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Toxicological Data on Ingredients: Potassium dichromate LD50: Not available. LC50: Not available.
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The substance may be toxic to blood, kidneys, lungs, liver, upper respiratory tract, skin, eyes.
Repeated or prolonged exposure to the substance can produce target organs damage. Repeated exposure to a
highly toxic material may produce general deterioration of health by an accumulation in one or many human
organs.
Skin Contact:
After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin
with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin.
Cold water may be used. Cover the irritated skin with an emollient. If irritation persists, seek medical attention.
Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention.
Serious Inhalation:
Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or
waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth
resuscitation. Seek medical attention.
Ingestion:
Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not
breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention.
Special Remarks on Explosion Hazards: Reacts explosively with hydrazine, and anydrous hydroxylamine.
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Section 6: Accidental Release Measures
Small Spill: Use appropriate tools to put the spilled solid in a convenient waste disposal container.
Large Spill:
Oxidizing material.
Stop leak if without risk. Avoid contact with a combustible material (wood, paper, oil, clothing...). Keep substance
damp using water spray. Do not touch spilled material. Prevent entry into sewers, basements or confined areas;
dike if needed. Call for assistance on disposal. Be careful that the product is not present at a concentration level
above TLV. Check TLV on the MSDS and with local authorities.
Storage: Oxidizing materials should be stored in a separate safety storage cabinet or room.
Personal Protection:
Splash goggles. Lab coat. Dust respirator. Be sure to use an approved/certified respirator or equivalent.
Gloves.
Exposure Limits:
CEIL: 0.1 (mg(CrO3)/m
) from OSHA (PEL) [United States]
TWA: 0.05 (mg(Cr)/m) from ACGIH (TLV) [United States]Consult local authorities for acceptable exposure limits.
Odor: Odorless.
Color: Orange-Red.
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Melting Point: 398C (748.4F)
Specific Gravity:
2.676 @ 25 deg. C(Water = 1)
Bulk Density: 1.6 g/m3 @ 20 deg. C
Solubility:
Easily soluble in hot water.
Soluble in cold water.
Solubility in water: 4.9 g/100 ml water @ 0 deg. C
Solubility in water: 10.5% (w/w) @ 20 deg. C
Solubility in water: 102 g/100 ml water @ 100 deg. C
Insoluble in alcohol.
Incompatibility with various substances: Reactive with reducing agents, combustible materials, organic materials, metals,
acids, alkalis.
Polymerization: No.
Toxicity to Animals:
Acute oral toxicity (LD50): 25 mg/kg [Rat].
Acute dermal toxicity (LD50): 14 mg/kg [Rabbit].
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Chronic Effects on Humans:
CARCINOGENIC EFFECTS: Classified A1 (Confirmed for human.) by ACGIH.
MUTAGENIC EFFECTS: Mutagenic for mammalian somatic cells. Mutagenic for bacteria and/or yeast.
May cause damage to the following organs: blood, kidneys, lungs, liver, upper respiratory tract, skin, eyes.
Products of Biodegradation:
Possibly hazardous short term degradation products are not likely. However, long term degradation products may
arise.
Toxicity of the Products of Biodegradation: The products of degradation are more toxic.
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chromium would remain as suspended matter and ultimately be deposited in the sediments. Chromium present
usually as (CrIII) in the soil and is characteriszed by its lack of mobility, except in cases where Cr(VI) is involved.
Chromium (VI) of natural origin is rarely found.
Identification: : Toxic Solids, Oxidizing, n.o.s (Potassium Dichromate) UNNA: 3086 PG: I
Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200).
Other Classifications:
WHMIS (Canada):
CLASS C: Oxidizing material.
CLASS D-1A: Material causing immediate and serious toxic effects (VERY TOXIC).
CLASS D-2A: Material causing other toxic effects (VERY TOXIC).
DSCL (EEC):
R21- Harmful in contact with skin.
R25- Toxic if swallowed.
R26- Very toxic by inhalation.
R37/38- Irritating to respiratory system
and skin.
R41- Risk of serious damage to eyes.
R43- May cause sensitization by skin
contact.
R46- May cause heritable genetic
damage.
R49- May cause cancer by inhalation.
R50/53- Very toxic to aquatic
organisms, may cause long-term
adverse effects in the aquatic
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environment.
S45- In case of accident or if you feel unwell,
seek medical advice immediately (show the
label where possible).
S53- Avoid exposure - obtain special
instructions before use.
S60- This material and its container must be
disposed of as hazardous waste.
S61- Avoid release to the environment. Refer to
special instructions/Safety data sheets.
HMIS (U.S.A.):
Health Hazard: 4
Fire Hazard: 0
Reactivity: 0
Personal Protection: E
Health: 4
Flammability: 0
Reactivity: 0
Specific hazard:
Protective Equipment:
Gloves.
Lab coat.
Dust respirator. Be sure to use an
approved/certified respirator or
equivalent. Wear appropriate respirator
when ventilation is inadequate.
Splash goggles.
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