2007 Chemistry Times With Answer

90
CHEMISTRY
http://cikguadura.wordpress.com/
Format of Chemistry Paper
SPM Level
>>>
PAPER NO ITEM CONTENT

JAWAPAN dan TIPS SPM berkesan boleh didapati di laman web http://www.timesguides.com
A Types of instruments Objective test
B Types of items Objective item; multiple choice each item either

three, four or five options- A,B and C, or A, B,
C and D, or A, B, C, D and E
50, answers all

PAPER C Number of questions
ONE 50 marks ( 1 mark for 1 question)
D Total marks
1 hour 15 minutes (75 minutes)
E Duration of test
Construct requirement
F Construct requirement i. knowledge-25% to 45%
ii understanding-35% to 45%
iii Application of skills-30% to 35%
G Level of difficulty Low-50%, Moderate-30%, High-20%
A Types of instruments Subjective test
PAPER Types of items

TWO i Section A Structured item-contains 6 questions, answer all
questions.
ii Section B 2 Questions (answer only one)

iii. Section C 2 Questions (answer only one)
Types of instruments Written practice test
Types of question -Structured questions

-Essay questions
Number of question 3 Questions

(Answers all)
PAPER - two structured questions
THREE - one open respond item
Total marks 50 marks
Time 1 hour 30 minutes

>>>
Construct requirement Problem solving: 100% (experimenting)
Level of difficulty Low-50%, Moderate-30%, High-20%

91
Analysis of Chemistry Paper

SPM Level
>>>
TOPICS PAPER 1 PAPER 2 PAPER 3
04 05 06 04 05 06 04 05 06
YEAR
Form 4
Introduction to chemistry
The structure of the atom 7 6 6 2 1 1
Chemical formulae and questions 4 6 6 1 1
Periodic table of elements 2 3 3 1 1
Chemical bonds 2 1 2 1
Electrochemistry 2 3 5 1 2
Acids and bases 5 4 3 1 2
Salts 1 - 2
Manufactured substances in industry 4 3 4 1 1 1
Form 5
Rate of reaction 4 5 4 1 1
Carbon compounds 6 7 6 2 1
Oxidation and reduction 6 7 4 1
Thermo chemistry 4 4 5 1 4 1
Chemical for consumer 2 1 2 1 1 1
>>>
92
CONTOH KERTAS SOALAN CHEMISTRY

PAPER 1 ONE HOUR FIFTEEN MINUTES
>>>
Instruction: Questions 1 to 50 are followed by four options A,B,C and D.

Choose the best option for each question and blacken the corresponding space on the objective answer sheet.
1. The most common chemicals used in our daily life is 6. Figure 2 shows the set-up of experiment
table salt. What is the chemical term for the table salt? Bulb
A. Potassium oxide C. Potassium choride

B. Sodium chloride D. Sodium oxide Carbon
Electrodes
2. Figure 1 shows the set-up of a simple cell
X
Figure 2
Electrode Copper
X The bulb in figure 2 will light up if X is
A. lead nitrate solution

B. solid sodium chloride
Figure 1 C. molten phosphorus
D. glucose
Which of the following metals will give the highest
voltmeter reading when used as electrode X? 7. All the following affects the rate of reaction except
A. Iron C. Tin A. volume of reactant

B. Lead D. Magnesium B. mass of reactant
C. size of reactant
3. Acidic and basic properties are found in aluminum oxide, D. temperature
therefore it is ____ oxide.
8. Which of the following reactions occur very slowly at a
A. an amphoteric C. a metalloid room temperature?
B. an acid D. a base
A. NH4Cl (aq) NH3 (g) + HCl (aq)
4. Which of the following uses of inert gasses is wrongly B. Zn (s) + H2SO4 (aq) ZnSO4 (aq) + H2 (g)
paired?
C. 2H2O2 (aq) 2H2O + O2 (g)
A. Helium To fill meteorological balloons D. CaCO3 (s) + 2HCl (aq) CaCl2 (aq) + H2O (aq) +
B. Radon CO2
Decays to give X-rays which is
used to destroy cancer cells
9. Which catalyst is used in the manufacturing industry of
C. Neon To fill advertising electric bulbs margarine?
D. Krypton To fill flash bulb of cameras
A. Platinum C. Iron
B. Nickel D. Copper
5. Consider a voltaic cell represented by the given symbol:
Zn(s)Zn (aq) Ag / (aq) / Ag (s) 10. When the concentration in a reaction is increased, the rate
refer the attached note) of reaction is increased. This is because the
What is the reaction that occur in the voltaic cell A. number of reactant particles are increased
represented by the symbols above? B. collisions between the particles are increased
C. effective collision is increased
A. Electrons flow silver ions to zinc D. activation energy is reduced
B. Zinc atoms receive electrons from silver ions
11. The rate of reaction usually decreases if the time of
>>>
C. Zinc is the reducing agent

D. Silver ions release an electron to zinc reaction increases. This is because.
A. concentration of product increased

B. concentration of reactant decreased
C. the movement of particles is slower
D. the activation energy increased
93
12. Mutton can be cooked faster if 19. Which of the following are the advantages of mercury
cell?
A. cut into a small pieces
B. cooked with spices I Portable
C. cooked in a big pot II Small in size
D. boiled with a lot of water III Gives a large current
>>>
IV Light
13. 2Fe3+ + Zn 2Fe2+ + Zn2+
A. I, II and IV only C. II, III and IV only
Which of the following is not true about the above redox B. I, III and IV only D. I, II, III and IV
reaction?
20. The electrochemical series is used to determine:
A. Zinc is reducing agent
B. Fe ion is oxidizing agent I The terminal of a cell
C. Oxidation number of iron decrease from +3 to +2 II The standard cell voltage
D. Electrons transfer from Fe to Zn III The ability of a metal to displace another metal from
its salt solution
14. Fe2+ Fe3+ + e IV To extract metal from its oxide
Which of the following chemicals can change Fe2+ to Fe3+ A. I, II and III only C. IV only
B. II and IV only D. I, II, III and IV
I Pottasium iodide solution
II Acidic potassium dichromate (VI) 21. The ionic formulae of elements X any Y are as follows:
III Acidic potassium manganate (VIII)
IV Pottasium thiocynate X3+ Y2+
A. I and II only C. II, and III only The compound reacts from the ions of elements X and Y
B. II and iv only D. I, II, III, and IV with the formula of X2Y3.
15. Which of the following chloride compounds dissolved in Which of the following ionic equations represents the
water? reaction?
A. Silver chloride C. Mercury chloride A. X3+ + Y2- X2Y3

