www.tnschools.co.

in
www.tnschools.co.in

gf Jiw

nkiy gfSfhd fw flf

mKf

khy fa Muh kW g Wtd, 2016-17M faho

nkiy gf fw juid ca nj Gfhoid nkgL

Jtjbfd j, My, fzF, aa, nta, c-jhtua, c-

ya, a, tuyhW, bghUa, tfa, fzFga Ma

ghlfSfhd fw flffis cUth csJ.

Fiwj kbg bgW khztid njbgw jFgLJtJ, nj

UF khztid mf kbg bgw itgJ, mf kbg

bgW tUw khztfis KG kbg bgw tfhLtjFkhd yFfis

KW flf totikfgLsJ.

mu dhjh l tiu mogil khztf nj Gfh

oid mfF neh cUthfgLs flfid khztfSF

eKiw vLJ brW, khztfis njfis vbfhsjf J

jdif ftfshf cUthFkhW khy fa Muh kW g

Wtd midJ Ma bgUkfis nfL bfhwJ.

 www.tnschools.co.in

Ntjpapay;
tpdhj;jhs; jpl;l tiuT (Blue print)

t.vz; ghlk; 1 khh;f; 3 khh;f; 5 khh;f; 10 nkhj;jk;

khh;f;
1 mZ mikg;G 2 1 1 -- 10
2 Mth;jd ml;ltiz 1 1 -- 1 09

3 P njhFjp jdpkq;fs; 1 2 -- 1 12

4 d njhFjp jdpkq;fs; 2 2 1 1 18

5 f njhFjp jdpkq;fs; 2 -- 1 -- 07

6 mizTr; Nrh;kq;fs; 1 -- 1 1 11
7 cl;fU Ntjpapay; 1 1 -- 1 09
8 jpl epiyik 1 1 -- 1 09
9 ntg;g ,af;ftpay; 2 1 1 -- 10
10 Ntjpr;rkepiy 2 1 1 -- 10
11 Ntjp tpid Ntftpay; 1 2 1 -- 12
12 Gwg;gug;G Ntjpapay; 3 1 -- 1 11

13 kpd; Ntjpapay; -I 1 1 -- 1(1) 14

14 kpd; Ntjpapay; -II -- -- 1 1 10

15 fhpk Ntjpapay; khw;wpak; -- 1 -- 1 08

16 i`buhf;rp topg;nghUl;fs; 1 2 -- 1 12
17 <jh;fs; 2 -- 1 -- 07
18 fhh;Nghidy; Nrh;kq;fs; 1 1 1 1 14
19 fhh;ghf;rpypf; mkpyq;fs; 1 1 1 1 14
20 iel;Nuh Nrh;kq;fs; 3 1 -- 1 11
21 caph;Ntjp %yf;$Wfs; 2 -- -- 1 07
22 eilKiw Ntjpapay; -- 1 1 -- 08
$Ljy; 30 21 12 14 233

khzth;fs; vspjpy; Njh;r;rp ngwTk; mjpf kjpg;ngz; ngWk; tifapYk;>

tpdhj;jpl;l tiutpd;gb Ntjpapay; ghlj;jpl;lj;jpy; cs;s ghlq;fs; mitfSf;F
toq;fg;gl;l kjpg;ngz; mbg;gilapy; fPo;f;fz;lthW ml;ltizg; gLj;jg;gl;Ls;sd.
www.tnschools.co.in

epiy 1
ml;ltiz 1
ghl vz; ghlk; 1 khh;f; 3 khh;f; 5 khh;f; 10 khh;f; nkhj;jk;

5 f njhFjp 2 -- 1 -- 07
jdpkq;fs;

7 cl;fU Ntjpapay; 1 1 -- 1 09

8 jpl epiyik 1 1 -- 1 09

9 ntg;g ,af;ftpay; 2 1 1 -- 10

10 Ntjpr;rkepiy 2 1 1 -- 10

22 eilKiw -- 1 1 -- 08
Ntjpapay;

$Ljy; 53

Nkw;fz;l ml;ltiz 1 -go khztfis njF jahh; nra;jhy; mjpfgl;rk; 53

kjpg;ngz;fs; ngwyhk;.

epiy 2
ml;ltiz 2
ghl vz; ghlk; 1 khh;f; 3 khh;f; 5 khh;f; 10 khh;f; nkhj;jk;

2 Mth;jd 1 1 -- 1 09
ml;ltiz

12 Gwg;gug;G 3 1 -- 1 11
Ntjpapay;

17 <jh;fs; 2 -- 1 -- 07

$Ljy; 27

Nkw;fz;l ml;ltiz 1 kw;Wk; ml;liz 2 -go khztfis njF jahh;

nra;jhy; mf gr 80 kjpg;ngz;fs; ngwyhk;.
www.tnschools.co.in

epiy 3
ml;ltiz 3
ghl vz; ghlk; 1 khh;f; 3 khh;f; 5 khh;f; 10 khh;f; nkhj;jk;

1 mZ mikg;G 2 1 1 -- 10

4 d njhFjp 2 2 1 1 18
jdpkq;fs;

6 mizTr; 1 -- 1 1 11
Nrh;kq;fs;

14 kpd; Ntjpapay; -II -- -- 1 1 10

$Ljy; 49

Nkw;fz;l ml;ltiz 1 kw;Wk; ml;ltiz 2 kw;Wk; ml;ltiz 3 -go

khztfis njF jahh; nra;jhy; mf gr 129 kjpg;ngz;fs; ngwyhk;

epiy 4
ml;ltiz 4
ghl vz; ghlk; 1 khh;f; 3 khh;f; 5 khh;f; 10 khh;f; nkhj;jk;

3 P njhFjp 1 2 -- 1 12
jdpkq;fs;

16 i`buhf;rp 1 2 -- 1 12
topg;nghUl;fs;

$Ljy; 24

150 f;F 150 ngw tpUk;Gk; khzth;fSf;F

Nkw;fz;l ml;ltiz 1 kw;Wk; ml;ltiz 2> ml;ltiz 3 kw;Wk; ml;ltiz 4 cld;
kpd;Ntjpapay; I > Ntjptpid Ntftpay; kw;Wk; fhpk Ntjpapa khw;wpak; Ma
ghlfis nrJ khztfis njF jahh; nra;jhy; mf gr 150
kjpg;ngz;; ngwyhk;.
www.tnschools.co.in

1) Fwpg;G:

ehd;F ml;ltizfspYk; cs;s ghlq;fspy; gapw;rp mspj;J NkYk; 19 ghlq;fspYk;

cs;s 1 kjpg;ngz; jd; kjpg;gPL tpdhf;fisAk;> i`buhf;rp topg; nghUl;fs;> d njhFjp

jdpkq;fs; Mfpa ghlq;fSf;F muRg;nghJj;Njh;T tpdhf;fs;> ngw;Nwhh; Mrphpah; fof

ifNaL Mfpatw;wpy; jug;gl;Ls;s tpdhf;fs; kw;Wk; gapw;rpf; fzf;Ffs; Mfpatw;wpy;

gapw;rp nra;jy; Ntz;Lk;. (muR tpdhj;jhspy; Nfl;fg;gLk; ve;j xU tpdhtpw;Fk;

Ntjpapay; ghlg;Gj;jfj;jpy; tpil ,Uf;f Ntz;Lk; vd;w muR tpjpapd; gb tpdhf;fs;

miktjhy; tpdhtpd; ikaf;fUj;ij khw;whky; tpsf;Ff> tpthp> Fwpg;G tiuf> Vd; ?>

Nghd;w thh;j;ijfs; kl;LNk khw;wg;gLtjhy; tpdhtpd; ikaf;fUj;ij Fwpg;gpLk;

thh;j;ijfSf;F Kf;fpakspj;J mij epidtpy; nfhz;L gapy Ntz;Lk;.

2) xU kjpg;ngz; tpdhf;fs;
19 ghlq;fspy; jug;gl;Ls;s jd;kjpg;gPL tpdhf;fs;> muRg;nghJj;Njh;T tpdhf;fs;> ngw;Nwhh;
Mrphpah; fof ifNaL Mfpatw;wpy; jug;gl;Ls;s tpdhf;fisAk; jahh; nra;jy;
Ntz;Lk;.
3)

dhjh l tiugo xU kbg dhf 14>15>22

nffglhj ghlf

dhjh l tiugo _W kbg dhf 5>6>14>17>21

nffglhj ghlf
www.tnschools.co.in

5. f-

( : 54)

1. ? .

M3+

. .

4f - .
, 4f - .
,

2. .

Ln3+ tjh Ln3+ (OH)3 cs
3+
Ln kW (OH) ilna .
Ln3+ maf gUk tir La3+ > Ce3+ > Lu3+
.
.

d - 2M 3 M
.

.

3. , ?
:

.
, .

, nghwit gagLwJ.
, fY, ahf

gagLwJ.
- gagLwJ.
,
, f gagLwJ.
:
-235= shf, mQ Mj
jahf cj.
-238=
.
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4. , .

+3 +2,+4

+4 +2,+3,+5,+6

5. , .

1. 4f - 1. 5f -
.
.

2. 4f- 2. 5f-
. .

3. +4 3. +6

4. . 4. .

5. 5.
. .

6. . 6. .

7. . 7. .

8. 8.
.
.

9. . 9. .
.
.
 www.tnschools.co.in

6. ?

H2SO4
2100C

- Ln3+, Th4+ , H3O+,

SO4 2- , HSO4-, H2PO4-
SiO2,TiO2, ZrSiO4

( )

HF
F

yh>

NaOH

Mh;fhd; kz;lyk;
1.
/1270K

/
2.
.
www.tnschools.co.in

8. .

: ( :38)

1. .

n = 2d sin

n = ;
= X- ;
d = ;
= .

2. ?

.
.

gig bgWs nrkf m flf vdgL.

3. ?

,
.
.

.
NMR
.

4. ?

.

5. .
.
.
www.tnschools.co.in

6.(a)sc (b)bcc (c) fcc .

7. CsCl .
CsCl .

, .

.

Nc 8
= ----- = --- = 1
8 8

=
Nb 1
= ----- = --- = 1
1 1

= 1

o Cs+
-
Cl
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8. ?
(1) (2) (3)

.
(.) , .

9. .

NaCl
.
NaCl
.

. .

10. .

.
kw;nwhU ,U
Neh;kpd; nfhz;l madp mzpf;Nfhit jsj;jpy; cs;sJ.

.
(.) FeO FeS .

11; mjpkpd; flj;J epiykhW ntg;gepiy (Tc) vd;why; vd;d ?

xU Fl ntg;gepiyapy; xU nghUspd; kpd; jilahdJ jpBnud g+r;rpaj;ij
miltjhFk;.
12. %yf;$W gbfq;fs; gw;wp Fwpg;G tiuf
%yf;$W gbfq;fspy; cs;s mzpf;Nfhit Gs;spfspy; kpd;Rikaw;w
%yf;$Wfs; mike;Js;sd.
%yf;$W gpize;Js;s tpirfs; ,U tifg;gLk;
1. ,UKid - ,UKid fth;r;rp tpir v. fh. gfo
2. thz;lh;thy;]; tpirfs; %yf;$W gbfq;fspy cs;sJ

( : 66())

1. .
.
, .
.
.
.
.
.
www.tnschools.co.in

2. .

() :

.
.
,
.

.
(.) NaCl .

() :

.
Ag+ .
,
.

.
(.) AgBr .

3.
X - X-
.
() .
.
X -
.

.
.

.
www.tnschools.co.in

(100)
5.90 , 11.850 18.150 .
0.103 , 0.205 0.312 . 1:2:3
. , , .
.

4. f.
()
(d) .
(d)
.
.
() .
(n=1) .
()
. (n=2) .
,
.
. .

3. .
it ehF tif () :
.
.
- -
. (.) .
-
.
( ) :
.
(.) .
() :
.
,
.
 www.tnschools.co.in

.
. (.) .
() :
.

