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q0 c
Langmuir: q - gives straight line of plot of 1/q vs. 1/c [3]
K c
The data are closest to a straight line on plot [3], indicating the Langmuir isotherm is the best fit.
The linearized form of the Langmuir equation is:
1 K 1 1
q q0 c q0
Using the line of best fit for the data in plot [3]:
1
Intercept 6.78
q0
1 g glucose
q0 0.147
6.78 g alumina
and
K
Slope 0.124
q0
Given:
S = 2.5 m3 solution
cF = 0.25 kg phenol / m3 solution
q F M c F S qM cS
03 0.252.5 q3 c2.5
Plot the equilibrium data and the operating line. At equilibrium, q and c are in equilibrium, at the
intersection of the two lines:
The equilibrium data are best fit by a Freundlich-type isotherm, as shown on the graph. Solving
analytically (or graphically) for the intersection of the two lines:
kg phenol
ceq 0.109
m 3 solution
kg phenol
q eq 0.118
kg carbon
Height of bed: HT = 14 cm
Diameter of bed: D = 4 cm
Flow rate = 754 cm3/s
c
t t ,new 1 dt A1 A2 t b ,new A2 8.5 1.51 10.01h
0
c0
t u ,new t b ,new 8.5h
t u ,new 8.5
0.849
t t ,new 10.01
(b) When the flowrate changes, the diameter needs to change to keep similar flow (velocity)
and mass transfer characteristics. The length of the bed and the fraction of capacity used
will change with the break point as calculated in (a): HT = 27.2 cm; tu/tt = 0.849.
For a constant flow velocity, the cross-sectional area will change proportionally to the volumetric
flow rate:
Flow new
Anew Aold
Flow old
2000 2
2
Dnew Dold
4 754 4
Dnew
2000
4cm 2 6.5cm
754
Q4. Ion-exchange column
Given:
HT = 30.5 cm
D = 2.59 cm
Mass of ion-exchange resin: 99.3 g
A1 A2
tb ts
Break point time: from the graph, when c/c0 = 0.010, tb = 460 s
Usable capacity of the bed: = 0 (1 ) = 1
0
- Can be solved by integrating the area above the curve graphically or numerically
- Alternatively, it can be shown that (A1+A2) = tt ts, the time when c/c0 = 0.5
- From the graph,
= 645
460
= = 0.713
645
460
= = 30.5 = 21.75
645
=
= 30.5 21.75 = 8.75
3 1
1.37 3
645 0.18 63.54 = 10.106
1000
10.106
= = 0.102
99.3
Q5. Scale-up of ion-exchange column
Given:
Column I: HT = 0.4 m Column II: tb = 13.0 min
Flow rate = 0.2 m3/h
tb = 8.0 min
tu/tt = 0.65
For Column II, the following relation can be applied to determine the length of used bed:
,2 ,2 ,1 ,2
= ,2 =
,1 ,1 ,1
0.26 13
,2 = = 0.4225
8
Total length for the column II, assuming that the length of unused bed (HUNB) is unchanged:
,2 = ,2 +
,2 = 0.4225 + 0.14 = 0.5625