Safety Data Sheet

Page 1 of 8
BONDERITE M-CR 407 CHROMATE COATING known as
MSDS-No. : 383820
ALODINE 407 (30 KG) V001.3
Revision: 07.01.2014
printing date: 08.01.2014

Section 1. Identification of the substance/preparation and of the company/undertaking

Product name:
BONDERITE M-CR 407 CHROMATE COATING known as ALODINE 407 (30 KG)

Identification of manufacturer, importer or distributor

Manufacturer: Henkel Thailand Ltd Amata Nakorn Industrial Estate, 700/349 Mu 6, Tambol Nong Mai Daeng, Amphur
Muang, Chonburi 20000, Thailand. Phone : +6638456300 Fax : +6638456393

Information office (content SDS):

ap-ua-psra.sea@henkel.com

Section 2. Composition / information on ingredients

Declaration of ingredients:

Hazardous components EINECS content Classification

CAS-No.
Orthophosphoric acid 231-633-2 30 - 60 % C - Corrosive; R34
7664-38-2
Chromium trioxide 215-607-8 10 - 30 % O - Oxidizing; R9
1333-82-0 carcinogenic, category 1; R45
Toxic for reproduction - category 3.; R62
T+ - Very toxic; R26
T - Toxic; R24/25, R48/23
C - Corrosive; R35
R42/43
N - Dangerous for the environment; R50/53
Mutagen category 2.; R46

Section 3. Hazards identification

Hazard classification:
T+ - Very toxic
N - Dangerous for the environment

Risk phrases:
R45 May cause cancer.
R46 May cause heritable genetic damage.
R21/22 Also harmful in contact with skin and if swallowed.
R26 Very toxic by inhalation.
R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation.
R35 Causes severe burns.
R42/43 May cause sensitization by inhalation and skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62 Possible risk of impaired fertility.
BONDERITE M-CR 407 CHROMATE COATING known MSDS-No. : 383820
as ALODINE 407 (30 KG) V001.3
Page 2 of 8

Section 4. First aid measures

Inhalation:
Move to fresh air.
If breathing is difficult, give oxygen.
Get medical attention.

Skin contact:
Immediately flush with large quantities of water for at least 15 minutes. Remove contaminated clothing. GET MEDICAL
ATTENTION.

Eye contact:
Immediately flush eyes with water (for 10 minutes), put on a bandage with sterile gauze, see an oculist.

Ingestion:
Drink 1 or 2 glasses of water.
Do not induce vomiting.
Get medical attention.

Section 5. Fire fighting measures

Suitable extinguishing media:
Use media appropriate for surrounding material.

Special protection equipment for firefighters:

Wear self-contained breathing apparatus and full protective clothing, such as turn-out gear.

Combustion behaviour:
Non-flammable (aqueous solution). In case of fire toxic gases can proceed after evaporation of water and further heating of the
product.

Section 6. Accidental release measures

Personal precautions:
Avoid skin and eye contact.

Environmental precautions:
Do not empty into drains / surface water / ground water.

Clean-up methods:
Contain spill.
Prevent further leakage or spillage if safe to do so.
Remove with liquid-absorbing material (sand, peat, sawdust).
Neutralize with acid-binding material (e.g. powdered limestone).

Section 7. Handling and storage

Handling:
Avoid skin and eye contact.
Do not empty waste into waste water drains.
Do not smoke, do not weld.
Open and handle container with care.
Use caution when combining with water; DO NOT add water to acid, ALWAYS add acid to water while stirring to prevent
release of heat, steam and fumes.
Do not mix this product with material which contain AMINES. NITROSAMINE may be formed.

Storage:
Keep container tightly sealed.
Keep container in a well ventilated place.
Keep away from heat and direct sunlight.
BONDERITE M-CR 407 CHROMATE COATING known MSDS-No. : 383820
as ALODINE 407 (30 KG) V001.3
Page 3 of 8

Section 8. Exposure controls / personal protection

PHOSPHORIC ACID Type: Short Term Exposure Limit (STEL):
7664-38-2
ppm:
mg/m3: 3
Remarks: ACGIH
PHOSPHORIC ACID Type: Time Weighted Average (TWA):
7664-38-2
ppm:
mg/m3: 1
Remarks: ACGIH
CHROMIUM, WATER-SOLUBLE INORGANIC Type: Time Weighted Average (TWA):
CR VI COMPOUNDS, AS CR
1333-82-0
ppm:
mg/m3: 0,05
Remarks: ACGIH
CHROMIUM, INSOLUBLE INORGANIC CR VI Type: Time Weighted Average (TWA):
COMPOUNDS, AS CR
1333-82-0
ppm:
mg/m3: 0,01
Remarks: ACGIH

Respiratory protection:
Suitable breathing mask when there is inadequate ventilation.