. . (.) NaCl .
6.
1.
.
.
2. , ,
.
3. .
.
4.
.
.
5.
.
.

9..
( :39)

1. ? ,
1. .

2. = ---------------------

q
S= ----- ;
T
3. : / / () eu / () J/K

3. ?

G = H - TS ; G = ; H = ; T = ; S =

4. .

,
,
.

5. .

21
// .
H vap
S(vap) = -------- = 21 / /
Tb
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5. () ?
, .
, .
madpAWk;; .
6. ?
,

.
, ,
.
7. jd;dpr;ir nray; Kiwf;fhd epge;jidfs; ahit?
G < 0 ; H < 0 kw;Wk; S > 0
G= vjph;FwpaPL > H = vjph;FwpaPL > S = Neh;;FwpaPL ngw;wpUf;fNtz;Lk;.

(muR nghJj; Njh;T kW; vLj;Jf;fhl;L fzf;Ffspy; gapw;rp ngWjy; Ntz;Lk;.)

1. .
:
,
,
.
:

.
:
.
.

:
.

:


= X 100

2. ?

I. .
q
II. S = ; =
T

III. .
.

IV. = +

= .
.
 www.tnschools.co.in

V. ,
.
VI.

(S) (+) (0) ( - )

x . : / / eu / . J/K

3. G- ?

1. G = H - TS ; G = ; H = ; T= ;
S = .
2. G = ; G = .
3. G ntg;g ,af;ftpay; gz;ghFk;.
4. G _W tif

(G)
(-) (0) (+)

5. G =H - TS;
H = E+PV;
E = q - w ;
TS = q
G= q w + PV - q
= - G = w - PV ;

10.

( :40)

1. .
, , ,

.
a A+b B c C+d D

[C]c[D]d
Kc=
[A]a[B]b

2. ?

.

www.tnschools.co.in

3. .

.

4. Q .
, ,

Q .

5. Cl2 PCl5 ?
PCl5 PCl3 + Cl2

[ PCl 3] [ Cl 2 ]
Kc =
[ PCl 5 ]

Cl2
. Cl2 PCl5 .

6. ng = 0, ng = -ve ng = +ve
?

ng=0 Kp = Kc ;

ng= -ve Kp Kc , (Kp < Kc ).

ng= +ve Kp Kc , (Kp > Kc).

7. ng .

1. H2 (g) + I2 (g) 2HI ( g)

n g = (n p - n r)g = 2 - 2 = 0

2. H2O (g) + 2 Cl2 (g) 4HCl (g) + O2 (g)

n g = (n p - n r)g = 5 - 4 = 1

8.
.

i) H2O2(g) H2O(g) + O2(g)

ii) CO(g) + H2O(g) CO2(g) + H2(g)
iii) N2O4(g) 2 NO2(g)
 www.tnschools.co.in

( :57)

1.
.
Fe
N2(g) +3H2(g) 2NH3(g) H = - 22 kcal / mole.

NH3

H2 : N2 3:1
300 - 500 atm.
5000C - 5500C
(Fe)
NH3 37%
.

2. (SO3)
.
V 2 O5
2SO2(g)+O2(g) 2SO3(g) H = - 47 kcal / mole.

SO3
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SO2 : O2 2:1

700 - 1200 atm.

4000C - 4500C

(V2O5)

SO3 97%

SO3 cld; Nrh;j;J xypak; kw;Wk; H2SO4 jahhpf;fg;gad;gLfpwJ..

3. KP =KC(RT)ng
.
aA+bB+cC+...... lL+mM+nN+.........

PLl PMm PNn ........

Kp =
PAa PBb PCc ........

[L]l [M]m [N]n .......

Kc =
[A]a[B]b[C]c .......

Ci = Pi/ RT Pi = niRT/V

(PL/RT)l (PM/RT)m (PN/RT)n .......

Kc =
(PA/RT)a (PB/RT)b (PC/RT)c .......
( l+m+n+. . . ) - (a+b+c+. . ..)

PLl PMm PNn ...... 1

Kc =
PAa PBb PCc ..... RT

Kp
Kc =
ng
(RT)
Kp = Kc (RT) ng
ng =tpidtpis nghUl;fspd; Nkhy;fspd; v;z;zpf;iff;Fk; tpidgL nghUl;fspd;
Nkhy;fspd; v;z;zpf;iff;Fk cs;s NtWghL
4. HI Kc Kp
.

H2(g)+I2(g) 2HI(g) ng=0 Kp=Kc ;

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H2 I2 HI

a b 0

X X 0

(a - x) (b- x) 2x

(a - x) (b - x) 2x

V V V
[ HI ]2

KC =
[ H2] [ I2 ]
2
2x

V
Kc =
(a - x) (b - x)

V V

4x2

Kc = = Kp Vnddpy; ( ng = 0 )
(a - x) (b- x)

X MdJ tpidepfOk; vy;iy

5. PCl5 Kc Kp
.

PCl 5 (g) PCl3 (g)+Cl2 (g)

PCl5 PCl3 Cl2

a 0 0
x 0 0

(a - x) x x

(a - x) x x

V V V

[ PCl 3] [ Cl 2 ]
Kc =
[ PCl 5 ]
www.tnschools.co.in

x x

V V x2 V

Kc = =
(a- x) V2 (a-x)

x2
Kc =
(a - x) V

rpijtile;j Nkhy;fspd; vz;zpf;if

X=
njhlf;fj;jpy; cs;s Nkhy;fspd; vz;zpf;if

PPCl3 P Cl2
Kp = atm
PPCl5

x2 P
Kp = atm
(1 - x ) 2

22. . ( :51,63)
%d;W
1. ? .)

. it U tifgL
: .
.
:
, .
(.) , , .
2. ? .

(t (m) t kUJf) .
(.) .
3. ?
.(
.(.) , .

4. () .
,
. .) , 0. 2% .
www.tnschools.co.in

5. ( ) ?
.. .

.
. 103 - 1060 F .

. .
. (.)
bfhL FzgLjyh.
6. ? .. .
, .
,
.
.
(.) .

7. ?

.
(.) , .
8. ? .. .
, ,
. (.) .
9. ,
?(M,08;)

, .

10 ? .. .
,
.(.)
.

11. .
.
. , ,
, .
(.) - C , - E , - .

12. -S .

,
.
Na
nCH2 = CH CH =CH2 + nCH = CH2 CH2 CH= CH- CH2 - CH CH2

gpl;lhilapd; C6H5 C6H5 n

-S
];ilhpd;

J v njkhd miltiy
,, .
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13. -N ?
, ,
-N .

Na

2CH2 = CH CH =CH2 + CH2 = CH CH2 CH - CH2 CH - CH CH2

gpl;lhilapd; CN
CH CH CN
mf;hpNyh iel;iuy;;

CH2 CH2
-S n

vbz bgnuh Matwh gUk bgUf milahJ.

fis .

14. (m)() PET ? .

.

n[OH- CH2- CH2 - OH] + n[HOOC COOH]

fpisf;fhy;

O- CH2 - CH2 -OOC co

, , , .

15 . -66 ? ?

, -66

. H2N-(CH2)6 - NH2+ HOOC-(CH2)4 -COOH (-HN-(CH2)6-NH-OC-(CH2)4 - Co -)n

-66
iHf tikahdit, v njtiy.
, , .

16 . .

, .

. (..) , .
www.tnschools.co.in

( :63)
1. .
1. .
2. , .
3. .
4. , , .

2. rhaq;fspd; epwk; kw;Wk; mikg;ig tpsf;Ff.

- ( )
.
(v.fh .)iel;Nuh > fhh;Nghdpy; > mNrh njhFjpfs;.
epwk; Njhw;Wtpg;ghd;fs;
epwk; cwpQ;rpfisg; ngw;wpUf;Fk; Nrh;kq;fisNa epwk; Njhw;Wtpg;ghd;fs;
vd;fpNwhk.;
v.fh <jPd; (CH2 = CH2) wkwJ. Mdh CH3- (CH = CH)6-CH3 kr wKilaJ.
epwk; cah;j;jp
epwk; Njhw;Wtpg;ghd;fspd; epwj;ij mjpfhpf;Fk; njhFjpfs; epwk; cah;j;jp
MFk;.
v.fh - OH, -NH2
rhak; v.fh. ghuhi`l;uhf;rp mNrhngd;rPd; (ufhrkhd t w)

3. .
1.

2. ,
.
3. , .
4. .
5. ,
j; . .
v.fh: , , .
7.
3 [ :37& 65()]

1. .

. t1/2 = 0.693 /
2. . Q ?

Q . Q = (mp - m r ) 931 MeV
Q = + = ;
Q = -- = .
www.tnschools.co.in

3. .:

.

29 Cu63 + 2He4 + 400 MeV 17 Cl37 + 14 1H1 + 16 0n1

4. cl;fU gpizg;G Mw;wy; vd;why; vd;d ?
Xh; cl;fU cUthFk; NghJ rpwpJ epiw Mw;wyhf khw;wg;gLfpwJ. MfNt
mZepiwahdJ mt;tZtpYs;s GNuhl;lhd;fs;, epl;uhd;fs; kw;Wk; vyf;l;uhd;fspd; epiwfspd;
$l;Lj;njhif tpl FiwthFk;. ,e;j epiw FiwT kw;Wk; Mw bjhlig E = mc2 vw
rkghil _y mayh.
5. fjphpaf;f fhh;gd; fhy eph;za Kiwapd; gad;fs; ahit?
.


.

(muR nghJj; Njh;T kw;W vLj;Jf;fhl;L fzf;Ffspy; gapw;rp ngWjy;Ntz;Lk;.)

5.
1. .
3.7 x 10 33
.

.
GNuhl;lhd; - GNuhl;lhd; rq;fpyp tpid

1 H1 + 1H1 1 H2 + +1 e0 +
ghrpl;uhd;

1 H2 + 1H1 2 He3 +
;

2 He3 + 1H1 2 He4 + e0 +

+1

Nkw;fh tpidfspd; njhFg;G

41H1 2He4 + 2 +1 e0 +

2. ?

Sl.No

1 ,,
, , .
.
2 . , .
3 . .
4 : / : MeV
5 idnghJ idnghJ
. .
www.tnschools.co.in

3. .
jhtu kW yFf
6C14 .

C14.

7 N14 + 0n1 6 C14 + 1H1

C14 14CO2 .
C14 ,
.
, C14 C14 .
6 C14 7 N14 + -1e0
5700 .
C14

.
.
2.303 x t1/2 C14
t= log
0.693 C14

4. .

Sl.No

1
2 - 11
3 - 14

4 - 131
ijjjajiraj
5 - 197
6 - 32
7 - 59
8 - 60
9 - 24
10 - 198

5. .
.

.

.
, .

(i) +

(ii) 3 Li6 + 0n1 1 H3 + 2He4 + 4.78 MeV

(iii) 1H + 1H He4 + 0n1 + 17.6 MeV

2 3
2
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6. cl;fU gpizg;G tpid kw;Wk; cl;fU gpsg;G NtWg;gLj;Jf.

Sl.No. :

1 fdkhd


2 eilbgw
kl;Lk; epfOk;. Njitapy;iy
3 rq;fpyp njhlh; tpid ,y;iy. rq;fpyp njhlh; tpid.
4 i`l;u[d; Fz;L ntbj;jypy; mZFz;L ntbj;jypy; ,t;tif
,t;tif tpid epfo;fpwJ. tpid epfo;fpwJ..
5 ntsptUk; Mw;wy; = 17.6MeV ntsptUk; Mw;wy; = 200MeV
7. ia tpsf;Ff.

. .

.
.
.
.
92U235 + 0n1 56Ba140 + 36Kr93 + 3 0n1 + 200MeV
8. ia tpsf;Ff.

.

