Sec: Sr.

IPLCO JEE-Advanced_GTA
Paper-1_Key & Solutions
KEYSHEET

Physics:
(01) B (02) C (03) C (04) B (05) A (06) B (07) D

(08) C (09) D (10) D (11) ACDorAD (12) AD (13) ACD (14) ABC

(15) ABCD (16) 5 (17) 2 (18) 5 (19) 1 (20) 2

Chemistry:
(21) C (22) A (23) D (24) B (25) A (26) A (27) C

.in
(28) C (29) D (30) A (31) BCD (32) ABCD (33) BD (34) BC

(35) ABC (36) 5 (37) 5 (38) 5 ay

(39) 1 (40) 2
2d
Mathematics:
bs

(41) D (42) C (43) A (44) D (45) B (46) B (47) B

.jo

(48) A (49) D (50) B (51) AD (52) AC (53) ABC (54) ABCD

w

(55) BCD (56) 4 (57) 7 (58) 9 (59) 4 (60) 6

w
w
 JEE-Adv_GT_P1_sol
HINTS
PHYSICS
dist R V
01. Average speed
tim e 2R / V 2

02. Phase difference between the waves at A is

2
x 0

2
C t 0

t 0

1 2

2 6 3

A A 1 A 2 2A 1 A 2 cos 5
2 2

.in

Vm 2V m
03. V av
sin d
ay
0
2d
2 2
2 Vm 2 Vm
V
eff


sin d 2
0
bs

g
04. In the tunnel, motion of the particle is simple harmonic with angular frequency . Just
.jo

g
before collision, V0 A R
w

gR
R
w

Just after collision, v eV0 gR / 5

w

Let new amplitude be A | , then

v gR / 5 R
A
1

g/R 5

7R
Net distance R R / 5 R / 5
5

5. Let x 1 a sin t and x 2 a sin t be two S.H.M.s

a a
a sin t and a sin t
3 3

1 1
sin t and sin t
3 3

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1 1 1
Eliminating t, cos 1 sin cos 8 1 cos 1
2

3 9 3

8 1 cos 1 cos
2 2

8 8 co s 1 co s 2 co s 0
2 2

9 co s 2 co s 7 0
2

co s 1 or 7/9 i.e., 1 8 0 0 or cos 1 7 / 9

Now 1 a cos t and 2 a co s t

If we put 1 8 0 0
We find that 1 and 2 are of opposite signs.

Hence 1 8 0 0 is not applicable.

cos
1
7 / 9

.in
6. Let y is the additional length immersed. Distance of bottom face of cube from free surface of

liquid is z
L
2
y yz
L
2
ay
2d
Again, tension = extra force of buoyancy developed
L 2
T y L g z L g
bs

2
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2
L
T L g z g
2

2
w

T k 1 z k 2 upto z = L
w

After z = L, buoyancy and hence T does not change as the body is completely immersed.
w

7. Initially for half revolution when magnet moves towards the loop, flux increases
clockwise current .

When magnet moves away from the loop, flux decreases anticlockwise current

8. Bd 1 0
I enclosed

Since I enclosed is same

9. Q nC T

Here Q is same for all the processes bout W I ve, W II ve and W III 0 and
U W Q

U I U III U II TI TII TIII

C I C III C II

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10.

Area of dielectric slab = A

Area of plate of capacitor = 2A
After time t slab will cover distance vt inside the capacitor and let A l b
Now capacitance at time t
K ( vt b ) 0 (l vt ) b 0
C(t)
d d

Q (t ) C V C C (t )

dQ ( t ) Kv b0 vb 0

.in
I
dt d d

(K 1) vb 0
I
d
constant ay
2d
i.e. I constant
Also when slab totally enters the capacitor after that it goes out from the other side, it will
bs

move inside the capacitor for some time with C remaining constant and than C will start
decreasing. So current will reverse its direction.
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11. As slab is pulled out of capacitor B capacitance of B decreases.

