1

42. d=0.10 cm = ghr

2

r=0.05 cm

=?

1 g m 1 Kg 100 cm
=
2( cm s )( )
1000 3 9.8 2 (10 cm)(0.05 cm)(
1000 g
)(
1m
)

g
H O =1000
cm 3
2

N
=245
m

1
43. = ghr
2

t / C 10 15 20 25 30

h/ cm 7.56 7.46 7.43 7.36 7.29

/cm
3 0.9997 0.9991 0.9982 0.9971 0.9957

r = 0.2mm
t 10
1 m g 100 cm 0.1 cm
= (7.76 cm)(9.8 2 )(0.9997 3 )(0.2 mm)( )( )
2 s cm 1m 1mm

3
=73.06 10

t 15

1 m g 100 cm 0.1cm
= (7.46 cm)(9.8 2 )(0.9991 3 )(0.2mm)( )( )
2 s cm 1m 1 mm

=73.0 .4 103
 t 20

1 m g 100 cm 0.1 cm
= (7.43 cm )(9.8 2 )(0.9982 3 )(0.2 mm)( )( )
2 s cm 1m 1 mm

=72.68 103

t 25
1 m g 100 cm 0.1cm
= (7.36 cm)(9.8 2 )(0.9971 3 )(0.2mm)( )( )
2 s cm 1m 1 mm

=71.92 103

t 25

1 m g 100 cm 0.1 cm
= (7.29 cm )(9.8 2 )(0.9957 3 )(0.2mm)( )( )
2 s cm 1m 1 mm

=71.13 103

N g
44. =7. 28 102 t=20 =0.998 3
m cm

N g
=5.8 102 t=100 =0.958 3
m cm

Para 1mm
1
= hgr
2

N 1 m g 1 Kg 0.1 cm 100 cm
5.8 102
m 2 ( )
= h 9.8 2 (0.9981 3 )(1 mm)(
s cm
)(
1000 g 1 mm
)(
1m
)

h=1.198

1
= hg
2

para 0.1mm
 N 1 m g 1 Kg
7.28 102
( )( )
= h 9.8 2 0.998 3 ( 0.1 mm )
m 2 s cm (
1000 g )( 0.11 mmcm )( 1001 mcm )
h=1.148 cm

2 N 1 m 0.998 g 1 Kg 0.1 cm 100 cm

5.8 10 = h(9.8 2 )( )(01 mm)( )( )( )
m 2 s cm3
1000 g 1 mm 1m

h=11.86cm

45. =ghr

N Kg m
0.072
m m s ( )
=100 3 9.8 2 h (1 102 m0.98 102 m)

h=0.03623 m

n1 t 1 1
46. = ( ) para el agua
n2 t 2 2

n1 1.52 min 1 cm3

= (
n2 2.25 min ) ( )
0.8 3
g
cm
a 20 n1=0.01005 poises

0.01005 poises
=0.844 4
n2

n2=0.011962 poses ( 1001poises

CP
)
n2=1.19 104 CP

47.
48. recorrido libre a rendir aire
2
0.43 n m

t=25 298 K

a. 10 atm k =1.38 10
23

b. 1 atm

c. 106 atm

A.

a= 0.43 n m2

P 10 atm 1.013 105

n P= =
Kt 1.38 1023 298

26
a=0.6557 nm n P=2.46 10

1
a=0.65 109 nm I=
4 a2 nP

1
I= 9 2 I =7.65 10
10
4 ( 0.65 10 ) (2.46 1026)

B.

a= 0.43 n m2

P 1 atm 1.013 10 5
n P= =
Kt 1.38 1023 298

a=0.6557 nm n P=2.46 10 25

1
a=0.65 109 nm I=
4 a2 nP

1
I= 9 2 25 I =7.65 10
9
4 ( 0.65 10 ) (2.46 10 )

C.
 a= 0.43 n m2

P 106 atm 1.013 105

n P= =
Kt 1.38 1023 298

a=0.6557 nm n P=2.46 10 19

1
a=0.65 109 nm I=
4 a2 nP

1
I= I =5.57 10
3
9 2
4 ( 0.65 10 ) (2.46 1019)

50.
t=1 s .
d (O ) 178 pm
2

T =25
d ( N ) 185 pm
2

P=1 atm

A.
1
P1 N A 2
Z=
1 2 RT
d
2 1 2 ( )( 2
RT )
=3.31 1033 m3 s1

z 12=
1 2 8RT
2
d 12
[ ( )( 1 1
+
M M )] ( PRTN )( PRTN )=2.66 10
1 A 2 A 34
m3 s1

51.

V=
3 RT
M
H=4 g /mol = 4 103 K g /mol

helio
 J
8.314 77 k
mol k

T =77 K 4 103 Kg /mol
3

=

T =2 93 K =1363.15 m/ s

T =1000 K =24.97 m/s

metano

J
8.314 77 k
mol k

T =77 K 16 103 Kg/mol
3

=

T =293 K =681.57 m/s

T =1000 K =1248.55 m/ s

52. V =? C H 4 P=200 atm t=0 Z=0.79

M
C H 4 =16 PV =R x t x ( PM )(Z)
0.79
64
200 =(0.082)(273015)( ) )
16

=0.35L

53.
V 2=V 1

V 2=0.994 V 1
 V =0.994 V 1V 1=0.001V 1

0.0001V 1
%V = 100 =0.1
V1

V 1=1 L P1=1 atm

V 2= P2=1 1atm

1 L 1 atm
V 2= =0.09 L
11 atm

V =0.09 L1 L=0.091 L

0.91 L
%V = 100 =91
1L

Si V 1=1 L

V 2=1 Le1.24 10 (5020)

V 2=1.038 L

(1.0381) L
%V = 100 =3.8
1L

313 k
V 2=1 L
293 k =1.102L

(1.1021)L
%V = 100 =10.2
1L

54. Mismo intervalo a presin cte

Para 1

P1 V 1=R t 1

V =V 2V 1

R t 2 R t1
V =
P2 P1

t2 t1
V =
P2 P 1

Para V2
P2 V 2 =R t 2

Problema 55
5

V 2=V 1 e(9.3 10 )(111)

V 2=0.999 V 1

V =0.009V 1V 1=0.001V 1

0.001 V 1
%V = 100 =0.1
V1

b)

1 L 1 atm
2= =0.09 L
1 atm
V

V =0.009 L1 L=0.91 L

0.91 L
%V = 100 =0.91
1L