Tabla de datos experimentales

Temperatur Presin 1 Presin Presin 1 Presin Masa

aK mmHg acido atm acido atm acido
mmHg
0.0210526 0.0368421 11.663
303.15 16 28 3 05
0.0407894 0.0578947
313.15 31 44 7 37
0.0421052 0.0881578
323.15 32 67 6 95
0.0526315 0.1276315
333.15 40 97 8 79
Secuencia de clculos
Determinacin de la presin
P=Pacido Paire

P=( 0.0368421050.02105263 ) atm= 0.01578947 atm

P=( 0.0578947370.04078947 ) atm= 0.01710526 atm

P=( 0.0881578950.04210526 ) atm= 0.04605263 atm

P=( 0.1276315790.05263158 ) atm= 0.075 atm

Presin de la no disociacin
11.663 g
moles de acido= =0.1943 mol
g
60
mol

atml
Pi =
(
( 0.1943 mol ) 0.082
mol K )
( 303.15 k )
= 48.3216351 atm
0.1 l

atml
(0.1943 mol)( 0.082 )(313.15)
mol K 49.9156194 atm
P i= =
0.1 l

atml
(0.1943 mol)(0.082 )(323.15 k)
mol K 51.5096037 atm
Pi = =
0.1 l
 atml
(0.1943 mol)(0.082 )(333.15 k )
mol K 53.1035881 atm
Pi = =
0.1 l

Calculo de la constante de equilibrio

2
2 PiP

4
Ka=

Ka=4 ( 248.32160.01578 )= 386.509923

Ka=4 ( 249.91560.0171 ) = 399.256534

Ka=4 ( 251.50960.04605 )= 411.892619

Ka=4 ( 253.10350.075 )= 424.528705

1
Calculo y graficacion de vs ln K a vs
T

ln ( 386.509923 )= 5.957157541

ln ( 399.256534 ) = 5.989604153

ln ( 411.892619 )= 6.020762683

ln ( 411.892619 )= 6.050272707

1
303.15 =0.003298697

1
= 0.003193358
313.15

1
= 0.003094538
323.15

1
= 0.003001651
333.15
 grafica ln(ka) vs 1/T

f(x) = - 0x + 0.02

cal
H=0.00321.987=6.358 x 104
mol k

H de disociacin

H
H de disociacin=
2

4 cal
6.358 x 10
mol k cal
H de disociacin= =3.179 x 104
2 mol k

Calculo de S

H
S=
T

cal
6.358 x 104 cal
mol k =-2.09744E-05
S= mol
303.15 k

4 cal
6.358 x 10 cal
mol k =-2.03046E-05
S= mol
313.15
 4 cal
6.358 x 10 cal
mol k
S= = -1.96763E-05 mol
323,15

4 cal
6.358 x 10 cal
mol k
S= = -1.90857E-05 mol
333.15