. .
(108k)
.
1 H2+ 1 H3 2He4 + 0 n1 +

+ + +

9. jf;f rhd;WfSld; fjphpaf;f INrhNlhg;Gfspd; gad;fis tpthp.

1) jhtu xspr;Nrh;f;if tpid topKiw

2) v];lh; ePuhw;gFg;G tpid :

v];liu ePuhw; gFf;Fk;NghJ O17 cs;s ePh; gad;gLj;jg;gl;L tpid epfo;e;J
fpilf;Fk; mkpyk; kw;Wk; My;f`hiy Muha;e;jhy;mkpyj;jpy O17 cs;sJ mwpag;gl;lJ.
www.tnschools.co.in

TLj dh il
mQ mik
_W kbg dhf (nf v;31)

1. bArg iyyh bfhifia vGJf. (M,06;O,07;M,08;O,09)

xnu neu f Jakhf E Jf iy kW irntf Matiw

msl KoahJ
x.p h/4

2. vF vyuh Mw KaJtij vGJf. .(J,08;J,09;J,10)

Koyh bjhiy cs xU vyuh Mw {a MF. J
{a Mw iy vdgL.
vyuh efJ mQfU ftF cgLnghJ mJ ntiyia
brtjh Mwiy HwJ.
vdnt vyuh Mw FiwJ bfhnl tJ {aijl
Fiwth vF kig bgWwJ

3. iz ju tiuaW. (J,07;M,10;)

iz Mlh vyuhf vifF , viz Mlh

vyuhf vifF cs ntWgho gh msthF.

Nb Na
iz ju =
2

N b = iz Mlh vyuhf
N a = viz Mlh vyuhf
4. He2 _yTW cUthtiy. V? (M,07;O,08;)

a vyuh mik 1S 2
He2 _yT ehF vyuhf csd.
2 2
He2 _yT vyuh mik : He2 : ( 1s) ( * 1s )

Nb Na 2 2
iz ju = = =0
2 2

iz ju {akhf Ugjh He2 _yTW cUthfhJ.

www.tnschools.co.in

5. Jf,miy ntWgLJf.(J,06.)

Jf miy

ml eF tiuaWfgl midJ lfY gu

lij bgWsJ. fhzgLwJ.

xU Jf lij kbwhU Jf uL myJ mjF nkgl

Mugiy. miyf xnu lij MuF.

Fl l cs Jff Fl l cs miyf
vif mt TLjYF vif bkhjijl
rk. TLjyhfnth, Fiwthfnth
UF.

6. dfy vwh vd?

VwFiwa rkkhd Mw bfhl mQ Mlhf xWl xW fyJ rkkhd

MwYila, xj totKila Mlhfis jUtJ dfy vdgL.

7. iAu# iz vwh vd?

xU _yT rfiz cs iAu# mQF , mf vyuh

ftjik bfhl mQF ilna fG UKid-UKid ft irna
iAu# iz vdgL.

8. iAu# iz cUthtjfhd fhuzf ahit?

iAu#Dl izJs mQthdJ

. a cUt ms

. mf vyuh vyuh ftjik bfhljhf Uj ntL.

9. Mlh tiuaW?

Mlh vgJ xU mQ mQfUit Rs gF Fl Mw

bfhLs mfgr vyuh fjf MF.

IJ kbg dhf (nf v: 52)

1. nlr b#k nrhjidia sF.

btggLjgl ll iHUJ btgL vyuh fiwia

cane mGj brYJnghJ KLf milwd.
vyuhf btntW irf jwofgLwd.
KLf bgw vyuh fiwia bga xiw f gof J H
brnghJ vyuhf btntW irf jwofgLwJ.

thW bgwgL tis X-ff _y bgwgl tisngh

csJ.
X-ff miygig bgUgjh vyuhfS miygig bgWsd.
www.tnschools.co.in

tis nrhjid _y mslgl miys k o-uhns rkgho

_y fzlgl miys k xwhf csJ
nkTa TWfUJ vyuh miyjikia bgUgJ %gzkhwJ.

2. _yTW Mlh bfhif nfhghLfis vGJ.

_yT vyuhf mikJs a Mlhf _yTW Mlhf

vdgL.
rk MwYila myJ VwFiwa rk MwYila mQ Mlhf iztjh
_yTW Mlhf cUthwd.
iz mQ Mlhf vif, cUthF _yTW Mlhf
vif rk.
uL mQ Mlhf izJ uL _yTW Mlhf cUthwd.
mt mf Mwiy bfhlJ v iz _yTW Mlh vd, Fiwj
Mwiy bfhlJ iz _yTW Mlh vd miHfgLwd.
_yTW Mlhf iz mQ Mlhf totijna bgWsd.
iz _yTW Mlhf : , ,
v iz _yTW Mlhf : * , * , *
_yTW Mlhf Mw VWtir uggLwd.(M~gh jJt)
xU _yTW Mlh v v RHia cila uL vyuhfis kLnk
ug aY.( bgs j jJt)
uL rk Mw cila _yTW Mlhfis unghJ xiw ujiy
brj wnf vyuh iz MF. (A] )

3. ieu# _yTW cUthjiy _yTW Mlh bfhifgo sFf.

ieu# mQ v: 7 , vyuh mik: 1s2 2s2 2px1 2py1 2pz1
ieu# _yT cs vyuhf vif = 1
2 2 2 2 2
_yTW Mlh vyuh mik : KK (2s) (*2s) (2px) (2py) (2pz)
Nb Na 8 2
iz ju = = = =3
2 2
iz ju 3 , vdnt Kiz csJ.
midJ vyuhfS izahf csjh ilah fhj jik cilaJ.
_yTW Mlh Mw kl tiugl:
www.tnschools.co.in

4. M# _yTW cUthjiy _yTW Mlh bfhifgo sFf.

2 2 2 1 1
M# mQ v: 8 , vyuh mik: 1s 2s 2px 2py 2pz
M# _yT cs vyuhf vif = 16
_yTW Mlh vyuh mik : KK 2s)2 (*2s)2 (2pz)2 (2px)2 (2py)2 (*2px)1 (*2py)1
(Nb - Na) 8-4
iz ju = -------- = ------- = 2
2 2
iz ju 2 , vdnt uil iz csJ. jj vyuhf uL
csjh ghuh fhj jik cilaJ.
_yTW Mlh Mw kl tiugl:

5. o-uhns bjhlid tU.

sh rkghL: E=h
IO rkghL: E = mc2
uil izf h = mc2
= c/ v
hc/ = mc2
= h/mc
www.tnschools.co.in

C F gyhf irntfij V vd vGdh

= h/mv (myJ) = h/p
= miys: h = sh kh; m= Jf iw; v = irntf
6. dfy ga Ka fUJfis vGJ.
VwFiwa rk Mw cila Mlhf dfy <LgLwd.
xnu mQ Mlhf dfy <LgLwd.
dfy <LgL Mlhf vif cUthF dfy
Mlhf vif rk.
dfy Mlhf xnu tot mik, xnu Mwiy bgWsd.
iz <LgL dfy Mlh xnu xU vyuhid kL bgWsJ.
yF ir fhuzkhf vyuhf mf bjhiy csd.
mQ Mlhf neuoahf nkbghUdh kh iz cUthwJ.
mQ Mlhf gftho nkbghUdh ig iz cUthwJ.

4.d-bjhF jkf.(nf v:35,36)

1. iliy jkf miz nrkfis cUthFtJ V? (J,06;O,07;J,08;J,09;M,10)
a cUt ms.
mf ne ml.
<f cs jj vyuhfis bgW izig VgLj fhahd (n-1) d
Mlhfis bgWsd.
2. d-bjhF jkf khWgL M#ndw iyia bgUgnj? (O,06;M,07;J,07;M,09;)
d- bjhF jkf (n-1)d kW ns vyuhfis bfhLsd.
(n-1) d kW ns MlhYF cs Mw ntWghL f Fiw.
3.d-bjhF jkf wKs mafis njhWgj fhuz ahJ?

jj vyuh mik.
xnu d iz To mLjLj Mw klfSF Mw ntWghL Fiw.
xU Mw klUJ mLj Mw kl bry Fiwj Mw nghJ.
j Mwiy fQF ydhF x UJ crgl xF <lhd
kbwhU wij mafSF bfhLwJ.
4. Fnuh Kyh Rj g vGJ.(O,06;M,08;M,10;)
v th : Fnuh Kyh r ntoa bghU
ne th : by jfL
gF : Fnuh my + fjf my
dh gFnghJ Fnuha bghU J (v th) gowJ.
Fnuh Kyh RtjF K f Kyh rgLwJ.
5. t cj vwh vd? mij vthW jfyh? (O,07;O,08;)

xU klF cUa t 20 klF M#id cRwJ.

jid FF nghJ ca M#id btLwJ. jF t cj
vW bga.cUa t J f glyij Rtj _y jid jLfyh.
www.tnschools.co.in

7. Fnuhik FnshiuL nrhjid g vGJ. (M,09;)

FnshiuL c + bghlha ilFnuhnk + ml fjf my fyitia
NLgLdh t MuR wKila Fnuhik FnshiuL cUthwJ.
gg gFgh FnshiuL cig fla id gagLwJ.
K2Cr2O7 + 4 KCl + 6 H2SO4 2CrO2Cl2 + 6KHSO4 + 3H2O

7. fhg <ufh vthW idwJ?

CO2 kW <ufhWl fhg idJ gir w fhu fhg fhgnd gotij jUwJ.
2Cu + O2 + CO2 + H2O Cu(OH)2.CuCO3

8.fhg J btg is ahJ?

fhgiu 1370K F btggLJnghJ fU w F MirL cUthwJ.
2Cu + O2 2CuO
fhgiu 1370K F nk btggLJnghJ t w Fu MirL cUthwJ.
4Cu + O2 2Cu2O
9. Fnuha ml r~ myJl vthW idwJ?
Fnuha ml r~ myJl idJ Fnuh rngil jUwJ.

2Cr + 6H2SO4 Cr2(SO4)3 + 3SO2 + 6H2O

10. shrg c myJ shrg fg vwh vd? mJ vthW jahfgLwJ?

MirL shrg c vd miHfgLwJ. fh 773K vJ J
cUthwJ. 773K

2Zn + O2 2ZnO

11. ie myJl vthW idwJ?

4Zn + 10HNO3(j) 4Zn(NO3)2 + N2O + 5H2O

ieu MirL
4Zn + 10HNO3(f j)
4Zn(NO3)2 + NH4NO3+ 3H2O
mnkha ienu
12. ml NaOH cl vthW idwJ?

ml NaOH cl idJ nrhoa nfil jUwJ.

Zn + 2NaOH Na2ZnO2 + H2

13. jf uh# uhtfJl vthW idwJ?

uh# uhtf = 3 gF ml HCl + 1 gF ml HNO3

jf uh# uhtfJl idJ M Fnshiuil jUwJ.

2Au + 9 HCl + 3 HNO3 2AuCl3 + 3 NOCl + 6 H2O

www.tnschools.co.in

14. bghlha il Fnuhnko M#ndw gid sF.

~bgu rngil , ~bg rnglhf M#ndw mila brwJ.

iAu# rigil , rguhf M#ndw mila brwJ.
bghlha mnahilil , mnahodhf M#ndw mila brwJ.

K2Cr2O7 + 6 FeSO4 + 7 H2SO4 K2SO4 + Cr2(SO4)3 + 3 Fe2(SO4)3 + 7H2O

15. fhg rng (k Jj) vthW jahfgLwJ?
F MirL, F iAuhirL myJ F fhgnd j H2SO4 cl
idJ fhg rng bgwgLwJ.

