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Applied Thermal Engineering 26 (2006) 22722278

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Eect of ethanolgasoline blends on engine performance


and exhaust emissions in dierent compression ratios
Huseyin Serdar Yucesu *, Tolga Topgul, Can C
inar, Melih Okur
Gazi University, Faculty of Technical Education, Department of Automotive, 06500 Teknikokullar/Ankara, Turkey

Received 18 May 2005; accepted 16 March 2006


Available online 5 May 2006

Abstract

Renewable energy sources for the gasoline engines alcohols gain importance recently. These renewable energy sources have attracted
the attention of researchers as alternative fuel due to their high octane number. In addition, these are also clean energy sources and can
be obtained from the biomass alcohols with low carbon like ethanol. In this study, the eect of compression ratio on engine performance
and exhaust emissions was examined at stoichiometric air/fuel ratio, full load and minimum advanced timing for the best torque MBT in
a single cylinder, four stroke, with variable compression ratio and spark ignition engine.
 2006 Elsevier Ltd. All rights reserved.

Keywords: Spark ignition engine; Compression ratio; Exhaust emissions; Alternative fuel; Ethanol

1. Introduction enable to storage and transportation safely. Since the oxy-


gen contain has positive eect on environment. In spite of
The majority of the energy used today is obtained from its positive eect when used in gasoline engine as alterna-
the fossil fuels. Due to the continuing increases in the cost tive fuel, it is necessary to make some modication on
of fossil fuels, demands for clean energy have also been the engine. The fuel system requires more fuel. The vehicle
increasing. Therefore, alternative fuels sources are sought. takes less distance with alcohol fuel than gasoline. Because
Some of the most important fuels are biogas, natural gas, of the rst cold starting problem of the pure ethanol, the
vegetable oil and its esters alcohols and hydrogen. Ethyl blend called E85 has a widespread usage as alternative fuel.
alcohol, which is one of the renewable energy sources This fuel consists of 15 vol% unleaded gasoline and
and is obtained from biomass, has been tested intensively 85 vol% ethanol. However, the other blend consisting of
in the internal combustion engines. Some properties of 90% gasoline and 10% ethanol called as gasohol. In addi-
ethyl alcohol with comparison to gasoline are given in tion, the ame of the alcohol is colorless in the natural
Table 1 [1]. burning processes and this is another advantage of alcohols
Due to the high evaporation heat, high octane number [2,3].
and high ammability temperature, ethyl alcohol has posi- The eects of ethanol and gasoline blends on spark igni-
tive inuence on the engine performance and increases the tion engine emissions were investigated by Hseih et al., [4].
compression ratio. The low reid evaporation pressure In their study, test fuels were prepared using 99.9% pure
ethanol and gasoline blended with the volumetric ratios
of 030% (E0, E5, E10, E20 and E30). These percentages
*
represent the ratios of ethanol amount in total blends. In
Corresponding author. Address: Department of Mechanical Educa-
tion, Faculty of Technical Education, Gazi University, Besevler, 06500
the experiments performed at dierent throttle openings
Ankara, Turkey, Tel.: +90 312 212 68 20/1850; fax: +90 312 212 00 59. and engine speeds, nearly the same torque values were
E-mail address: yucesu@gazi.edu.tr (H.S. Yucesu). obtained when used dierent ratios of ethanolgasoline

1359-4311/$ - see front matter  2006 Elsevier Ltd. All rights reserved.
doi:10.1016/j.applthermaleng.2006.03.006
H.S. Yucesu et al. / Applied Thermal Engineering 26 (2006) 22722278 2273

