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Abstract: The efficiency of oxygen transfer depends on many factors including the type, size and shape of diffusers
and the tank geometry. In this paper, the effect of the depth of water in the tank and, the extension of coverage area of
diffusers on each of oxygen transfer capacity (OC), efficiency (E) and, on a percentage of oxygen absorption () is
tested. Experimental procedure is adopted to evaluate the effect of these parameters. The results of the study showed
that, both the depth of water and the extent of coverage area of diffuser had a significant effect on the tested
parameters. The values of oxygen transfer capacity (OC) and efficiency (E) ranged from 18 to 170 grO2/m3. hr and
from 2 to 17 grO2/m3air, respectively; depending on the depth of water in tank and the ratio of diffusers coverage area.
The percentage of oxygen absorption ranged from 0.45-5.4% depending on the testing conditions. Specific
mathematical models to .describe the effect of each parameter were also derived. The exponential form of equation
proved to be efficient in describing the effect of a depth water on oxygen transfer capacity (OC) whereas; the linear
form of equation was good enough in representing the effect of the other parameters.
diffuser system consists of a matrix of perforated tubes particular system is usually reflected by the overall mass
(or membranes) or porous plates arranged near the transfer coefficient, KLa; without attempting to separate the
bottom of the tank to provide maximum gas to water factors KL and (At/V):
contact (Figure 1). Various types of diffusers and
diffuser systems are presented in the Environmental At
Protection Agencys technology transfer design manual KLa = KL ..... (1)
on aeration systems [4]. V
Where:
KLa = apparent volumetric oxygen mass transfer coefficient
in clean water, hr-1
V = water volume in the tank, m3
A, = interfacial area of mass transfer, m2
A
a = t
.... (2)
V
The interfacial area per unit volume, m2/m3
The fraction of oxygen transferred to the water due tank on each of oxygen transfer capacity (OC), efficiency
to pass one-meter cubic of air is expressed as (E), and on the percentage of oxygen absorption () of
oxygenation efficiency (E) of the diffuser system, which subsurface aeration systems; and to determine the effect of
can be written as: coverage area of diffusers on each of oxygen transfer
capacity (OC), efficiency (E), and on the percentage of
OC H oxygen absorption () of subsurface aeration systems.
E= . (5)
I
Experimental Work
Where:
H = the liquid depth in the tank in meters. Oxygen transfer efficiency information ordinary
/ = the aeration intensity, or volumetric air flux per unit obtained by using laboratory (bench-scale) apparatus [4]. All
area of tank surface. tests reported herein were carried out by using two laboratory
scale tanks (0.55m 0.35m 0.38 m) and (0.5m 1.0m
If the oxygen concentrations are measured in mg/L, 1.0 m), (Length Width Depth) see figure (2), which were
and the time interval to determine KLa is expressed in operated on the batch mode.
hours, dc/dt in equation (4) gives the oxygen uptake rate The experiment program was divided into four groups.
in mg/L at 0 mg/L dissolved oxygen (DO) concentration In each group, the effect of side of water depth (H), on the
in the test water. By multiplying this value by the studied parameters at a given (f/B) ratio was investigated (f:
quantity of water aerated, the mass oxygen uptake rate is total width of diffuser band, B: width of the tank), see figure
obtained, and oxygen absorption () is determined by: 2. Four different ratios were studied during these tests. These
ratios were (25%, 50%, 75% and 100%).
= (rate of oxygen uptake by test water/ rate of oxygen
input by aerator) 100 ... (6)
K L a (C st ) V K L a (C st ) H
= = ... (7)
I j AT I j
Where:
j = constant = 298; (the amount of oxygen in gram/m3 of
air T = 20C and normal atmospheric pressure),
V = the aeration tank liquid volume, m3
AT = the aeration tank surface area, m2.
