii) What is the volume of oxygen at room temperature needed to burn 2.3 g of liquid A completely?
[Atomic relative mass : H,2 ; C,12 ; O,16. Volume of 1 mole of gas at room temperature is 24 dm3 ]
_____________________________________________________________________________________________
(10 marks)
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4. Diagram 4 shows part of the Periodic Table of Element. A, B, C, D, E, F, G and H do not represent the actual symbol of elements
A
B C D
E F G

Diagram 4
Using the letters in the Periodic Table of Elements in Diagram 4, answer the following questions.
(a) (i) State the number of proton of atom G.

_____________________________________________________________________________________________
[1 mark]
(ii) Write the formula of ion of atom G.

_____________________________________________________________________________________________
[1 mark]
(b) 12 C is one isotope of C.

6

(i) Name another isotope of C
_____________________________________________________________________________________________

(ii) Both isotopes have same chemicals properties. Eaplain why.
_____________________________________________________________________________________________
[2 marks]
(c) Atom D is more electronegative compared to atom C. Explain why.
_____________________________________________________________________________________________
_____________________________________________________________________________________________
[3 marks]
(d) E reacts with G to form a compound

(i) Write the chemical equation for the reaction.
_____________________________________________________________________________________________
[1 mark]
(ii) Draw the diagram of electron arrangement for the compound that is formed between E and G.
_____________________________________________________________________________________________
_____________________________________________________________________________________________
[2 marks]
(10 marks)
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5. An experiment is carried out to determine the rate of reaction for the reaction between 50 cm3 of dilute sulphuric acid and
excess copper(II) carbonate powder. Table 1 shows the results of the volume of carbon dioxide gas collected at regular
intervals of 30 seconds.
Time, s 0 30 60 90 120 150 180 210 240

Volume of CO2, cm3 0.0 20.0 29.0 36.0 41.0 44.0 45.0 45.0 45.0
Diagram 5
(a) Draw a labeled diagram for a set-up of the apparatus used in this experiment.
_____________________________________________________________________________________________
_____________________________________________________________________________________________
[2 marks]
(b) Plot the graph of volume of carbon dioxide gas collected against time for this experiment.
_____________________________________________________________________________________________
[4 marks]
(c) Based on the graph plotted, determine

(i) the average rate of reaction in this experiment
_____________________________________________________________________________________________
_____________________________________________________________________________________________
(ii) the instantaneous rates of reaction at 2 minutes.

_____________________________________________________________________________________________
_____________________________________________________________________________________________
[3 marks]
(d) Explain why the rate of reaction decreases with time.

_____________________________________________________________________________________________
[1 mark]
(10 marks)
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6.
X Y
electrode carbon
crucible
Copper (II) chloride

Diagram 6
Diagram 6 shows an electrolytic cell that is used to electrolyse copper (II) chloride, CuCl2.

(a) Name the electrode where oxidation occurs.
_____________________________________________________________________________________________
(1 mark)
(b) Describe the transfer of electrons in this electrolysis.

_____________________________________________________________________________________________
_____________________________________________________________________________________________
(2 marks)
(c) i) Name the ion that is reduced.

_____________________________________________________________________________________________
(1 mark)
ii) Write the reduction half-equation
_____________________________________________________________________________________________
(1 mark)
iii) State the change in the oxidation number during the reduction.
_____________________________________________________________________________________________
_____________________________________________________________________________________________
(2 marks)
d) i) State an observation at Y electrode.

_____________________________________________________________________________________________
(1 mark)
ii) Name the reaction that occurs at Y

_____________________________________________________________________________________________
(1 mark)
e) Write the ionic equation for this experiment