CuO + H2SO4 CuSO4 + H2O

Cu(OH)2 + H2SO4 CuSO4 + 2H2O

CuCO3 + H2SO4 CuSO4 + CO2 + H2O

16. fhg rngo J btg is ahJ?

btgiy 100oC 230oC 720oC

isbghU CuSO4.H2O CuSO4 CuO + SO3

100oC 230oC 720oC

CuSO4.5H2O CuSO4.H2O CuSO4 CuO + SO3
(y w) - 4H2O - H2O (btik w)

17. t ienu myJ dh fho vthW jahfgLwJ?

cnyhf t j ie myJl idnghJ t ienu cUthwJ.
3Ag + 4HNO3 3AgNO3 + NO + 2H2O
18. t ienu J btg is ahJ?

btgiy 723K 980K

isbghU t ieiu (AgNO2) cnyhf t (Ag)

723K 980K
2AgNO3 2AgNO2 + O2 ; AgNO2 Ag + NO2

19. nfa Cjh g vGJf.

nfa Cjh vgJ Tk nfhL , nl iAuhirlh crgl fyit
MF.
fU Cjh myJ t w cilaJ. nfa vgtuh flaglJ
f j nfhL FnshiuLl nld Fnshiuil idgLdh ilF
nfhL , nl iAuhirlh crgL J ilwJ.
gaf: % t w fzho , caju kghlf jahf gagLwJ.
 www.tnschools.co.in

2AuCl3 + 3 SnCl2 2 Au + 3 SnCl4

SnCl4 + 4 H2O Sn(OH)4 + 4 HCl

20. bghlha il Fnuhnko J btg is ahJ?

4K2Cr2O7 4K2CrO4 + 2Cr2O3 + 3O2
bghlha Fnuhnk
21. d bjhF jkf idahf gagLwd V?
I) ntWgl M#ndw iyfis bgUgjh it gy idgL
bghUfSl nrJ iliy bghUfis jUwd.
II) it jkfSilgl nrkfis cUthF jikia bgUwd.
nrkf gu ftF cgL idgL bghUfis sw brwd.
22.fhyik jahF Kiw ahJ?

rng fiurYl NaHCO3 fiuriy nrJ idgLJ nghJ ZnCO3

clhwJ.

ZnSO4+2NaHCO3 ZnCO3+Na2SO4+H2O+CO2

IJ kbg dhf [nf v: 53, 70(M)]

1. bsoUJ vthW bjLfgLwJ?

1 cnyhf

2 Ka jhJ s (ZnS)
3 mlj Eiu j Kiw
4 Cnyhfa (i) tWj mlfgl jhJ 1200K fh tWfgLwJ.
2ZnS + 3O2 2ZnO + 2SO2
(ii) xLf ZnO + C Zn + CO
v th: a jfL
5 dh ikgLJj ne th: khR fyj
gF: ZnSO4 + j H2SO4 rhuij
brYJnghJ a v th gowJ.

2. t mj Ka jhJUJ vthW bjLfgLwJ?

1 cnyhf t

2 Ka jhJ mb#il(Ag2S)

3 mlj Eiu j Kiw

4 cnyhfa: (i)jhJ NaCN mlfgl jhJ 0.4-0.6% nrhoa

kh Mj cl id j raidLl idgL nrhoa mb#nlh
ghu raidL raidL cUthwJ.
Kiw (ii)t
Ag2S + 4 NaCN 2Na[Ag(CN)2] + Ag2S
www.tnschools.co.in

gothj nrhoa mb#nlh raidL Sl

idJ t gothwJ.

2Na[Ag(CN)2] + Zn 2Ag + Na2[Zn(CN)4]

5 dh ikgLJj v th: a t jfL ne th: khR

fyj t gF: AgNO3+ 1 % j HNO3
rhuij brYJnghJ a t v
th gowJ.

3.nfhL(jf) mj Ka jhJUJ vthW bjLfgLwJ?

1 cnyhf jf

Ka jhJ MW gLif kYs nfhL

mlj Eiu j Kiw

mlfgl jhJit fh tWFnghJ S, As,

Te Mait MirLfshf btnaWwd
(i)tWj

cnyhfa: 0.5 % KCN cl idJ fiuaToa

kh Mj bghlha Mnuh raidL cUthwJ.
ghu (ii)KCN nrj
4Au + 8 KCN + 2 H2O + O2 4K[Au(CN)2]
raidL Kiw
+4KOH

(iii)nfhil bghlha Mnuh raidL Sl

gothf idJ nfhL gothwJ.
2K[Au(CN)2] + Zn 2Au + K2[Zn(CN)4]
dh ikgLJj v th: a nfhL jfL ne th: khR
fyj nfhL gF: AuCl3+ 10-12% j HCl
rhuij brYJnghJ a nfhL v
th gowJ

4.mYndh btg xLf Kiw sFf?

Fnuha MirL, mYa 3 : 1 j fyJ bka ,nga

bguhirLl fk F bka ehlhdh lgLwJ.Fnuh MirL
Fnuhakhf xLfgLwJ. Al2O3 frlhf fgLwJ.

Cr2O3 + 2Al 2Cr + Al2O3 + 468.6 kJ

www.tnschools.co.in

5.Fnuhik jhJ UJ bghlha il Fnuhik vthW jahfgLwJ?

(i)Fnuhik jhJ UJ nrhoa Fnuhnk jahj mlfgl jhJ nrhoa

o
fhgnd, Rl Rzhl v md ciy 900-1000 C idgL kr w nrhoa
Fnuhnklhf khWwJ.

4FeO.Cr2O3+8Na2CO3 +7O2 8Na2CrO4+2Fe2O3+ 8CO2

(ii)nrhoa Fnuhnko UJ nrhoa il Fnuhnk bgWj nrhoa Fnuhnk fiurYl

r~ my nrf nrhoa il Fnuhnk cUthwJ.

2Na2CrO4 + H2SO4 Na2Cr2O7 + Na2SO4 + H2O

(iii)nrhoa il Fnuhnkil bghlha il Fnuhnklhf khWjnrhoa il Fnuhnk KCl

cl idJ bghlha il Fnuhnk cUthwJ.

Na2Cr2O7+ 2KCl K2Cr2O7 + 2NaCl

6. cnyhf nrk gaf

1. bghlha il Fnuhnk (K2Cr2O7) (1)gUkd gFgh (2) njh gjgLJj (3)

fhnfh mLj (4) rha bjh (5)xgla (6) b#yho iHfis fodgLJj .

2. fhg rng (k Jj) (CuSO4.5H2O) (1)U eh (2) bfh (3) fhg

rng + fha iAuhirL fyit nghnlh fyit vw bga bfh (4)
Kyh Rj (5) fhnfh mLj (6) nglf.
www.tnschools.co.in

3. t ienu (dh fho) (AgNO3) (1)ifgl bjh gagL t

AhiyLf jahf (2) fzhofSF rhf (3) ik, Korha jahf (4) t Kyh
r (5) Mtf ntfuahf.

4. fhgnd (fhyik) (ZnCO3) (1)njh nehia FzgLJ fghf (2) mHF

bghUf jahf (3) ug bjhrhiy wahf.

5. nfa Cjh (1)% t w fzho jahf (2) caju kghlf jahf.

7. cnyhf nrkf gafis vGJ.

7. t ehza UJ tiu vthW fyh?

t ehza tU, fhgU fyj cnyhf fyit.

t ehza + ie my t ienu + fhg ienu

ml HCl

t FnshiuL

t FnshiuL nrhoa fhgndlh xLfgL tuhf khwgLwJ.

4AgCl + 2Na2CO3 4Ag + 4NaCl + 2CO2 + O2

ilj t cl nghuh nrfgL dh ikahf bragLwJ.

6. miz nrkf
IJ kbg dhf [nf v:55&65(m)]
11. btd miz nrk ga bfhifid t.

xbthU cnyhf ma U tif izwfis bgWsd.

mit (i) Kjik izw (ii) ulh iy izw.

t. v Kjik izw ulh iy izw

1. M#ndw iyia FF. miz viz FF.

2. maW izw mawh izw.

www.tnschools.co.in

3. ir neha a ilahJ. ir neha a bfhlit.

4. v mafsh kLnk iw bragL. v maf (m) eLiy

_yTWfsh iw
bragL. it <f
vdgL.

5 <f cs g bgwhj vyuh izf ika cnyhf maF

tHfgLtjh miznrkf cUthwd.

2. .

.

-
.

. .

miz v dfy mik

2 Sp nenfhL
4 sp3 ehK
4 dsp2 rJu js
6 d2sp3 vK
6 sp3d2 vK

fhj U w s = n(n+2) BM

xiw fhj U
vyuhf w(BM)
vif
1 (1+2) = 3 = 1.73
2 2(2+2) = 8 = 2.83
3 3(3+2) = 15= 3.87
4 4(4+2) = 24 = 4.90
5 5(5+2) = 35 = 5.92
www.tnschools.co.in

3. bfhLfgLs miz nrkfSF tUtdtiw Ff. (a)

IUPAC bga (b) ika cnyhf ma (c) < (d) miz v (e) tot.
4.
1 miznrk K4[Fe(CN)6] K3[Fe(CN)6] [Cu(NH3)4]SO4
2 ika cnyhf U (II) U (III) fhg (II)
ma
3 < randh randh mik
4 M#ndw +2 +3 +2
iy
5 miz v 6 6 4
6 mik vK vK rJu js
7 IUPACbga bghlhabArh bghlhabArh bluhmik
randh~bgnu(II) randh~bgnu(III) fhg(II)rng
8 miz [Fe(CN)6]4- [Fe(CN)6]3- [Cu(NH3)4]2+
nfhs
9 miz 4- 3- 2+
nfhs J
Rik

4. miz nrkf fhzgL kha g vGJf.

miz kha:
U cnyhf miz nrk U miz nfhsfY
<f gL ntWgLtjh miz kha cUthwJ.

(v.fh) [CoIII(NH3)6] [CrIII(CN)6] kW [CrIII(NH3)6] [CoIII(CN)6]

ma kha:
xnu _yTW thghil, fiur ntWgl mafis
jU nrkf ma khaf vdgL.

(v.fh) [Co(NH3)5Br]SO4 kW [Co(NH3)5SO4]Br

iAnu (nuW) kha:
miz _yTWf vif ntWgL nrkf
iAnu khaf vdgL.
(.) [Cr(H2O)4Cl2]Cl.2H2O ; [Cr(H2O)5Cl]Cl2.H2O [Cr(H2O)6]Cl3

iz kha:
ika cnyhf mal izig VgLJ U mQfis bfhl
xU Kid <f, xWF
nkgl Kiwf ika cnyhf mal nrtjh iz kha
VgLwJ.
(v.fh) [Co(NH3)5ONO]Cl2 - ienlh kha kW [Co(NH3)5NO2]Cl2 -
ienuh kha
www.tnschools.co.in

5. izw iz bfhif _y tUtdt dfy,fhj gid

sFf.
(i) [Ni(NH3)4]2+ (ii) [Ni(CN)4]2-
[Ni(NH3)4]2+ [Ni(CN)4]2-
1. Ni mQ vyuh mik 3d84s2 3d84s2
2. Ni2+ ma vyuh 3d8 3d8
mik
3. < jik tik FiwjJ. tik fJ.
4. < xiw vyuhfis xiw vy
iz brahJ. uhfis iz
br.
5. xiw vyuhf 2 0
vif
6. fhj U w k 2.83BM 0
7. fhj jik ghuh fhj jik. ilah fhj jik.
8. d fy sp3 dsp2
9. mik ehK rJu js

6.
, .

