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CHEMICAL EQUILIBRIUM
*IRREVERSIBLE REACTIONS
A reaction which proceeds in a definite direction till its completion is known as
irreversible reactions
Or
The reaction in which reactants are completely converted into products is known as
irreversible reactions
this reaction is also known as (one way reaction) (complete reaction) (uni-directional)
EXAMPLE
1) AgNO3 + Nacl AgCl + NaNO3
2) C + O2 CO2
REPRESENTATION
It is denoted by single arrow ()
*REVERSIBLE REACTIONS
Reactions in which reactants are partially converted into products are known as
reversible reactions
Or
A reaction in which reactants forms product and after some time products are
converted into reactants and an equilibrium is establish is known as reversible
reactions
(bi-directional reaction)
REPRESENTATION
It is denoted by double arrow ( )
*FORWARD REACTION
Chemical reaction in reversible reaction which take place in forward direction is known
as forward reaction
OR
The reaction which proceed from reactants to product side is known as forward
reaction
EXAMPLE
H 2 + I2 2HI
*BACKWARD
BACKWARD REACTION
Chemical reaction in reversible reaction which take place in backward direction is
known as backward reaction
OR
The reaction which proceed from product to reactants side in known as backward
reaction
EXAMPLE
H 2 + I2 2HI
*EQUILIBRIUM
When forward reaction and backward reaction occur at same rate the then that time
is called the time of equilibrium.
OR
A time when the rate of forward reaction is equal to the rate of backward reaction is
known as state of equilibrium or chemical equilibrium
GRAPH
A B
When the reaction begins reactants A starts converting into product B its mean
concentration of A decreases by the passage of time and the concentration of B
increases than at time t equilibrium will establish (which is called the time is
called the time of equilibrium ) and the line of the graph will be straight
OR
OR
REPRESENTATION
It is denoted by square brackets [ ]
UNIT
Moles/dm3
-: 1dm3=1litre
The rate at which a substance reacts is directly proportional to its active mass
(concentration) and the rate of reaction is directly proportional to the products of
concentration of its reactants
EXPLANATION ( IN URDU
URDU )
Reaction ki raftaar reactant ki concentration py depend hai aur agar aik sy ziada reactants hon to
products banny ki raftaar reactants k product yani (multiplication) py depend hgi.
Matlab ye k jitni ziada reactants ki concentration hgi products banny ki speed ya raftaar utni hi ziada
hgi..
A+BC+D
-: k = rate constant
-: dx = change in concentration
-: dt = change in time
XA + YB aC + bD
X Y
rf = k1 [A]X [B]
a b
Rate of backward reaction [C] [D]
a b
rf = k2 [C] [D]
at equilibrium
Y a b
k1 [A]X [B] = k2 [C] [D]
a b
K1 / K2 =[C] [D] /[A] X Y
[B]
a b
kc =[C] [D] /[A] X
[B]
Y
kc = [products]/[reactants]
EQULIBRIUM CONSTANT
It is a ratio of concentration of products to the concentration of reactants
EXAMPLE
H 2 + I2 2HI
-: kc = [products]/[reactants]
kc = [H2].[I2]/[HI]2
Kp = [PC].[PD]/[PA].[PB]
EXAMPLE
Kp = [ P.PCl3].[PCl2]/[P PCl5]
RELATION BETWEEN KC AND KP
There are three cases in which kc and kp relate
1) Kc = kp
2HI H 2 + I2
2) Kc > kp
N2 +3H3 2NH3
3) kc < kp
2NH3 N2 +3H3