Professional Documents
Culture Documents
Fill in the blanks (In some cases you may have to choose among some given options in
bracket)
3. Silver chloride is sparingly soluble in water because its lattice energy is greater than
.. energy. (1987-1 Mark)
8 When Fe(s) is dissolved in aqueous hydrochloric acid in a closed vessel, the work done
is.. (1997-1 Mark)
9. Silver Jewellery items tarnish slowly in the air due to their reaction with.
(1997-1 Mark)
True/False
3. Silver chloride is more soluble in very concentrated sodium chloride solution than in pure
water. (1984-1 Mark)
4. Dipositive zinc exhibits paramagnetism due to loss of two electrons from 3d-orbital of neutral
atom. (1987-1 Mark)
5. Both potassium ferrocyanide and potassium ferricyanide are diamagnetic (1989-1 Mark)
4. In the metallurgy of iron, when limestone is added to the blast furnace, the calcium ion ends
up in
(A) slag (B) gangue
(C) metallic calcium (D) calcium ion carbonate (1982-1 Mark)
6. Amongst the following the lowest degree of paramagnetism per mole of the compound at
298 K will be shown by
(A) MnSO4.4H2O (B) CuSO4.5H2O
(C) FeSO4.6H2O (D) NiSO4.6H2O (1988-1 Mark)
7. Read the following statement and explanation and answer as per the options given below:
Statement (S): To a solution of potassium chromate if a strong acid is added it changes its
colour from yellow to orange
Explanation (F) The colour charge is due to the oxidation of potassium chromate.
Code
(A) Both (S) and (E) are correct and (E) is the correct explanation of (S)
(B) Both (S) and (E) are correct but (E) is not the correct explanation of (S)
(C) (S) is correct but (E) is wrong
(D) (S) is wrong but (E) is correct. (1988-2 Marks)
11. Which compound is formed when excess of KCN is added to aqueous solution of copper
sulphate?
(a) Cu(CN)2 (b) K2 [Cu(CN)4]
(c) K[Cu(CN)2] (d) K3[Cu(CN)4] (1996-1 Mark)
13. An aqueous solution of FeSO4. Al2(SO4)3 and chrome alum is heated with excess of Na2O2
and filtered. The materials obtained are:
(a) a colourless filtrate and a green residue (b) a yellow filtrate and a green residue
(c) a yellow filtrate and a brown residue (d) a green filtrate and a brown residue
(1996-1 Mark)
14. Among the following, the compound that is both paramagnetic and coloured is
The Transition & Co-ordination Compounds 3
15. Ammounium dichromate is used in some fireworks. The green coloured powder blown in the
air is
(a) CrO3 (b) Cr2O3
(c) Cr (d) CrO(O2) (1997-1 Mark)
16. The number of moles of KMnO4 that will be needed to react with one mole of sulphite ion in
acidic solution is
(A) 2/5 (B) 3/5
(C) 4/5 (D) 1 (1997-1 Mark)
18. Read the following statement and explanation and answer as per the options given below:
Assertion: Zn+2 is diamagnetic.
Reason: The electrons are lost from 4s orbital to form Zn+2
(a) If both assertion and reason are correct, and reason is the correct explanation of the
assertion.
(b) If both assertion and reason are correct, but reason is not the correct explanation of the
assertion.
(c) If assertion is correct but reason is incorrect.
(d) If assertion is incorrect but reason is correct. (1998-2 Marks)
21. The chemical processes in the production of steel from haematite ore involve
(a) reduction (b) oxidation
(c) reduction followed by oxidation (d) oxidation followed by reduction
(2000-Scr.)
22. The complex ion which has no d electrons in the central metal atom is
(A) [MnO4] (B) [Co(NH3]6]3+
3
(C) [Fe(CN)6] (D) [Cr(H2O)6]3+ (2001-Scr.)
24. When MnO2 is fused with KOH, a coloured compound is formed, the product and its colour
is:
(A) K2MnO4, purple green (B) KMnO4, purple
(C) Mn2O3, brown (D) Mn3O4 black (2003-Scr.)