_____________________________________________________________________________________________
_____________________________________________________________________________________________
(2 marks)
(11 marks)
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SECTION B (20 MARKS)
Answer One question in this section. The time suggested to answer this question is 30 minutes
7. (a) Benzene, C6H6 is an unsaturated hydrocarbon. Benzene burns completely in excess air.
(i) Write a balanced chemical equation to show the burning process above. [3 marks]
(ii) The relative molecular mass of benzene is 78. What is meant by this statement ? [3 marks]
(iii) When 7.8 g of benzene is completely burned, determine the volume of oxygen gas evolved in cm3.
[1 mole of gas occupies 24 dm3 at room temperature and pressure] [4 marks]
(b) The diagram below shows a molecular formula of 2-methyl propan-2-ol.
C4H9OH
(i) Draw the structural formula of 2-methylpropan-2-ol.
(ii) Draw and name other isomers of 2-methylpropan-2-ol.
(iii) Compare the physical and chemical properties between the isomers [10 marks]
8. Diagram below shows three symbols for the elements X, Y and Z
7 12 35
X Y Z
3 6 17
(a) Compare the subatomic particles between any two of the elements. [4 marks]

(b) Element X reacts with element Z to form a compound. Based on a labeled diagram, explain the formation of the
compound [10 marks]
(c) Element Y also can react with element Z to form a compound. Explain how the compound is formed [3 marks]
(d) Compare the melting point of compound in (b) and (c). Explain your answer [3 marks]
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Section C (20 marks)
Instructions: Answer any one question from this section. The time suggested to complete this section is 30 minutes.
9. (a) A chef who makes cakes for his restaurant wants to make the food tastier, last longer and of course look better.
State the food additives that can help the chef with the above purpose. Explain how the additives act. (6 marks)
(b) A fish seller washes his oily hands using soap

Explain the cleansing action of the soap on the oily dirt on the hand. (6 marks)
c) Ionic compounds can conduct electricity in molten state but cannot conduct electricity in solid state. Covalent
compounds cannot conduct electricity in solid and molten states.

Describe an experiment to prove the above statements. In your description, include all the chemicals apparatus and
observations involved. (8 marks)
10. Diagram 7.1 and Diagram 7.2 show the electron arrangement for atoms of two elements from Group 17 in the Periodic Table
of Elements.
Diagram 7.1 Diagram 7.2

(a) Based on Diagram 7.1:
(i) Write the electron arrangement for the atom of the element and name the element. [2 marks]
(ii) Write a chemical equation for the reaction between these elements and sodium hydroxide. [3 marks]
(b) Compare the attractive forces between the nuclei and the valence electrons in the atoms in Diagram 7.1 and
Diagram 7.2 and relate this to their respective reactivity. [6 marks]
(c) Another element in Group17 is a black coloured solid. Predict the reactivity of this element in its reaction with sodium
hydroxide compared to that of the element in Diagram 7.2 [1 mark]
(d) Diagram 7.3 shows the set up of the apparatus to investigate the reaction of an element from Group 17 with iron metal
Chlorine Iron wool

Concentrated gas
hydrochloric acid
Heat
Sodium hydroxide
solution
Potassium manganate (VII) chips
Part G Part H
Diagram 7.3
(i) State two safety precautions that are needed to be taken when carrying out the experiment [2 mark]
(ii) Explain and write down the chemical equations for the reactions occurring in Part G and Part H. [6 mark]
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CHEMISTRY
Paper 3
Nov./Dis
1 hour 30 minutes
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Time : 1 hour 30 minutes
Answer all Questions
1.
Time/minutes 0 0.5 1.0 1.5 2.0 2.5 3.0 3.5 4.0 4.5 5.0 5.5 6.0 6.5 7.0
Experiment I 0 3.0 5.5 8.0 10.5 13.0 15.0 16.5 18.0 19.5 20.5 21.5 22.5 23.5 24.5
(volume of gas/cm3)
Experiment II 0 6.0 10.5 15.5 18.5 21.5 24.5 27.0 29.0 31.0 x 34.0 35.0 36.0 37.0
(volume of gas/cm3)
Table 1

Table 1 Shows the data obtained by a student fromm two experiments that were carried out to study the decomposition of
hydrogen peroxide.
In Experiment I, 8 cm3 of 2.0 mol dm-3 hydrogen peroxide solution was added to 42 cm3 of distilled water and 2 chips of
manganese(IV) oxide. The total volume of gas produced was recorded at regular intervals.
In Experiment II, 8 cm3 of 3.0 mol dm-3 hydrogen peroxide solution was added to 42 cm3 of distilled water and 2 chips of
manganese(IV) oxide. The total volume of gas produced was recorded at regular intervals.
(a) Name the gas produced in the above experiments.
_____________________________________________________________________________________________
[1 markah]
(b) (i) State the manipulated variable and the responding variable in the experiment.

