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New homework is assigned, Chapter 4, set 3: 51, 52, 53, 55, 57 (a),
59, 61, 63, 65, 67, 71, 72, 75.
hybridization orbitals showing the amplitude of a single
wavefunction.
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Characteristics of Multiple Bonds
Ethene, CH2=CH2 has a double bond.
All six atoms in ethene lie in the same plane, with bond
angles near 120.
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Characteristics of Multiple Bonds
The unhybridized 2p-orbital, is
perpendicular to the C-C
plane.
-bond spin-pairing
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Double bond properties
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Ethyne HCCH (acetylene) has sp
hybridized Cs.
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Valence-bond theory, describes O2 as having all es paired.
However, oxygen is a paramagnetic with unpaired es.
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Lewiss theory fails to account for the compound diborane,
B2H6, that bursts into flame on contact with air.
Bridging Hydride
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Molecular Orbitals
In every case, molecular orbitals are built by adding
together -or superimposing- atomic orbitals belonging to
the valence shells of the atoms in the molecule.
For H2:
A is atom A
B is atom B
1s is the 1s-orbital for hydrogen
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Molecular Orbitals
A is atom A
B is atom B
1s-orbital for hydrogen
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Molecular Orbitals
bonding antibonding (*)
constructive interference deconstructive interference
LCAO-MOs
Bonding
Molecular orbitals
form when atomic
orbitals interfere
constructively.
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