w

B
w

A
w

a b
Now consider given circuit
As capacitance of B decreases net capacitance also decreases
C1 C2

q C V i .e . charge on A decreases i.e., +charge moves from a to b but still A and B are in
series
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Q A QB

External force F does work while taking slab out. This work (energies) is partly absorbed
by battery since it does ve work and rest appears as heat in circuit since charge is flown.
20 V 20 8
12. For circuit (A) I A 2A
6 6

20
For circuit (B) I A 5A
4

For circuit (c) I A 0

(Balanced Wheatstones Bridge)
For circuit (d) 6 is in parallel with 6 6 1 2
6 12
Their effective resistance is 4
6 12
Net resistance of the circuit 4 6 1 0

.in
I A 20 / 10 2 A
13. As the train moves with constant velocity, a frame attached to it will be inertial. With respect
ay
to train, the bob is in circular motion with necessary centripetal force provided by tension.
Use the formula, V V V to find velocity of bob with respect to ground.
2d
b ,G b ,t t ,G

14.
y
bs

L is parallel to k
M L is parallel to k
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L 0 about po int s onthis line

P
w

45
w

x
O
L Lv
L Lv
w

about po int s onthis line N

nhf
15. Intensity I where n = no.of photons falling on the metal per second.
A

Saturation photo current i n

KE max hf W 0

h W0
Stopping potential V 0
f
e e

16.

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P

A
A
A
Q R

2A
2A
2A

A
2A
2 2 2 2

5A

2 2

A 36
5

.in
17. Let us denote the final volume and pressure by V ' 1.25V0 and P ' , respectively. Taking
ay
helium to be an ideal gas, we can write that P0 V0 P ' V ' under isothermal conditions, so that
P ' 0.8P0 . Since the external pressure is 0.5P0 , then net outward pressure on the surface of
2d
the balloon is 0.3P0 . Thus the net pressure of the balloon is 0.3P0 . Thus the net pressure
bs

force on half of the balloon is 0 .3P R 2 , where R is the final radius of the balloon, given by
1.25 V 0 4 R / 3 .
.jo

3
But this must just balance the elastic force A , where A 2 R t is the
cross-sectional area of the balloon material at its mid-plane. Here t is the thickness of the
w

balloon material, obtained from m / 4 R 2 t .

w

0 .3P R 2
2 R t
w

0.3P0 R 4 R 3P0 3 P0 5
2
0.3P0 R
4 R 3 4 3V 0
2t 2 m 20 m 20 m

9 P0 V0 9 P0 8 1500 750
P0
16 m 16 18 2

340 10 330
18. fA 85 Hz
340 10 10 4

340 10 350
fB 85 Hz
340 10 10 4

f beat f B f A 5 Hz

19. The change in internal energy of the gas is

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 JEE-Adv_GT_P1_sol
25
U 1.5 nR ( T ) 1.5(1 mol ) J / m ol K (2 K ) 25 J
3

The heat given to the gas = 42 J

The work done by the gas is
W Q U 42 J 25 J 17 J

If the distance moved by the piston is x, the work done

Is W (100 kPa )(8.5 cm ) x 2

Thus, (10 N / m )(8.5 10 m ) x 17 J

5 2 4 2

Or x 0 .2 m 2 0 cm = 2 10 m 1

20. Speed of C is maximum when A,B and C become collinear with C in between A and B.
Initial momentum of system =0. Form conservation of linear momentum and symmetry A
and B should move with half the speed of C at that instant in opposite direction.
KE i U i KE f U f

.in
V
Q Q
m m m
A
V
C
V
B ay
2d
2 2
2 2 2
KQ 1 V 1 KQ
O mV 2m
2
bs

2 2 2 2
2
3 KQ 1
mV 1 2
.jo

4
12
2 9 10 10
2 9
w

2KQ 1
V 4 V 2ms
2

3 m 3 3
3 10
w

2
w

CHEMISTRY
21. absence of H-bond
22. (A)
O
Mg 1.H C H
CH 3CH 2
CH 3CH 2 MgBr CH 3CH 2OH
2.H 3O
23. (D)
It is example of EAS reactio0n which involves Arenium ion intermediate
24. (B)
Cyclisation occurs by attack of -OH group on carbonyl group. In structure b), the relative
position of available OH groups. Can form upto 5 membered ring
25. (A)