B. Lead (III) chloride D. Copper (II) chloride B. 2X + 3Y X 2Y 3
C. 2X3+ + 3Y2- X2Y3
16. The element Q has a proton number of 19. the chemical D. 3X3+ + 2Y2- X2Y3
properties of element Q is predicted to have the same
chemical properties with the element which has the
proton numbers of 22. 3.2 g of copper(II) oxide powder reacts with excess dilute
nitric acid. What is the mass of copper(II) nitrate formed
A. 11 C. 17 in the reaction?
B. 13 D. 20 (relative atomic mass of N= 14, O = 16 and Cu = 64)
17. Which of the following material is an ionic compound? A. 3.76 g C. 5.04 g

B. 4.96 g D. 7.52 g
Melting point,oC Boiling point,oC Solubility in water
A. -7 59 Soluble 23. In an experiment between hydraulic acid and zinc
B. -80 75 Soluble produces 25cm3 hydrogen gas. The reaction completes in
C. 800 1432 Soluble 50 seconds. What is the average rate of the reaction?
D. 1562 6720 Not Soluble
A. 0.5 cm3 s-1 C. 2.0 cm3 s-1
18. Electrolyte used in lead-acid accumulator is B. 1.0 cm3 s-1 D. 4.0 cm3 s-1
A. ammonium chloride paste 24. The following equation is the equation heptanes
B. dilute sulphuric acid combustion, C7H16, in excess Oxygen.
C. potassium hydroxide
D. mixture of zinc hydroxide and potassium hydroxide C7H16(l) + 110 2(g) 7CO2(g) + 8H2O,
H= -5 512 kJ mol-1
>>>
The combustion of heptane in excess oxygen releases

1 378 kJ of energy. What is the mass of heptane
used?(relative atomic mass of H=1, C=12)
A. 25.0 g C. 77.0 g
B. 36.0 g D. 88.0 g
94
25. The table below is the information about three simple 29. Which of the following shows the increasing order of
cells. reactivity when an alkali metal reacts with chlorine?
Pair of metals Potential Metal at negative A. Rb, K, Na, Li

differences/V terminal B. Na, K, Li, Rb
C. Li, Na, K, Rb
>>>
X and copper 0.45 X

Y and copper 1.30 Y D. Li, Na, Rb, K
Z and copper 0.56 Cu
30. Which of the following ions soluble in excess sodium
hydroxide solution
What is the potential difference of the pair of metals Y
and Z? I Al3+ III Pb2

II Mg2+ IV Zn2+
A. 0.85 C. 1.86
B. 1.01 D. 2.31 A. I and II only C. I, II and III only
B. II and IV only D. I, II and IV only
26. The reactivity of the halogen can be determined by a
reaction between halogen halide solution. The result of 31. The information given shows the sub-atomic particles of
the reaction is shown in the table. atom W
Halogen
Electron configuration 2.1
Halide Chlorine Bromine Iodine
Number of protons 3
Solution
Number of neutrons 4
Potassium Reaction No reaction
Bromide occurs Which of the following diagram shows an atom W?
Potassium Reaction Reaction
iodide occurs occurs A.
3p + 4n
The reactivity series of halogen in descending order is
A. bromine, chlorine, iodine
B. chlorine, bromine, iodine
C. iodine, bromine, chlorine
D. iodine, chlorine, bromine B.
3p + 4n
27. Which of the following reaction shows the oxidation of
copper
A. Reaction of zinc with copper (II) oxide
B. Reaction of copper with silver nitrate solution C.
C. Electrolysis of copper (II) sulphate solution by using 3p + 3e
carbon electrodes
D. Chemical cell with copper and zinc electrodes in dilute
sulphuric acid
28. Figure 3 shows the set-up apparatus for a displacement D.

reaction. 3p + 3e
Figure 3 32.
Silver Energy
nitrate
solution OH- (aq) + H+(aq)
Copper H = -57 kJ mol-1

plate
H2O(l)
What is observed after 10 minutes? The diagram can be concluded that