(i) [FeF6]4- (ii) [Fe(CN)6]4-

[FeF6]4- [Fe(CN)6]4-
1. FemQ vyuh mik 3d64s2 3d64s2
2. Fe2+ ma vyuh 3d6 3d6
mik
3. < jik tik FiwjJ. tik fJ.
4. < xiw vyuhfis xiw vy
iz brahJ. uhfis iz
br.
5. xiw vyuhf 4 0
vif
6. fhj U w k 4.90BM 0
7. fhj jik ghuh fhj jik. ilah fhj jik.
8. d fy sp3 d2 d2sp3
9. mik vK. vK.
www.tnschools.co.in

7.nkhFnsh g F tiuf.
Eiupu UJ M#id RfSF vLJ brY uj
tgQfns nkhFnshf MF.
RthjYF M#id RbrYF vLJ brYnghJ mit
brwkhf, mUJ
fhgilMiril EiupuYF bfhL tJ Rthr _ybtnaWnghJ
Cjh wkhf csJ.
iknahFnsh-xUgo: nkhFnsh - ehFgo.
uL U-nghig nrkfshd bjhFia bfhlit.
uL Fe 2+ ma,nghig bjhFfis bfhlit.
xbthU nkhFnsh _yTW xU koj r nghw ehF Jiz
gFfis bfhlJ.
nkhFnsh bragL bjhF bjhFahF.
bjhF cs Fe2+ ma nghig bjhF cs ehF ieu#
mQfSlD, oo bjhF cs xU ieu# mQlD <j
izig VgLJwJ.
vK mik Mwh Kid M# _yTiw izwJ.
8. Fnshnuh g F tiuf.
o Fnshnuh bka, nghig nrk MF.
o bka M#ndw v +2. rW khWgl nghig <ahf
bragLwJ. Fnshnuhavw w_o x Mwiy nt Mwyhf
khWwJ.
o Na x Kiy Fnshnuh vw gira fh cs
fhgilMirL kW _yTWfis fhnghiAnu kW
M#dhf khW bra xnrif vdgL.
o Ka bra Fnshnuh x jikgLJ bghUshf
bragLwJ.
o Fnshnuh ju xU khfR nrk, U U nrkf, xU jhu
nrk Ma ehF cnyhf nrkf x nrifF Jiz wd.
o Uff nkhFnsh _y M#id vLJ bfhL
fhgilMiril btLwd.
o jhtuf Fnshnuh _y fhgilMiril vLJ bfhL
M#id btLwd.
o M# _yTW kj clbr vbghUshf gagLwJ.
www.tnschools.co.in

9. <f vwh vd? mt tiffis sFf.

ika cnyhf maF vyuh izia tHF v maf myJ
eLiy _yTWf <f vdgL. <f fhufshF.
(1) v <f:
it v maf MF. t bgafSl -O- vw bdhL
UF. (v.fh) F- ~Snuh, Cl- Fnshnuh, Br- nuhnkh, I-mnahnlh, CN- randh,
2
SO4 - rngnlh, NO3- ienunlh.
(2) eLiy <f:
it Rikaw eLiy _yTWf MF. t
abganu tHfgL.
(v.fh) H2O - mth ; NH3 -mik; CO - fhgid; NO -
ienuhir; NH2-CH2-CH2-NH2 vilm(en);
(3) :
.
+
. (.) NH2-NH3 -.

11.ntidntfa.

_W kbg dhf(nf v:41,42)

1.idtif tiuaW.(J,07;J,08;M,09;)

xU nt id nrhjid _y zfgl idntf cs br

cWf mLFf TLjny idtif vdgL.

2.sbfh Mw tiuaW.(O,07;M,08;O,08;M,10;)

o Fiwj gr Mwiy miltjF nrfgL Mwny sW Mw

vdgL.

o sW Mw = Fiwj gr Mw - nkhj <LgL _yT

Mw.

3.ma rkghil vG sFf.(M,07;M,09;)

k= A e- Ea / RT

k=idntf kh ; Ea= sW Mw; A= m fhu ; R= th kh;

T=btgiy ;
www.tnschools.co.in

4.miuth fhy tiuaW.

idgL bghU bjhlf br kghdJ ghahf FiwtjF njitgL fhy

miu th fhy vdgL.

0.693
t1/2 =
k
5.va kW fyhd idf vwh vd?(O,07;O,08;)

va idf fyhd idf

1 xnu xU go eilbgWwJ gy gof eilbgWwJ

6. idf myJ vbu idfSF rhWf jUf.(M,06;J,07;J,09;)

cUthF isbghUf idgL idgL bghUfis jUwd.

2SO2 + O2 2SO3 ;

PCl5 PCl3+Cl2

7.mLjLJ fG idf g F vGJf.(J,06;O,06;)

idgL bghU Kj iliy bghUis, iliy bghU xW myJ

mjF nkgl bjhlidfisbghUis cUthdh midf
mLjLJ fG idf vdgL.

v.fh. fhu Kiy il vl uhgFfgLj

8.iz idf vwh vd? vLJfhL jUf.(M,07;M,10;)

idgL bghUf uL myJ mjF nkgl tf idgL uL

myJ mjF nkgl isbghUfis jjh midf iz idf
vdgL.

Br2 Mnjh il nuhnkh bg

nuhnkh bg------- ghuh il nuhnkh bg

www.tnschools.co.in

9.ngh Kj tif id vwh vd? X vLJfhL jUf.(M,08;)

X ulh tif id , VjhtJ xU idgL bghU brit kwitfisl

mfkhf (10 Kj 100 klF)vLJ bfhSnghJ mid Kj tif
idahwJ. mjifa id ngh Kj tif id vdgL.

(v.fh) vliu my Kiy uh gFj id.

10. Fiwj gr Mw vwh vd?

nkhj <LgL midJ _yTWfS bgUF Fl ms Fiwj

MwyhdJ Fiwj gr MwvdgL.

11. idtif waf ahit?

o idtif v k {akhf, dkhf, KG vzhf Ufyh.

va idfSF dkhf UfhJ, Vbd mit xnu go

fwd.

o nrhjid _y kLnk zfKo, rkghL mogil

zfKoahJ.

idntfij bghUJ y idf d idtifia bgWsd.

12. va idf, fyhd idf ntWgLJf.

t.v va idf fyhd idf

1 xnu xU go eilbgWwJ. gy gof eilbgWwJ.

2 bkhj idtif 0,1,2,3 nghw bkhj idtif 3Il

a kfis bgWsJ. mfkhf1/2,1/3,3/2 nghw d
kfis bgWsJ.

3 gf idf iy. gy gf idf cL.

13.idntf rkghL vwh vd?

idntf rkghL vgJ id ntfij idntf kh kW

idgLbghUf brf goia bjhlgLJwJ.

14.Kj tif idF v.fhLf jUf?

238 234 + 4
1. 92U 90Th 2He

2. SO Cl SO + Cl
2 2(g) 2(g) 2(g)

3. H2O2 H2O + 1/2O2

www.tnschools.co.in

15.fk nta kha.

_W kbg dh f(nf v:45)

1. dnahk, laonahk - Matiw ntWgL fhLf. (J,06;)

t.v dnahk lahonahk

1 xj RH msit, vkiwahd xRH msnyna khWgLwJ.

Fpil bfhlit.

2 nkbghUjhj bghU Mo g Mo g bjhl ilahJ.

bjhlila wbt mik
bfhlit.

3 x RHW ir kL khWgL, vyh aa gfY ntWgL.

kw vyh gfY xUF.

4 khafis jjna j jjna j vJ.

vjy.

2.Rkh fyit vwh vd? vLJfhLl sFf.(M,08;J,09;)

d kW l khafis rk ms fyjh ilgJ Rkh fyit MF.

J Rkh fyitahf vdgL.

fyit x RHW jikawJ.

d kha xRH l kha xRHdh rk bragL fu

x Uw {akhwJ. J wkhj <L brj vdgL.

(v.fh) rk ms fyj d l yho my.

3. nrh lhlh my ifu fhgid bfhl xRHW jikyhj nrk -

ahagLJf.(M,06;O,06;M,10;)

nrh lhlh my uL ikjikaw fhg mQf UjhY

xW kbwh Mo gkhf csJ.

is _yTW ikjksjhf UwJ.

_yT ikjs xW UwJ. ikjs _yTiw U rk

ghahf wJ.

_yT wbt mik Mo g nkbghUJtjhf csJ.

_yTW x RHW jikawjhwJ. J cshj <L brj vdgL.

www.tnschools.co.in

4.nrh mikig, Rkh fyitUJ ntWgLJf.(M,07;)

t.v Rkh fyit nrh fyit

1 J xU fyit. J xnu xU nrk.

2 khafis j aY. j ayhJ.

3 wkhj <L brjyh x RHW cshj <L brjyh x RHW

jikia HwJ. jikia HwJ.

4 khaf ifu jiksit. ifu jikawit.

5.xU nrk x RHWtjfh gjidf ahit?(O,07;M,09;)

ikjikaw fhg mQ.

ifu jik.

js Kidw xia lJ myJ tyJwkhf RHW.

6.x RH kha vwh vd? vLJfhL jUf.(J,08;)

fk nrkf js Kidw xia RHW g x RH kha

vdgL.

mnrkf x RH khaf vdgL.

xia tyw RHW nrkf tyRH myJ d khaf vdgL.

xia lw RHW nrkf lRH myJ khaf vdgL.

(v.fh) d kW l yho my.

1. d my E kW z mikig vGJ

C6H5 H C6H H

C C

C C

HOOC H H COOH
Z E
www.tnschools.co.in

IJ kbg dhf:[nf v:68(m)]

1. tisa bArdh tr mikfis t.t iyjik g

FLf.

tisa bArdh U ehfh totf csd. mit

(I) mR t mik (II) nfhz t mik

.
.

mik (I) mik(II)

- OH bjhF mR t iz nfhz t iz

cshw J mf Fiw

iyjik Fiw mf

rk iy 10% 90%

mR t - OH bjhF mjF _wh fhg mQ izfgLs mR

t iAu# mQfSl bfhl ir <LgLwd.

J mR t mik iyjikia FiwwJ.

ijna 1 : 3 Uko mRt irf vnwh.

jifa irf nfhz t mik iy.

www.tnschools.co.in

2. lhlh my x RH khafis t.(M,12)

lhlh my iliAuh ilah my.
uL xj ifu fhgf csd.

d - lhlh my l - lhlh my

d - lhlh my: J jsKidw xia tygf RHWwJ.

l- lhlh my: J jsKidw xia lgf RHWwJ.

Rkh fyit: J d kW l lhlh my rk ms fyj fyit.

d - lhlh my x RHW jikia l - lhlh my <L brtjh

fyit x RHW jikawjhwJ. jid wnj khj vg.

nrh lhlh my: _yT ikjs xW csJ.

ikjs _yTiw U rk ghahf wJ.

cs xU ifu fhg xia tywK, kbwhW lwK rk

ms, v v ir RHWtjh fu RH {akhwJ. jid cshj
<L brj vg.
www.tnschools.co.in

2. yho my x RH khaid t.

xU ifu fhg csJ.uL x RH khaf csd. mit

d - yho my l - yho my

d - yho my: J jsKidwxia tygf RHWwJ.

l - yho my: J jsKidwxia lgf RHWwJ.
Rkh fyit: J d kW l yho my rk ms fyj fyit.
d - yho my x RHW jikia l - yho my <L brtjh
fyit x RHW jikawjhwJ. jid wnj khj vg.

2. tot kha myJ - ouh kha g vGJ.

uil izgh izfgl fhg mQfSl izJs mQf
myJ bjhFf wbt mikfgL Kiw khWgLtjh tot kha
VgLwJ.
khaf Mo g bjhl cilait my.
C = C izig bghUJ RH VgLtiy, vdnt khafis a iy
j jna f aY.

xj bjhFf xnu ir mikUF tot kha,

xj bjhFf vbu ir mikUF tot ouh kha

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kha ouh kha

1 xj bjhFf xnu ir v v ir
mikUF mikUF

2 nt gf xnu kh UF xnu kh UF

3 aa gf khWgL UF khWgL UF

4 thl th yF csJ iy
irf

5 bfhljil csJ iy

6 Mw mf Fiw

7 id w mf Fiw

8 iy jik Fiw mf

17. <jf

IJ kbg dhf(nf v:60)

1. <jf fhzgL khaf g vGJ.

id bra bjhF kha: xnu _yTW thghil, btntW

idbra bjhF bfhl <jfS, MfAhfS idbra bjhF

khaf MF.

