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Journal of Loss Prevention in the Process Industries 33 (2015) 124e128

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Journal of Loss Prevention in the Process Industries


journal homepage: www.elsevier.com/locate/jlp

Short communication

A new approach on troubleshooting of cathodic protection: A case


study
M.H. Allahyarzadeh*, N. Zendehdel, GH. R. Saberi, P. Dehghan, F. Ahdeno, J. Kavid
Technical Protection and Corrosion Engineering Department, Iranian Offshore Oil Company (IOOC), Iran

a r t i c l e i n f o a b s t r a c t

Article history: The aim of this paper is to suggest an effective procedure to eliminate a major deciency in impressed
Received 6 October 2014 current cathodic protection (CP). Current work describes performed activities through jetty cathodic
Received in revised form protection troubleshooting as a case study. Although CP troubleshooting is straightforward, sometimes it
30 October 2014
is very complicated and confusing. To eliminate the appeared imperfection, different procedures were
Accepted 29 November 2014
Available online 2 December 2014
carried out; the root cause of the trouble in the system was shown to be in reversed current. Here the
current which passed throughout installed junction were measured to survey reversed current. Current
work offers a new approach in CP troubleshooting.
Keywords:
Cathodic protection
2014 Elsevier Ltd. All rights reserved.
Troubleshooting
Corrosion monitoring

1. Introduction 2. Brief summary of the problem

Corrosion management has an important role in corrosion en- ICS which has been applied on a jetty shown in Fig. 1, cathodi-
gineering through different industries. According to Corrosion cally protected the submerged parts of that. This ICS was
Costs and Preventive Strategies in the United States, which was comprising a rectier/transformer with the maximum voltage of
supported by FHWA (Federal Highway Administration) and NACE 50 V and the maximum current of 150 A and also six leadesilver
(National Association of Corrosion Engineers), the total cost of submersed anode in order to distribute the current more uniformly
corrosion was estimated about $276 billion, which is about through entire of immersed structures. For more assurances
3.1 percent of gross national product (GNP) (Roberge, 2008). One regarding to establish the CP circuit, the electrical connections
primary methods of corrosion control which applied extensively in which denoted by J connect the bridges to Loading (L.D.), Berthing
offshore oil industries for submerged metal structures is cathodic (B), and Mooring (M) structures electrically. Since the minimum
protection. Cathodic protection has been applied in two methods: cathodic potential for full protection is 800 mV with respect to
impressed current systems (ICS) and sacricial anodes. In an (w.r.t) Ag/AgCl/Sea-water electrode based on NACE TM0497 (NACE,
impressed current system (ICS) a direct current is applied through 2002), monitoring of cathodic potential of the jetty structure
water from a source outside the structure to the structure (Morgan, revealed that only the immersed Loading structures were near the
1987; Uhlig and Revie, 2011). Applying the ICS for corrosion control fully protected conditions; and other underwater structures,
is not sufcient and use of monitoring is necessary to ensure its including B1, B2, M1 and M2 were not protected and based on NACE
performance (Wang et al., 2014). However, the basic fundamentals TM0497 they were corroding. The problem was the lack of full
of ICS seem to be easy and straightforward, troubleshooting of protection criteria in B1, B2, M1 and M2. Table 1 represents the
these systems is sometimes very complicated and confusing. Pre- potential of the jetty with respect to an Ag/AgCl/Sea-water refer-
sent paper investigates the troubleshooting of ICS, which has been ence electrode before troubleshooting. Fig. 2 schematically depicts
applied on a jetty as a case study. distribution of rectied current among immersed 30inch
leadesilver anodes. The history of the jetty and previous eld data
exhibited that, in the ordinary conditions, the jetty should be
protected by applying a cathodic current about 100e105 A. Hence,
rst of all, the overall cathodic current was increased up to 103 A.
* Corresponding author. However, this increase led to fully protection of underwater parts of
E-mail address: allahyarzadeh.mh@gmail.com (M.H. Allahyarzadeh). Loading and B1, the other structures, especially the last one (M2)

http://dx.doi.org/10.1016/j.jlp.2014.11.022
0950-4230/ 2014 Elsevier Ltd. All rights reserved.
M.H. Allahyarzadeh et al. / Journal of Loss Prevention in the Process Industries 33 (2015) 124e128 125

Fig. 1. Schematic of side and top view of jetty including Loading, B1 (Berthing), B, M1 (Mooring), M2, and electrical joints from J1 to J16.

Table 1 2nd phase: anode replacement/addition


Jetty cathodic potentials (emV) w.r.t. Ag/AgCl/Sea-water reference electrode.