>>>
A. Gas bubbles are released A. the heat of neutralization is -57 kJ mo

B. Brown deposits formed B. 57 kJ of energy is needed for the reaction.
C. the products contain more energy than the reactants.
C. The solution turns blue D. the temperature at the end of the reaction is lower than
D. The copper plate becomes thicker that at the beginning of the reaction
95
33. The result for three chemical cells are shown as in the 37. The reaction between etanoic acid and ethanol produces
table compound K. which of the following are true about
compound K?
Chemical Metal Negative Cell
cell pairs terminal voltage/V I it is sweet-smelling
>>>
X P and R R 1.9 II it is insoluble in water
Y R and S S 0.8 III it has a low boiling point
Z Qand R R 0.3 IV its molecular formula is CH3COOCH3
Which of the following can be deduced from Table 3? A. I and II only C. I, II and IV only
B. I, II and III only D. I, II, III and IV
I.The cell voltage is 1.6 V when P and Q are used as
electrodes. 38. Which of the following compound is added to processed
II. The cell voltage is 1.1 V when P and S are used as meat as an antioxidant?
electrode.
III. Electrons flow from terminal Q to terminal S in the A. Sodium Chloride
metal pair Q and S B. Sodium benzoate
IV. P functions as a positive terminal when it is paired C. Sodium nitrate
with Q, R, or S in a cell D. Sodium acetate
A. I and IV only C. I, II, and III only 39. Astatine is below iodine in group 17 of the Periodic
B. II and III only D. I, II, III and IV Table. Which of the following are likely to be true about
astatine?
34. Brass is harder than ferrum because
I it is a solid at room temperature
A. the bond between the atoms of brass is stronger II it forms diatomic molecules
B. the arrangement of atoms in brass is more compact III it forms At- ion
C. the atoms of brass are harder to compressed IV it reacts with sodium to form a white compound
D. the layers of atoms in brass d not slide easily over one
another A. I, II and III only C. II, III and IV only
B. I, III, and IV only D. I, II, III and IV
35. Ethanol is boiled in acidic potassium manganate(VII) to
produce substance, X. substance X is reflxed with ethanol 40. The reaction between calcium carbonate and sulphuric
to produce compound Y. compound Y is acid produces carbon dioxide gas. Which of the following
pairs of reactants will have the highest initial rate of
A. ethanoic acid C. ethyl methanoate production of carbon dioxide gas?
B. ethyl ethanoate D. ethane
A. 50cm3 of 2.0 dm-3 sulphuric acid and 2g of calcium
carbonate powder
36. The products at anode and cathode each are
B. 30cm3 of 2.0 dm-3 sulphuric acid and 2g of calcium
carbonate pellets
C. 100cm3 of 2.0 dm-3 sulphuric acid and 2g of calcium
carbonate powder
Potassium D. 20cm3 of 2.0 dm-3 sulphuric acid and 2g of calcium
bromide
solution carbonate powder
Carbon
electrodes 41. Carbon and sulphur reacts according to the equation given
below
C(s) + 2S (s) CS2 (l), H= +88 kJ mol -1
Anode Cathode Which of the following statements is true according to the

equation. [ relative atomic mass; C, 12 , S, 32]
A. Oxygen Hydrogen
>>>
B. Oxygen Potassium A. the breaking of bonds in carbon and sulphur absorbs

C. Bromine Hydrogen 88kJ
D. Bromine Potassium B. formation of 1 mol of carbon disulphide releases 88 kJ
C. reaction of 32g of sulphur absorbs 88 kJ
D. reaction of 6g of carbon absorbs 44 kJ
96
42. The table shows the conditions of two experiments 45. Which of the following oxides will dissolve in water to
carried out to investigate the rate of decomposition of produce a solution with a pH of less than 7?
hydrogen peroxide catalysed by manganate (IV) oxide.
I Magnesium oxide
Experiment Mass of Hydrogen II Silicon dioxide
>>>
manganate(IV) peroxide solution III Phosphorus pentoxide

oxide IV Sulphur dioxide
I 0.5 g 100 cm3 1.0 mol dm-3
A. I and II only C. III and IV only
II 0.5 g 400 cm3 0.5 mol dm-3 B. II and IV only D. II, III and IV only
Which of the following graphs is that of the results 46. When powdered calcium carbonate reacts with dilute
obtained from experiments I and II? hydrochloric acid, the carbon dioxide gas is produced. If
the complete reaction of calcium carbonate with dilute
A. volume of oxygen gas (cm3) B. volume of oxygen gas (cm3) hydrochloric acid produces a maximum volume of 30cm3
I of carbon dioxide gas in 100 seconds, what is the average
II
II I rate of this reaction?
time (s) time (s)

A. 0.1 cm3s-1 C. 0.6 cm3s-1
B. 0.3 cm3s-1 D. 0.9 cm3s-1
C. volume of oxygen gas (cm3) D. volume of oxygen gas (cm3)
47. Figure 4 shows the set-up of an apparatus used to prepare
II I a carbon compound.
I II
time (s) time (s)
43. The tables shows the proton numbers of four elements;

E, F, H and I
Element E F H I
Lime water
Proton 2 4 12 16
number A mixture of sugarcane water + yeast
Which of the following pairs of elements will form a

compound with a high melting point? Figure 4
A. E and H C. F and H The carbon compound that is produced

B. E and I D. H and I
A. burns with a sooty flame
44. The electron arrangement of atom X is 2.8.5. which of the B. does not dissolve in water
following statements are true about atom X? C. has a double bond in its structural formula
D. can decolourises and acidified potassium manganate
I The nucleon number of X is 15. (VII) solution
II X has 15 nucleons is its nucleus
III X forms a covalent compound with hydrogen
IV The compound formed by X and chlorine has the
empirial formula XCl3
A. I and II only C. II and IV only

B. III and IV only D. II, III, and IV only
>>>
97
48. Which of the following describes the properties of
hydrogen chloride?
I This gas can dissolve in water and turns damp blue

litmus paper to red
>>>
II This gas contain hydroxonium ions
III this gas burns the skin if it is in contact with it
IV This gas is only made up of covalent molecules
A. I and II only C. II and III only
B. I and IV only D. II and IV only
49. Which of the following is a characteristic of copper?
I It can conduct electricity in both solid and molten

states
II it has strong ionic bonds
III It has a high boiling point
IV It has an oxidation number of +2
A. I and II only C. II and IV only

B. I and III only D. I, III and IV only
50. When exposed to air, fats and oils will be oxidised.

Name the food additives used to prevent oxidation from
occuring.
A. Preservatives C. Antioxidants
B. Stabilisers D. Thickeners
>>>
98
PAPER 2
TWO HOURS AND THIRTHY MINUTES
Section A
[60 marks]
>>>
Answer all questions in the section. The time suggested to complete Section A is 90 minutes.
1. Table 1 shows four substances and their respective formulae
Substances Chemical Formulae

Iodine I2
Copper Cu
Naphthalene C10H8
Copper(II) Sulphate CuSO4
Table 1
a) Use information from Table 1 to answer the following questions.