(v.fh) v MfAh kW il bk <j.

iz kha: xnu _yTW thghil, xnu idbra bjhF bfhL

M#Dl U gfK izJs Mif bjhF ntWglh iz

khf MF.

(v.fh) bk-n-uig <j kW il v <j.

 www.tnschools.co.in

<jf MfAhf

mik thghL bga mik thghL bga

C2H5OC2H5 ilv <j CH3CH2CH2CH2OH n-il

MfAh

CH3OCH2CH2CH3 bk CH3CHCH2OH Inrh il

n-uig <j MfAh
CH3

CH3OCHCH3 bk CH3CHCH2CH3 <iza il

Inrhuig MfAh
CH3
<j
OH

CH3 _iza
CH3- C- OH il
MfAh
CH3

2. <jf tifghoid t.

idbra bjhF -O- cila nrkf <jf MF.

M#Dl U mif bjhFf izfgL Ujh mJ m~gho

<j MF.

va <jf : M#Dl xnu khahd U Mif bjhFf izfgL

Ujh mit va <jf MF.

(v.fh) il v <j

fy <jf : M#Dl ntW ntW Mif bjhFf izfgL Ujh

mit fy <jf MF.

(v.fh) v bk <j.

M#Dl xU miu bjhFahtJ izfgL Ujh mJ mnuhnko

<j MF. (v.fh) mnrh
www.tnschools.co.in

5. il v <jid jahF _W Kiwid vGJ.

H2SO4

C2H5OH + C2H5OH C2H5OC2H5 + H2O

413K

ar <j bjhF Kiw

C2H5ONa + C2H5I C2H5OC2H5 + NaI
nrhoa v ilv <j
<jhirL mnahilL
C2H5I + Ag2O + C2H5I C2H5OC2H5 + 2AgI
cy t MirL
4. mnrh jahF_W Kiwfis vGJ.

ar <j bjhF Kiw:

C6H5ONa + CH3I C6H5OCH3 + NaI
nrhoa bk mnrh
dhirL mnahilL
C6H5OH + CH2N2 C6H5OCH3 + N2
~dh ilanrh
nj
C6H5OH + (CH3)2SO4 C6H5OCH3 + CH3HSO4
ilbk rng

5. il v <j tUtdtWl vthW id wJ?

(m) O2/ mf neu bjhl (M) mfs HI () PCl5 (<) j H2SO4

(c) ml H2SO4 (C) Cl2

[O]

C2H5OC2H5 C2H5 - O - O - C2H5

(btoF aila bguhirL)

C2H5OC2H5 + 2HI 2C2H5I + H2O

C2H5OC2H5 + PCl5 2C2H5Cl + POCl3

j H2SO4
C2H5OC2H5 + H2O 2C2H5OH
ml H2SO4 H
C2H5OC2H5 (C2H5 O C2H5) HSO4-
+

(il v Mnrha iAu# rng)

www.tnschools.co.in

C2H5OC2H5 + Cl2 U CH3 CHCl O CHCl CH3

/
, il Fnshnuh il v <j
x
C2H5OC2H5 +10Cl2 C2Cl5OC2Cl5 + 10 HCl

(bg;Fnshnuh il v <j)

6. mnrhYF(mnuhnko <j), il v <jUF(m~gho <j) cs

ntWghLfis jUf.

mnrh(mnuhnko <j) il v <j(m~gho <j)

1 mf bfhiy cila k v MahF k

2 thrid bghU cz

3 fiugh my fiugh

4 bgnuhYF gyhf gaglhJ MfAhYl fyJ bgnuhYF gyhf

gagL

5 vjhf bguhirL cUthfhJ fh cs M#Dl nrJ

bguhirL cUthwJ

6 ienuh Vw fyitl ienuh Vw eilbgwhJ

ienuh mnrh jUwJ

il v <j tUtdtWl vthW id wJ?

a) HI b ) ml HCl c) PCl5 d) BF3 e)CH3mgI

a) C2H5OC2H5+HI C2H5OH+C2H5I

b)

c)
www.tnschools.co.in

d)

e)

v bk <j tUtdtWl idahJ?gaid vGJf?

a) HI b) mf ms HI

a) C2H5OCH3+HI C2H5oH + CH3I

v bk<j v MfAh bk mnahilL

b)C2H5OCH3 + 2HI CH3I + C2H5I +H2O

ga

j id Mfh bjhFia Kakhf jh bjhFia b#r Kiw

fla gagLwJ.

ilv <j gaf ahit?

1) F rhjd bgo Fghdhf bragLwJ.

2) cz ahf gagLwJ.
www.tnschools.co.in

3) dhL id bghU fiughdhf bragLwJ.

4) fk nrkfis bjLf fiughdhf bragLwJ.

5) <jf vjdhYl fyJ bgnuhYF gyhf gagLwJ.

mnrh fG a) ienuhVwid b ) nuhndw idfis sFf?

a) ienuh Vw

b) nuhndw

g; ;
F: gulh tF nta ghl Eh cs g dhf kW
mjfhd ilf kL gF bfhLfgLsd.

1. (2 x 1 = 2)

1. E n = - 3 1 3 . 6 / n 2 , E i = - 3 4 . 8 4 n - [3]
2. [ ]
3. - [ = h/mv]
4. [0.529 x 10-8 cm]
www.tnschools.co.in

5. -
[ - ]
6.
- E ,
? [ - 4E]
7. E n = [-22me4/n2h2]
8. [2]
9. S F 6 [sp3d2]
1 0 . H - [ o - ]

2. -II (1x1 =1)

1. C-C
[1.54A o]
2.
[]
3. [Z*=Z-S]
4. rhpahd $w;W. [ ]
5.
[ ]
6. ?
[ ]
7. [ ]
8. ? []
9.

? [ ]

10. ? [ -1]
11. Cl2 [1.98 Ao]
12. [s > p > d > f]
13. , []
14. ______ []
15. XA >> XB A-B [ ]

3. p- (1x1 =1)

1. 13 ? [Ge]
2. ? [Si]
3. A . A
B . B C
. C
. A
[P2O3]
4. ? [P2O3]
5. PCl5 ? [ ]
6. ? [PH3]
www.tnschools.co.in

7. -1 ? [F]
8. ? [HF]
9. ? [HF]
10. ? [17]
11. ,
[ ]
12. XeF4 [ ]
13. ? [ArF6]
14. , ? [He]
15. ? [He]

4. d- (2x1 = 2)
1. d- [(n-1)d1-10ns1-2]
2. .
[ ]
3. ?
[d-]
[Ti(H2O)6]3+ [d-d ]
4.

[3d54s1]
5.

6. [ ]
7. d-
[d-d ]
8. [3d104s1 ]
9. ? [ ]
10. ? [AgBr]
11.
[ ]
12.
? [Na2ZnO2 ]
13. ?
[C6H5Cl ]
14. ? [Cu+ ]
15. ? [NaCdI4 ]
16. Cu
[2CuFeS2 +O2 Cu2S + FeS + SO2 ]

17. . [ ]
18. K2Cr2O7- .
[ ]
19. BM-
. [ = n(n+2)]
20. KCN
[ Cu2(CN)2 + (CN)2 ]
21.
? [Mn2+]
22. ? [ ]
www.tnschools.co.in

23. [FeSiO3 ]
24. [ ]
25. ? [Os]
26. d- ?

a.

b.

c. , .

d.

5. f- (2x1 =2)
1. [ [Xe] 4f1-14 5d1 6s2 ]
2. [ [Rn] 5 f0-14 6d 0-2 7s2 ]
3.
[ Zr Hf ]
4. [+3]
5. ______ . [ ]
6. (n-2)f ________
. [ f ]
7. _________ [4f ]
8. ? [ ]
9. ________ [ CeO2 ]
10. ______ . [ -]
11.
_________ . [ ]
12. ________ . []
13. [+4]
14. [ ]

6. (1x1 = 1)

1. ? [ K2SO4 . Al2(SO4)3 . 24H2O ]

2. [Cu(NH3)4] Cl2
3. [Cu(NH3)4]2+ [ ]
4. [ en ]
5. [Fe(CN)6]4- [ ]
6. [NiCl4]2- [+2]
7. ? [Cu(NH3)4] Cl2
8. [Ni(CN)4]2- [ ]
9. ? [ NO2 - ]
10. [FeF6]4- [F - ]
11. [FeII (CN)6]4- [Fe+2 ]

12. [Ni(CN)4]2- Ni(II) [4]

13. [PtIV (NH3)2Cl2]2+ [(IV)]
14. K4[Fe(CN)6] 4K+ + [Fe(CN)6]4- [ [Fe(CN)6]4- ]
www.tnschools.co.in

15.
4.9 BM .
. [Fe2+ ]
16. [ BM ]
17. [Co(NO2)(NH3)5]SO4 [Co(SO4)(NH3)5]NO2 ?
[ ]
18.
? [ ]

7. (1x1 =1)
1. [ ]
2. ? [ ]
3. 92U238 82Pb206
[ 8 , 6 ]
4. 13Al27 15P
30

[ ]
5. 5B8 4Be8 [ ]
6. [ ]
7. 92X232 89Y220
[ 3 , 3 ]
8. 92U235 54Xe139 , 38Sr94 x
. x [ 3 ]
9. - __________ .

a. , b. C. a b
10. [ ]

8. II (1x1 =1)

2. NaCl Na+ Cl- [6]

3. [ n = 2d sin ]

4.
[ ]

5. ]
6. CsCl [ bcc ]

7. [AgCl ]

8.
[ n- ]

8. n [ ]

9. [8]

10. [ ]
www.tnschools.co.in

11.
[8]
12.
[ ]
13. bcc [2]
14. [ TiO2 ]

15. Fiwflj;jpfspd; gad;fs;

a) Fiwfisthd; b) khw;wpfs; c)R+hpa kpd;fyk; d) ,it midj;Jk;
16. [ FeS ]

9. -II (2x1 =2)

1.
___________ . [ H ]
2. __________
. [ ]
3. ? [q = 0]
4. [ ]
5. G , (]
6. ?
[ ]
7. ? [H > 0,S < 0]
8. G = H TS ]
9. 2Cl(g) Cl2(g) , H S [ - , - ]

10. -II ( 2x1 =2)

1. [ ]
2. 2A B - K1 B 2
A - K2 -
[ K1 = 1/K2 ]
3. 2HI H2 + I2 Kp [ Kc - ]

4. N2 + 3H2 2NH3
[ ]
5. 600 K KC -
4NH3(g) + 5O2(g) 4NO(g) + 6H2O(g) [ mol.dm -3 ]
6. 1.0 dm3 NH3
. NH3 NH3
. KC [27/16 (mol.dm-3)2 ]
7. T1 T2
K1 K2 T2 T1
(T2 > T1) [ K 1 < K2 ]
11. -II ( 1x1 =1)
1. HCl
[ ]
2. [ -1 -1 ]
3. [ ]
www.tnschools.co.in

4. [ k = Ae - Ea/ RT ]
5. A [ ]
6. [ ]
7.
[ ]
8. 10
[6.932 x 10 -2 min -1 ]
9. aA bB , A
. [ k[A]1/2 ]
10. 2N2O5 4NO2 + O2 , d[N2O5]/dt = k1 [N2O5] , d[NO2]/dt = k2[N2O5]
d[O2]/dt = k3[N2O5] k1,k2 k3 2k1 = k2 = 4k3
11. Ea = 0 300 K k = 4.2 x 10 5 sec -1 310 K k
[4.2 x 10 5 sec -1 ]
12. (3x1 =3)
1. [ ]
2.
? [ ]
3. [ ]
4. [ ]
5. []
6. _______
. [ ]
7.
[ )
8.
[ O/W ]
9.

