Useful Information:

R = 8.314 Kpa. Dm3/mol. K = 0.0821 atm. Dm3/mol. K = 8.314 J/mol.

K. 1 atm = 760. mmHg = 101.3 kPa. = 760. torr.
T (K) = T (C) + 273, PV = nRT
Tf = iKfXA, Tb = iKbXa
G = H-TS, G = -96 nE.
Arrhenius equation : K = Ae Ea/RT

0.0592 Log Q
Nernst Equation: E = E - n

At. Wt: H = 1.0, C = 12.0 , O = 16.0, Mg = 24.3, Cu = 63.5, S = 32.0.

Circle the correct answer for each of the following questions and put
"X" on the corresponding choice on the front page:

General:
1. Which one of the following statements is not correct?
a) do not lay the stopper of a bottle down, as impurities will be picked
up and contaminate the stock solution.
b. If the mass of a flask and solution is 102.32 + 0.01g and the mass
of the flask is 82.02 + 0.01g then the mass of the solution is 20.3 +
0.02g.
c. In any experiment in which poisonous or unpleasant vapors are
discharged, perform the operations under the fume hood.
d. To protect your clothing from corrosive chemicals, always wear a
laboratory coat.

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Avogadors Number
2. Given the following set of data:
- Number of moles of stearic acid needed to form a monomolecular
layer on water = 6.70 x 10-7 mol.
- Volume of monomolecular layer = 5.40 x 10-6 cm3.
- Area of the monomolecular layer = 90.0 cm2.
- Avogadro's number = 6.02 x 1023.
a. 2a b. 9a c. 7 a d. 4a

Stoichiometry:
3) Given the following set of data:
- Mass of empty crucible = 12.65g.
- Mass of crucible + potassium alum = 13.20g.
- Mass of crucible + anhydrous salt = 12.90g.
- Molar mass of water = 18.0g / mp.
- Molar mass of KA1 (SO4)2 = 258.0g/mol.

Calculate the mass percent of water in the alum.

a. 96 b. 36 C 35 D 45

Volumetric analysis:
4. 13.80 mL of 0.290 M NaOH solution were needed to titrate 10.0 mL
of vinegar solution (molar mass of acetic acid = 60.0g/mol). Calculate
the number of grams of acetic acid per dm3 of vinegar solution.
a. 210 b. 12.6 c. 24.0 d. 40.0

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Redox- Titration:
5. 10.0 mL of acidic bleach solution (0.0: 30 M) were treated with access
solid KI. The liberated iodine is titrated with 24.70mL of Na2S2O3
solution. Calculate the molar concentration of Na2S2O3.
a. 0.410 b. 0.0168 c. 0.0336 d. 0.0672

Molecular weight of a Volatile Liquid:

6. Calculate the temperature (in C) of 1.53g of a vapor of a volatile
liquid (molar mass = 74.0g/mol) which occupies a volume of 650.0
cm3 at a pressure of 86.0 kPa.

Colligative properties:
7. Given the following set of data:
- Freezing point of benzene = 5.5C.
- Freezing point of benzene solution containing a non- associating,
non-dissociating and non volatile solute = 3.0C.
- Kf (benzene) = 65.6 deg.
- Kb (benzene) = 33.7 deg.
- Boiling point of benzene = 80.1C.

Calculate the boiling point of the solution in C.

a. 81.4 b. 81.7 c. 81.1 d. 78.8

Thermochemistry:
8. Given the following set of data (using a 250mL beaker as a
calorimeter):
- Temperature of cook water (40.00g) = 20.0 C.
- Temperature of hot water (51.40g) = 40.0C.

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 - Highest temperature after mixing = 30.0 C.
- Specific heat of water = 4.184J/g. deg.

The heat capacity of the calorimeter (breaker) in J/deg.

a. 48.0 b. 259 c. 24.0 d. 16.0

9. Given the following set of data for the reaction:

Mg(s) + 2H+ (aq) H2(g) + Mg2+ (aq)
- Mass of a beaker = 100.00g.
- Mass of a beaker + solution (after reaction) = 200.00g.
- Rise in temperature = 15.0 deg.
- Heat capacity of the beaker = 50.0J/deg.
- Specific heat of solution = 4.07J/deg.
- Mass of solid Mg (Molar Mass = 24.3g/mol) = 0.49 g.