(i) State one substance from Table 1 which exist as molecules
_______________________________________________________________________________________
[1 mark]
(ii) Which substance has the highest melting point, iodine, copper or naphthalene?
_______________________________________________________________________________________
[1 mark]
(iii) What is the state of matter of copper (II) sulphate at room temperature?
_______________________________________________________________________________________
[1 mark]
(iv) State the substance in Table 1 which can conduct electricity in the solid state.
_______________________________________________________________________________________
[1 mark]
(v) Draw the arrangement of particles in the substance in (a) (iv).

[2 marks]
(vi) Write the chemical formulae for the substance in (a) (iv)
>>>
_______________________________________________________________________________________
[1 mark]
99
(b) Graph 1.1 shows the temperature against time when solid naphthalene is heated.
Tempreature/ C
>>>
S Graph 1.1
Q R
Times / s
(i) State the melting point of naphthalene.
_______________________________________________________________________________________
[1 mark]
(ii) Explain why there is no change in temperature from Q to R.
_______________________________________________________________________________________
_______________________________________________________________________________________
_______________________________________________________________________________________
_______________________________________________________________________________________
[3 marks]
(iii) State how the movement of naphthalene particles changes between R and S during the heating.
_______________________________________________________________________________________
_______________________________________________________________________________________
[1 mark]
2. 12 16 23
C O Na
6 8 11
Figure 1
23
(a) Write the electron arrangement of Na.
11
_______________________________________________________________________________________
[1 mark]
(b) Write the symbol of an isotope of carbon.
>>>
_______________________________________________________________________________________
[1 mark]
100
(c) Using the dot and cross method, draw the electron arrangement of carbon dioxide and sodium dioxide to show the bonds
formed in them.
>>>
Carbon Dioxide Sodium Oxide

(d) Between carbon dioxide and sodium oxide, which is acidic and basic?
_______________________________________________________________________________________
[2 marks]
(e) State two differences in the physical properties of carbon dioxide and sodium oxide.
_______________________________________________________________________________________
_______________________________________________________________________________________
[2 marks]
3. Diagram below shows the set-up of apparatus to investigate the redox reaction in a chemical cell.
Steam
Steam
(a) State the redox reaction in Combustion tube I
(i) State the observations made in the two combustion tubes.

I: ________________________________________________________________

II:________________________________________________________________
[2 marks]
(b) Write the equation for the reaction occurred in combustion tube I.
_______________________________________________________________________________________
[ 1 mark]
(c) (i) Name gas X
_________________________________________________________________________________
>>>
[1 mark]
(ii) Explain the production of gas X
_________________________________________________________________________________
[1 mark]
101
(d) Calculate the mass of the substance produced in combustion tube 1 when 2.4 g of magnesium powder is reacted in excess
steam flow. [ Relative atomic mass: H,1;O,16:Mg, 24]
>>>
[2 marks]
(e) Write the equation for the reaction occurred in combustion tube II.
_______________________________________________________________________________________
[1 mark]
(f) Name the substance that acts as an oxidizing agent in each combustion tube.
I: _______________________________________________________________________________________
II: _______________________________________________________________________________________
[2 marks]
4. The diagram is classification of drugs
Modern Drugs
P Q R Hormone
Streptomycin Aspirin Amphetamine Insulin
(a) Name the type of drugs P,Q and R

P __________________________________________________

Q __________________________________________________

R___________________________________________________ [3 marks]
(b) Explain the function of the respective drugs

P __________________________________________________

Q __________________________________________________

R___________________________________________________ [3 marks]
(c) Why streptomycin must be taken constantly even after recovering from illness?
_______________________________________________________________________________________
[1 mark]
d) What is the disadvantage of taking aspirin?
_______________________________________________________________________________________
>>>
[1 mark]
e) State the function of insulin
_______________________________________________________________________________________
[1 mark]
102
5. Study the diagram given. It shows the conversion of a few organic compounds beginning from glucose.
Glucose CH3CH2OH CH3COOH

>>>
CH2 = CH2 CH3COOCH2CH3
(a) What is process I?

_______________________________________________________________________________________
[1 mark]
(b)
i. Write an equation for the reaction which occurs in process II
___________________________________________________________________________________
[1 mark]
ii. Name the enzyme used in process II
____________________________________________________________________________________
[1 mark]
(c)
i. Write a balanced chemical equation for the reaction that occurs in process III
____________________________________________________________________________________
[1 mark]
ii. Name the reagent used in process III
____________________________________________________________________________________
[1 mark]
iii. Name the reaction that occurs in process III
____________________________________________________________________________________
[1 mark]
(d)
i. Name the reaction and the catalyst that are required in process IV
____________________________________________________________________________________
[2 marks]
ii. What is a physical property of the product formed in process IV?
____________________________________________________________________________________
[2 marks]
iii. Name the homologous series of the process IV
____________________________________________________________________________________
[1 mark]
>>>
103
6. The diagram is the set-up apparatus showing the transfer of electrons at a distance between bromine water and iron (II)
sulphate solution
>>>
P Q
carbon electrodes
iron(II)
sulphate bromine water
solution
sulphuric acid
(a) Mark the flow of electrons in the diagram
_______________________________________________________________________________________
[2 marks]
(b) Write the change in oxidation number of
(i) bromine in bromine solution
___________________________________________________________________________________
[1 mark]
(ii) iron in iron (II) sulphate solution
___________________________________________________________________________________
[1 mark]
(c) Suggest how to confirm the presence of the product formed at electrode P
_______________________________________________________________________________________
_______________________________________________________________________________________
_______________________________________________________________________________________
[3 marks]
(d) Name the substance that is reduced and oxidized in the reaction:
(i) reduced : ___________________________________________
(ii) oxidixed : ___________________________________________

[3 marks]
>>>
104
Section B
[20 marks]
Answer any one question in this section. The time given to answer is 30 minutes.
7. (a)
>>>
A container with oil stains is washed with soap

Explain the cleaning action of the soap on the oily stairs.
[8 marks]
(b) A student conducted four experiments to study the cleaning effects of soap and detergent in soft water and hard water.
The diagram shows the set-up of the experiment.