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 JEE-Adv_GT_P1_sol
aT
2

RT b
C
P V
V
RT b
2
aT
P C
V V
C 1
P ( R T b )V aT V
2

So by comparing the equation with given equation

A RT b
B aT
2

m = -C
n = -1
26. (A)
Let there be 1 mol of iron atom. We will have
mols of Fe(III) = (1/4) mol
mols of Fe(II) = (3/4) mol

.in
Total positive charges = (l/4) (3) + (3/4) (2) = (9/4) mol
Let a be the amount of oxygen atoms. We have
Total negative charge = a (2)
To satisfy electrical neutrality, we have
ay
2d
Total positive charges = Total negative charge
9
mol = 2a or a = (9/8) mol
4
bs

Hence, composition of the compound is FeO9 /8 or Fe8 O 9

27. (C)
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2A B C

w

K [ B ][ C ]

w

[ B ] [C ]
2 30
[C ] 10
w

15
[C ] 10
15
10 mole ions in 1000 cc
So 10 18 mole ions in 1cc
6.023 10 23 10 18 ions/cc
28. (C)
(P) In a group the tendency to exhibit inert pair effect increase downwards
(Q) PbI 4 : because of more polarazability of I it act as reducing agent.
(R) SiO 2 : PbO 2 and SnO 2 are amphoteric in nature
(S) N H 3 : In VA group hydrides the M-H bond energy decrease down words the group and
thermal stability decreases.
29. (D) Conceptual
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 JEE-Adv_GT_P1_sol
30. (A)

Ag Ag e ; E 0.800 V
0

A gI e A g I ; E 0.152 V
0

A gI A g I ; E 0.952 V
0

0.0591
E E
0
log Q
n
0.0591
0 0.952 log K sp
1
log K sp 16.1

31. (C,D)
32. (A,B,C,D)
33. (B) (D)
34. (B,C)
35. (A,B,C)

NH 4 NO2
N 2 2 H 2O

.in
2 N H 3 3 C uo
N 2 3 H 2 O 3C u

3Ba( N 3 )2
B a3 N 2 8 N 2
36. y5
5 5
ay
2d
H RT 2 300 1500 calorie 300 y
2 2
bs

37. D-Fructose -L-Xylofuranose Maltose

L-Arabinose Lactose D-ribos
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w

38.
w

Cl O
w

+ CCl3 C H
H 2 SO4
CCl3 CH Cl

(DDT)
Cl

39. the orbital that can satisfy all the given conditions is only one i.e. 3 Pz
40. (2)
Bn+
B(n + 4)+
Millimole at t = 0 a 0 2e + Bn+
B(n - 2)+
t=t (a x) x 5e + B(n + 4) +
B(n 1)+
Let normality be N for reducing agent.

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 JEE-Adv_GT_P1_sol
Thus, at t = 0, V1N1 = V2N2
or, a 2 = N 25
25
a= N
2

and at t = t, (a x) 2 + x 5 = N 32
7
x= N
3

2.303 25 / 2 N 2.303 25 6
Now, K log log = 2.07 102 min1
10 25 7 10 2 61
N
2 3

MATHEMATICS
n n 1
n ( n 1)( n 2)( n 3) ( n 1) n ( n 1)( n 2)
41. tn tr tr
8

8
r 1 r 1
n ( n 1)( n 2)