Manipulated variable : _____________________________________________________________________________
Responding variable : _____________________________________________________________________________

[2 markah]
(ii) State the hypothesis of the experiment.

_____________________________________________________________________________________________
_____________________________________________________________________________________________
[1 markah]
Diagram 1
Diagram 1 shows the initial burette reading at 0 minute and the final burette reading after 5 minutes.
Determine the value of X, which is the volume of gas collected at the 5th minute.
_____________________________________________________________________________________________
_____________________________________________________________________________________________
[1 markah]
Lihat sebelah
4541/3 SULIT
SULIT
(d) (i) Plot the graphs of the volume of gas against time for Experiment I and Experiment II on the graph paper below by
using the same axes
[3 markah]
(ii) Predict the volume of the gas produced at the 7.5th minute of Experiment II from the graph in (d)(i).
_____________________________________________________________________________________________
[1 markah]
(iii) Determine the rate of reaction in Experiments I and II at the 3rd minute using the graph in (d)(i).
Rate of reaction in Experiment I at the 3rd minute
_____________________________________________________________________________________________
[1 markah]
Rate of reaction in Experiment II at the 3rd minute
_____________________________________________________________________________________________
[1 markah]
(e) What is the factor that caused the difference in the rates of reaction for the two experiments in (d)(iii)?
_____________________________________________________________________________________________
[1 markah]
(f) Why does the rate of decomposition of hydrogen peroxide decrease with time ?
_____________________________________________________________________________________________
[1 markah]
(g) What is the function of manganese(IV) oxide in both the experiments?
_____________________________________________________________________________________________
[1 markah]
(h) The total volume of gas released with 7 minutes in Experiments II is greater than that in Experiment I. Give your reason.

_____________________________________________________________________________________________
[1 markah]
Lihat sebelah
4541/3 SULIT
SULIT
(i) Write a balanced chemical equation for the decomposition of hydrogen peroxide.
_____________________________________________________________________________________________
[1 markah]
2. Diagram 2 below displays the set-up of the apparatus of an experiment to determine the heat of neutralization between aqueous
sodium hydroxide and dilute hydrochloric acid.
200 cm3 of 1 mol dm-3 dilute

hydrochloride acid

Plastic cup
200 cm3 of 1 mol dm-3
aqueous sodium hydroxide
Diagram 2
The respective initial temperatures of the two reactants and the maximum temperature of the mixture are displayed by the
thermometer readings in the figure below.
40 40 40
30 30 30
20 20 20
Initial temperature of Initial temperature of dilute Maximum temperature of
aqueous sodium hydroxide hydrochloric acid the mixture
(a) Based on the figure above, write the temperature readings of each of the solutions in the appropriate spaces in the table
below.
Initial temperature of aqueous sodium hydroxide/ oC

Initial temperature of dilute hydrochloric acid/ oC
Maximum temperature of the mixture/ oC
[3 markah]
(b) (i) Write the equation for this neutralization reaction.
_____________________________________________________________________________________________
[1 markah]
(ii) Calculate the total energy that was released from this reaction.
[The specific heat capacity of water = 4.2 J g-1 oC-1; Density of the solution = 1.0 g cm-3]
[2 markah]
(c) (i) Calculate the heat of neutralization for this reaction
_____________________________________________________________________________________________
[2 markah]
(ii) Draw the energy level diagram of this reaction.
_____________________________________________________________________________________________
[3 markah]
Lihat sebelah
4541/3 SULIT
(d) (i) Write the observation noted in this experiment other than changes in the temperature.
_____________________________________________________________________________________________
[1 markah]
(ii) What is the inference deduced from the observation above?
_____________________________________________________________________________________________
[2 markah]
(e) What are the precautions to be taken for this experiment.

