Construccin de la curva de calibracin Construccin Curva Ringbom

Nivel Concentracin (mg/L) Respuesta (A) log [ ] Absortancia

1 20 0.123 1.30 24.664
2 30 0.221 1.48 39.883
3 40 0.258 1.60 44.792
4 50 0.348 1.70 55.125
5 60 0.393 1.78 59.542
6 70 0.452 1.85 64.682
7 80 0.503 1.90 68.595
8 90 0.573 1.95 73.270

Muestra problema X1 0.252

Curva de Calibracin
0.700
0.600
0.500 f(x) = 0.006175x + 0.01925
0.400 R = 0.9922536635
Seal obtenida A 0.300 Column D
0.200
0.100
0.000
10 20 30 40 50 60 70 80 90 100

Concentracin Cr2O7 mg/L

 Curva de calibracin corregida por Ringbom
Concentracin (mg/L) Respuesta (A) Curva Calibracin-R
20 0.195
30 0.275 0.600
40 0.335
50 0.391 0.400 f(x)
R =
Pendiente (L/mg) 6.53E-03 Respuesta (A)
0.200
Intercepto 0.076
Absorbancia muestra 0.000 0.000
Concentracin de la muestra diluda (mg/L) -11.6 20 30 40
Concentracin de la muestra concentrada (mg/L) -116.4
Concentrac

Column G
Curva Ringbom Linear (Column G

80.000

f(x) = 72.8466122782x - 69.6536338072

60.000
R = 0.9943129402

40.000
Absortancia
Column D
20.000

0.000
0 80 90 100 1.20 1.30 1.40 1.50 1.60 1.70 1.80 1.90 2.00
/L Log [ ]
 Column D
va Calibracin-Ringbom
Linear (Column D)

0.600

0.400 f(x) = 0.00594x + 0.0344

R = 0.9853882503
0.200

0.000
20 30 40 50 60 70 80
Concentracin (mg/L)

Column G
Linear (Column G)

338072

70 1.80 1.90 2.00

Nmero repeticin Absorbancia
1 0.376
2 0.376
3 0.376 Sensibilidad analtica 0.017
4 0.377
5 0.379 Precisin del mtodo 0.49%
6 0.378 Criterio precisin Cumple con precisin
7 0.381
8 0.380
9 0.376
10 0.377
Promedio 0.3776
Desviacin STD 0.0018
 Nmero repeticin Absorbancia blanco
1 0.002
2 0.001 Lmite de deteccin (A) 0.007
3 0.004 Concentracin Lmite de deteccin (mg/L) 0.7
4 0.005
5 0.001 Lmite de cuantificacin (A) 0.017
6 0.003 Concentracin lmite de cuantificacin (mg/L) 2.3
7 0.001
8 0.003
9 0.002
10 0.004
11 0.004
12 0.000
13 0.001
14 0.001
15 0.004
16 0.001
17 0.004
18 0.001
19 0.003
20 0.001
Promedio 0.002
Desviacin STD 0.0015
Pendiente curva (L/mg) 6.53E-03