Vdc Inet
dc M2 M1 B2 B1 L.D. Based on the current distribution among immersed anodes
shown in Fig. 2, the A3 anode consumed the least current amount.
Before troubleshooting 7.5 80 704 717 722 734 762
After rst step 8.8 103 750 791 793 800 849 In this stage, the rst assumption was about the A3 anode; and it
After second step 8.4 115 736 781 812 831 861 was expected that the least current consumed here might be the
After third step 9.5 135 749 797 827 839 891 reason of the failure. Therefore, a new one replaced this anode.
Replacing this anode increased the current consumption of A3
anode from 2.5 A to 22 A. This increase in current consumption and
were not protected, and they were corroding based the existed enhancing to better current distribution over the immersed struc-
criteria. This problem was dominant, even so, the applied cathodic ture, however, did not eliminate the problem completely, but it led
current increased up to 135 A. to increase in the cathodic potential of L.D. and B1 structures. After
this step, lack of full protection in B1, B2, M1 and M2 structures was
also evident hence another new anode named (A10 ) was added next
to the rst. The new one has been subjoined to increase the current
3. Results
consumption and distribution through M2 and M1 structure. In
order to increase the cathodic current over the structures, the D.C.
ICS troubleshooting was carried out in four independent phases.
voltages of transformer/rectier were also increased to 8.8 V from
In each phase, the problem was corresponded to an assumption or a
its initial value 7.5 V; therefore, this led to increase of the rectier
specic part of cathodic protection systems (CPS). In order to
output current up to 103 A (Based on the history of structure po-
remove the failure, separately in each phase, several main solutions
tential measurements and previous data, the jetty should be fully
in different steps were conducted; however, performed activities
protected by this amount of current). Further cathodic potential
were much more than it was expected. The main phases are:
measurements were performed after complete polarization. Fig. 3
Transformer/rectier, Anode replacement/addition, External con-
and Table 1 represent the new current distribution and jetty
sumers/interference risk, and Reversal current.
cathodic potentials, respectively, after rst step.
As represented in Table 1, the potentials of M2, M1, and B2
structures were still less than the required amount for full protec-
1st phase: transformer/rectier tion (800 mV w.r.t. an Ag/AgCl/Sea water reference electrode).
New condition, after rst step, led to decrease of the quantity of
The starting point for all troubleshooting in ICS is the rectier. current consumption in A4 anode as shown in Fig. 3. Therefore, in
Detailed surveying of the transformer/rectier has shown that it the second step, anode A4 was removed and a new leadesilver
was working properly and all the current and voltage measure- anode was also employed. The current distribution was measured
ments regarding to the rectier were in their normal state. After in new condition after devoting appropriate time for full polariza-
investigating transformer/rectier and ensuring its normal condi- tion. The new condition, after second step, leads to increasing up
tion, next phases were carried out.

Fig. 2. Schematic distribution of rectied current among immersed leadesilver anodes before troubleshooting.
126 M.H. Allahyarzadeh et al. / Journal of Loss Prevention in the Process Industries 33 (2015) 124e128

Fig. 3. Schematic distribution of rectied current among immersed leadesilver anodes after rst step.

the potentials of B1, B2, and Loading structures due to devoting applied current and stabilizing polarization phenomenon, the
more current (Fig. 4), but it lowered the potentials of M1 and M2 cathodic potential of M2 structure was measured accurately. These
structures subsequently owing to less current distribution as a actions were repeated in a sequential manner (i.e. rectier voltage
result of new arrangement. increasing and subsequently measuring M2 structure potential).
It was expected that by increasing the overall current in the Consecutive increase in net applied current led to small increment
system and compensate the current shortage in A1, A10, and A2 in M2 cathodic potential. As a rule of thumb, the increase occurred
anodes the problem would be solved. Therefore, in the third step, in cathodic potential deduced the risk of interference approxi-
the voltage of transformer/rectier was raised up to 9.5 V, in order mately while any decrease in cathodic potential as a result of the
to increase the consuming current of A1, A10, and A2 anodes and current increment could demonstrate the certain presence of
consequently increasing up the potential of M1 and M2 structures. interference.
This action, however, led to increase of the net current distribution
and consequently increase in potentials, but the problem was not
removed completely. Fig. 5 shows the current distribution among 4th phase: reversal current
immersed anodes after the third stage.
As denoted above, applying mentioned activities did not remove Despite all performed procedures, the problem has not been
the problem completely. After the third step, the main problem was solved yet. Therefore, the inspection of the reversed current
concentrated on the M2 structure. The voltage of transformer/ through protected structures to the rectier was carried out.
rectier has been severally increased, but no noticeable increase However, the net current in was equal to the net current out of the
was observed in M2 structure potential. A1 and A10 have been system near the transformer/rectier; a more detailed surveying
substituted variously, but no signicant improvement was occurred needed to investigate the reversal current thoroughly. For this
in the system. Since addition of one more anode near M2 structure purpose, the amount of passed currents was measured through the
did not affect the structure potential, the complexity of the problem electrical junctions from J1 to J16 depicted in Fig. 1. Measurements
became more evident. revealed that, the summation of reversed current was not equal to
the quantity of current applied for the protection of the jetty; and in
J10, J13 and J16 joints no current was crossed through (i.e. they were
3rd phase: external consumers/interference risk nearly disconnected). This assumption that the whole of current
could not return completely back through the structures and
The rst assumption, in the third phase, was the presence of an electrical joints became more evident, however, partial amount of
external object around M2 on sea bed, which consumes the excess reversed current might return through the metallic structures and
applied current. This assumption became more evident when the welded joints of the jetty. Therefore, this assumption inspired the
current distribution near M1 and M2 structure has been increased authors to renovate the electrical joints from J1 to J16. After reno-
in previous phase, and no signicant improvement was observed. vation of the joints, the reversed currents were measured again.
Therefore, diving operation was carried out, and these operations The new amount of currents passed throughout J1 to J16 electrical
revealed that there was no external object, and the areas were joints revealed that the amount of crossed currents in each joint
completely clear. was noticeably increased. The measured cathodic potential of the
Mentioned conditions made the risk of interference to be jetty structures demonstrated that, the problem has been
increased. As a simple test to evaluate whether the interference completely solved. Results exhibited that the trouble occurrence
problems were present or not the voltage of transformer/rectier was mainly owing to incompetency of reversal current. Fig. 6 shows
has been increased one more time again. After increasing the total the reversed current values before and after renovation of joints.