_____________________________________________________________________________________________

_____________________________________________________________________________________________
[3 markah]
3. Food that is kept in a refrigerator will last longer than that of food being kept at room temperature.
Based on the above statement, plan a laboratory experiment to investigate the effect of temperature on the rate of reaction
between magnesium ribbon and dilute sulphuric acid.
Your planning should include the following aspect :

(a) Statement of the problem
(b) All the variables involved
(c) Hypothesis
(d) List of apparatus and materials
(e) Procedure
(f) Tabulation of data
[17 markah]
END OF QUESTION PAPER
Lihat sebelah
4541/3 SULIT
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Kertas 1
1. D 26. C
2. D 27. B
3. C 28. A
4. D 29. B
5. D 30. C
6. D 31. C
7. A 32. B
8. B 33. C
9. A 34. C
10. C 35. B
11. B 36. B
12. B 37. C
13. B 38. C
14. C 39. D
15. B 40. A
16. A 41. B
17. C 42. B
18. C 43. C
19. C 44. B
20. C 45. C
21. B 46. D
22. B 47. D
23. C 48. D
24. C 49. B
25. C 50. C
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SECTION A
1. (a) A change from chemical energy to electrical energy
(b) It serves as the salt bridge to complete the electric circuit so that ions can move through it.
(c) The mass of zinc rod decreases gradually. Zinc rod gives up its electrons to silver rod.
(d) (i) Oxidation
(ii) Zn Zn2+ + 2e-
(e) Zinc rod is the negative terminal. Zinc is more electropositive than silver and its position is higher than silver in the
electrochemical series. It has a greater tendency to donate its electrons.
(f) Zn + 2Ag+ Zn2+ + 2Ag
2. (a) Zn(NO3)2
(b) (i) Zn Zn2+ + 2e-
(ii) Cu2+ + 2e- Cu
(c) (i) Oxidation
(ii) Reduction
(d) The blue colour of copper (II) sulphate solution diminishes gradually.
(e) (i) Switch Voltmeter
Zinc copper plate
porous pot
Zinc nitrate solution
copper (II) sulphate solution
(ii) A change from chemical energy to electrical energy.
(f) A change from 0 to +2

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3. (a) H H H H
H C C H H C C OH
H OH H H
(b) (i) Ethanoic acid
(ii) CH3COOH / C2H4O2
(c) (i) Concentrated sulphuric acid
(ii) Ester
(d) (i) Ethene
(ii) C2H4Br2
(e) (i) C2H5OH + 3O2 2CO2 + 3H2O (complete combustion)
(ii) 2.3 g of ethanol = 2.3/46 = 0.05 mol
(to react with) 0.05 x 3 = 0.15 mol of oxygen gas

Volume of oxygen is 0.15/1 x 24 dm3 = 3.6 dm3
4.(a)(i) 17
(ii) Cl-
(b) (i) Carbon-13
(ii) Both have the same number of valence electrons which is 4. Hence, they demonstrate similar reactivity.
(c) Atom D has 6 valence electrons compared to atom C which has 4. Atom D requires only 2 more electrons to reach its
octet stability. Therefore, it is more electronegative.
(d) (i) Mg + Cl2 MgCl2
(ii)
Cl mg Cl
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5. (a)
(b)
(c) (i) 45/180 = 0.25 cm3 s-1
(ii) 19/141 = 0.135 cm3 s-1
(d) The rate of reaction in inversely proportional to the time taken. This means the longer the time taken, the lower the rate
of reaction.
6. (a) Electrode Y
(b) Electrons are transferred from the anode (electrode Y) to the cathode (electrode X)
(c) (i) Copper ion
(ii) Cu2+ + 2e- Cu
(iii) The oxidation number of copper decreases from +2 to 0
(d) (i) Greenish-yellow gas is evolved.
(ii) Oxidation
(e) CuCl2 Cu2+ + 2Cl-

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7.(a)(i) SECTION B
General formula CxHy

CxHy + (x + y/4)O2 xCO2 + y/2 H2O
C6H6 + 7 6CO2 + 3H2O
(ii) Relative atomic mass: H,1 ; C,12

(12x6) + (1x6) = 78
78 is the relative molecular mass of one molecule of benzene, which
means, it is 78 times heavier than one twelfth (1/12) of the mass of
carbon-12 atom.
(iii) 7.8 g/78 g x 1 mol = 0.1 mol

