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Heusler alloy
From Wikipedia, the free encyclopedia
Contents
In the case of the full Heusler alloys
with formula X2YZ (e. g., Co2MnSi)
1 Discovery and properties
two of them are occupied by X-atoms
2 List of Heusler alloys (L21 structure), for the semi-Heusler
3 References alloys XYZ one fcc sublattice
remains unoccupied (C1b structure).
4 Further reading
5 External links
Oxley found a value of 357 C for the Curie temperature, below which the alloy becomes ferromagnetic.[10]
Neutron diffraction and other techniques have shown that a magnetic moment of around 3.7 Bohr magnetons
resides almost solely on the manganese atoms.[1][11] As these atoms are 4.2 Angstroms apart, the exchange
interaction, which aligns the spins, is likely indirect and is mediated through conduction electrons or the
aluminium and copper atoms.[10][12]
Electron microscopy studies demonstrated that thermal antiphase boundaries (APBs) form during cooling
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References
1. Bouchard M. (1970). Ph.D. Thesis, Imperial College London. Missing or empty |title= (help)
2. Heusler F. (1903). "ber magnetische Manganlegierungen" (http://www.archive.org/stream
/verhandlungende33unkngoog/verhandlungende33unkngoog_djvu.txt). Verhandlungen der Deutschen
Physikalischen Gesellschaft (in German) 12: 219.
3. Knowlton A.A. and Clifford O.C. (1912). "The Heusler alloys". Trans. Faraday Soc. 8: 195206.
doi:10.1039/TF9120800195 (https://dx.doi.org/10.1039%2FTF9120800195).
4. Bozorth, Richard M. (1993). Ferromagnetism. Wiley-VCH. p. 201. ISBN 0-7803-1032-2.
5. Bradley A.J. and Rogers J.W. (1934). "The Crystal Structure of the Heusler Alloys". Proc. Roy. Soc. A144 (852):
340359. Bibcode:1934RSPSA.144..340B (http://adsabs.harvard.edu/abs/1934RSPSA.144..340B).
doi:10.1098/rspa.1934.0053 (https://dx.doi.org/10.1098%2Frspa.1934.0053).
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6. Nesterenko Y.H.G., Osipenko I.A. and Firstov S.A. (1969). Fiz. Metal. Metalloved. (in Russian) 27: 135. Missing
or empty |title= (help)
7. Ohoyama T., Webster P.J. and Williams K.C. (1968). "The ordering temperature of Cu2MnAl". J. Phys. D 1 (7):
951. Bibcode:1968JPhD....1..951O (http://adsabs.harvard.edu/abs/1968JPhD....1..951O). doi:10.1088/0022-3727
/1/7/421 (https://dx.doi.org/10.1088%2F0022-3727%2F1%2F7%2F421).
8. West D.R.F. and Lloyd Thomas D. (1956). "The constitution of copper rich alloys of the copper-manganese-
aluminum system". Journal of Industrial Metals 85: 97.
9. Johnston G.B. and Hall E.O. (1968). "Studies on the Heusler alloysI. Cu2MnAl and associated structures". J.
Phys. Chem. Solids 29 (2): 193, 201. Bibcode:1968JPCS...29..193J (http://adsabs.harvard.edu
/abs/1968JPCS...29..193J). doi:10.1016/0022-3697(68)90062-0 (https://dx.doi.org
/10.1016%2F0022-3697%2868%2990062-0).
10. Oxley D.P., Tebble R.S. and Williams K.C. (1963). "Heusler Alloys". J. Appl. Phys. 34 (4): 1362.
Bibcode:1963JAP....34.1362O (http://adsabs.harvard.edu/abs/1963JAP....34.1362O). doi:10.1063/1.1729511
(https://dx.doi.org/10.1063%2F1.1729511).
11. Endo K., Ohoyama T., and Kimura R. (1964). "On the Magnetic Moment of Mn in Aluminum Heusler Alloy". J.
Phys. Soc. Japan 19 (8): 14941495. doi:10.1143/JPSJ.19.1494 (https://dx.doi.org/10.1143%2FJPSJ.19.1494).
12. Geldart D.J.W. and Ganguly P. (1970). "Hyperfine Fields and Curie Temperatures of the Heusler Alloys
Cu2MnAl, Cu2MnIn, and Cu2MnSn". Physical Review B1 (7): 3101. Bibcode:1970PhRvB...1.3101G
(http://adsabs.harvard.edu/abs/1970PhRvB...1.3101G). doi:10.1103/PhysRevB.1.3101 (https://dx.doi.org
/10.1103%2FPhysRevB.1.3101).
13. Lapworth A.J. and Jakubovics J.P. (1974). "Effect of antiphase boundaries on the magnetic properties of
Cu-Mn-Al Heusler alloys". Phil. Mag. 29 (2): 253. Bibcode:1974PMag...29..253L (http://adsabs.harvard.edu
/abs/1974PMag...29..253L). doi:10.1080/14786437408213271 (https://dx.doi.org
/10.1080%2F14786437408213271).
14. . doi:10.1016/j.jmmm.2008.003 (https://dx.doi.org/10.1016%2Fj.jmmm.2008.003). Missing or empty |title=
(help)
15. Kumar, K. Ramesh; Bharathi, K. Kamala; Chelvane, J. Arout; Venkatesh, S.; Markandeyulu, G.; Harishkumar, N.
(2009). "First-Principles Calculation and Experimental Investigations on Full-Heusler Alloy Co2FeGe". IEEE
Transactions on Magnetics 45 (10): 3997. Bibcode:2009ITM....45.3997K (http://adsabs.harvard.edu
/abs/2009ITM....45.3997K). doi:10.1109/TMAG.2009.2022748 (https://dx.doi.org
/10.1109%2FTMAG.2009.2022748).
Further reading
Elert, Glenn. "Ferromagnetism" (http://hypertextbook.com/physics/electricity/ferromagnetism/). The
Physics Hypertextbook.
G. Sauthoff: Intermetallics, Wiley-VCH, Weinheim 1995, S. 83 u. 90.
T. Block, M. J. Carey, B. A. Gurney, O. Jepsen (2004). "Band-structure calculations of the
half-metallic ferromagnetism and structural stability of full- and half-Heusler phases". Physical
Review 70 (20): 205114. Bibcode:2004PhRvB..70t5114B (http://adsabs.harvard.edu
/abs/2004PhRvB..70t5114B). doi:10.1103/PhysRevB.70.205114 (https://dx.doi.org
/10.1103%2FPhysRevB.70.205114).
PJ Webster (1969). "Heusler alloys". Contemporary Physics 10 (6): 559577.
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Bibcode:1969ConPh..10..559W (http://adsabs.harvard.edu/abs/1969ConPh..10..559W).
doi:10.1080/00107516908204800 (https://dx.doi.org/10.1080%2F00107516908204800).
External links
National Pollutant Inventory Copper and compounds fact sheet (http://www.npi.gov.au/database
/substance-info/profiles/27.html)
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