The observations made in the experiments are recorded in Table 3 below.
Experiment W X Y Z
Oily stains Oily stains Oily stains Oily stains
Observation disappeared remained disappeared disappeared

Compare the cleaning effects between
(i) Experiment W and Experiment X
(ii) Experiment X and Experiment Z
Why are there differences in the observations? Explain your answer; state the substances that is more suitable as a cleaning
agent to remove oily stains
[8 marks]
(c) gives two advantages and two disadvantages of using detergents

[4 marks]
>>>
105
8. (a) Describe the haber process in the manufacture of ammonia

[6 marks]
(b) Describe an experiment to prepare ammonium sulphate fertilizer in the laboratory
>>>
[9 marks]
(c) List the uses of ammonium in daily life

[5 marks]
>>>
106
Section C
[20 marks]
Answer any one question in this section. The time given to answer is 30 minutes.
9. (a) You have and iron key that rusts easily.
>>>
State how you would solve this problem using and electrolysis process
[4 marks]
(b) Electrolysis is carried out on a dilute sodium chloride solution using carbon electrodes.
Explain how this electrolysis occurs. Use a labeled diagram to explain your answer.
[6 marks]
(c) Aluminum is placed above zinc in the electrochemical series.

Aluminum and zinc can be used to built a chemical cells, using suitable apparatus and the following chemicals;
Aluminum sulphate solution

Zinc sulphate solution
Sulphuric and solution
Describe how you built this chemical cell

Include a labeled diagrams in your answer.
On your diagram, mark the direction of the electron flow, the positive and the negative terminal.
[10 marks]
10. (a) A farmer discovered that his vegetables were not growing well because the soil was poor and acidic. As a chemistry
student, you can help the farmer. Suggest how the farmer can solve the problem
[ 2 marks]
(b) Figure 8 shows an incomplete flow chart of cation and anion tests for salts X.
Salt X
Cation Test Anion Test
Pb2+ CO3-2
Use the reagents listed below and complete the flow chart to confirm that salt X contains Pb2+ ions and CO3-2 ions. Includes
your observations.
REAGENTS
Dilute hydrochloric acid, dilute nitric acid, and lime water
[8 marks]
(c) You are required to prepare dry magnesium chloride salt. The chemicals supplied are
Magnesium sulphate solutions

Dilute hydrochloric acid
Potassium carbonate solution.
>>>
Describe a laboratory experiment to prepare the salt. In your description, include the chemical equations invoved
[10 marks]
107
PAPER 3
Time: One hour and thirty minutes
[50 marks]
Answer all questions.
1. An experiment was carried out to examine the effect of temperature on the rate of reaction.
>>>
50 cm3 of 0.05 mol/dm3 sodium thiosulphate solution at 30 0C was put into a 250 cm3 conical flask. The flask was then placed
on an X sign drawn on a piece of white paper. 10 cm3 of 1 mol/dm3 hydrochloric acid was added to the sodium thiosulphate
solution, and the mixture was then shaken. At the same time ,the stopwatch was started. The stopwatch was stopped once the
X sign disappeared.
The steps were repeated using sodium thiosulphate solution heated to 36 0C, 42 0C, 48 0C and 54 0C.
Figure 1 shows the readings on the stopwatch for each reaction.
Times, t1 = ____________________s Times, t2 = ____________________s Times, t3 = ____________________s

at 300C at 360C at 420C
Figure 1
Times, t4 = ____________________s Times, t5 = ____________________s

at 480C at 540C
(a) Record the time for each reaction.

[3 marks]
(b) Construct a table and record the temperature, time and

1 for this experiment.
time
[3 marks]
>>>
108
(c ) (i) Plot a graph of temperature against 1 on the graph paper below.

time
>>>
[3 marks]
(ii) Based on your graph in (c) (i), state the relationship between the rate of reaction and temperature.
__________________________________________________________________________ [1 mark]
(d) Predict the time when the X sign disappear if the experiment is repeated at 60 0C.
_________________________________________________________________________________ [1 mark]
(e) State the hypothesis of this experiment.
_________________________________________________________________________________ [1 mark]
(f) (i) State the variables involved in this experiment.
Manipulated variable:____________________________________________________
Responding variable :____________________________________________________

Constant variable :____________________________________________________
_____________________________________________________ [3 marks]
(ii) Explain how you would manipulate one variable while keeping the other variables constant.

____________________________________________________________________
____________________________________________________________________ [1 mark]
(g) The relationship between temperature and the rate of reaction is applied in our daily life,
>>>
for example in keeping perishables like fish in refrigerator.
Using your knowledge in chemistry, state the relationship between temperature and the rate at which food turns spoiled.
_________________________________________________________________________________ [1 mark]
109
2. The following apparatus is set up in an experiment determine the heat of neutralization between dilute hydrochloric acid and
aqueous sodium hydroxide
100 cm3 of 2 mol dm-3
>>>
dilute hydrochloride acid
100 cm3 of 2 mol dm-3
Glass aqueous sodium hydroxide
Figure 2 (a)
The initial temperatures of the two reactants and the maximum temperature of the mixture are shown b the thermometer
readings in figure 2 (b).
Initial temperature of Initial temperature of Maximum temperature

aqueous sodium hydroxide dilute hydrochloric acid of the mixture
Figure 2 (b)
>>>
110
(a) Based on the diagrams given in figure 2 (b), write down the temperature of each of the solutions in the appropriate spaces
in table 3.
Initial temperature of aqueous sodium hydroxide/oC

>>>
Initial temperature of dilute hudrochloric acid/oC
Maximum temperature of the mixture/oC
Table 3
[3 marks]
(b) i. Write the ionic equation for this neutralization reaction
______________________________________________________________
[1 mark]
ii. Calculate the total energy released in this reaction.

