CHEM1041 Dr.

Padolik SI Leader: Karleigh Smith

2/2/2017

Review
1) A concentrated solution of aqueous ammonia is 28.0% by mass NH3 and has a density of

0.899 g/mL. What is the molar concentration of NH3 in this solution?

2) The maximum allowed concentration of chloride in a municipal drinking water supply is 102

ppm Cl. When the supply of water exceeds this limit, it often has a distinctive salty taste. What

is this concentration in moles Cl/liter?

3) Calculate the vapor pressure lowering of an aqueous glucose solution that is 30.0 g of glucose

(non volatile) in 100.0 g water at 20oC (Pwater= 17.5 torr; MM glucose = 180.1 g/mol)

4) Ethylene glycol (MM = 62.1 g/mol ) is used in car radiators as antifreeze. What is the freezing

point of an aqueous solution that is 35% ethylene glycol by mass? Kf(water)=1.86C/m

Tf = Kf m

Vant Hoff Factor Coligative Properties

5) What is the osmotic pressure in mmHg of 6.00 L of a 0.108 M solution of barium chloride at

30C?

6) The freezing point depression of a 0.10 m solution of HF(aq) solution is -0.201 C. Calculate

the Vant Hoff Factor. (Challenge: what is the percent dissociation of HF (aq)?)
CHEM1041 Dr. Padolik SI Leader: Karleigh Smith
2/2/2017

7) An isotonic solution will produce an osmotic pressure of 7.84 atm measured against pure

water at human body temperature (37.0C). How many grams of sodium chloride must be

dissolved in a liter of water to produce an isotonic solution? (MW sodium chloride = 58.45

g/mol)

8) What will be the freezing point and boiling point of a solution containing 150.0 g NaCl in

300.0 g diethyl ether? BP diethyl ether = 34.6C; MP diethyl ether = -116.3C; Kb = 2.02 C/m;

Kf = 1.70 C/m

9) How many grams of glucose (C6H12O6) per liter should be used for an intravenous solution to

match the 7.65 atm at 37 C osmotic pressure of blood?

10) Calculate the vapor pressure of a solution prepared by dissolving 35.0 grams of magnesium

chloride in 85.0 g of water at 50.0C. (Vapor pressure of water = 93 mmHg)