[ Pd ]
9. ?
[ ]
11. [ ]
12. [ ]

13. -I (1x1 =1)

1. _____
[ ]
2. __________ [ ]
3.
_________ [ ]
4. ___ [ ]
5. 0.01 M KCl 25oC 0.0014 -1 . -1
[ 140 -1 . -1 ]
2

6. CH3COOH 25oC 80 -1. 2 -1

400 -1 .

-1
2
[ 0.2 ]
7.
___________
[ ]
8. NH4OH __________ [ ]
www.tnschools.co.in

9.
C
[K= 2 C/1 - ]
10. ? [ CH3COOH ]
11. ? [ pH = log10 1 / [H+] ]
12. 10-6 M pH =
6
13. pH = 2
/___________ [ 1 x 10 -2 ]
14. 0.1 N NaOH pH_______ [ 13 ]
15. pH
_________ [ ]
16.
_________ [ [H+] = Ka [Acid] / [Salt] ]
17. - __________ [
]
18.
___________ [ ]

16. (1x1 =1)
1. ? [ C2H5OH ]
2. ? [ ]
3.

1o > 2o > 3o
4. ? [ ]
5. CH3MgI- ?
[CH3MgI ]
6. +
? [ ]
7.
.
[1 o ]
8. [2- ]
9. ? [2- -2-]
10. ,
[ ]
11. ? [ CH3OH ]
12. p-

13. p- pKa
[p-
]
14. ? [ (CH3)3COH ]
15. Zn- [ ]
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16. [ ]
17. [ ]
18. [ ]
19. [ ]
20. 1-, 2- [
]
21.
a) ,dpg;Gr; RitA+l;l b) ey;yjukhd Nrhg;G jahhj;jypy;
c) iel;Nuh fpsprhpd; jahhpg;gpy; d)
22. []
23. [1]
24. [ ]
25. PI3 [ CH2 = CH2 ]

17. (2x1 =2)

1. C2H5OC2H5, CH3-O-CH-CH3 [ ]
2. ? [ C 2 H5 - O - C 2 H5 ]
3. [ HI ]
4. [ ]
5. , , [ ]
6.
[ C2H5OC2H5 ]
7. , ?
[ ]
8. ?[ ]
9.
[]
10., .
[ ]

18. (1x1 =1)

1. 2- [ ]
2. ? []
3. 520 K
[]
4. [ ]
5.
? [ 2- ]
6. [ ]
7. [ ]
8.

[ Cu2O ]
9. [ ]
10. ?
[ ]
11. BaSO4 Pd
[ ]
www.tnschools.co.in

12.
? [CH3COCH3]
13. , C2H5ONa
[ R-CH3 ]
14. [3- ]
15. LiAlH4
[ ]
16. ? [,
]
17. X
. X [ CH3CHO ]
18. CH3 - C = CH - C - CH3 IUPAC
CH3 O [4--3--2-]
19. ?
[ ]
20. []
21. CH3COCH3 H2SO4 ? []
22. ?
[ CH3CH2CH2OH ]
23. []
24. +
[ ]
25. ?
[ , ]

19. (1x1 =1)

1. ? [C2H5OH ]
2. ? [ ]
3. [ , ]
4. ,
[ ]
5. [ ]
CH3
6. CH3-CH2-CH-COOH IUPAC [2- ]
7. CH3CH2COOH CH3COOCH3 [ ]
8. [ ]
9. ?
[ CH3CH2COOH < CH3COOH < HCOOH < ClCH2COOH ]
10. P2O5
[ ]

11. H-C = O 160oC ? H2 + CO2

OH

12. P
[ ]
www.tnschools.co.in

13. NaHCO3 , CO2 ?

[ ]
14.
CO2 . CO2 [ ]
15. ,
[
]
16. [ Cl3CCOOH ]
17. ? [ CH3CH(OH)COOH ]

18. CH3CH(OH)COOH [O] [ CH3COCOOH ]

H2O2/ Fe2+

19. [ ]
20. [ ]
20. (3x1 =3)
1. [C2H5NO2]
2. CH3-CH2-NO2, CH3CH2-O-N = O
[ ]
3. -NO2 -NH2
[ Sn/HCl ]
4. Zn/NH4Cl [CH3NHOH ]
5.
[]

6.
[ 1- -2- ]
7. ? [ ]
8. [ m-]
9.
[ C6H5NHOH ]
10. [ ]
11. CH3-CH2 - C N
[ CH3-CH2-CH2-NH2 ]
12. [ ]
13. [ C2H5 NH2 ]
14. [ ]
15.
[ p- ]
16. ? [ ]
17. C6H5NH2 NaNO2/HCl X X [ C6H5N2Cl ]
18. ? [ ]
19.
? [ ]
20.
[ ]
www.tnschools.co.in

21. (2x1 =2)

1. ? [ ]
2. . [ ]
3. ? [
]
4. , ? [ C1 - C2 ]
5. ? [ HNO3 ]
6. [ , , ]
7. + + ?
[ ]
8. [ ]
9. [ - ]
10. ?[NaOH ]
11. A B (
12. [ ]
13. ? [ ]
14. ? [
]
15. ?

a) mkpNdh mkpyq;fspd; thpir b) ,uz;lhk; epiy mikg;G c) %d;whk; epiy mikg;G

d)
16. [ ]
17. [ ]
18. ? [ ]
19. ? [ ]
20. ? [ ]
21. [ ]
22. ? [ ]
23.
a) Nrhg;G b) fpspruh c) nfhOg;G mkpyk; d) a b
24. [ ]
25. [ ]

1 kbg dhf
xU kbg dhf KG kbgf bgw ghlEh cs jkL, muR
bghJnj kW PTA ifnaL Mat cs dhfF eF g bgw.
www.tnschools.co.in

3 kbg dhf
muRbghJ nj mf Kiw nffgl dhf y nH jugLsd.
tiw khztfSF g tf.
Mtd gf
1. rfiz Mu - fzl?

2. maahF Mw xLf?

a)B & Be b) N & O c) Li & Be d) B & C e) F & Ne f) Mg & Al

3. S vyuh ehl Fnsh vyuh ehlij l Fiw - V?

4. Kf msL vwh vd?

5. gh msL kW Kf msL Mat FiwghLf ahit?

6. vyuh ehl - tiuaW

7. maahF Mw tiuaW
P- jkf-II
1. kj iz is vwh vd?
2. sngh rht g F vGJf
3. H3PO3U fhuJt cilaJ V?
4. P2O5 xU fwj h; F fhu vgij %.
5. H3PO4xU KfhuJt my vgij %.
6. bghlhZ gofhu vthW jahfgLwJ?
7. ghgu my vthW jahfgLwJ?
8. ghgu myij btggLJ nghJ vd fG?
9. H3PO3,H3PO4- totik kW vyuh thghil jUf.
10. ghgu my xU wj xLF fhu vgij %.
11. H3PO4, - xLF gF cjhuz jUf.
12. gh xU wj xLF fhu vd %.
13. ~S M#ndw w g vGJf?
14. nAh Kdgh ntaiy t?.
15. brdh~gSiuL nrkf vthW jahfgLwd?
16. HF fzho ghof ghJfhfgLtiy V?
17. ah gaf ahit?
18. nAy# ilnrkf vwh vd? it vthW cUthwd?
19. a gaf ahit?
20. HF bfhL fzho vthW gl tiuth?
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wgu nta
1. idntf khw tiff ahit? vLJfhL jUf?
2. lgl idntf khw vwh vd? vLJfhL jUf?
3. j idntf khw vwh vd? vLJfhL jUf?
4. caf vwh vd? vLJfhL jUf?
5. idntf khf eRf vwh vd? vLJfhL jUf?
6. th-th Tk cUthtiy - V?
7. Tkkhf vwh vd?
8. bAnAh uil mLF vwh vd?
9. olh is vwh vd?
10. busa af vwh vd?
11. gjLj g F tiuf?
12. Foiu Rfg Tk nta gF ahJ?
13. bllh vthW cUthwJ?
14. ghkf vwh vd? mt tiff ahit?
15. kUJtJiw Tkf ga ahJ? vLJfhL jUf?

muRbghJ nj mf Kiw nffg 5 kbgf dhf

P-bjhF jkf
1. nfhf mikig sFf.
2. nfhf gaf ahit?
3. ~S khWgl jikia sFf.
4. by bgUks vthW jahfgLwJ?
5. bl Kiw ~nsh vthW bjLfgLwJ?
6. kjthf uhnr-uhny Kiw vthW bjLfgLwd?
7. th Kiw caa thf vthW bjLfgLwd?
wgu nta
1. Tkf bjhF Kiw vthW jahfgLwJ. (VnjD uL Kiwf)
2. Tkf jahfgL if Kiwfis sFf.
3. Tkf ntKiw vthW bgwgLwJ?
4. WF vGJf. 1.Tk 2.a Tk 3.Etfl.
5. a rL gut vwh vd? sFf.
6. F tiuf. Kid ft
7. idntf khw iliy nrk bfhifia t.
8. idntf khw gu ft bfhifia sFf.
9. idntf khw idf bghJthd wafis vGJf.
10. aa gu ftF, nta gu ftuF ilnaahd
ntWikfis vGJf.
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3 kbg dhf

nj v.1
1. izju vwh vd?
2. 1s22s22p63s23p5 vyuh mikig bfhl mQ fil vyuhDfhd fu
mQfU Rikaia fzLf.
3. kj iz is vwh vd?
4.Mnjh ghgh my t ienuLl vthW idwJ?
5. ienuh cnyhf fyit ia kW ga ahJ?
6. K2Cr2O7 J btg is ahJ?
7. cfUid Q k vwh vd?
8. Sc, bcc, fcc mikf gl tiuf.
9. 400 K.btgiy xU ntid H kW S kf Kiwna -10K.Cal Mol-1
kW 20 Caldeg-1 Mol-1 v idG k fhf.
10. idFzf tiuaW.
nj v-2
1. id tif w af ahit?
2. sbfhMw tiuaW.
3. th th Tik mik V cUthtJ iy?
4. nfhuhZ ia TW.
5. 1,3 lhilp , ouh mikig tiuf.
6. sruhiy vthW mnuhdhf khWth?
7. vjhdhiyl isfh mf ghFjik bgUgnj?
8. l uh Kiw bgnrhndh vthW jahfgLwJ?
9. gh my gaf ahit?
10. A vw xU mnuhnko ienuh nrk Sn kW - Hcl bfhL xLF nghJ
B-ia jUwJ. A kW B I flf.
nj v.3
1. v M#ndf vwh vd? (v.fh. jUf)
2. dfy tiuaW.
3. nrhjid _y bgwgl d (Si-C) k 1.934 A0 fhg mQ Mu 0.77 A0 v
fh mQ Muij fzLf.
4. nAy# ilnrkf vwh vd? mit vthW cUthwJ?
5. H3PO4 KfhuJt cilaJ %?
6. iliy jkf miz nrkfis cUthFtJ V?
7. t cj vwh vd? mij vthW jfyh?
8. iAu# FL brtYs m fUij vGJf.
9. fzho vthW cUthwJ?
10. vnuh vwh vd? mj myF ahJ?
nj v.4
1. rha bfhifia vGJf.
2. va kW fyhd idf vwh vd?
3. xU Kjtif id idntf kh k 1.54 X 10-3 Sec-1 v
miuth fhyij fzLf.
4. idntf khw vwh vd? vLJfhL jUf.
5. Mtho j ia TW?
6. d my Z kW E mikfis fhLf.
www.tnschools.co.in

7. ung 2 M kW 2 bk ung 2 M Matiw ntW gLJ U

nrhjidfis TW?
8. id bka nuhikoUJ bgir MfAh vthW bgwgLwJ?
9. bg idia vGJf.
10. yhil FnshiuL, yhilL t mikig vGJf.
nj v.5