Fig. 4. Schematic distribution of rectied current among immersed leadesilver anodes after second step.
M.H. Allahyarzadeh et al. / Journal of Loss Prevention in the Process Industries 33 (2015) 124e128 127

Fig. 5. Schematic distribution of rectied current among immersed leadesilver anodes after third step.

Fig. 6. Schematic of reversal current throughout electrical joints: (a) before and (b) after the renovation.

Results here, clearly illustrated the importance of reversal current, with lower resistance to pass. This will cause corrosion of the metal
whereas this critical subject was ignored through corrosion moni- at the point where the current leaves (Piron, 1991). Since renova-
toring and CP troubleshooting. tion of junction points brings proper paths for current; the problem
has been completely eliminated by removing incompetency in
reversal current.
4. Discussion The fact of reversed current and its monitoring through the
system, however, is forgotten sometimes, it is a common rule for
There are many factors affecting the corrosion in the corrosive inspectors to measure the current-out and the current-in the sys-
media, such as (Brichau and Deconinck, 1994; Brichau et al., 1996): tem only near the transformer/rectier. In the mentioned system,
(1) conductivity, (2) aeration and permeability, (3) acidity, (4) hu- even though, the net current in the system was equal to the net
midity, (5) presence of sulfates and chlorides, (6) presence of bio- current out; it was possible that parts of current did not return from
logical species and (7) presence of stray currents. During the the metallic structure, and might return through the corroding
electrochemical corrosion process, different anodic (oxidation) and media (i.e. here sea water). And this phenomenon led to corrosion
cathodic (reduction) reactions occur. The principal anodic reaction of structures at where the current left. Monitoring of reversal cur-
in the corrosion of offshore structures is (Morgan, 1987; Roberge, rent through the system (point by point) and controlling of the
2008): metallic path to return the reversal current through, is the unre-
garded key point in the CP monitoring schedule.
Fe / Fe2 2e (1) Results here clearly illustrated the importance of reversal cur-
rent, whereas this critical subject was ignored through corrosion
and the principal cathodic reaction is (Morgan, 1987; Roberge, monitoring and CP troubleshooting. It seems that, cathodic po-
2008): tential measurement individually is not enough, and it is necessary
 to recheck the reversal current in a scheduled monitoring program
O2 2H2O 4e / 4OH (2) to prevent such failures (Table 2).

If an external current (cathodic current) were to be impressed


on the corroding structure, the reactions will be shifted by an
amount depending on the direction and magnitude of the current
(Roberge, 2008) (i.e. polarization). When the structure is placed
under the control of a suitable CP, the anodic reactions are trans-
Table 2
ferred from the structure to the impressed current anodes. The
Jetty cathodic potentials w.r.t. Ag/AgCl/Sea-water reference electrode after renova-
current ow is reversed by this electrochemical phenomenon and tion of electrical junctions.
the structure surface becomes the cathode upon which reaction (2)
Test M2 M1 B2 B1 Loading
occurs. It is necessary that current to be reversed properly through
points structure structure structure structure structure
the CP system. When a barrier is placed in current ow path (i.e.
resistance increase in junction box) the current could not pass C.P. 996 1012 969 971 997
(emV)
easily throughout its circuit; hence it will nd an easier direction
128 M.H. Allahyarzadeh et al. / Journal of Loss Prevention in the Process Industries 33 (2015) 124e128

5. Conclusion Offshore Oil Company (IOOC) for their financial supports. The rst
author specially would like to appreciate Mr. Mortza Hoseinieh and
CP troubleshooting is very easy and straightforward; however, Mr. Saeed Hatami for their sincere cooperation.
sometimes it will be extremely confusing and complicated. One of
the important subjects in cathodic protection is the quantity of
reversal current. Here, welded joints could not completely return
the applied current. Results exhibited that the trouble occurrence
was mainly owing to incompetency of reversal current. The failure
References
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Acknowledgments Uhlig, H.H., Revie, R.W., 2011. Uhlig's Corrosion Handbook, vol. 51. John Wiley &
Sons.
Wang, W., Wang, Q., Wang, C., Yi, J., 2014. Experimental studies of crevice corrosion
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(NIOC) and research and development department at Iranian Prev. Process Ind. 29, 163e169.

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