The Transition & Co-ordination Compounds 4
[X] + Zn [Y] + Au
Identify the complexes [X] and [Y]
(A) X = [Au(CN)2], Y = [Zn(CN)4]2 (B) X = [Au(CN)4]3, Y = [Zn(CN)4]2
4
(C) X = [Au(CN)2] , Y = Zn(CN)6] (D) X = [Au(CN)4], Y = [Zn(CN)4]2
(2003-Scr.)
30. Which of the following pair is expected to exhibit same colour in solution?
(A) VOCl2 ; FeCl2 (B) CuCl2; VOCl2
(C) MnCl2 ; FeCl2 (D) FeCl2 ; CuCl2 (2005-Scr.)
Multiple Choice Questions with ONE MORE THAN ONE correct answer: I
2. The aqueous solutions of the following salts will be coloured in the case of
(a) Zn(NO3)2 (b) LiNO3
(c) Co(NO3)2 (d) CrCI3
(e) Potash alum (1990-1 Mark)
3. Among the following ions which one has the highest paramagnetism?
(a) Cr(H2O)6]3+ (b) [Fe(H2O)6]+2
+2
(c) [Cu(H2O6)6] (d) [Zn(H2O)6]+2 (1993-1 Mark)
5. In nitroprusside ion the iron and NO exist as Fe +2 and NO+ rather than Fe+3 and NO. These
forms can be differentiated by .
(a) estimating the concentration of iron
The Transition & Co-ordination Compounds 5
6. Addition of high proportions of manganese makes steel useful in making rails of railroads,
because manganese
(a) gives hardness to steel (b) helps the formation of oxides of iron
(c) can remove oxygen and sulphur (d) can show highest oxidation state of + 7
(1998-2 Marks)
Subjective Problems
2. An unknown solid mixture contains one or two of the following: CaCO 3, BaCl2, AgNO3,
Na2SO4, ZnSO4 and NaOH. The mixture is completely soluble in water and the solution gives
pink colour with phenolphthalein. When dilute hydrochloric acid is gradually added to the
above solution, a precipitate is produced which dissolves with further addition of the acid.
What is/are present in the solid? Give equations to explain the appearance of the precipitate
and its dissolution. (1981-2 Marks)
(xxii) Write a balanced equation for the reaction of argentite with KCN and name the
products in solution. (1996-1 Mark)
(xxiii) Write balanced equations for the oxidation of cuprous oxide to cupric hydroxide by
alkaline KMnO4. (1997-1 Mark)
(xxiv) Write balanced equations for the reaction of alkaline perbromate with zinc giving
tetrahydroxozincate anion. (1997-1 Mark)
(xxv) Write balanced equations for the reaction of zinc with dilute nitric acid.(1997-1 Mark)
4. Give balanced equations for extraction of silver from its suiphide ore. (1982-2 Marks)
6. State the conditions under which the following preparation is carried out. Give the necessary
equations which need not be balanced.
Potassium permanganate from manganese hydroxide (1983-1 Mark)
8. Mention the products formed when Zinc oxide is treated with excess of sodium hydroxide
solution. (1986-1 Mark)
9. What is the actual reducing agent of haematite in blast furnace? (1987-1 Mark)
10. The acidic, aqueous solution of ferrous ion forms a brown complex in the presence of NO3- ,
by the following two steps. Complete and balance the equations:
[Fe(H2O)6]+2 + NO3- + H+ . + [Fe(H2O)6]+3 + H2O
[Fe(H2O)6] + ..........
+2
........ + H2O (1992-2 Marks)
13. Compare qualitatively the first and second ionization potentials of copper and zinc. Explain
the observation. (1996-2 Marks)
14. Write the IUPAC name of the compound [Cr(NH3)5(NCS)] [ZnCl4] Is this compound
coloured? (1997-2 Marks)
15. Write equations for the reaction of: (1997-1 Mark each)
(i) silver bromide with hypo in photographic process.
(ii) cobaltous chloride with excess KNO2, in aqueous acidic solution.