0.1 mol/1 mol x 24 dm3 = 2.4 dm3
(b) (i)
(ii)
(iii) 2-methylpropan-2-ol has a branched carbon chain and the hydroxyl (OH) group is positioned at carbon 2.
Butan-2-ol has a straight carbon chain and the hydroxyl (OH) group is positioned at carbon 2.
2-methylpropan-1-ol has a branched carbon chain and the hydroxyl (OH) group is positioned at carbon 1.
The isomers have different physical properties such as melting and boiling points because they have different
molecular structures; but they have the same chemical properties because they belong to the same homologous series.
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8. (a)
Subatomic particles Element X Element Y
Electron 3 6
Proton 3 6
Neutron 4 6
(b) Element X reacts with element Z to produce a compound with formation of ionic bond.
The electronic configuration of atom X is 2.1 and the electronic configuration of atom Z is 2.8.7. To attain the stable
duplet electron arrangement, atom X donates one electron to form a positive ion.
X X+ + e-
Atom Z will receive an electron to form Z- ion and attains the stable octet electron arrangement with 8 electrons in the
valence electron shell.
Z + e- Z-
The X+ ion and Z- ion will attract each other with a strong electrostatic force and form an ionic compound with the
formula XZ.
(c) Element Y reacts with element Z to form a compound with formation of covalent bond.
To attain the stable octet electron arrangement with 8 electrons in the valence electron shell, atom Y shares electrons
with atom Z. One atom Y contributes 4 electrons and four atom Z contribute one electron each. Atom Y shares 4 pairs
of electrons with four atom Z to form a covalent compound with the formula YZ.
(d) Compound XZ has a higher melting point than compound YZ. In compound XZ, the electrostatic force of attraction
between oppositely charged ions is very strong and a lot of heat energy is required to overcome it. In compound YZ,
the intermolecular force of attraction between molecules is weak and a little heat energy is required to overcome it.
9. (a) For those purposes, the chef can use flavouring agents, preservatives, antioxidants and colouring agents.
Flavoring agents are added to food to make it taste better. The agents are of two types: artificial flavours and flavour
enhancers.
Artificial flavours include sweeteners and others such as peppermint or vanilla. Examples are aspartame and saccharin.
These two are actually substitutes for sugar to enhance the sweetness of food.
Flavour enhancers are chemicals added to food to bring out the flavours or to enhance the taste, for example,
monosodium glutamate (MSG).
Preservatives and antioxidants protect food from being spoiled by bacterial and fungal attack, and atmospheric
oxidation, respectively.
Preservatives, for example sodium nitrite, benzoic acid and sodium benzoate, retard or prevent growth of
microorganisms so that food can be kept longer.
Examples of antioxidants include sulphur dioxide and sodium sulphite. They are added to food to prevent oxidation of
fats and oils by oxygen in air.
Colouring agents are synthetic dyes used to restore the colour of food lost during processing and enhance natural
colours to increase attractiveness. Examples are azo and triphenyl compounds.
(b) Soap molecules contain hydrophilic and fat insoluble heads and hydrophobic hydrocarbon tails.
When soap is used on oily wetted hands, the negatively charged heads of soap ions dissolve in water, whereas, the
hydrocarbon tails dissolve in the layer of oil. During washing, the oily dirt is lifted and washed away from the hands.
Soap also can emulsify the oily dirt by breaking large drops of oil into smaller droplets.
If the hands are dipped in water, the oily droplets repel one another because they carry the same charge. As a result, the
oil is suspended.
During washing, the droplets will be carried away.
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(c) To investigate the electrical conductivity of compounds
Apparatus
Crucible, spatula, graphite rods, batteries, light bulb, switch, connecting wires, tripod stand, clay triangle and Bunsen
burner.
Materials
Lead (II) bromide and naphthalene.
Methods
1. Three spatula of lead (II) bromide solid is put in a crucible.
2. Two graphite rods are dipped in the lead (II) bromide solid and the circuit is completed by connecting to the batteries
and switch.
3. The switch is turned on and the bulb is checked if it lights up.
4. Lead (II) bromide is heated strongly until it melts. The switch is turned on again to check if the bulb lights up.
5. Steps 1 to 4 are repeated using naphthalene to replace lead (II) bromide.
Results
Compound State Observation Inference
Lead (II) bromide Solid Light bulb does not light up Conducts electricity in the molten but not in the solid state
Molten Light bulb lights up

