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51. The quantum number which is responsible for (@) 9.65x10°C (b) 9.65x10°C a (©) 9.65x10°C — (€) 9.65%107 C (a) spin ‘azimut 4 s 53. “Electrons are filled in energy orbitals, in @'mndel! = —_ mages increasing order of ees This statements 52. To deposit one equivalent weight of silver at cathode the cha (@ Pigpeks rule (b) Hunds rule bi gD ‘srule (4) Aufbau principle 54, Ascorbic acid is a (@) enzyme (b) vitamin (© protein (@) None of these 55, The outer electronic configuration of transitional elements is (@) (n—1)s?nd* @& @+Dsnd © (@-1s*p%(n-1)d™, ns? @) ns? (n+ 1) 56. Strongest base is (a) RbOH (b) LiOK (©) KOH (d) NaOH 57. If the pH of an aqueous solution is 4.7, then its HY concentration will be (a) 3x10° (b) 3x10 (©) 2x10% @) 5x10 58. Conjugated double bond is present in (a) butylene (b) butadiene (©) isobutylene (@) propylene 59. A radioactive element has a half-life of 10 yr. ‘What percentage of the original amount of it would you expect to remain after 20 yr? @ 125 © 8 oo cr 60. Given, HF+ H,0 = H F+Hp oS He +on Which of the following relation is correct ? (@ Ky=Ky () Ky xKy= Ke © ake @K % 61. The allowed values of m for. @ O41 b) #1,+2 (G4142 @0+2 62. Alkaline dilute KMnO,, solution is called (a) Btard reagent (b) Benedict reagent (©) Mullikan’s reagent (@) Baeyer’s reagent 63. 2 moles of PCI, is heated in one litre vessel. At equilibrium 0.4 mole Cl, is formed. The value of equilibrium constant will be (@ 1x10 (b) 1x107 (© 2x10" @ 1107 64, If 19 is the atomic number of an element, then. this element will be 69. n. (a) a metal with +3 oxidation state (b) a metal with +1 oxidation state (©) an inert gas (@ a metal with -3 oxidation state . At 25°C the solubility of sparingly soluble binary salt AgCl is 1.25%10°° mol/L. What will be the value of Ky at the same temperature ? (@) 1.25x10° —_(b) 1.56x107° (1x10 @ 1.44 «107° . Nessler’s reagent is used to detect (@ Po, (b) Mn0,, © NAY @ coe ‘The comrect increasing order of electron affinity is (@) BeB,N,C (b) C,N,B, Be (© Be,N,B,C — (@) Be,B,CN . Nitrobenzene, on reaction with fuming nitric acid at 90°C, the product is 102 NOQ NOg nlaeds~ -O ‘The oxidation number of Cin CH, CHCl, CHCl, CHCl, and CCl, is respectively (a) -4,-2,0,+2,+4 () +2,4,0,-2,-4 © 4,2,0,-2,-4 @) 0,2,-2,4,4 ). Latent heat of vaporisation of a liquid at 500 K and 1 atm pressure is 10.0 keal/mol. What will be the change in internal energy of 3 moles of liquid at same temperature ? (@) 13.0 kcal (b) -27.0 keal (© 27.0keal (A) 13.0 keal IFLPG cylinder contains mixture of butane and isobutane, then the amount of oxygen that ‘would be required for combustion of 1 kg of it will be (@) 2.7 kg (© 3.58kg () 1.8 kg @ 45%8 74. 78. 77. 78. 79. 80. 