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Contoh
Oxidation of ethylene to ethylene oxide while avoiding complete cornbustion
to to carbon dioxideand water.
Series reactions (also called consecutive reaction
are reactions where the reactant forms an intermediate product, which
reacts further to form another product
Contoh
reaction of ethylene oxide (EO) with ammonia to form mono-, di-, and triethanolamine:
Complex reactions
are multiple reactions that invoIve a combination of both series and
parallel reactions, such as
Contoh
The formation of butadiene from ethanol
Independent reactions
are reactions that occur at the same time but neither the products nor
reactants react with themselves or one another.
Contoh
Cracking of crude oil to form gasoline where two of the many reactions
occurring are
DESIRED (Di inginkan) & UNDESIRED (Tak di inginkan) products
Desired product D
Undesired product U
Paralel reaction
Series
Overall selectivity
Case 1
1 > 2 For the case where the reaction order of the desired product is
greater than the reaction order of the undesired product. (a > 0)
A = frequency factor,
E = the activation energy,
subscripts D = Desired product and U = Undesired product.
Case 3
ED > EU, In this case the specific reaction rate of
the desired reaction kD (and therefore the overall
rate rD) increases more rapidly with increasing
temperature than does the specific rate of the
undesired reaction kU
Sehingga suhu reaksi harus tinggi untuk
memaksimalkan SD/U
Case 4
EU > ED In this case the reaction should be carried
out at a low temperature to maximize SD/U but not
so low that the desired reaction does not proceed
to any significant extent.
Example 6-2 Maximizing the selectivity for the Trambouze Reactions
Reactant A decomposes by three simultaneous reactions to form three
product, one that is desired, B, and two that are undesired, X and Y.
These gas-phase reactions. along with the appropriate rate laws, are
called the Trambouze reactions
Solution
(E6-2)
Lihat hal 14
Pers 1-9