.in

2

1
tn

2
n ( n 1)( n 2)
Define a n
2
( n 1)( n 2)
ay
then

4
2d
2 2
a n a n 1
( n 1)( n 2) n ( n 1) n ( n 1)( n 2)
bs

n
1 1 1 1
Thus
tn

2
( a n 1 a n ) . Hence tr

2
( a0 an )
r 1
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2
1 2 n 3n
1 (4)
2 ( n 1)( n 2) 2( n 1)( n 2)
w

2 r
w

2 r 2 r i
42. sin i cos ie 11 Hence
11 11
w

2 i 10

2

e i e 11 1
11

10
2 r 2 r
11 sin i cos i
2 i
11
r 1
e 11 1
2 i

i 1 e 11



i
2 i
e 11 1

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 JEE-Adv_GT_P1_sol
p
32 10 2 r 2 r
32

(3 p 2) sin 3 p 2 i
p
i cos
11 11
p 1 r 1 p 1
32 32

p p
3 pi 2 i
p 1 p 1
= 3 A 2 B (1)
32
2 3 32 i (1 i ) 32 i 32 i
A i 2 i 3i ....... 32 i 16(1 i )
2 1 i 1 i
(1 i )

32
i 1 i
32
0

p
B i A ns: 48(1 i )
1 i
p 1
22n 2n
Ci C j
2 cn
43. 2
2 2 2
n C C ....... C n 2 C iC j n 2 nc
0 1 n 2
0i j n 0i j n

.in
n 1 2 nc
2n
2
n
44. Total ways = 64 c
2
Favourable ways = 2 2 (1 2 .... 6 ) 7 9 8
ay
2d
98 7
Hence probability
32 63 144
bs

n r 2 n r 2 2r 4
n 2 19 28 39 n 2n 4
2
3 2 4 2
45. ........ ......
r 2 n 2 n 4
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2 2
r 3 r 2r 4
3 2 4 2 n 2 7 12 19
r 3

n 3 n 2 2 n 1
w

1.2.3.4
.
n 1 n n 1 n 2 7.12
w

n 3 (n
2
3) n 2
2n 4 2
w

r 8 2
lim lim
7 n ( n 1) n ( n 1)( n 2)
n r 3 r3 8 7

46. Let f ( x )
x
2
then f 1 ( x )

x 400 x
3
. Hence 1
f ( x) 0 for o x 3 400
x 3 200
3 2
x 200

And f 1 ( x ) 0 for x 3 400 . Hence longest term is a 7 or a8

49
Since a 7 a8 Maximum term a 7
543
47. The line y g x passes through the centre g , g
2 2 2
2g g g 2 g ( g 1) 1
[ 1, )

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 JEE-Adv_GT_P1_sol
48. Let xi , y i 1 i 4 be the points of intersection of the given curves From the given
2 4
2 5
equation x 1 4 r
2
xi 4
x 1 i 1
4
2 2
y 2
2
Also r yi 0
2
y 2 i 1

x x 2 x 3 y1 y 2 y 3 4 x 4 y 4
Centroid of ABC = 1 , ,
3 3 3 3
This lies on the line y 3 x 4
y 4 (4 x 4 ) 4 Hence locus of D is y 3 x (1)
3
49. A B i 2 j k and A C 6 i 3 j 3 k
Then A B 6 and A C 54 3 6 Now D divides BC in the ratio 1:3

3 i 2 j k 1 6 i 3 j 3 k 3i 9 j

.in
Internally Hence AD
4 4

AD
90
4

3 10
4
Ans : 4 ay
2d
7 4 2
50. cos x cos x 2 cos x 0
2 5 2
cos x 0 or cos x cos x 2 0
bs