Hand protection:
The use of chemical resistant gloves such as Nitrile is recommended.

Eye protection:
Wear chemical goggles; face shield (if splashing is possible).

Body protection:
Wear suitable protective clothing.

Engineering controls:
Ensure adequate ventilation.
Ventilation should effectively remove and prevent buildup of any vapor/mist/fume/dust generated from the handling of this
product.

General protection and hygiene measures:

Eyewash fountains and emergency showers are required.

Hygienic measures:
Good industrial hygiene practices should be observed.

Section 9. Physical and chemical properties

Appearance:
dark
Liquid
Odor:
characteristic
pH:
<3
Boiling point:
> 100 C (> 212 F)
Density:
1,48 g/cm3
Solubility:
Solvent: Water, Miscible
BONDERITE M-CR 407 CHROMATE COATING known MSDS-No. : 383820
as ALODINE 407 (30 KG) V001.3
Page 4 of 8

Section 10. Stability and reactivity

Conditions to avoid:
Avoid heating.

Materials to avoid:
Reacts with alkalis: Heat generated.

Hazardous decomposition products:

In case of fire toxic gases can be released.

Section 11. Toxicological information

Oral toxicity:
Harmful if swallowed.

Inhalative toxicity:
May cause cancer by inhalation.

Skin irritation:
Primary skin irritation: corrosive, May cause sensitization by skin contact.

Eye irritation:
Primary eye irritation: very irritating, Risk of serious damage to eyes

Acute oral toxicity:

Phosphoric acid Value type LD50

7664-38-2
Value 2.600 mg/kg
Species rat
Method OECD Guideline 423 (Acute Oral toxicity
Chromium trioxide Value type LD50
1333-82-0
Value 80 - 114 mg/kg
Species rat
Method
BONDERITE M-CR 407 CHROMATE COATING known MSDS-No. : 383820
as ALODINE 407 (30 KG) V001.3
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Acute inhalative toxicity:

Phosphoric acid Value type Acute toxicity estimate (ATE)

7664-38-2
Value 5,1 mg/l
Exposure time
Species
Method Expert judgement
Chromium trioxide Value type Acute toxicity estimate (ATE)
1333-82-0
Value 0,31 mg/l
Exposure time
Species
Method Expert judgement
Chromium trioxide Value type LC50
1333-82-0
Value > 0,31 mg/l
Exposure time 4h
Species rat
Method

Acute dermal toxicity:

Chromium trioxide Value type LD50

1333-82-0
Value 57 mg/kg
Species rabbit
Method OECD Guideline 402 (Acute Dermal Toxicity)

Skin corrosion/irritation:

Phosphoric acid Result corrosive

7664-38-2
Exposure time 24 h
Species rabbit
Method
Chromium trioxide Result highly irritating
1333-82-0
Exposure time
Species rabbit
Method

Serious eye damage/irritation:

Chromium trioxide Result corrosive

1333-82-0
Exposure time
Species rabbit
Method

Respiratory or skin sensitization:

Phosphoric acid Result not sensitising

7664-38-2
Test type no data
Species human
Method

Germ cell mutagenicity:

Phosphoric acid Result negative

7664-38-2
Type of study / Route of administration bacterial reverse mutation assay (e.g Ames test)
Metabolic activation / Exposure time with and without
Method OECD Guideline 471 (Bacterial Reverse Mutation Assay)
Chromium trioxide Result positive
1333-82-0
Type of study / Route of administration bacterial reverse mutation assay (e.g Ames test)
Metabolic activation / Exposure time with and without
Method
BONDERITE M-CR 407 CHROMATE COATING known MSDS-No. : 383820
as ALODINE 407 (30 KG) V001.3
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Repeated dose toxicity

Phosphoric acid Result NOAEL=250 mg/kg

7664-38-2
Route of application oral: gavage
Exposure time / Frequency of treatment 6 w daily
Species rat
Method OECD Guideline 422 (Combined Repeated Dose Toxicity
Study with the Reproduction / Developmental Toxicity
Screening Test)
Chromium trioxide Result NOAEL=0,0007 mg/l
1333-82-0
Route of application inhalation
Exposure time / Frequency of treatment 90 days taeglich 20 Stunden
Species rat
Method

Section 12. Ecological information

General ecological information:

Do not empty into drains, soil or bodies of water.
Because of the low pH of this product, it would be expected to produce significant ecotoxicity upon exposure to aquatic
organisms and aquatic systems.