1. Br2 HNO2 NaNO2

C6H5CONH2 X Y Z
KOH HCL Cu+
X, Y, Z Matiw flf.
2. cz ghJfhghf vwh vd? v.fh. jUf.
3. vyuh Mw vF KatJ vd?
4. nghuh maahF Mw bgaij l Fiw V?
5. P2O5 xU wj F fu vgij %.
6. a gaf ahit?
7. uh#uhtfJl jf idia TW.
8. Ag108 cfU miuthfhy 2.31 lf mj ij kh vd?
9. a iyik vwh vd?
10. xU nkh k 1000 C btgiy bfhF nghJ Mahj btg 540
fnyh/uh v Mahj vnuh khwij fzLf.
nj v - 6
1. mLjLJ fG id vwh vd? v.fh. jUf.
2. sbfh Mw tiuaW.
3. olh is vwh vd?
4. bghJ ma is vwh vd? rhW jUf.
5. Rkh fyit tiuaW.
6. _iza MfAhYfhd lnka nrhjidia TW?
7. my vwh vd? mJ vthW dhUJ jahfgLwJ?
8. nuhnuh vwh vd? mj gaf ahit?
9. C6H7N vw _yTW thghLila A vw mnuhnko Xizia m
ilanrhMf idFgL B-I jUwJ. B- a fiuriy bfhf itf
C-I jUwJ. A, B, C flf.
10. my KaJt ahJ? v.fh. jUf.
nj v.7
1. bArbg iyyh bfhifia TW.
2. S vyuh ehl Fnshidl Fiw V?
3. sngh rht F tiuf.
4. d-bjhF jkf khWgl M#ndw iyia bgUgnj.
5. U238 cfU t1/2 = 140 ehf mj ruhr thfhyij fzLf.
6. m fl vwh vd?
7. fl iy khw nghJ vnuh khwij fzLf. 1 nkh Sn
(, 13o bra) 1 nkh Sn (, 13o bra)
8. vbu idfSF _W rhWf jUf.
9. Kid ft vwh vd?
10. ~ghunl ulh ia TW.
www.tnschools.co.in

nj v.8
1. nrhlhlh my ifufhgid bfhl x RHW jikaw nrk
ahgLJf.
2. dh vthW dh jdhf khwgLwJ?
3. tUtdt IUPAC bgafis jUf. m) FnuhldhoiAL,
M)bk n nuhignlh, )bgrhoiAL
4. fhgh myij fltjfhd U nrhjidfis TW.
5. C2H5NO (A) vw KyTW thghLila fknrk Br2/ NaOH cl idJ
(CH5N vw (B) fk nrkij jUwJ. B LiAlH4 Kiy xLfkilJ C2H7N(C)
vw nrkij jUwJ. nrkf A, B and C flf.
6. t thuf vwh vd? v.fh. jUf.
7. Al(Z)=13) Kj maahF Mwiy Mg (Z=12) cl xLf. cdJ ilfhd
rahd fhuzij TWf.
8. ah _W gafis jUf.
9. Fnuhik FnshiuL nrhjidia cjhuzJl sFf.
10. U235 Inrhlhig uhid bfhL jhdh gL id fwJ X kW
Y- kfis fhf. 92U235 + 0n1 42Mo
98 +
54Xe
136 + x e0 + y n1
-1 0

nj v.9
1. CHCl3 - bfhiy 61.5 o bra MF. CHCl3 eajik
bragL nghJ mj nkhyh Mahj btgij fzLf.
2. xU Kj tif miuthfhy idgL bghUf bjhlf brit bghWJ
mikahJ vd %.
3. busa af tiuaW.
4. jhf fiur vwh vd? v.fh jUf.
5. dnahkh, lanahk ntWgLJf.
6. MoiALfSfhd U nrhjidf ahit?

7. Sn/HCl Alcholic KOH H2/Pt

CH3NO2 A B C
CHCl3
A,B,C fhf
8. HF-I fzho ghof nrff ayhJ V?
9. faf fhg fhyza Kiw gaf ahit?
10. xU btg au 110 o bra 25 o bra btgiyfSil
bragLwJ v mj mfgr rjj wid fzLf.

nj v.10
1. ngh Kj tif id vwh vd? v.fh. jUf.
2. ma rkghil vG sFf.
3. Rkh fyit, nrh fyit ntWgLJf.
4. l uh Kiw mnlh ndh vthW jahfgLwJ?
5. rhaf _W wafis TW?
6. bga kW ieu# vyuhd ehl kf {a V?
7. Fnuh Kyh Rj F tiuf?
8. iz idf vwh vd? v.fh. jUf.
www.tnschools.co.in

9. (373K.) uh (373K.) vw braKiw vnuh khwij fzLf.

H vap =40850 J mol-1 at 373k
10. caf vwh vd? v.fh. jUf.

nj v.11
1. l Kiwia sFf.
2. nuhnuh vwh vd? mj ga ahJ?
3. rh my nrhjidfis TW.
4. A vw mnuhnko iAnuh nrk Sn kW HCl bfhL xLF nghJ B- I
jUwJ. B fhigy idF cgLwJ. A kW B -ia flf.
5. bgilL iz vwh vd? v.fh. jUf.
6. dhYfhd nrhjidia TW.
7. ieyh -66 vthW jahfgLwJ. mj gaf ahit?
8. gh my lhy id bghUis xLFwJ. Mdh mo my
xLFtiy. V?
9. bgrhoiAL frhnuh idF cgLwJ. Mdh mlhoiAL
cgLtiy V?
10. He2 V cUthiy?

5-kbg dhf
nj v.1
1. o -uhns rkghil tU. mj KaJt ahJ?
2. mj Ka jhJUJ vthW bjLfgLwJ?
3. yhjidL MoidL ntWgLJf.
4. nkhFnsh g F tiuf.
5. btg afa ulh gntW TWfis TW.
6. N2(g) + O2(g) 2NO(g) rhah jJtij gagL nkfl
ntid br kW mGj isfis t.
7. fl idf vthW eilbgWwd. I) ilv <j 1.dhL id
bghU, 2.j fjf my, 3. fk myf. II). v bk <j mf ms
Nlhd ml HI cl.
8. uhbf cf waf ahit?

nj v.2
1. _yTW Mlh bfhifia t?
2. jf vthW mj jhJUJ bjLfgLwJ?
3. yhjidLf gaf ahit?
4. miz kha maahj khafis cjhuzJl sFf?
5. foyh Mw waf ahit?
6. PCl5 ijtiljYfhd Kc kW Kp bjhlig tU.
7. fltWl il v <j vthW idwJ. i) O2 mf neu,
ii) mfs HI iii) PCl5 iv) Cl2 v) BF3
8. MogahoF g t. jir Wf t thuf ga ahJ?

nj v.3
1. _yTW Mlh bfhifia gagL ieu# _yTW cUthjiy t.
2. vnuh waf ahit?
3. nkhdir kzUJ yhjidLf vthW bjLfgLwJ?
www.tnschools.co.in

4[Cr(en)3]Cl3vw nrkF tUtdtiw Ff. m) IUPAC bga M) ika

cnyhf ma ) < <) miz v c) miz nrk totik.
5. Kp = Kc (RT) ng vw rkghil xU bghJthd ntrkiy idF tUf.
6. Kjtif idfhd idntf rkghil tU.
7. <j fhzgL khafis cjhuzJl sFf.
8. kaf kUJf g F tiuf.

nj v.4
1. _yTW Mlh bfhifia gagL M# _yTW cUthjiy t.
2. t mj jhJfUJ vthW bjLfgLwJ?.
3. yhjidL FWf isf ahit?
4. [Ni(CN)4]2- and [Ni(NH3)4]2+ Ma _yTWf dfy, fhjjik kW
totik tiw sFf.
5. oul ia TWf. UJ yf milJs nrkfis sFf.
6. idtif w af ahit?
7. ilv <j jahF _W Kiwfis vGJf.
8. Buna-S, Buna-N kW ieyh 66 vthW jahfgLwJ? mt gaf ahit?

nj v.5
1. S,P kW d Mlh totfis sFf.
2. mYndh btg xLfKiw g F tiuf.
3. MoidL FWf vwh vd? mj fhuzf kW isfis t?
4. iz kha, nuW kha Matiw cjhuzJl sFf.
5. jir idf vwh vd? jir id eilbgw njitahd
gjidf ahit?
6. nAg Kiw mnkhah jahjiy t.
7. mnrh jahF _W Kiwfis t.
8. rhaf w kW mik g t.

nj v.6
1. iAu# iz vwh vd? mj tiff ahit?
2. Fnuhik jhJUJ bghlha il Fnuhnk vthW bjLfgLwJ
vgij sFf.
3. rha bfhifia gagL bjhL Kiw mfs SO3 bgWtjfhd
gjidfis vGJ?
4. va kW fyhd idfSF ilnas ntWghLfis jUf.
5. i) mLjLJ fG idf, ii) iz idf, iii) vbu idf g F
tiuf.
6. mnuhnko <j, mgho <j ntWgLJf.
7. mnrh ienuh Vw kW nuh Vw g sFf.
8. F tiuf. i) tthuf, ii) Ruthuf, iii) v M# Vf,
4) iujLgh
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10- kbg dhf.

nj v.1
1. m) bjhF kW tir maahF Mw vthW khWgLwJ vgij
sFf.
M) q IJ gafis vGJf.
2. m) miznrkf ga btd fUJ nfhf ahit?
M) cfUidF, ntidF cs ntWghLf ahit?
3. m) FiwghL sFf.
M) Tk Miyia gagL au ijj kW dh ijj _y
Tkf vthW jahfgLwd?
4. m) myjhf fiur braKiwia cjhuzJl sFf?
M) fy ma fhQ brhbwhlfis g F tiuf.

nj v.2
1. m) gh Kiw ma Mu fzL Kiwia sFf.
M) nfhf gaf ahit?
2. m) izw iz bfhif fUJ nfhf ahit?
M) faf fhg fhy za Kiw g F vGJf.
3. m) uh w ukh Kiwia sFf.
M) ntKiw _y Tkf vthW jahfgLwJ?
4. m) ma gF ifailj bfhiffhd rhWf ahit?
M) IUPAC Kiwfis bfhL fy thghoid vthW vGJth?

nj v.3
1. m) vyuh ftw fzL gh msil sFf. mj FiwghLf
ahit?
M) q khWgl jikia t.
2. m) RWNH nta Fnshnuh KaJt ahJ? mj
braghLfis t?
M) faf Inrhnlhf kUJt gafis t.
3. m) fzho jikia sFf.
M) idntfkhw ga gu ft bfhifia sFf.
4. m) wfho gia FndhdhL bfhifia t.
M) be rkghil jU.

nj v.4
1. m) vyuh ehlij ghF fhuf ahit?
M) uhnr uhny Kiw fhUJ kjthf vthW bjLfgLwd?
2. m)i)eLiy <, ii)bfhLiz nrkf, iii)miz nfhs, iv)miz v,
v)v < Matiw sFf.
M) Na fG idf g F tiuf.
3. m) magoff gf ahit?
M) i)Kid ft, ii) E tofl, iii) bA nAh uil mLF
Matiw sFf.
4. m) bAlr rkghil tU.
M) l iAu# th vthW mikfgLwJ. mJ bragL jij t.
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nj v.5
1. m) maahF Mwiy ghF fhuf ahit?
M) th Kiw kjthf vthW bjLfgLwd?
2. m) izw iz bfhif _y tU nrkf dfy kW
fhj gfis sFf.
M)cfU s kW cfU iz idfSF ilnaahd ntWghLf ahit?
3. m) aa gu ftF, nta gu ftF ilnaahd
ntWghLf ahit?
M) idntf khw id bghJthd w af ahit?
4. m) nfhuhZ ia T sFf.
M) EMF F foyh MwYF cs bjhlig sFf.
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