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Fibre Auxiliaries | Pretreatment | DYEING | Colours | Textile Printing | Finishing | Coating | Garment

COTOBLANC SEL
MULTIFUNCTIONAL SOAPING 40 C 98 C

Do your reactive soaping processes in a variable way!


Save water, energy and time

COTOBLANC SEL
Synergistic blend of sequestering Application quantities
agents and polymers with affinity to
Continuous soaping:
dyes,
0.5 - 2.0 g/l COTOBLANC SEL
anionic, liquid
Discontinuous soaping:

Advantages 0.3 - 2.0 g/l COTOBLANC SEL
(LR 1:5 - 1:8)
Soaping at 40 C 98 C

Optimal soaping result, independent of Light shade dyeing (< 2.0 % dye)

hardness degree and salt content 0.3 0.6 g/l COTOBLANC SEL

Saving of water and energy effectiveness by Medium shade dyeing (2.0 4.0 % dye)

shorter processing time 0.6 1.5 g/l COTOBLANC SEL

Antibackstaining effect Deep shade dyeing (> 4.0 % dye)



1.5 2.0 g/l COTOBLANC SEL
Optimisation potential depends on applied
reactive system

Approved by GOTS; Bluesign; ZDHC (ZERO


DISCHARGE OF HAZARDOUS CHEMICALS)

How does COTOBLANC SEL work:

SEPARATION OF DYE COMPLEX PREVENTION OF


HYDROLYSATE FORMATION RE-ABSORPTION

(independent of temperature) (even in presence of


(Dye hydrolysate electrolyte)

+ COTOBLANC SEL)

Soaping and rinsing baths with COTOBLANC SEL using an


aftertreatment process at 60 C

Rinse at 60 C Soap at 60 C Rinse at 60 C


Soaping at 40 C 98 C 1 BEZAKTIV GO
SARABID MIP
common salt
x%
1.0 - 2.0 %
40.0 g/l

Depending on applied reactive system 2 dosing in 45 min


soda ash 5.0 g/l
NaOH 38 B z ml/l
3 COTOBLANC SEL 1.0 g/l
4 acetic acid 1.0 ml/l
Dyeing and soaping at 40 C REWIN ACP 1.0 %

BEZAKTIV GO 140
130
120
Low temperature dyeing 110
100 Reactive dyeing rinse soaping rinse cationic
aftertreatment
Temperature [C]

45 - 60' / 40 C 40 C 15 - 20' 40 C
Dye with high fixing degree 90
40 C 20' / 40 C
80
70
Dye easy to be washed off 60 1 2 3 4
50
40
30
20
10
0
0 20 40 60 80 100 120 140 160 180 200
Time [min]

Dyeing at 40 C and soaping at 60 C


BEZAKTIV GO 140
130
Dye with high fixing degree 120
110
100 Reactive dyeing rinse soaping rinse cationic
Dye easy to be washed off
Temperature [C]

90 45 - 60' / 40 C 60 C 15 - 20' 60 C aftertreatment


60 C 20' / 40 C
80 3

very dark shades 70


60 1 2 4
(black, navy, dark red) 50
40
30
20
10
0
0 20 40 60 80 100 120 140 160 180 200
Time [min]

Dyeing at 60 C and soaping at 80 C 98 C


Conventional reactive dyes 140
130 soaping
120 15 - 20'
Dye with lower fixing degree 110
80 C - 98 C

100 Reactive dyeing rinse rinse cationic


Temperature [C]

45 - 60' / 60 C 60 C 60 C aftertreatment
Dye difficult to be 90 20' / 40 C
80
washed off 70
1 2 3

60 4
50
40
30
20
10
0
0 20 40 60 80 100 120 140 160 180 200
Time [min]
Optimal soaping result
Independent of hardness degree and salt content
Fig.:
Reduction of salt quantity by rinsing
processes in standard process series
(estimated retention coefficient = 3).

Soaping test for reactive dyeings


Elimination of reactive dye hydrolysate

1. Reactive dye hydrolysate Basic fabric

Recipe:

2.5 g/l BEZAKTIV dark blue V-HR


10.0 g/l soda ash 5.0 dH 2x soaped accompanying accomp.
boil 4 h at reflux 5.0 g/l NaCl basic fabric material 1 material 2
(= Hydrolysation)

Padding: liquor pick-up: 80 %


(pad 1x)
Stenter: dry for 4 min at 120 C without
soaping agent
= Basic fabric
2. Soaping test (50 ml/soaping test) with
bleached CO woven fabric 1.0 g/l

COTOBLANC
Machine: Labomat SEL
LR: 1:10
Recipe: Water at 5dH with
5.0 g/l NaCl 1,0 g/l
aftersoaping
x g/l auxiliary agent based on
pH 8.5 with soda ash acrylate/
15 min at 98 C phosphonate
= Accompanying material 1
2.0 g/l
Repeat soaping process aftersoaping
agent based on
= Accompanying material 2
acrylate/
phosphonate
Optimal soaping result
by complex formation dye + COTOBLANC SEL

