Saad Rashed

Model answer for second booklet

1- Maekownikoff's rule

2- due to weak overlapping between its covalent bond as a result of its small bond angle
(60)
3- Because water make a co-ordinate bond with acid-proton by its lone-pairs of (e)
forming H3O+
S.T
4- CO2 + Ca(OH) CaCO3 + H3O
CaCO3 + H2O + CO2 Ca(HCO3)2

5- Red pot Cu = 0.34 ( Cathode )

Red pot Zn = -0.76 ( Anode )
E M F = R p c - RpA = 1.1 Volt

6- state of equilibrium between the unionized molecules of weak electrolyte and its ions
when the rate of dissociation equals the rate of association.

7- 2FeSO4 Fe2O3 + SO2 + SO3

8- Cu, zn both are completely filled

9- To decrease pH value which prevent the growth of bacteria

10- Tri-basic
11- tertiary
12- C
13- It given violet color with phenol and no change with ethanol
14- H = HP- Hr = -400-(-150) = -250 kj/mol
15- exo H = - HP < Hr
16) -50-(-150) = 100 kj

17- red agent +( equation phenol + zn ...

18- electrode acting as anode and corroded instead of iron used specially in moist so
it for iron - pipes protection

19- Iron in medical field used in manufacture of surgical tools and mainly in concrete,
pylons
 Saad Rashed
Model answer for second booklet

20- C
21- Al2(CO3)3 2Al+3 + 3CO3- -
2X 3X
2
(2X) (3X)3
=108X5
22- It forms non porous layer of its oxide has a larger radius than iron atoms prevents the
reaction to continue
23- H+ = 2X0.2=0.4
pH= -log(0.4) =0.39
24- Using H2SO4 to absorb water that prevents reversible reaction
25- propanoic acid, ethyl alcohol
26- C2H5COOC2H5
27- C4H9COOH pentanoic acid
28- CuSO4 + H2S HCl CuS + H2SO4
CuS black ppt is formed

29- Na+ + e Na (s)

Cu++ + 2e Cu (s)
30- it decreases as AgNO3 will ppt Cl in form of AgCl
31 and 32 : Look at your book

33- neutrlization is
Acid + base salt + water
Hydrolysis
Salt + water acid + Base

34- A- H2O B- O2
C -Water(v)
35- 2H2 + O2 2H2O
120 60 0.6
36- M = = =
96500 65000 1

37- 1) lightest metal

2) lowest red pot = -3.04

38- = =3

nx = 3 , ny = 1
so y-3 x+1
Mf = X3Y
 Saad Rashed
Model answer for second booklet

39- C2H2 : Color discharge

C6H6 : Color remains
40- mix CO - H2 by fisher-tropsch
method using iron as catalyst
41- NH3 + HCl NH4Cl white fumes
NH3 blue color
42- Solution in which a dy eq state between solute and solvent a certain temp when solute
reach its max degree of solubility

43- H2 + I2 2HI
Colorless violet colorless

the reaction mic color is pale violet as the reaction incomplete not colorless and the
color remains

44- C2H5OH 140 C2H5O C2H5 + H2O

45- C
46- C12H22O11 + H2O 2C6H12O6
47 -

48- Answered before

49 - look at your book