[ the specific heat capacity of water = 4.2 J g-1 oC-; Density of the solution = 1.0g cm-3]
[2 marks]
(c) i. Calculate the heat of neutralization for the reaction

>>>
[2 marks]
111
ii. Draw the energy level diagram for this reaction

>>> JAWAPAN dan TIPS SPM berkesan boleh didapati di laman web http://www.timesguides.com
[3 marks]
(d) i. state the observation of this experiment other than the changes in temperature.
_______________________________________________________________________________________
[1 mark]
ii. State the inference from i.
_______________________________________________________________________________________
_______________________________________________________________________________________
_______________________________________________________________________________________
_______________________________________________________________________________________
[2 marks]
(e) State the safety precautions to be taken up in this experiment.
_______________________________________________________________________________________
_______________________________________________________________________________________
_______________________________________________________________________________________
_______________________________________________________________________________________
[3 marks]
>>>
112
3.
Lorry tyres made from natural rubber have been modified so that the
tyres can be used to last a distance of 60 000 km. The raw rubber material
used has gone through a process called vulcanization.
>>>
Based on the above statement, describe an experiment on how you would compare the properties of vulcanized rubber from
latex and also include the following aspects.
a) Objective of the experiment

b) Statement of the hypothesis
c) List of materials and apparatus
d) Methods of the experiment
e) Tabulated data of the experiment

[17 marks]
>>>
ANSWERS
CHEMISTRY
Paper 1
1. B 26. B
2. D 27. B
3. A 28. B
4. B 29. A
5. C 30. D
6. A 31. A
7. C 32. A
8. B 33. A
9. B 34. D
10. A 35. A
11. B 36. A
12. A 37. B
13. D 38. C
14. D 39. D
15. D 40. C
16. A 41. D
17. C 42. D
18. B 43. D
19. A 44. B
20. D 45. C
21. A 46. B
22. B 47. D
23. A 48. B
24. A 49. D
25. C 50. C
ANSWERS
PAPER 2
SECTION A
1 (a) (i) iodine

(ii) copper
(iii) solid
(iv) copper
(v)
(vi) Cu
(b) (i) T1 = 800C / 780C

(ii) Energy is absorbed o overcome the force between molecules of naphthalene.
So, there is no increase in temperature.
(iii) The naphthalene particles move faster as it changes between R and S
2 (a) 2.8.1
(b) 146C
(c)
o
carbon electrodes
iron(ll)
sulphate brominee water
solution
sulphuric acid
(d) Carbon dioxide is acidic

Sodium oxide is basic
(e) 1) State of matter of carbon dioxide is gas / sodium oxide is solid
2) The melting or boiling period of sodium oxide is higher than carbon dioxide
ANSWERS
3 (a) (i) I: grey powder to white

II: white powder to shiny grey / silvery powder / solid
(b) Mg + H2O MgO + H2
(c) (i) Hydrogen

(ii) when it tested with the burning wooden splinter, the pop sound is heard
(d) Mg + H2O MgO + H2
male Mg = 24 / 24
= 0.1 mol
From eg : 1 mol Mg = 1 mol MgO

0.1 mol = 0.1 mol
The mass of substance = o.1 x (24 + 16)

= 4.0 g
(e) 2Ag2O + H2 4Ag + 2H2O
(f) I: Steam
II: Silver oxide
4 (a) P: Antibiotics
Q: Analgesics
R: Psychotherapeutic drugs
(b) P: To prevent the growth of disease-spreading microorganisms

Q: To relieve or reduce pain
R: To treat patients with psychological problem
(c) To prevent bacteria from becoming more resistant to the antibiotic
(d) 1) it cause stomach irritation to some patient

2) it is believed to cause brain / liver damage to children
(e) To reduce glucose level in food.

ANSWERS
5 (a) oxidation
(b) (i) C6 H12 O6

(ii) Zymase
(c) (i) CH3 CH2 OH

(ii) Sulphuric acid / porcelain
(iii) Dehydration
(d) (i) Esterification , concentrated sulphuric acid

(ii) It has fruity smell / volatile
(iii) ester
6 (a)
(b) (i) from 0 to -1

(ii) from +2 to +3
(c) A few drops of hexacyanoferrate (III) are added to the product forhed in test tube
P. if the products turns blue, it means that ion ferum (III) Fe3+ is formed.
(d) (i) Bromine gas

(ii) ion ferum (III) Fe2+
ANSWERS
SECTION B
7 (a) - cleaning action of soap on the oily stains

x The structure of soap consists of ionic heads which are hydrophilic, and
hydrocarbon tails which are hydrophobic.
x When the soap is mixed with water, the hydrophilic part will dissolve into
water and reduce the tension on the water surface.
x With this, water can wet all surface better
x When the soap gets into contact with the oily stains, the hydrophilic part
of the soap will dissolve in the oily stains while the hydrophilic par will
dissolve in water,.
(b) - comparison between the cleaning effects in experiment W and Z

x The cleaning oily stains in Experiment W is more effective compare with
that in Experiment X
x The oily stains in Experiment W can be removed while those in Experiment
X cannot be removed.
x In Experiment X, the stains cannot be removed because soap forms scams
with the Mg2+- and Ca2+ ions in the hard water; these scams are insoluble in
water.
x In Experiment W, stains can be removed because soft water does not contain
the ions Mg2+ and Ca2+
- comparison between the cleaning effects in experiment X and Z

