1. The radius of the first Bohr orbit ef the H atom 7.‘ The five d-orbitals are designated as is r. Then, the radius of the first orbit of Li?* dy, Ayes deer daa and d_». Choose the correct wal be elec et me Seer one @s wt (@) The shapes of the first three orbitals are 5 3 Mista bat Ghat ‘ofthe fourth wd Rit ox @ 5 Sabla ee different (b) ‘The shapes of all five d-orbitals are similar 2. ‘The molarity of a solution obtained by mixing. 800 ml. of 0.5. M HCI with 200 mL. of | M HCl will be (@) The shapes of all five dorbitals are (08M @) 06M © 04m (@ 02M diferent 3. An etheral solution of alkyl halide is heared ‘Arrange in decreasing order, the energy of 28 orbital in the following atoms 1H, Li, Na, K (@) Basan > Basa) > E2una) > E2000) () Essay > Basen > Ease > Ea.) (©) Basan > Eancne) = Basen) > Ez) (@) Ea ye) < Ea.) < Eau < Ean 9. Arrange the following compounds in increasing, order of their boiling points with sodium metal. The reaction is known as (a) Frankland’s reaction (b) Sandmeyer's reaction (@) Wurtz-Fittig reaction (@) Wurtz reaction 4. What is(are) number(s) of unpaired electrons in the square planar, [Pt(CN),]*" ion ? @o ma @4 @6 CH,CHO, CH,CH,OH, CH,OCH,, CH,CHCH, 5. An aqueous solution of borax is (a) CH,CH,CH, < CH,OCH, < CH,CHO. (@) neutral (> acidic CH,OCH, 6. Order of reactivity eH On substitution reaction of PUCE > CHCHO > CHIOCRS = CH,CH,OH Mea NO2 HOH < CH,CHO - which are colourless species ? (a) Cu,Cly and NiCly a a No: () Co” and Nici” o “ io (©) CoF3~ and Tire a (@) THF? and Cu,Cly 11. Which of the following displaces Br, from an Onn NO2 aqueous solution containing bromide ions ? (cr @) cl, ©5 @ b ee 12, Which of the following hybridisations has ing planar geometry \ (a) spid () dsp" is © dsp? @ x One tener 18. Which of the following compounds of chlorine Oem ot Contains both fonie and covalent bonds ? (a) NaCl (b) NaclO, Gite wet a © Pcl, (@) Pocl,14. 15. 16. 17. 18. 19. 20. 21. Which physical property in the alkali metal group increases with atomic number ? (a) Melting point (b) Electronegativity (© Hydration enthalpy (d) Density Which among the following is not a borane ? (@) BH, (b) BH © Bio (@) None of these [Fe(CN),]* ion is (a) hexacyanoferrate (11) ion (b) hexacyanoferrate (1) ion (© hexacyanide iron (11) ion (@) iron (IUD hexacyanide ion Which of the given properties depends on the ‘manner in which a change is brought about ? @ aE Gia Gi) W (@) AE only (b) qand aE © qandW (@ Wonly Which of the following pairs of solutions is expected to be isotonic at the same temperature ? (a) 0.2 M urea and 0.2 M NaCl (b) 0.1 M urea and 0.2 M MgCl, (© 0.1 MNaCl and 0.1 M Na,SO, 5. (@) 0.1 MGa(NO,), and 0.1 M Na,SO, Three elements A, B an cubic solid lattice. Atoms B atoms, the cube centres a edge. The formula of the compound is @ ABC (b) ABC, (© ABC, @ ABC, When equal volumes of AgNO; and NaCl solution are mixed, the precipitation of AgCl (K,, = 1.81 x107) will occur with (a) 10 M (Ag* and 10°" M(cI-) (b) 10°* M (Ag” )and 10° Mc") (© 10° M (Ag )and 10° Mic") (@) 10 M (Ag’ )and 10 M(C’) Consider the following reactions, 22, 24, 26. 27. 1.H,¢cl, O84 /Ag(NH J” OH® i. wccHo Sets On, IIL H,CCO,C,H, 8, Carboxylic acid is the final product only in the reaction(s) @ 10 © u () 1m @ m oped = Which of the following is the industrial method of preparation of acetaldehyde ? “Sn, @ cu,en 82, cHycH=Nu 2°, cH,cHo (b) CH,COCl+ H, gti? CH,CHO + HL (©) CH, =CH, + H,0 ae, CH,CHO (d) None of the above Increasing order of ionic size for the ions, FO, Na®, Al®* is (a) O* < F< Na* H,0(s) at normal pressure and 274 K are given below AS yam =~ 22-138. Supp = + 22.05 ‘The process is non-spontaneous because. (surr’ stands for surrounding and ‘v’ stands’ for universe) (@) ASyacem is — ve (D) AS sun iS + ve (© AS, is—ve (@ AS ctem # 2Ssur In the following structure, HOCH oH “on HO 2 § ou anomeric carbon is @1 ) 2 ©3 @428. Which of the following is soluble in sodium 34. Products of the following reaction hydroxide ? ‘i ni Me,¢ —cHcH, —°s__, 2 W(Ciy),8 @ H {ONHCHy ae (a) CH,CHO + CH,COOH (b) Me,CO + CH,CHO| © Hs SO;N(CHa)2 (©) Me.CO + CH,COOH (a) 2Me,co ore Ss 35. K, and Kare the equilibrium constants of the two reactions, given below @ wc¢_\ nie BML) + FHale) we NH) Na(g)+ 3H,(@) = 2NHA(@) 29. Which one of the following species will be most ‘Therefore, K, and K; are related by reactive in Sy2reaction ? (@ k,=K? k,=\kK, @ 4 @ sLa (© Kp=2K, @ Ky=K, Cl cl 36. Critical temperature of H,O, NH, CO, andO, © @ | are 647 K, 405.6K, 304.10K and 154.2K respectively. If the cooling starts from 500 K to their critical temperature, the gas that liquefies 30. Which one of the following species is involved first is in the sulphonation of aromatichydrocarbons ? (a) 44,9 (b) NH, (a) HSO; s (©) CO, @) 0, © 80, ‘Ihig the given reaction, 31. Hyperconjugation effect is 10% (A+B 0.05 x (a) Baker-Nathan effect (b) No bond resonance (2) x +B 22989, y (©) Both (a) and (b) ry = 0001 (@) None of the above @) ¥+ a =O), ay 32. Predict the main product. (@ ay+B 42019, aye O- NHy/Cu20, will be determined by (@) Step 1 : because the reaction starts with the formation of X (a) phenyl cyanide (b) Step 2 : because it is the fastest step (b) nitrophenol (© Step 3 : because it is the slowest step {9 enlin (@) Step 4 : because it ends the reaction 6c) Shyseonylamuins 38. The critical temperature of 33. ‘The order of reactivity of the alkenes, Op, No, Hy and CO, are 154.3 K, 126 K, 33.2K © (CH,),C =CH,, and 304K. The extent of adsorption on ) CH.CH=Ch,, tungsten may be highest in case of (I) CH, CH, (a) Hy (b) Ny when subjected to acid catalyzed hydration is © 0, (@) CO, (@) I> >i @) 1>m>1 (© M> >t @ > 1>m 39. Which of the following polymers is prepared from caprolactam ? (a) Nylon-6,6 ——(b) Nylon-6, 10 (©) Nylon-6 (@) Nylon-1141. 42. ‘The standard reduction potentials for Cu*/Cu and Cu*/ Cu* are 0.337 and 0.153V respectively. The standard electrode potential of Cu*/Cu half-cell is (@) 0.184V. (b) 0.827V © 0.521 @ 0.490V ‘A gas X at 1 atm is bubbled through a solution containing a mixture of 1 M ¥~ and 1 MZ" at 25°C. If the reduction potential order is Z>Y>X, then (a) ¥ will oxidize X but not Z (b) ¥ will oxidize both X and Z (© Y will oxidize Z but not X (@ Ywill reduce both X and Z Which characteristic is not associated with chemical adsorption ? (a) Is irreversible (b) Forms monolayer (©) Not very specific (@) Heat of adsorption > 50 kJ mol Which of the groups has (@) HC (b) CH,CH, (© (CH,),CH @ (CH,),C For the following reaction, Do (@ Mg, E20 Gi Cox) product [A] is (ii) H30* co[>-coon © (coms eply @ > ‘The potential of standard hydrogen electrode is zero. This implies that (a) AGF(H", ag)=0 (b) HCH", ag)=0 [a] 47. 48. 49. (© AGFCH", aq) <0 (@) AGF (HT, ag)>0 Which of the following is the statement ? (a) Order of a reaction has always an integral value (b) Mechanism of a reaction proposed is always final (© Zero order reactions (@) Order of reaction can be predicted even without knowing the rate law If pK, of acetic acid and pK, of ammonium hydroxide are 4.76 each. The pH of ammonium acetate is (@7 (b) less than 7 (©) more than 7 (d) zero Reactions that have standard free energy changes less than zero always have equilibrium constantequal to correct reactions are multi-step bigs (@) zero In Na,O, having antifluorite structure (a) oxide ions have a cubic close packed arrangement and Na* occupy all the eight tetrahedral voids (b) oxide ions have a cubic close packed arrangement and Na’ occupy all the octahedral voids (©) Na* ions have a cubic close packed arrangement and O* occupy all the octahedral voids (@) N* ions have a cubic close arrangement and O* occupy all the tetrahedral voids Solubility(s) of CaF, in terms of its solubility product is given as, @ s=Ky)”? ©) s=Ky/2? © s=Ky/4? @ s=Ky/2?Answer — Key 1b 2b 3a aa an 6c To 8 a 9a 10.4 1Lb Rec B.b 14d 15.b | 16.6 Tc 18. 19.¢ 20.4 21.b 2 23. b 24.4 25. a 26. ¢ 2a 28, a 29.0 30.4 B1c 32 3B.c 34. b 35.b | 36b | 37. 38d 39.¢ 40. ¢ aia ac Bd a 45. a %.d | aa 48. b 49. a 50. ¢