Using the following thermochemical equation:

H2O (I) H2 (g) + 1/2 O2 (g).
MgO (s) + 2H+ (aq) Mg2+ (aq) + H2O (1).
Calculate Hf for MgO (s) in kJ/mol.
a. 476 b. 368 c. 551 d. 701.

10. For the reaction of 0.60g MgO and excess (0.5M) HCl. Which one
of the following cases will raise the temperature (T) more than it
should be?
a. The addition of the same amount of MgO solid to 80mL of HCl
solution instead of 100Ml.
b. Using a beaker with greater heat capacity.

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 c. If some MgO solid adheres to the beaker's wall and does not mix
with Hcl solution.
d. Increasing the concentration of HCL solution.

Chemical Kinetics
11. At a certain temperature, the following data are collected for the
reaction:
2 NO(g) + Br2 (g) 2 NOBr (g).
Run [NO], M [Br2], M Rate, M. S-1
1 0.10 0.10 4.0
2 0.10 0.20 8.0
3 0.10 0.30 12.0
4 0.30 0.10 36.0

The rate constant for the above reaction would be:

a. 4.0 x 104 M -3. S-1. b. 4.0 x 103 M-2. S-1.
c. 4.0 x 102 M-1 S-1 d. 4.0S-1

12. The rate constant for the reaction,

3I- (aq) + H2O2 (aq) + 2H + (aq) I3- (aq) + 2H2O.
At 5.0C is 3.30x 10-3L. mol-1. S-1, and at 25.0C is 6.60 x 10-3L.
mol-1. Calculate the activation energy for the reaction (in J. mol-1).
a. 36 b. 2.4 x 104 c. 4.4x 104 d. 3.4 x 104

13. For the reaction:

3I- (aq) + H2O2 (aq) + 2H + (aq) I3- (aq) + 2 H2O.

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In which of the following cases, the rate constant would be affected?
a. Doubling the temperature of the reaction.
b. Doubling the volume of thiosulfate solution.
c. Reducing the concentration of KI.
d. Reducing the volume of starch to the half.

Chemical Equilibrium:
14. Which one of the following statements is correct?
a. Addition of KSON to Fe (NO3)3 solution produces a white precipitate.
b. Addition of aqueous HCl to a solution Fe (NO3)3 and Ag metal
produces a white precipitate.
c. Turnbull blue precipitate is formed upon the reaction of AgNO3 and
K3Fe (CN)6.
d. Addition of KSON to FeSO4 solution produces a white precipitate and
a blood red color.

15. When excess NaOH solution is added to an aqueous solution of

iodine, the color of solution disappears due to the formation of:
a. HI + HIO b. NAI + NaOI.
c. I- + I2 d. I2 + HIO.

16. A test tube curtaining water and a precipitate of AgI. The precipitate
will disappear upon the addition of:
a. solid AgI. b. few milliters of dilute NH4OH.
c. Solid AgNO3 d. Solid KI.

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Equilibrium and Ksp:
17. Given the following set of data:
- Volume of saturated CH3COOAg solution used in titration =
25.0mL.
- Volume of 2M HNO3 solution = 5.0 Ml.
- Volume of ferric alum indicator solution = 0.5 Ml.
- Molarity of JSCN solution = 0.15M.
- Ksp for CH3 COOAg = 2.3 x 10-3.

Calculate the volume (mL) of KSCN) used in the titration.

a. 8.0 b. 9.6 c. 32 d. 42

18. What is the maximum number of grams of solid sodium acetate

(CH3COONa) that can be added to 50.0mL of 0.011 M AgNO3
solution without precipitation of CH3COOAg? (Molar Mass of CH3
COONa= 82, Ksp for CH3 COOAg = 2.30 x 10-3).
a. 0.047 b. 1.9 c. 0.094 d. 0.049

19. Which one of the following statements is correct?

a. The solubility of solid silver acetate is increased by the addition of
concentrated HNO3 solution.
b. The solubility of solid silver acetate is increased by addition of
saturated sodium acetate solution.
c. The end point of the titration of saturated CH3COO Ag solution with
KSCN solution was indicated by the appearance of a red silver
thoicynate precipitate.
d. The titration of saturated CH3CCOAG solution with KSCN solution
was carried out in a basic medium.