81. . The oxidation number of Cr in CrO {ly is @ +2 (b) +3 +4 @ +6 Tonisation energy is highest in (@) Ne] 33! (b) [Ne] 3573p? (© [Ne] 30”, 452, 4p? (@) [Ne] 3°°3p* In the following molecules, the hybrid state at ‘Land 3 carbon atom =cH—cH, (@ sp? &) =" (© spd @ ‘The IUPAC name of (CHs),C—CH=CH, is (a) vinyl trimethyl methane () 2,2-dimethyl-3-butene (©) tertiary butyl ethene (@) 3,3-dimethyl-1-butene ‘The number of ¢ and x bonds in cH, =cl—cH=cH, (@) Sond 2x bonds (@) Soand ix bond (©) 9oand 3x bonds (@) 9o and 2x bonds: CuSO, dissolves in NH, due to formation of (a) Cu(OH), () [Cu(NH 4(0H),] (©) [Cu(NH,),]SO, CH= (@) cud Phenacetin is used as (a) antiseptic (b) analgesic © antipyretic (@) antimalarial ‘The highest magnetic moment will be shown by (@) Ni (b) co (© Fe @ a Gypsum is (@) CaS0,-2H,0 @) Caco, 24,0 (©) Ca80,-1/2H,0 @ so, He Propene 185 4 Ms/eter (i H,0/bo! In the above sequence of reactions B is (@) propane (b) butane (©) propene (@ ethane 82. 8s, 97. 88. 89. 90. Which is a characteristic ofa catalyst ? (a) It changes the equilibrium point (b) It initiates the reaction (©) It alters the rate of a reaction (@) It increases the average kinetic energy of the molecules | The product CHy—§—CHCl, is formed 3 when HOCI reacts with (@) CH,—cH,—C=cH (0) CHy—Csct (©) CH,—C=C—CH, @ cH=cH |. Which ofthe following is an electrophile? (@) HO (b) NH (©) AlCl, (@ C,HNH, A sample of radioactive substance with a ty =3 days was found to contain 3g of it, when received exactly after 12 days. The amount of radioactive substance when it was sealed (a) 48g (b) 128 (© 24g @ 6g The correet electronic configuration of Cu (29) is GW) HF, 25228, a5*apSa0”, 4st (b) 1s, 25%2p%, a62apiad", ast (©) 1s*, 2572p®, 36°3p%3d", 4s" (A) 1s?, 25?2p%, a6%3p%3d!, 4s? Which enzyme is effective in the following CebifOg —> 2C,H,OH+ 260, (@) Invertase ——(@) Zymase (© Maltase (4) camylase Which ofthe following is a buffer? G@) NHOH+ NCL () NaOH+ Na,S0, (© NaOH + CHjCOONa (@ KS0,+H,S0, ‘The most electronegative element in periodic table is (a) Fr ® F (© He @N Cryolit is the ore of (@) Fe (b) cu © Ag @ Al 91, Which of the following is not a member of Sdctransition series? @ Fe (b) Co © Aw @ cu 92, The solubility of Ca3(PO,), is *s' mol/L, Its solubility product is (@ 725° ) 108s5 © (@) 88° 93. A group 16 element exists in the monoatomic state in the metalic lattice. It also exists in two crystalline forms, The meta is @s @) Po © se @ Te 94, The bond energies of Fy, Cla, Bry and Ip are 155, 244, 193 and 151 ki/mol. The weakest bond will be (@ Cl, (b) By Ob @r 95. The process of converting hydrated alumina into anhydrous alumina is called (a) smelting (b) roasting (© calcination (@) dressing 96. 97. 100. If the hydrogen fon concentration in an acid is 10° moY/L then the pH @9 7 @<7 @ >8 Tischenko reaction proceeds inthe presence of (a) Zn and ZnCl, () Alpowder (©) AMOC,H,), and anhydrous AICI, (@ FeCl, ‘Which is most soluble in water? (a) Agbr @) Agcl (©) AgF (@) Agt Blue vitriol is (a) MgS0,:7H,0 (b) CuSO,-5H,0 (©) FeS0,:7H,0 (4) CaSO,-24,0 The silver is extracted by Parke’s process. The basis of this method is (@) silver is immiscible in molten Zn (b) Agiis miscible in NaCl (© Ag is more miscible in molten Zn than in molten Pb (@) Ag is more miscible in molten Pb in comparison to molten 2n 6 IbigDeal Answer — Key 55. 56. 66. 88 y 76. d ‘ :

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