The saturation values for oxygen in water at Figure2: Tanks used in the experiments (one tank is shown)
equilibrium with normal atmosphere standard with water
vapor (CSO)760 are available in standard tables [2, 9]. Theses The oxygen transfer tests were conducted using potable
values must be corrected for actual test pressure conditions, water obtained from the distribution system. The normal
which vary from atmospheric at the water surface to procedure described in an ASCE standard [1, 19]
atmospheric plus the depth of water at the tank bottom. recommended to conduct oxygen transfer tests with tap water
Because the value of KLa thus determined relates to rather than wastewater. Many authors [4, 9, 19] have
the test water temperature, it must be corrected to demonstrated the necessity of this to obtain consistency and
standard conditions (20C) by the relationship: comparability of results. To introduce the effect of
wastewater on the results obtained from this procedure, the
(K L a )T
(K L a )20 = ...... (8)
following equation for admixtures correction factor is usually
used [7]:
1.024T 20
Where:
(K L a ) f = K La
...... (9)
(KLa)20 = value of KLa at 20C,
Where:
(KLa)T value of KLa at test water temperature, and
KLa = oxygen transfer coefficient for the specific admixture.
T = test water temperature, C.
= the admixtures correction factor
Research Objectives
In table (1), the values of correction factor for some
types of wastewater are represented. Within the tank, the
This research aims to achieve the following
diffusers were placed, close to the bottom in that arrangement
objectives: To determine the effect of water depth in the
304 Int. J. Environ. Res. Public Health 2006, 3(3)
so that the longitudinal placement of diffusers is Sufficient cobalt chloride was added to provide a minimum Co+2
achieved (see figure 3). Many authors have shown that, concentration of 1.5 ppm [13].
the longitudinal placement of diffusers is clearly superior Dissolved oxygen determinations were made on samples
to other arrangements with respect to oxygen transfer collected near the side of basin. Because of the small volume
efficiency [8, 10]. of basin, one sample location was assumed to be
representative of the total basin volume [4], In some runs, the
Table 1: Values of the correction factor for some readings were conducted with another positions but no
types of wastewater [15] difference was noted. The dissolved oxygen concentrations
of the samples were determined using a dissolved oxygen
Type of Wastewater - factor meter type (EXTECH; model 407510) with stirrer. The probe
was calibrated immediately before and after each run, using
Domestic wastewater 0.85 modified Winkler dissolved oxygen titration procedure [4],
Periodic calibration checks were made during the run using
Dairy wastewater 0.82 distilled water samples of known DO concentrations. Water
temperatures were measured before and after each test, and
Wastewater from chemicals industries 0.7 the average values were used in data analysis. It was not
possible to conduct all tests at 20C [9]; therefore, the values
Pulp and paper industry wastewater 0.7 of KLa obtained had to be adjusted to the standard
temperature of 20C according to equation (8). The air
Wastewater from acidic industries 0.5 flowrate was measured with a pre-calibrated gauge. In figure
4, some results of the experimental work were represented.
10
H= 0.5m
H= 0.6m
(Cst - Ct ), mg/L
H= 0.9m
1
0 5 10 15 20 25 30
Figure 3: Two types of diffusers placement. (A): time, minutes
transverse arrangement. (B): longitudinal arrangement
Figure 4: Sample of the experimental results showing the
Prior to each group of runs, the tanks were drained, variation of log (Cst Ct) over time at various water depths.
cleaned and filled with clean water to avoid salt
accumulation [13]. Each run was carried out at a given The major shortage in these tests is that they were
(f/B) ratio and submergence of diffusers. carried out in small scale so, their results mainly limits by the
At each run, the following measuring procedure was test circumstances. Accordingly, in this paper a number of
adopted: DO depletion with sodium sulfite in the points from published paper were also collected [3, 6, 7, 11-
presence of a cobalt catalyst, measurement of DO 14, 16-18]. The points were selected from plants which have
concentration versus time of aeration, and determination a scale larger than that adopted by the experimental work,
of water temperature and air pressure. (Depth of water in these plants range from 1.4 to 6.0 m, f/B
The sodium sulfite (Na2SO3) was added to the tanks as ratio from 12.5 % to 100 %). After separation, all data were
a slurry. The total amount of (Na2SO3) required per run treated and combined with the experimental points in order to
were calculated based on the theoretically demand of expand the applicability of the results. Individual
(Na2SO3) (7.9 ppm are required to remove l ppm dissolved mathematical models to describe the effect of each parameter
oxygen) [1]. Depending on the dissolved oxygen were also derived.