Soil or dye hydrolysate suspending capacity

2.5 g of fabric are treated at a liquor ratio of 1:20, with Basic 2.5 % 7.5 %
a bath of 50 ml at 95 C for 20 min. fabric dye dye

Test of the soiling of solution with BEZAKTIV dark blue


V-HR hydrolysed before in a standardised procedure.
2.5 g/l of BEZAKTIV dye are hydrolysed with 10.0 g/l without
soda ash at 98 C for 4 h. soaping agent

1.0 ml of this solution corresponds to the residual dye


of dyeing of 2.5 %, with fixing to 80 % at a liquor ratio
of 1:20.
3.0 ml of this solution correspond to dyeing of
7.5 %.
1.0 g/l

To determine the soil suspending power of the COTOBLANC
soaping agent, the quantity of dye is measured after SEL
the treatment which has been absorbed by the ready
to dye material in comparison to the untreated
material.

2.0 g/l

COTOBLANC
SEL

Material: CO knit fabric

LR: 1:20 1.0 g/l


aftersoaping
Water: Soft water (4 5dH) agent based on
acrylate/
phosphonate
Bath A: 20.0 ml/l hydrolysed dye
X g/l soaping agent
= 2.5 % dyeing

Bath B: 60.0 ml/l hydrolysed dye 2.0 g/l


X g/l soaping agent aftersoaping
= 7.5 % dyeing agent based on
acrylate/
Heat up at 95 C phosphonate
20 min at 95 C,
Rinse on overflow
Process shortening for existing
procedures
Saving of water and energy by optimised rinsing processes
140 2.0 g/l Standard soaping
130 neutralize soaping
20' / 30 C 15 - 20' agent
120 80 - 98 C
reactive dyeing rinse rinse rinse rinse
110 45 - 60' / 60 C 30 C 60 C 60 C
80 C
100
rinse rinse rinse Rinse +
Temperature [C]

90 rinse
30 C 30 C 30 C 30 C
80 1 2 soap
70
60
50
40
30
3 4

11
20 baths
10
0
0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Time [min]


140 1.5 g/l COTOBLANC SEL
130 soaping
neutralize 15 - 20'
120 20' / 30 C 80 - 98 C
reactive dyeing rinse
110 45 - 60' / 60 C 60 C
rinse
100 30 C rinse rinse Rinse +
Temperature [C]

90 30 C 30 C
80 1 2 soap
70
60
50
40
30
3 4
7
20 baths
10
0
0 20 40 60 80 100 120 140 160 180 200 220 240 260 280 300 320 340 360 380
Time [min]

Process data: 12.0 % Reactive black (VS) Process costs rinse/soap

Process time
Material: CV(CO/LY
Standard process 251 minutes

Quantity: 500 kg COTOBLANC SEL 164 minutes
Saving 87 minutes 34.7 %
LR: 1:8
Water consumption
Filling time: 5 min 3
Standard process 22.00 m
3
Let off time: 5 min COTOBLANC SEL 17.75 m
3
Saving 8.25 m 31.7 %
Heating gradient: 3.0 C/min
Steam consumption
Cooling gradient: 3.0 C/min
Standard process 2.462 kg

Water retention power: 2.5 l/kg COTOBLANC SEL 1.595 kg
Saving 867 kg 35.2 %
Power input: 50 kWh
Energy consumption
Standard process 140 kWh

COTOBLANC SEL 93 kWh
Saving 47 kWh 33.6 %
Antibackstaining
Soaping test on CO thread By afterwashing of thread dyed materials

with COTOBLANC SEL a bleeding on light
colours is prevented.
Material: CO thread, pretreated
LR: 1:10

Dyeing:
4.0 % BEZAKTIV dark blue V-HR
Rinse 2 x at 70 C, dry

Soap:
Colour fabric/white fabric 1/1
pH 7.0
20 min at 98 C, rinse

Basic fabric

2.0 g/l standard soaping agent


1.0 g/l COTOBLANC SEL


2.0 g/l COTOBLANC SEL
Antibackstaining in enzyme treatment
(dyed fabrics)
minimal colour shade change with application of BEIZYM BPN 300 (neutral cellulase)


prevention of soiling of accompanying material by addition of COTOBLANC SEL

Material: CO knit fabric, bordeaux


CO knit fabric, white

Bordeaux and white ratio 1:1

LR: 1:10

Recipe: 1) 1.0 % BEIZYM BPN 300


pH 7.0
60 min at 50 C, rinse, enzyme stop

2) 1.0 % BEIZYM BPN 300



0.5 ml/l COTOBLANC SEL
pH 7.0
60 min at 50 C, rinse, enzyme stop

Bordeaux White

Basic fabric

BEIZYM BPN 300

BEIZYM BPN 300



COTOBLANC SEL

February 2015, De Qualittsmanagement ISO 9001:2008 I Umweltmanagement ISO 14001:2004

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