Table 1 of 8% of hydrogen with 30% of ethanol into a gasoline


Some properties of gasoline and ethanol [2] engine operating at nine compression ratios and 1500
Gasoline Ethanol rpm causes a 48.5% reduction in CO emission, 31.1%
Chemical formula C4C12 C2H5OH reduction in NOx emission and 58.5% reduction in spe-
Molecular weight 100105 46 cic fuel consumption. The engine power and thermal e-
Oxygen (mass%) 04 34.7 ciency were increased by 4.72% and 10.1%, respectively.
Net lower heating value (MJ/kg) 43.5 27
Latent heat (kJ/L) 223.2 725.4
When ethanol was added to the gasoline, NOx and CO
Stoichiometric air/fuel ratio 14.6 9 emissions decreased and specic fuel consumption
Vapor pressure at 23.5 C (kPa) 6090 17 increased. When hydrogen was added to the blend, CO
MON 8292 92 emission decreased and NOx emission increased. In addi-
RON 91100 111 tion, thermal eciency increased and specic fuel con-
sumption decreased.
Eect of ethanol and unleaded gasoline blends on engine
blends compared with pure gasoline. Only the torque performance was investigated by Al-Hasan [10]. Ten dier-
values obtained using E5 and E30 blends were lower than ent ethanolgasoline blends were prepared for the experi-
that of pure gasoline (E0) especially at high engine speeds ments. The ethanol amount in the blend was in the range
(after 4000 rpm) and partly open throttle in 20%. It is of 025% and the percentage of ethanol was increased
reported that, this arose from the original fuel injection 2.5% in each blend. The ethanol was 99% pure. The results
system strategies which prepare rich fuel mixtures. There- obtained from the experimental studies showed that the
fore, the leaning eect of ethanol to increase the air fuel engine emissions and performance were improved. The
equivalence ratio (k) to higher value, and make the burning engine power, brake thermal eciency and volumetric e-
closer to be stoichiometric. As a result the better combus- ciency were increased by 8.3%, 9% and 7% mean average
tion can be achieved and higher torque output can be values, respectively when the ethanol blended fuels were
acquired. used. In addition brake specic fuel consumption decrease
The eects of nine dierent volumetric percentages of 2.4% and equivalence air fuel ratio decrease by about 3.7%.
ethanolgasoline blends, ranging from 10% to 40%, on The blends had positive inuence on exhaust emissions.
engine emissions were tested at six dierent cars which were The CO and HC emissions decreased by 46.5% and
produced between 1990 and 1992. In the experiments, lin- 24.3%, respectively. The CO2 increased 7.5% nearly. The
ear variations of emissions were observed with respect to best performance and emissions results were obtained for
ethanol percentage. In the highest ethanol percentage 20% ethanol 80% unleaded gasoline blend.
which is 42%, the HC and CO emissions decreased about The eects of gasoline ethanol blends and compression
30% and 50%, respectively, and the fuel consumption ratio on engine performance were investigated [11]. In the
increased approximately 15% [5]. experiment 10%, 20% and 30% ethanolgasoline blends
The eects of gasoline blends containing oxygen on were used as fuel. Optimum compression ratio which
emissions were tested on six cars produced in European obtained maximum indicated power was determined for
countries. The experiments were performed on chassis each blend. For the 10%, 20% and 30% ethanolgasoline
dynamometer using ECE cruise cycle. In the cycle 10% blends, the optimum compression ratios of 8, 10 and 12
MTBE, 15% MTBE and 5.2% ethanol were used as fuel, were obtained.
the CO emission 1530%, HC emission 1020% and NOx Wu et al. [12] investigated the eect of airfuel ratio on
emissions 1.31.7% decreased [6]. SI engine performance and pollutant emissions using
The eect of alcohol and gasoline blends contained by ethanolgasoline blends. The result of engine performance
mass ratio of 1.25%, 2.5%, 3.75% and 5% oxygen on engine tests showed that torque output improves when using eth-
emissions were investigated experimentally by Taylor et al. anolgasoline blends. However, there is no appreciable dif-
[7]. Methanol, ethanol, i-propanol and n-propanol were ference on the brake specic heat consumption. CO and
used as fuel. When using alcohol and gasoline blends con- HC emissions reduced with the increase of ethanol content
tained by mass ratio of 5% oxygen, the emissions HC and in the blended fuel. The maximum CO2 emission was
CO decreased 40% and 75%, respectively. obtained at k  1.01, but the smallest amount CO2 emis-
Cowart et al. used methanol M85 and ethanol E85 as sion obtained with E30. In their study found out that by
fuels [8]. When alcohols blended fuels were used the engine using 10% ethanol fuel, can reduce pollutant emission
performance increased. The engine torque and power eciently.
increased with the both fuels M85 and E85 7% and 4%, In this work, eects of compression ratio on engine per-
respectively. formance and exhaust emissions were investigated with dif-
Hydrogen, ethanol and gasoline blends were examined ferent ethanolgasoline fuel blends. Experiments were
in a four stroke spark ignition engine [9]. In the experi- performed at three dierent engine speeds which were
ments, ethanol blended gasoline in volumetric ratios 2000, 3500 and 5000 rpm and wide open throttle. The
ranging from 0% to 30% and hydrogen were added to the aim of this work is to clarify best working conditions at dif-
blend in mass ratios ranging from 0% to 20%. The addition ferent compression ratios.
2274 H.S. Yucesu et al. / Applied Thermal Engineering 26 (2006) 22722278