x The cleaning oily stains in Experiment Z is more effective then that in
Experiment X.
x The oily stains in Experiment Z can be removed while those in Experiment
X cannot be removed.
x In Experiment Z, detergent does not form scams in hard water. Detergent
reacts with Mg2+ and Ca2+ ions to produce salts there soluble in water.
x Therefore, detergent is a suitable cleaning agent to remove oily stains and
dirt.
(c) - Advantages
1. Detergents are effective in both soft water and hard water.
2. Detergents are cleaning agents that can be synthesized to have certain
characteristics.
- Disadvantages
1. Detergents are not biodegradable; bacteria cannot decompose detergents.
2. The phosphate in detergents enhances the growth of water weed and algae
when it gets in water bodies.
ANSWERS
8 (a) Haber process in the manufacture of ammonia.

x One part of nitrogen gas and three parts of hydrogen gas, all are pure and dry,
are mixed.
x The mixture of gasses is compressed at 200 500 atmospheres.
x Chemical reaction takes place, and ammonia is produced.
x Excess hydrogen and nitrogen gasses are then used in the next cycle of
ammonia production
x Chemical equation for the reaction that occurs is N2 (g) + 3H2(g)
2NH3(g)
(b) Experiment to prepare ammonium sulphate fertilizer in the laboratory;

x 25 cm3 of 1 mol/dm3 sulphuric acid is poured into a beaker.
x 1.0 mol/dm3 ammonia solution as added to the sulphuric acid. The mixture is
the stirred using a glass rod.
x Addition of ammonia is stopped once the pungent smell of ammonia is
detected.
x The solution mixture is then heated until it becomes saturated.
x The saturated solution is allowed to cool at room temperature
x Crystallization takes place, and white crystals of ammonium sulphate are
formed
x The solutions filtered to obtain the ammonium sulphate crystals.
x The crystals are then dried on a filter paper.
x The chemical equation to represent the reaction that takes place is as follows;
2NH3 (aq) + H2SO4(aq) (NH4)2SO4(aq)
(c) Uses of ammonia in daily
x To make nitrogenous fertilizers
x To make nitric acid by Ostwald process
x As a coolant
x As a cleansing agent
x Used in the manufacture of other chemicals
ANSWERS
SECTION C
9 (a) - iron key can be electroplated with nickel by electrolysis
- iron key acts as cathode whereas nickel acts as anode and nickel sulphate act as
the electrolyte.
(b) - the apparatus set-up for the electrolysis of sodium chloride solution is shown as
below:
- the ions present in the sodium chloride solution are Na+, Cl-, and OH- ions
- when the switched is switch on, Na+ and H+ ions will be attracted to the cathode.
- the H+ ions will be discharged to produce hydrogen gas because it is located at a
lower position in the electrochemical series compared to Na+ ions.
2H+ + 2e H2
- the Cl- and OH- ions are attracted to anode

- the OH- ion will be discharged to produce oxygen gas because it is located at a
power position in the electrochemical series
4OH- O2 + 2H2O + 4e
(c) - dilute sulphuric acid is filled into the U-tube as the salt bridge
- Aluminum sulphate solution is filled into one of the arm of the U-tube and zinc
sulphate solution is filled into another arm of the U-tube
- aluminium plate and zinc plate are immersed respectively into aluminium
sulphate as shown in the figure
- the circuit is completed
10 (a)- scatter some cacium hydroxide/lime and add calcium phosphate/phosphate

fertilizers to reduce the acidity of the soil and to supply nitrate ions which will
be absorbed by the roots of the plants when it dissolved in water.
(b)- place salt X into a test tube and add with nitric acid heated and shake it. The gas
released is flown into lime water. The presence of CO3-2 ions is indicated when
the lime water turns chalky. Whe saltX is added with the nitric acid and heated, a
colorless solution forms.
The solution containing the cation of X is added with dilute hydrochloric acid
and is shaken gently. The formation of white precipitated indicates the presences
of Ph2 ions.
(c)- step 1;
- pour 25 cm3 of 1 mol dm3 magnesium sulphate solution in a beaker and add
with 25cm3 of mol dm 3 potassium carbonate solution
- the mixture is stirred. White magnesium carbonate preticitated form is filtered
and dried in between filter papers
- the equation involved is
MgSO4 + K2CO3 MgCO3 + K2SO4
ANSWERS
PAPER 3
Question 1
(a) At temperature of 30C, time t1 = 50s

At temperature of 36C, time t2 = 44s
(b)
Temperature (C) 30 36 42 48 54
Time (s) 50 44 39 35 32
1/Time 0.020 0.023 0.026 0.029 0.031
(c) (i)
(ii) Rate of reaction is directly proportional to temperature.
(d) 30s
ANSWERS
(e) Increase in temperature increases the rate of reaction/The higher the temperature, the
higher the rate of reaction.
(f) (i) Manipulated variable : temperature of reaction
Responding variable : rate of reaction
Constant variables : concentrations and volumes of sodium thiosulphate and
hydrochloric acid
(ii) By heating sodium thiosulphate to various temperatures while maintaining

fixed concentration.
(g) The lower the temperature, the lower the rate of food spoilage.
Question 2
(a)
Initial temperature of NaOH 250C
Initial temperature of HCl 260C
Maximum temperature of the mixture 370C
(b) (i) NaOH + HC1NaC1 + H2 O
(ii) Average initial temperature

= (25 + 26) 0 C
2
0
= 25.5 C
The rise in temperature
= (37.0 25.5) 0 C
=11.5 0 C
Total energy released
= mc
= 200 4.2 11.5
= 9660 J
ANSWERS
(c) (i) Number of moles of NaOH
= 100 2.0
1000
= 0.2 mol
Number of moles of HCI
= 100 2.0
1000
= 0.2 mol
The heat of neutralisation

= - (1 9660)
0.2
= -48.30 kJ mol
Energy
NaOH + HC1
H = -48.30 kJ mol-
NaCI + H2 O
(d) (i) The plastic cup becomes hot.
(ii) The neutralisation reaction is an exothermic reaction.
(e) - A plastic cup must be used for this experiment.
- The mixture must be constantly stirred using the thermometer.