Naphthalene Solid Light bulb does not light up Does not conduct electricity in any state
Molten Light bulb does not light up
10. (a)
(i) The electronic configuration for Diagram 7.1 is 2.8.7. The element is chlorine.
(ii) Cl2 + 2NaOH NaCl + NaOCl + H2O
(b) The distance between the nucleus and the valence electrons of atom in Diagram 7.2 is greater than that in Diagram 7.1
as the atom in Diagram 7.1 has 3 electron shells but the atom in Diagram 7.2 has 4 electron shells. Because of this, the
attractive forces between the nucleus and the valence electrons become weaker in Diagram 7.2 compared to the atom in
Diagram 7.1.
As a result, the atom in Diagram 7.1 has a stronger attraction towards electrons compared to the atom in Diagram 7.2.
The atom in Diagram 7.1 is more electronegative, therefore, it is more reactive compared to the atom in Diagram 7.2.
(c) The element in Diagram 7.2 reacts more actively with sodium hydroxide compared to the black coloured solid.
(d) (i) 1. Concentrated acid is corrosive and the experiment must be conducted in a fume chamber.
2. Make sure that the apparatus are connected tightly to prevent leakage of chlorine gas, which is poisonous.
(ii) Part G Chlorine gas will react with iron wool to produce iron (III) chloride solid.
2Fe + 3Cl2 2FeCl2
Part H The excessive chlorine gas will flow into sodium hydroxide solution to produce sodium chloride,
sodium chlorate and water.
Cl2 + 2NaOH NaCl + NaOCl + H2O
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1.(a) Oxygen gas
(b)(i) Manipulate variable : concentration of hydrogen peroxide

Responding variable : decomposition rate of hydrogen peroxide
(b)(ii) The higher the concentration of hydrogen peroxde, the higher is the rate of its decomposition
(c) x= 49.5-17.0 = 32.5 cm
(d)(i) volume of O2 gas cm
40
35
30
25
20
15
10
0 1 2 3 4 5 6 7 8
time/minute
(ii) 38.0 cm (0.5cm)

(iii) Rate of reaction of Experiment I at the 3rd minute = 3.6cm min (+0.2 )
Rate of reaction of Experiment II at the 3rd minute = 5.6cm min (+0.2 )
(e) Concentration of hydrogen peroxide in Experiment II is higher than that in Experiment I.
(f) Concentration of hydrogen peroxide decreases with time due to occurrence of decomposition.
(g) It acts as a catalyst.
(h) The reason being the higher concentration of hydrogen peroxide in Experiment II compared to the concentration of
hydrogen peroxide in Experiment I
(i) 2H2O2 2H2O + O2

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2.(a) 28C; 28C ; 39C
(b)(i) NaOH + HC1 NaC1 + H2O
(ii) Total (heat) energy released
= mass of solution x specific heat capacity x rise in temperature
= (200 + 200) x 4.2 x (39 28)
= 400 x 4.2 x 11
= 18480 J
(c)(i) no. of moles of NaOH = (200 x 1.0) 1000 = 102mol

no. of moles of HCI = (200 x 1.0) 1000 = 0.2 mol
no. of moles of H2O produced = 0.2 mol
Heat Neutralisation
= -[(1 0.2) x 18.480 kJ]
= - 92.40 kJ mol-1

(ii) Energy
NaOH + HC1
H = -92.40 kj mol -1
NaCl + H20
d)(i) The plastic cup becomes hot

(ii) The reaction is an exothermic reaction.
(e) 1 A plastic cup must be used for this experiment

2 The mixture must be stirred constantly with the thermometer
3 The dilute acid must be added quickly and carefully to the alkali
3.(a) Problem Statement