2. Experimental procedure and equipment Table 4


Specications of Sun MGA 1200
In the experimental study, a single cylinder Hydra spark Measurements range Accuracy
ignition engine with injection system was used. Specica- Lambda (k) 0.802.00 0.001
tions of the test engine are given in Table 2. CO (vol%) 010% 0.01%
The tests were performed at 2000, 3500 and 5000 rpm CO2 (vol%) 020% 0.01%
HC (ppm) 020,000 1
and at stoichiometric air fuel ratio given MBT (Maximum O2 (vol%) 021% 0.1%
Brake Torque timing) and at full open throttle (WOT). The
test fuels were gasoline (E0) and gasoline ethanol blends
E10, E20, E40 and E60, the numbers following E indicate
percentage of volumetric amount of ethanol. The experi- 3. Results and discussion
ments were performed at six dierent compression ratios
ranging from 8:1 to 13:1 for each fuel and the eect of Engine torque and brake specic fuel consumption vari-
engine performance was investigated. The purity ratio of ations at 2000 rpm engine speed are seen in Fig. 2. The
ethanol is 99.5%. Properties of ethanolunleaded gasoline engine torque increased with increasing compression ratio
blended fuels are shown in Table 3. up to 11:1, the increasing ratio is about 8% when compared
Air consumption was measured using Go-power M 5000 with 8:1 compression ratio. However, from 11:1 to 13:1
model air-meter. A suitable venturi for the engine was used compressions ratio, increments are about 0.95% with E0.
in air meter to obtain 1 mm water column sensitivity. Fuel The highest increasing ratio of engine torque was obtained
consumption was measured using Ohaus GT 8000 model at 13:1 compression ratio with E40 and E60 fuels, the incre-
scale in sensitivity of 0.1 g and for time measurement; ment is about 14% when compared with 8:1 compression
Robic SC-700 model chronometer was used. Airfuel ratio ratio. Minimum brake specic fuel consumption (BSFC)
and exhaust emissions were measured using Sun MGA was obtained at 11:1 compression ratio with E0 fuel. Com-
1200 model emission tester. Specications of the emission parison with 8:1 compression ratio, the BSFC decreased
tester are given in Table 4 and the schematic view of test 10% and after 11:1 compression ratio the BSFC increased
bench is seen in Fig. 1. again. The maximum decrease in BSFC was found to be
15% when E40 was used. Variation of MBT related to
the compression ratio is seen in Fig. 3. To reach the max-
Table 2 imum engine torque in the gasoline tests, the ignition
Test engine specications advance increased gradually at 8:1, 9:1 and 10:1 compres-
Item Specication sion ratios. In compression ratios of 8:1, 9:1 and 10:1, the
Type Hydra
octane number of the gasoline allowed increasing spark
Number of cylinder 1 advanced timing and after the compression ratio of 10:1,
Cylinder bore stroke 80.26 88.9 mm the spark ignition timing could not be increased to reach
Maximum speed 5400 rpm MBT. Therefore, the engine operated at advanced timing
Maximum power 15 kW which did not cause detonation at a given compression
Compression ratio 5/113/1
Valve arrangement Overhead camshaft, two vertical valves
ratio. Because of sucient octane number, the E40 and
Fuel system Petrol injection E60 fuels are advantageous in terms of engine
Timing range 70 BTDC20 ATDC performance.

Table 3
Properties of ethanolunleaded gasoline blended fuels (E0, E10, E20, E40 and E60)
Property item Method Test fuels
E0 E10 E20 E40 E60
Distillation (vol%)
70 C ASTM D 86 24 40.2 39.3 37.7 18.2
100 C 46.8 53.9 66 84.2 92.5
180 C 97.6 97.3 98 98.2 98.7
Density (kg/m3 at 15 C) ASTM D 1298 764.9 768 771.5 780.6 789.5
RVP (kPa) ASTM D 323 57.6 66.7 66.2 63 57.4
Lead content (g/L) ASTM D 3237 0.004 0.003 0.002 0 0
Sulfur (wt%) ASTM D 5453 0.012 0.017 0.022 0.026 0.032
Stoichiometric airfuel ratio (weight)a 14.7 14.13 13.56 12.42 11.28
Lower heating value (kJ/kg)a 43,932 42,185 40,430 36,870 33,400
RON ASTM D 2699 86.4 87.4 89.8 90.9 92.7
MON ASTM D 2700 98.8 99.9 101.6 101.7 102.8
a
Typical or calculated values.
H.S. Yucesu et al. / Applied Thermal Engineering 26 (2006) 22722278 2275

Fig. 1. Schematic view of the test bench.