- The temperature has to be monitored closely throughout the experiment so
that the maximum temperature reached will be noted.
- The dilute acid has to be added as quickly and as carefully as possible to the
alkali.
ANSWERS
Question 3
(a) Aim of the experiment:

Is it true that vulcanised rubber is stronger than natural rubber?
(b) Hypothesis:
Vulcanised rubber is stronger and more elastic than natural rubber.
(c) List of substances and apparatus:

Latex, disulphur dioxide solution, a square glass pane, razor blade, beaker, weights,
thread, clip, retort stand, ruler.
(d) Procedure
A Preparation of the vulcanised rubber.
1)Latex was poured onto a piece of square glass pane.

2)The layer of latex was adjusted to acquire a thickness of 1 mm.
3)The layer of latex was then left aside for two to three.
4)The piece of rubber so formed was then cut into two pieces, each of equal size.
5)One of the pieces was dipped into disulphur dioxide solution for about five
minutes before being taken out and left to dry.
B Testing the properties of vulcanised rubber and natural rubber.
1) The piece of natural rubber was hung from a retort stand as shown in the figure
given.
2) The original length of the natural rubber was measured.
3) A weight of 50 g was then hung from the end of the rubber piece and the
extension of the rubber piece was measured.
4) After the weight was removed, the final length of the rubber piece was measured
again.
5) Steps 1 or 4 were then repeated for the piece of vulcanised rubber.
(e) Tabulation of data:

The measurements were recorded in the following table:
Type of rubber Original length Extension with the Final length when
(cm) weight added (cm) the weight is
remarked (cm)
Natural rubber
Vulcanised
Discussion:
Vulcanised rubber is stronger than natural rubber because the above results show that the
extension in the vulcanised rubber was smaller than that in natural rubber.
Vulcanised rubber is also more elastic than natural rubber because the vulcanised rubber
returned to its original length (final length = original length ) after the weight was
removed.

2007 Chemistry Times With Answer

Uploaded by

Document Information

Copyright

Available Formats

Share this document

Share or Embed Document

Sharing Options

Did you find this document useful?

Is this content inappropriate?

Copyright:

Available Formats

2007 Chemistry Times With Answer

Uploaded by

Copyright:

Available Formats

90

PAPER NO ITEM CONTENT

A Types of instruments Objective test

B Types of items Objective item; multiple choice each item either

50, answers all

G Level of difficulty Low-50%, Moderate-30%, High-20%

A Types of instruments Subjective test

PAPER Types of items

ii Section B 2 Questions (answer only one)

Types of instruments Written practice test

Types of question -Structured questions

Number of question 3 Questions

Time 1 hour 30 minutes

Construct requirement Problem solving: 100% (experimenting)

Level of difficulty Low-50%, Moderate-30%, High-20%

Analysis of Chemistry Paper

CONTOH KERTAS SOALAN CHEMISTRY

Instruction: Questions 1 to 50 are followed by four options A,B,C and D.

A. Potassium oxide C. Potassium choride

A. lead nitrate solution

A. Iron C. Tin A. volume of reactant

C. Zinc is the reducing agent

A. concentration of product increased

A. Silver chloride C. Mercury chloride A. X3+ + Y2- X2Y3

17. Which of the following material is an ionic compound? A. 3.76 g C. 5.04 g

The combustion of heptane in excess oxygen releases

Pair of metals Potential Metal at negative A. Rb, K, Na, Li

X and copper 0.45 X

and Z? I Al3+ III Pb2

28. Figure 3 shows the set-up apparatus for a displacement D.

Copper H = -57 kJ mol-1

What is observed after 10 minutes? The diagram can be concluded that

A. Gas bubbles are released A. the heat of neutralization is -57 kJ mo

C(s) + 2S (s) CS2 (l), H= +88 kJ mol -1

Anode Cathode Which of the following statements is true according to the

B. Oxygen Potassium A. the breaking of bonds in carbon and sulphur absorbs

manganate(IV) peroxide solution III Phosphorus pentoxide

time (s) time (s)

43. The tables shows the proton numbers of four elements;

Which of the following pairs of elements will form a

A. E and H C. F and H The carbon compound that is produced

A. I and II only C. II and IV only

I This gas can dissolve in water and turns damp blue

A. I and II only C. II and III only

49. Which of the following is a characteristic of copper?

I It can conduct electricity in both solid and molten

A. I and II only C. II and IV only

50. When exposed to air, fats and oils will be oxidised.

1. Table 1 shows four substances and their respective formulae

Substances Chemical Formulae

a) Use information from Table 1 to answer the following questions.

(v) Draw the arrangement of particles in the substance in (a) (iv).

(i) State the melting point of naphthalene.

(ii) Explain why there is no change in temperature from Q to R.

Carbon Dioxide Sodium Oxide

(a) State the redox reaction in Combustion tube I

(i) State the observations made in the two combustion tubes.

(c) (i) Name gas X

(a) Name the type of drugs P,Q and R

(b) Explain the function of the respective drugs

Glucose CH3CH2OH CH3COOH

CH2 = CH2 CH3COOCH2CH3

(a) What is process I?

ii. What is a physical property of the product formed in process IV?

Times, t1 = s Times, t2 = s Times, t3 = s

Times, t4 = s Times, t5 = s