Does the increase in the temperature of sulphuric acid increase the rate of reaction.
(b) Variables
i. Manipulated variable: temperature of sulphuric acid
ii. Responding variable: time take for magnesium ribbon to dissolve completely / rate of action
iii. Fixed variable: mass of magnesium ribbon; volume and concentration of sulphuric acid.
(c) Hypothesis
The higher the temperature of sulphuric acid, the shorter is the time taken for the magnesium ribbon to dissolve
completely; the higher the temperature of sulphuric acid, the higher is the reaction between sulphuric acid and
magnesium.
(d) Apparatus and materials

(i) Magnesium ribbon 0.1 mol dm sulphuric acid
(ii) stopwatch, conical flask, electronic balance, measuring cylinder, Bunsen burner, thermometer, tripod stand, wire gauze.
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(e) Procedure
1 25 cm of 0.1 mol dm sulphuric acid is measured and poured into a conical flask.
2 Using a thermometer, the temperature of sulphuric acid solution is measured.
3 -5g of magnesium ribbon is weighed out and put into the acid in the conical flask.
4 A stop watch is started simultaneously
5 The conical flask is slowly shaken throughout the experiment
6 The time taken for the magnesium ribbon to dissolve completely in sulphuric acid is recorded.
7 Steps 1 to 6 are repeated with unchanged conditions and methods at different temperatures i.e 35C, 40C, 45C,
50C and 55C respectively.
(f) Tabulation Of Data
Temperature, 0C Time for magnesium ribbon

to dissolve completely, S
Initial Time
350C
400C
450C
500C
550C
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134 SOALAN ULANGKAJI SPM 2008

TIMES HIGHER EDUCATION

SOALAN ULANGKAJI SPM 2008

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1. Answer all the questions

6. Diagram2 shows the formation of ammonia through the

Diagram 1 Hyrogen Nitrogen

2. Which of the following is true about acids.

3. Which of the following substance is a non electrolyte? Catalyst X Temperature Pressure

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Glass Main composition

A 1, II and IV only B 1, II and III only C 50 x T x 4.2 x 1

A I and IV only C II and III only

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Which of the following factors increases the heat of

Diagram 9 A Size of molecules decreases

Particle Proton Electron Step II

III To build the bodies of aircrafts

A I and II only C II and III only [ CH3( CH2 )16COO]2Ca( s )

37. What is the number of molecules in 12 dm-3 of oxygen gas,

and pressure; Avogadro constant 6.0 x 10 particles]

A Increase the cell voltage A CH3-CH2-CH2Br solution

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Diagram 14 A Beaker IV C Beaker II

20 cm of aqueous ammonia. The temperature of mixture

50. Diagram 16 shows the graph obtained when an experiment

was repeated with the change of one variable.

density of mixture = 1 gcm ]

TIMES HIGHER EDUCATION

SOALAN ULANGKAJI SPM 2008

DO NOT OPEN UNTILL INTSRUCTED TO

1. Answer all the questions

Silver Rod Zinc Rod

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Diagram 2 shows a chemical cell.

(b) Write the half ionic equation for reactions at

(c) Name the reaction that occurs at

(d) State one observation in the experiment [1 mark]

(e) (i) Shows the direction of electron flow in Diagram 2 [1 mark]

Acidified K2Cr2O7 solution

(ii) Write the molecular formula for liquid B

(ii) Name the homologous series for liquid C.

(i) Name gas D.

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(a) (i) State the number of proton of atom G.

(ii) Write the formula of ion of atom G.

(b) 12 C is one isotope of C.

(d) E reacts with G to form a compound

Time, s 0 30 60 90 120 150 180 210 240

(c) Based on the graph plotted, determine

(ii) the instantaneous rates of reaction at 2 minutes.

(d) Explain why the rate of reaction decreases with time.

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(b) Describe the transfer of electrons in this electrolysis.

(c) i) Name the ion that is reduced.

d) i) State an observation at Y electrode.

ii) Name the reaction that occurs at Y

e) Write the ionic equation for this experiment

SECTION B (20 MARKS)

(b) The diagram below shows a molecular formula of 2-methyl propan-2-ol.

(ii) Draw and name other isomers of 2-methylpropan-2-ol.

8. Diagram below shows three symbols for the elements X, Y and Z

Section C (20 marks)

(b) A fish seller washes his oily hands using soap