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Electrochemistry:
20. A concentration cell was constructed as follows:
Half cell A: ZN electrode dipped into 50.00Ml of 0.100 Zn2+.
Half cell B: Zn Electrode dipped into a solution made of 44.90mL of
0.10M Na2S.
Given that Ecell = 0.470 V, calculate Ksp of ZnS.
a. 6.7 x 10-37. b. 2.5 x 10-22.
c. 1.3 x 10-19. d. 5.0 x 10-27.

21. A concentration cell is composed of the following half cells:

Cu/Cu2 + (1.0 x 10-4 M) and Cu / Cu2+ (0.10M).
beaker 1 beaker 2.

Which one of the following statements is correct?

a. Addition of 5 ml of 0.10 M Na2S solution to beaker 1 has no effect
on the cell potential.
b. The salt bridge can be filled with Na2S solution since it is strong
electrolyte.
c. Addition of 5 ml of 0.10 M Na2S solution to beaker 1 will increase
the cell potential.
d. Addition of 5 ml of 0.10 M Na2S solution to beaker 1 will decrease
the cell potential.

22. A galvanic cell is made of:

Zn (s) / Zn2 + (0.01 M)//Cu2+ (0.10M) / Cu (s).
(Standard reduction potentials, EZn = -0.76 V and E CU = 0.34 V).
The potential (E) for the above cell will be:

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a. E = ECU - E Zn.
2+
0.0592 Log [Zn 2+]
2 [Cu ]
b. E = (E CU - E ZN)

0.0592 [Zn2+]
c. E = - Log
2 [Cu2+]
2+
d. E = (ECu- EZn) 0.0592 log [Zn 2+]
[Cu ]

For the following reaction

3I- + H2O2 + 2H+ I3- + 2 H2O.

Given the following set of kinetic data.

Run No. (KI) (H2O2) Rate of appearance of 0.01 MI3- Temp. C
1 0.020 0.10 400 25.0
2 0.040 0.10 200 25.0
3 0.40 0.20 50 25.0
4 0.020 0.10 900 5.0

Assume the order with respect to (H++) = 0.

a. Write the rate law. (Sow your calculation).

b. Calculate the rate constant for runs 1 &4 (specify the units).

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c. Calculate the activation energy Ea. (R = 8.314 J mol-1 K-1).

1. Given the following set of data:

- Volume of Cr2O7 solution = 25.0 cm3.
- Volume of 0.097 M S2O3 = 20.5 cm3.
Calculate the concentration of Cr2O7 solution.

2. Given the following set of data:

- Volume of 0.10 M Na2S2O3 solution = 17.5 cm3.
- Volume of diluted bleach solution = 25.0 cm3.
- Density of original bleach solution = 1.15g / cm3.
- Mass % of original (concentrated) bleach solution = 5.6 %
- Molar mass of NaClO = 74.5.

Calculated the dilution factor for the bleach solution.

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Circle the correct answer:
1. Addition of KSCN solution to a solution containing Ag+ will give a
(colorless solution), red precipitate, (white precipitate), red color
solution.
2. Addition of K3Fe (CN)6 to a solution containing Fe+2 will give a
(blue color solution, red precipitate, blue precipitate, red color
solution).
3. Addition of excess AgNO3 to a solution containing I- will give a
(colorless solution, yellow color solution, white precipitate, yellow
precipitate).
4. Addition of KI(s) to a solution containing AgI(s) will (increase,
decrease, not effect) the quantity of the precipitate.
5. Addition of KCI(s) to a solution containing AgCI(s) will (increase,
decrease, not affect) the solubility of the solid AgCI.
6. Solubility of solid AgCI in water is less than, more than, the same as
its solubility in NH4OH solution.
7. Solubility of solid I2 in JI solution is (less than, more than, the same
as) its solubility in H2O.
8. Solubility of Solid I2 in water will increase, decrease, not be
affected) upon the addition of NaOH solution.
9. Fe3+ + Ag (s) ======= Ag+ + Fe2+ (true, false, I can't tell).
10. SCN- (aq) + Fe2+ (aq) ====== (Fe SCN) 2+ (true, false, I can't
tell).

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