35 450 take over. In our study, to obtain k = 1 the opening dura-


E0 E10 E20 tion of the injector increases depend on the ethanol per-
34 420
E40 E60 centage. Thus the energy amount in the cylinder remains
33 390 nearly constant. Therefore in all compression ratios the

BSFC (g/kWh)
better engine performance was obtained than E0 by using
Torque (Nm)

32 360
blends up to the 60% ethanol. The relative airfuel ratio
31 330 (k) is dened as
30 300 AFRact:
k
AFRst:
29 270
(AFR)act is actual airfuel ratio and (AFR)st. is stoichiom-
28 240
8 9 10 11 12 13 etric airfuel ratios of test fuels.
Compression Ratio
Ignition timing variations, causing detonation, with
Fig. 2. Variation of BSFC and engine torque versus compression ratio compression ratio at 2000 rpm is seen in Fig. 4. Sound of
(engine speed: 2000 rpm). detonation could be heard at low speeds, particularly when
increased in advanced timing. At the same time the knock
formations were observed on oscilloscope screen. In the
32
experiment performed with E40 and E60 ethanol blends
E0 E10 E20
28 were not observed knock formations with MBT. When
MBT (CA, BTDC)

E40 E60
24 the ignition timing increased above the MBT, the knock
phenomena can be seen with E40 and E60. Higher octane
20
number of ethanol and blends compared with gasoline
16 yield better detonation resistance.
12 Variation of BSFCs at the same experimental conditions
8
at 3500 and 5000 rpm engine speeds are shown in Fig. 5
7 8 9 10 11 12 13 14 and Fig. 6, respectively. With increasing compression ratio
Compression Ratio
at both engine speeds, the engine torque increased. At the
Fig. 3. Variation of MBT versus compression ratio (engine speed: compression ratio of 13:1 compared with compression
2000 rpm).

In Ref. [11], in the 10 compression ratios, the E10 fuel 40


Ignition Timing at Knocking Limit

blend increases the maximum pressure over that of pure 35


unleaded gasoline. However the ethanol percentage above
30
10% results in a decrease of the maximum pressure to a
(CA, BTDC)

value even lower than E0s pressure. This explains as the 25


addition of ethanol to gasoline has two eects on the fuel 20 E0
blend properties: E10
15 E20
E40
(1) An increase of the octane number. 10
E60
(2) A decrease in the heating value. 5
8 9 10 11 12 13 14
These eects have opposite results in terms of engine Compression Ratio

performance. The rst eect dominates up to an ethanol Fig. 4. Variation of detonated ignition timing versus compression ratio
percentage of 10%, after which the second eect starts to (engine speed: 2000 rpm).
2276 H.S. Yucesu et al. / Applied Thermal Engineering 26 (2006) 22722278

36 490 Variations of MBT with the compression ratio at


E0 E10 E20 3500 rpm and at 5000 rpm are shown in Fig. 7 and in
34 E40 E60 440 Fig. 8, respectively. At higher compression ratios, MBT
values were close at all fuel blends compared with

BSFC (g/kWh)
Torque (Nm)

32 390 2000 rpm engine speed. It can be seen from the graphics
that MBT is not only related to compression ratio and type
30 340 of fuel but also related to the engine speed. Increasing com-
pression ratio increases the temperature of end gas area
28 290 which caused detonation. The resistance of the mixture to
the detonation is important in this area. One of the most
26 240 important parameters aecting the engine performance is
8 9 10 11 12 13
Compression Ratio

Fig. 5. Variation of engine torque and BSFC versus compression ratio


(engine speed: 3500 rpm). 40
E0 E10 E20
36

MBT (CA, BTDC)


E40 E60
32 480
E0 E10 E20 32
30 E40 E60 440
28
28 400
BSFC (g/kWh)
Torque (Nm)

24

26 360 20
7 8 9 10 11 12 13 14
24 320 Compression Ratio

Fig. 8. Variation of MBT ignition timing with compression ratio (engine


22 280
speed: 5000 rpm).
20 240
8 9 10 11 12 13
Compression Ratio
820
Fig. 6. Variation of engine torque and BSFC versus compression ratio
E0 E10 E20
(engine speed: 5000 rpm). 800
E40 E60

780
ratio of 8:1, the engine torque increased with E0 fuel by
5000 rpm
14.6% at 3500 rpm and 18.4% at 5000 rpm engine speeds,
respectively. The maximum increase in the engine torque 760

was obtained with E60 fuel by 19.2% and 21.5% at


3500 rpm and 5000 rpm, respectively. At the compression 740

ratio of 13:1 compared with compression ratio of 8:1, the


improvement of BSFC with E0 fuel was about 10.4% and 720
Exhaust Temperature (C)

