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EXERCISE NO. 3
JOULE-THOMSON COEFFICIENT
Laboratory Instructor:
Rochelle Ibabao
I. Introduction
Berthelot EOS:
Ti=
3a
Rb
P
Figure 3.2. The plot
on the determination of the Joule-Thomson Coefficient of CO 2.
Table 3.3. Data summary for the determination of the JT coefficients and the
inversion temperatures of the various EOS against the
experimental value.
Experimental Lit. Value Van der Waals Berthelot
Where aij is based on the gas composition and the density at standard
conditions
(calculated experimentally)
is the reduced temperature
is the reduced density
The calculated results yield only a %error no greater than 1.5%, while using short
ranges of pressure and temperature unlike ordinary methods of determination
(Pistun, Matiko and Masnyak, 2015).
On the other hand, the temperature at which the sign changes is called the
inversion temperature. The inversion temperature (T I) is the temperature at which
below it the gas cools down upon expansion, and above it the gas heats up upon
expansion. For the carbon dioxide, the inversion temperature is 1500 K. Thus, above
1500 K, carbon dioxide heats up upon expansion instead of the usual cooling
process (Shoemaker et al., 2009). Meanwhile, based on the calculations, the
inversion temperatures for CO2 are 2053.80554 K and 9.80480300 K using the vdW
and Berthelot EOSs, respectively.
Correction of P, cmHg:
TR = 25.7 C
Pcorr = P[11.8 104 ( T R ) ]
Pcorr =5 cmHg [ 11.8 104 (25.7 ) ]
4.97687 cmHg
Theoretical JT
2a
b
RT
JT =
Cp
Pa m6
(
2 36.490 x 102
mol2 ) 6
42.74 x 10
m3
J mol
JT =
( 8.314
K mol )
( 25+273.15 K )
J
37.11
molK
K 101325 Pa
(6.781848145 106 )( )
Pa 1atm
K
JT =0.6871707633
atm
Berthelot constants for CO2:
Pa m6
a= 8.490 x 10 3
2
K
mol
b = 31.867 x 106 m3/mol
Cp = 37.11 J /mol-K
3a
b
R T2
JT =
Cp
6
(
3 8.490 x 103
Pa m
mol
2
K ) 3 1.867 x 106
m
3
J mol
JT =
( 8.314
K mol )
( 298.15 K ) 2
J
37.11
mol K
K 101325 Pa
(8.577886634 )( )
Pa 1atm
K
JT =0.08691543632
atm
Inversion temperature
(
2 36.490 x 102
mol2 )
m3
( 8.314
J
K mol )(
42.74 x 106
mol )
2053.80554 K
Berthelot EOS:
T I=
3a
Rb
3 Pa m 6
3( 8.490 x 10 2
K)
mol
( 8.314 K Jmol )(42.74 10 6 3
m / mol)
= 9.80480300 K
% error:
Experimental vs Literature:
3.742070821.11
error = x 100
1.11
error =237.1234973
VdW EOS
experimentalTheoretical
%error= x 100
Theoretical
3.742070820.6871707633
error = x 100
0.6871707633
error =444.5619953
Berthelot EOS
experimentalTheoretical
%error= x 100
Theoretical
3.74207082(0.08691543632)
error = x 100
0.08691543632
error =4405.415676
V. Summary and Conclusion
In the experiment, CO2 gas was allowed to pass through in a porous disk
using the Joule-Thomson apparatus. As the pressure is increased and decreased
continuously, the change in temperature was measured. Through this, the slope (JT
coefficient) was then determined.
It was found out that the Joule-Thomson coefficients for the experiment were
3.74207082 K/atm and 1.886178796 K/atm for the increasing-pressure and
decreasing-pressure setups, respectively. Both experimental value yielded high
%errors. On the other hand, using the EOSs, the inversion temperatures were
calculated as 2053.80554 K and 9.80480300 K for the vDW and Berthelot EOSs,
respectively.
Overall, the experiment was successful because the Joule-Thomson coefficient of
CO2 at 25 C was determined, and the inversion temperatures using the van der
Waals and Berthelot EOS were calculated.
VI. References
Atkins, P. and de Paula, J. 2010. Physical Chemistry 9 th Ed. New York: W.H. Freeman
and Co.
Castellan, G. 1983. Physical Chemistry 3rd Ed. London: Addison-Wesley Pub. Co.
Pistun, Y., Matiko, F. and Masnyak, O. 2015. Simplified Method for Calculation of the
Chemistry