Toxicity:

Phosphoric acid Value type LC50

7664-38-2
Value > 100 mg/l
Acute Toxicity Study Fish
Exposure time
Species
Method OECD Guideline 203 (Fish, Acute Toxicity Test)
Phosphoric acid Value type EC50
7664-38-2
Value > 100 mg/l
Acute Toxicity Study Daphnia
Exposure time 48 h
Species Daphnia magna
Method OECD Guideline 202 (Daphnia sp. Acute Immobilisation Test)
Phosphoric acid Value type NOEC
7664-38-2
Value 100 mg/l
Acute Toxicity Study Algae
Exposure time 72 h
Species Desmodesmus subspicatus
Method OECD Guideline 201 (Alga, Growth Inhibition Test)
Value type EC50
Value > 100 mg/l
Acute Toxicity Study Algae
Exposure time 72 h
Species Desmodesmus subspicatus
Method OECD Guideline 201 (Alga, Growth Inhibition Test)
Chromium trioxide Value type LC50
1333-82-0
Value 52 mg/l
Acute Toxicity Study Fish
Exposure time 96 h
Species Carassius auratus
Method OECD Guideline 203 (Fish, Acute Toxicity Test)
Value type NOEC
Value 0,105 mg/l
Acute Toxicity Study Fish
Exposure time 60 d
Species Salvelinus namaycush
Method
Chromium trioxide Value type EC50
1333-82-0
Value 0,3 mg/l
BONDERITE M-CR 407 CHROMATE COATING known MSDS-No. : 383820
as ALODINE 407 (30 KG) V001.3
Page 7 of 8

Acute Toxicity Study Algae

Exposure time 72 h
Species Scenedesmus subspicatus (new name: Desmodesmus subspicatus)
Method OECD Guideline 201 (Alga, Growth Inhibition Test)

Section 13. Disposal considerations

Product
Method of disposal:
Dispose of in accordance with local and national regulations.
Packaging
Disposal for uncleaned package:
Packaging that cannot be cleaned are to be disposed of in the same manner as the product.

Section 14. Transport information

Road transport ADR:

Class: 8
Packaging group: II
Classification code: C1
Hazard ident. number: 80
UN no.: 3264
Label: 8
Technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Phosphoric
acid,Chromic acid)

Railroad transport RID:

Class: 8
Packaging group: II
Classification code: C1
Hazard ident. number: 80
UN no.: 3264
Label: 8
Technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Phosphoric
acid,Chromic acid)

Inland water transport ADN:

Class: 8
Packaging group: II
Classification code: C1
Hazard ident. number:
UN no.: 3264
Label: 8
Technical name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Phosphoric
acid,Chromic acid)

Marine transport IMDG:

Class: 8
Packaging group: II
UN no.: 3264
Label: 8
EmS: F-A ,S-B
Seawater pollutant: -
Proper shipping name: CORROSIVE LIQUID, ACIDIC, INORGANIC, N.O.S. (Phosphoric
acid,Chromic acid)
BONDERITE M-CR 407 CHROMATE COATING known MSDS-No. : 383820
as ALODINE 407 (30 KG) V001.3
Page 8 of 8

Air transport IATA:

Class: 8
Packaging group: II
Packaging instructions (passenger) 851
Packaging instructions (cargo) 855
UN no.: 3264
Label: 8
Proper shipping name: Corrosive liquid, acidic, inorganic, n.o.s. (Phosphoric acid,Chromic acid)

Section 15. Regulations - classification and identification

Indication of danger:
T+ - Very toxic, N - Dangerous for the environment
Risk phrases:
R45 May cause cancer.
R46 May cause heritable genetic damage.
R21/22 Also harmful in contact with skin and if swallowed.
R26 Very toxic by inhalation.
R48/23 Toxic: danger of serious damage to health by prolonged exposure through inhalation.
R35 Causes severe burns.
R42/43 May cause sensitization by inhalation and skin contact.
R51/53 Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment.
R62 Possible risk of impaired fertility.

Safety phrases:
S53 Avoid exposure - obtain special instructions before use.
S23 Do not breathe gas/fumes/vapour/spray.
S26 In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S28 After contact with skin, wash immediately with plenty of water.
S36/37/39 Wear suitable protective clothing, gloves and eye/face protection.

Global inventory status:

Regulatory list Notification

EINECS yes
TSCA yes
AICS yes
DSL yes
ENCS (JP) yes
KECI (KR) yes
PICCS (PH) yes
INV (CN) yes
ISHL (JP) yes
NZIOC yes

Section 16. Other information

Issue date:
08.01.2014
Disclaimer
This information is based on our current level of knowledge and relates to the product in the state in which it is delivered. It is
intended to describe our products from the point of view of safety requirements and is not intended to guarantee any particular
properties.

This safety data sheet was prepared in accordance with Council Directive 67/548/EEC and it's subsequent amendments, and
Commission Directive 1999/45/EC.