concentration in the test water, the approximate (Na2SO3)
requirements were estimated. 10-30% excess sodium sulfite Results and Discussions
was used each run [9]. The sodium sulfite was maintained
in suspension by mixing. Cobalt was added to the tank as Diffuser oxygen transfer capacity (OC) was plotted in
cobalt chloride (CoCl2.6H2O) at the beginning of each test. two ways. Figure 5 shows the capacity as a function of depth
Int. J. Environ. Res. Public Health 2006, 3(3) 305
than 3. With increasing the depth, the factor is increased oxygen transfer efficiency. Its effect is similar to its effect on
gradually to reach to about 16 at a depth of 4.6 m and oxygen transfer capacity.
f/B ratio equal to 0.98. If the airflow rate and the depth of water are kept
constant, the oxygen transfer efficiency (E) is directly
16 proportional to the coverage ratio of diffuser. At (f/B = 0.25)
and depth of water of 0.5 m the aeration efficiency of the
Oxygenation efficiency, E, grO 2/m 3air
f/L = 0.98
f/B=0.98
14 diffuser is about 2.5 whereas this value is increased about 4
f/L = 0.50
f/B=0.50 at the same depth if the (f/B) ratio is increased to 0.95.
12
f/L = 0.25
f/B=0.25
However, the results of these curves comply with the normal
10 values of the diffused aeration systems. Some researchers
8
showed that the standard oxygen transfer ranged from 3.9 to
17.1 percent depending on the type of diffusion unit, its
y = 3.00x + 1.30
6
R2 = 0.98
placement, and the tankage configuration [1].
4
y = 2.10x + 1.57
6.0
2 R2 = 0.97 f/B =0.98
5.5
y = 1.31x + 1.24 5.0 f/B =0.50
0
Oxygen absorption, %
R2 = 0.94 4.5 f/B =0.25
0 0.5 1 1.5 2 2.5 3 3.5 4 4.5 5
4.0
Depth of water, m 3.5
y = 1.142x
3.0 R 2 = 0.9735
2.5
2.0 y = 0.8584x
Figure 7: Effect of water depth level (h) on oxygenation R 2 = 0.9466
efficiency (E) at constant air flow rate. 1.5
1.0 y = 0.6981x
As shown in the figure, equations that control this 0.5 R 2 = 0.9382
16
H=2.7 m ratios. As shown in the figure, the equations that control this
14 H=1.4 m relationship are linear. At constant airflow rate, increasing
12 H=0.5 m both of depth of water and (f/B) ratio significantly increasing
H=0.4 m the amount of oxygen transferred, i.e. percent of oxygen
10
y = 5.37x + 10.44
absorption. At water depth equal to 0.4 m and (f/B) ratio of
8 0.25, the percentage of absorption is about 5%, with
y = 3.93x + 3.70
6 increasing the (f/B) ratio to 0.98 and at fixed water depth, the
y = 2.15x + 2.75 ratio is increased to about 14%. As noted in the figure, the
4
y = 2.17x + 1.69 depth of water plays considerable role on percent of oxygen
2 absorption of diffused aeration system. If the (f/B) still
y = 1.00x + 1.33
0
constant, increasing the depth of water from 1.0 to 4.0 m will
0 0.1 0.2 0.3 0.4 0.5 0.6 0.7 0.8 0.9 1
increase the percentage value from 15% to 40%. However,
the effect of these parameters on the percentage value is
f /B ratio expected, since they enlarge the amount of both of the
oxygen transfer capacity (OC) and efficiency (E).
In the design point of stand, figurers 5 and 6 can be used
Figure 8: Effect of (f/B) ratio on oxygenation efficiency to select the optimum option with respect to depth of water in
(E) of the system at constant air flow rate. the tank and the coverage area of diffuser system. Typically,
influent and effluent BOD are known or assumed, and, after
In figure 8, the oxygen transfer efficiency (E) was selection of aeration tank loadings, the oxygen transfer per
plotted as a function of (f/B) ratio at different depths of day per unit volume of aeration tank become fixed and may
water. As expected, this factor has positive effects on be readily determined or estimated. These figures can be used
Int. J. Environ. Res. Public Health 2006, 3(3) 307
directly in determining the most suitable depth of water percentage ranged between 0.45 - 5.4 % depending on
in thank as well as the optimum (f/B) ratio. testing conditions.
Figures 7 and 8 are very important in the design
process since they give the efficiency (E) of the diffused References
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