2
cos x 0 x ,
2 2
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5 2
cos x cos x 2 0 co s x 1 x 2 n

w

Hence the roots in , , 0, Ans :B

2 2
w

1
51. Put 1 x . T hen
w

t
1
dt
t
2 dt dt
I
1 1 t 1 t
1
2
t
2
tt
2

1 2t t
2
1 3t t
2

t t t

dt 1 2t 3 1 3 x 1
sin c sin c
2 5 5 x 1
5 3
t
4 2

1 2
3x 1 1 2 1 x x c
sin c cos Ans : A,D
5 x 1 5 x 1

52. Equation of the tangent at P ( x1 , y1 ) is
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 JEE-Adv_GT_P1_sol
y y1 m ( x x1 )

y1
Put y=0 A x1 ,0
m

y1 x1 y 1 2a 2


Area of 2
O AP a m

dx
Or xy y 2 2a
2
dy
2
dx x a
2
dy y 2
y
1
dy
1
y
This is linear in x . I.F= e
y

.in
2 2
2a x a
Solution is dy c.
y 3 2

x cy
a
y
2
y

Ans : A,C
ay
2d
y

53. Let , be the roots of x 2 ax b 0 Then 1, 1 Now

bs

b 1 also f ( 1) 0 and f (1) 0

Thus 1 a b 0 and 1 a b 0 a b 1 and b a 1
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Ans : A,B,C
54. Assume (i), That is A B C A C C A . Now
w

ABC A B C AC CA AB BC CA AC AB BC
w

Thus ( A I )( B I )( C I ) A B C A B B C A C A B C I I
w

Inverse of C I ( A I )( B I ) ( C I )( A I )( B I ) I
CAB CA AB CB C A B I I
CAB CB BC
Then i and iii are equivalent. Similarly we get i and ii equivalent Ans: ABCD

4 2
1 x x 3 1 1
1
55. 1) tan tan x 1


x x
2

x
4
1

4
x 4

n
1 1
n
1 2 k 1 2 k 1 n 1 1
2) tan tan tan 2 k 1 tan 2 k 1
1 2 k 1 2 k 1 k 1
2
k 1 2k k 1
1
2 n 1 tan 1 1 1 1 1
tan tan 2 n 1 tan
4 2 2n 1 4

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 JEE-Adv_GT_P1_sol
1 1
= tan
4 2n 1
1 1
3) 0 x 1 0 tan x tan x 0 . Thus
4 4
1 1 1 1 1 1
2

4
sin x cos x tan x
2
0
4
sin x cos x tan x
2
1 4 7 5
4) sin sin and cos 1 cos Hence sum=
3 3 6 6 2
Ans : B,C,D
56. Rank of MOTHER = 2 (5 !) 2 ( 4 !) 3(3!) 1( 2 !) 0 (1!) 1
240 48 18 2 1 309 = 3 103
No of divisiors of 3 0 9 is 4
1 2
57. Taking A as origin, Let AB , AC the AK , AL
3 3
2

.in
s 6 3
Equation AL is r t and CK is r 1 s on solving we get s ,t .
3 3 7 7

Then A P
2
7
ay
2d
1 5 2 6

1 1 2
2=Area of B C P PB PC 14
2 2 7 7 49 7
bs

2 Area of A B C 7
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/2
2 x sin x x sin x sin x
58. I 2 4 4 dx
w

2 2 2
0
1 cos x 0
1 cos x 0
1 cos x
w

/2
4 tan 1
cos x 0
4 0 I 9
4
2
w

x cos y sin
59. Tangent equation in 1 (1)
a b

Auxillallary circle is x 2 y 2 a 2
2
x cos y sin
Homogonising we get x 2 y 2 a 2 =0
a b
cos 2 sin
2
These lines are perpendicular a 2 2
2 2
a b
2
2 a 2
cos sin 2
2
b

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 JEE-Adv_GT_P1_sol
2 2 2
a 2 2 a 1 sin
sin sin 1
2 2 2
b b sin

b
2 sin 2 1
e 1 1
2 1 sin 2 2
1 sin
a
2
4

sin( A B ) sin C SinB

60. Given sin( A B ) sin( A B ) sin B
Sin ( A B ) SinC
1
sin B 2 cos A sin B cos A tan A 3
2
2
2Tan A 6

.in
ay
2d
bs
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w
w
w

Sr.IPLCO_Advanced Page 15