16. Write the formulae of the following complexes: (1997-1 Mark each)
The Transition & Co-ordination Compounds 7
18. Work out the following using chemical equations. In moist air copper corrodes to produce a
green layer on the surface. (1998-2 Marks)
19. A, B, and C are three complexes of chromium (III) with the empirical formula H 12O6Cl3Cr All
the three complexes have water and chloride ion as ligands. Complex A does not react with
concentrated H2SO4 whereas complexes B and C lose 6.75% and 13.5% of their original
mass, respectively, on treatment with concentrated H2SO4 Identify A, B and C.
(1999-6 Marks)
20. Write the chemical reaction associated with the brown ring test. (2000-2 Marks)
21. Draw the structures of [Co(NH3)6]3+ [Ni(CN)4]2 and [Ni(CO)4] Write the hybridization of
atomic orbitals of the transition metal in each case. (2000-4 Marks)
22. (i) Write the chemical reactions involved in the extraction of metallic silver from argentite.
(ii) Write the balanced chemical equation for developing photographic films. (2001-2 Marks)
23. A metal complex having composition Cr(NH 3)4 Cl2Br has been isolated in two forms (A) and
(B). The form (A) reacts with AgNO3 to give a white precipitate readily soluble in dilute
aqueous ammonia, whereas (B) gives a pale yellow precipitate soluble in concentrated
ammonia Write the formula of(A) and (B) and state the hybridization of chromium in each
Calculate their magnetic moments (spinonly value). (2001-5 Marks)
24 Deduce the structure of [NiCl4]2 and [Ni(CN)4]2 considering the hybridization of the metal
Calculate the magnetic moment (spin only) .of the species. (2002-5 Marks)
25. Write the IUPAC nomenclature of the given complex along with its hybridization and
structure K2[Cr(NO)(NH3)(CN)4], = 1.73 BM (2003-4 Marks)
26. Nickel chloride, when treated with dimethylgyloxime in presence of ammonium hydroxide,
a bright red precipitate is obtained Answer the following. (2004-4 Marks)
(a) Draw the structure of the complex showing H-bonds
(b) Give oxidation state of nickel and its hybridization
(c) Predict the magnetic behaviour of the complex
27. A1 & A2 are two ores of metal M. A1 on calcination gives black precipitate, CO2 & water.
n Black solid + CO2 + H2O
atio
l cin
Ca
A1 dil HCl
KI I 2 ppt
A2
roasting Metal gas
K 2 Cr2 O 7 H 2SO 4
29. Write balanced chemical equation for developing a black and white photographic film. Also
give reason why the solution of sodium thiosulphate on acidification turns milky white and
give balance equation of this reaction. (2005-4 Marks)
Moist air Zn
(B) MCl4 (A)
white fumes having smell (M = transitionelement colourless)(purple color)
Identify the metal M and hence MCl4. Explain the difference in colours of MCl4 and A.
(2005-4Marks)
The Transition & Co-ordination Compounds 9
ANSWERS
B 1. F 2. T 3. T 4. F
5. F 6. T
E 2. ZnSO4 NaOH
8. sodium zincate, water 9. CO 11. (iii), (iv)
12. (i) pentamminenitritocobalt (III) chloride
(ii) potassium hexacyanochromate (III)
(iii) pentamminecarbonatochromium (III) chloride
14. pentammine isothiocyanotochromium (III) tetra chlorozincate
16. (i) [CoCl(NH3)5]2+ (ii) LiAlH4
19. [Cr(H2O)6]Cl3, [Cr(H2O)5Cl](H2O)Cl2, [Cr(H2O)4Cl2](H2O)2Cl
23. [Cr(NH3)4BrCl]Cl, (d2sp3), [Cr(NH3)4Cl2]Br, (d2sp3), 3.87 BM, 3.87 BM
25. Potassium aminetetracyanonitrosoniumchromate (I), octahedral shape
26. (b) +2, dsp2, (c) diamagnetic
27. CuCO3, Cu(OH)2, Cu2S, Cu, CuO, Cu2I2, SO2
28. Fe(SCN)3, [FeF6]3; trithiocyanoiron (III); 5.92 BM
30. [Ti(H2O)6]Cl3, HCl, TiCl4