13.6% at 3500 rpm and 5000 rpm engine speeds, respec-


3500 rpm
tively. The improvement of BSFC with E60 fuel was about 700

14.7% and 17% at 3500 rpm and 5000 rpm engine speeds,
respectively. 680

660

36
E0 E10 E20 640
32 E40 E60
MBT (CA, BTDC)

28 620
2000 rpm
24
600
20

16 580
12
7 8 9 10 11 12 13 14
560
Compression Ratio 7 8 9 10 11 12 13 14
Compression Ratio
Fig. 7. Variation of MBT ignition timing with compression ratio (engine
speed: 3500 rpm). Fig. 9. Variation of exhaust gas temperature versus to compression ratio.
H.S. Yucesu et al. / Applied Thermal Engineering 26 (2006) 22722278 2277

octane number of the used fuel especially at low engine 26 0


speed. As the engine speed increases, the ame surface to 24 0 E0 E1 0
E2 0 E4 0
be formed by spark plug reaches rather early to the end 22 0 E6 0

HC (ppm)
gas area and the probability of the detonation decreases. 20 0
However it must be indicated that the octane number 18 0
has an important eect on detonation. Because of the 16 0
increasing octane number, higher engine torque was 2000 rpm
14 0
obtained. In the experiment the E60 fuel enabled to
12 0
increasing the MBT at 5000 rpm engine speed so the higher 7 8 9 10 11 12 13 14
torque was obtained. Compression Ratio

Variations of the exhaust gas temperature depending on 18 0


the compression ratios are shown in Fig. 9 for 2000, 3500 16 0
and 5000 rpm engine speeds. In general, the exhaust gas 14 0

HC (ppm)
temperatures decrease with increasing compression ratio. 12 0
Increasing compression ratio increases the pressure and
10 0
temperature of the mixture at the end of the compression
80
stroke and decreases the advanced timing requirement for
60 3500 rpm
the MBT. The amount of energy converted to the useful
work increases. However, use of fuels with lower octane 40
7 8 9 10 11 12 13 14
number like E0, aected the combustion process badly Compression Ratio

after the 10:1 compression ratio. This situation was 120

100

0.9
HC (ppm)

80
E0 E10 E20
0.8 E40 E60 60

40 5000 rpm
CO (vol %)

0.7
20
0.6 7 8 9 10 11 12 13 14
Compression Ratio

0.5
2000 rpm
Fig. 11. Variation of HC emission versus compression ratio.

0.4
7 8 9 10 11 12 13 14 improved using fuels with higher octane number and
Compression Ratio
increasing engine speed.
0.9 Variations of the CO and HC emissions depending on
the compression ratio are shown in Figs. 10 and 11 at
0.8
2000, 3500 and 5000 rpm engine speeds. Especially, consid-
CO (vol %)

0.7 erable decrease was observed when the fuels contained


higher amount of ethanol like E40 and E60. The most sig-
0.6 nicant decrease in CO emission was observed with the use
0.5 of E40 and E60 fuels at 2000 rpm engine speed. Average
3500 rpm
decreasing ratios of CO emission were 11% and 10.8%
0.4 for E40 and E60, respectively. In respect of HC emissions,
7 8 9 10 11 12 13 14
Compression Ratio the highest decreases were observed at 5000 rpm engine
speed as 9.9% and 16.45% for E40 and E60, respectively.
1.1
Decreasing ratio of HC emission was found to be higher
1 than that of CO emissions.
0.9
CO (vol %)

4. Conclusions
0.8

0.7 In this work the following results were obtained:


0.6 5000 rpm
With increasing compression ratio up to 11:1, engine
0.5
7 8 9 10 11 12 13 14 torque increased with E0 fuel, at 2000 rpm engine speed.
Compression Ratio
Compared with the 8:1 compression ratio, the increment
Fig. 10. Variation of CO emission versus compression ratio. ratio was about 8%. At the higher compression ratios
2278 H.S. Yucesu et al. / Applied Thermal Engineering 26 (2006) 22722278

the torque output did not change noticeably. At 13:1 leum Research Center of METU. As researchers, we thank
compression ratio compared with 8:1 compression ratio, Scientic Research Foundation of Gazi University and
the highest increment was obtained for both fuels E40 Petroleum Research Center of METU.
and E60 as nearly 14%.
At 11:1 compression ratio compared with 8:1, the BSFC
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