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Lara Baxley
Thermochemistry Worksheet
Answers given at the end
This is NOT the Thermochemistry Homework that is due for credit. Look on the course website
for Thermochemistry Assignment Due
1. Circle the correct choice to indicate weather energy is absorbed or released, and whether
each process is endo or exothermic.
2. There is an attractive force between a rock and the earth (gravity). Energy is released when:
3. There is an attractive force between a magnet and your fridge door. Energy is released when:
a. ClCl bond breaks, separating two atoms with an attractive force, __________________
b. CC bond breaks, separating two atoms with an attractive force, ___________________
c. 2 CCl bonds form, joining two atoms with an attractive force,_____________________
Chem 201A Dr. Lara Baxley
6. A 36.9 g sample of metal is heated to 100.0 C, and then added to a calorimeter containing
141.5 g of water at 23.1 C. The temperature of the water rises to a maximum of 25.2 C
before cooling back down.
b. How many joules of heat was exchanged between the water and the metal?
7. 16.0 g of ice at 0.00C is placed in 525.0 mL of water at 80.2 C. What is the final
temperature? Cw = 4.184 J/gC, Hfus = 6.01 kJ/mol.
Chem 201A Dr. Lara Baxley
8. Butane, which is the fuel used in cigarette lighters, combusts according to the following
thermochemical equation:
If 10.0 g of butane burns completely in oxygen and the heat is used to warm up 25.0 L of
water at 22.0 C, what will be the final temperature of the water (assuming that no heat is
lost to the surroundings and that d = 1.00 g/mL for water))?
9. Evaporating sweat cools the body because evaporation is an endothermic process, as shown
below. Estimate the mass of water that must evaporate from the skin to cool a 95 kg person
by 0.50 C. Assume that the specific heat capacity of the body is 4.0 J/gC.
10. Calculate the amount of heat energy released in burning 1 mole of liquid ethanol, C2H5OH in
O2, and for 1 mole of liquid methanol CH3OH in O2 using Hf values from your book (you
will have to look in Appendix B).
11. Use the information in the previous question to compare the energy density (kJ/g) of each
substance. Describe which substance would you choose as a fuel for your car.
Chem 201A Dr. Lara Baxley
a. SO2(s)
b. HCl(g)
c. C2H5OH(l)
13. Care must be taken when diluting acids with water because the dilution process is very
exothermic. For the dilution of H2SO4, the process is shown below:
H2SO4(l) H2SO4(aq)
a. Use Appendix B to find the H for dilution 1.00 mol of H2SO4(l) (d = 1.83 g/mL) to 1 L
of 1.00 M H2SO4(aq) (d = 1.060 g/mL).
b. Suppose you carry out the dilution in a calorimeter. The initial T is 25.0 C and the
specific heat capacity of the final solution is 3.50 J/gC. What is the final T?
Chem 201A Dr. Lara Baxley
Answers
1. Melting ice requires ice to absorb energy; _endothermic______
Boiling water requires water to absorb energy; ___ endothermic ____
Condensing steam to water release energy; _ exothermic______
Freezing water to ice release energy; __ exothermic ____
2. b. the rock falls and hits the ground
3. b. the magnet is pulled out of your hand toward the fridge
4. b. chemical bonds are formed
5. a. absorbed b. absorbed c. released
6. a. The water absorbed heat from the reaction b. 1.2 X 103 J c. the metal is iron
7. 75.5 C
8. 26.4 C
9. 78 g
10. C2H5OH(l): 1234.8 kJ; CH3OH(l): 638.5 kJ (H is negative, but question doesnt ask for H, it
asks for the amount of heat energy released, which is positive).
11. C2H5OH(l): 1234.8 kJ/mol (1 mol / 46.07 g) = 26.80 kJ/g
CH3OH(l): 638.5 kJ/mol (1mol / 32.04 g) = 19.93 kJ/g
ethanol provides more energy per gram, so itd probably be better in your car
12. a. S(s) + O2(g) SO2(g) Hf = 296.9 kJ/mol
b. H2(g) + Cl2(g) HCl(g) Hf = 92.5 kJ/mol
c. 2 C(graphite) + 3 H2(g) + O2(g) C2H5OH(l) Hf = 278 kJ/mol
13. a. 93.52 kJ/mol b. 50.2 C