Gaseous state

Fill in the blanks

1.
The absolute temperature of an ideal gas is . to/than the average kinetic energy of the gas molecules
2.
Eight gram each of oxygen and hydrogen at 27C will have the total kinetic energy in the ratio of .. .
3.
The value of PV for 5.6 litres of an ideal gas is .. RT, at N.T.P.
4.
The rate of diffusion of gas is . proportional to both . and square root of molecular mass.
1. A vessel of 120 mL capacity contains a certain amount of gas at 35 C and 1.2 bar pressure. The gas is transferred to
another vessel of volume 180 mL at 35 C. What would be its pressure? [0.8 bar]
2. Pressure of 1 g of a gas A at 27 C is found to be 2 bar. When 2 g of another gas B is introduced in the same flask at same
temperature the pressure becomes 3 bar. Find a relationship between their molecular masses.[ MB = 4MA]
3. A student forgot to add the reaction mixture to the round bottomed flask at 27 C but instead he/she placed the flask on the
flame. After a lapse of time, he realized his mistake, and using a pyrometer he found the temperature of the flask was 477
C. What fraction of air would have been expelled out?[ 3/5]
4. At 0C, the density of a certain oxide of a gas at 2 bar is same as that of dinitrogen at 5 bar. What is the molecular mass of
the oxide?[ 70 g/mol]
5. (a) A container has 3.2 g of a certain gas at NTP. What would be the mass of the same
gas contained in the same
vessel at 200C and 16 atm. Pressure?
(b) A certain quantity of a gas measured 500 mL at a temperature of 15C and 750 mm Hg. What pressure is required to
compress this quantity of gas into a 400 mL vessel at a temperature of 50C? [(a)29.55 g, b=1051 mm]
4
1
6. Calculate root mean square speed of O3 at 20C and 82 cm Hg [3.9 10 cm sec ]
7. The mass of molecule A is twice the mass of molecule B. The rms speed of A is twice the rms speed of B. If the samples of
A and B contain the same number of molecules, what will be the ratio of pressure of two samples in separate containers of
equal volume? [PA = 8PB]
8. Compressibility factor (Z) for N2 at 50C and 800 atm pressure is 1.95. Calculate mole of N2 gas required to fill a gas
cylinder of 100 litre capacity under the given conditions.[ 2240.8]
9. Calculate the temperature of gas if it obeys Van der Waals equation from the following data. A flask of 25 litre contains 10
2
2
1
mole of agas under 50 atm. Given: a = 5.46 atm lit mol and b = 0.031 lit mol [1256.93C]
10. The drain cleaner, Drainex contains small bits of aluminum which react with caustic soda to produce dihydrogen. What
volume of dihydrogen at 20 C and one bar will be released when 0.15g of aluminum reacts?[ 202.5 mL]
11. (a) Two flasks of equal volume connected by a narrow tube (of negligible volume) are at 27C and contain 0.7 moles of H2
at 0.5 atm. One of the flask is then immersed into a bath kept at 127C, while the other remains at 27C. Calculate the
final pressure and the number of moles of H2 is each flask.[ (a) 0.571 atm, 0.3 and 0.4 moles]
(b) 1 gm of an alloy of Al and Mg reacts with excess HCl to form AlCl3, MgCl2 and H2. The evolved H2 collected over
mercury at 0C occupied 1200 ml at 699 mm Hg. What is the composition of alloy?[ 44 % Mg, 56 % Al]
12. if a sample of ozonised oxygen containing 86.16% of O 3 by weight required 430 secs to diffuse under conditions where
pure O2 required 369.5 secs. Determine the vapour density of O 3.[ 23.3]
13. Critical temperature for carbon dioxide and methane are 31.1 C and -81.9 C respectively. Which of these has stronger
intermolecular forces and why?
14. 9 litre of gaseous mixture consisting of gaseous organic compound A and just sufficient amount of O 2 required for complete
combustion yielded on burning 4 litre of CO2, 6 volumes of water vapour and 2 litre of N2 all volumes measured at the
same temperature and pressure. If the compound A contained only C, H and N
(i) how many volumes of O2 required for complete combustion?
(ii) What is the molecular formula of the compound A? [7litre, C2H6N2]
o
15. (a) How large a balloon could you fill with 4.0 g of He gas at 27 C and 760 mm of Hg?
0
(b) Calculate the density of CO2 at 100 C and 800 mm Hg pressure. [25.65 litre,1.5124 g/litre]
16 Arrange the following in increasing order of property mentioned for the respective graph
For graph (a) temperature For graph (b) presures For graph (c) volume For graph (d)temperature

n
i
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t
spo

y
r
t
s
mi

m
y
b

s
e
k
u

g
o
l
b
sir.

che

(c)
17 Pay load is defined as the difference between the mass of displaced air and the mass of the balloon. Calculate the pay

load when a balloon of radius 10 m, mass 100 kg is filled with He at 1.66 bar at 27C. (d of air = 1.2 kg m -3 )
18 A balloon is filled with hydrogen at room temperature. It will burst if pressure exceeds 0.2 bar. If at 1 bar pressure the
gas occupies 2.27 L volume, upto what volume can the balloon be expanded ?[ 11.35 L]

1 The ratio of rates diffusion of SO2, O2 and CH4 is

(A) 1 : 2 : 2 (B)1 : 2 : 4
(C) 2 : 2 : 1(D)1 : 2 : 2
2. The Van der Waals equation explains behaviour of
(A) Ideal gases(B) Real gases
(C) Vapour(D) Nonreal gases
3. Which of the following is not a crystalline solid?
(A) KCl(B)Cl(C)glass(D)Rhombic sulphur
4. The density of neon will be highest at
(A) STP(B) 0C, 2 atm
(C) 273C, 1 atm(D)273C, 2 atm
5. Absolute zero is defined as the temperature
(A) at which all molecular motion ceases
(B) at which liquid helium boils
(C) at which ether boils
(D) all of the above
6. At constant temperature, in a given mass of an ideal
gas
(A) The ratio of pressure and volume always remains
constant
(B) Volume always remains constant
(C) Pressure always remains constant
(D) The product of pressure and volume always
remains constant
7. At the same temperature and pressure, which of the
following gases will have the highest kinetic energy
per mole?
(A) Hydrogen(B)Oxygen(C)ethane(D)All are same
8. Which of the following mixture of gases does not
obey Daltons law of Partial pressure?
(A) O2andCO2(B)N2andO2(C)Cl2andO2(D)NH3and
HCl
9. The temperature at which real gases obey the ideal
gas laws over a wide range of pressure is called
(A) Criticaltemperature(B)Boyle temperature
(C) Inversiontemperature(D)Reduced temperature
10. The compressibility factor for an ideal gas is:
(A) 1.5(B)1.0(C)2.0(D)
11. According to Grahams law at a given temperature,
the ratio of the rates of diffusion r A/rB of gases A and
B is given by

y
r
t
s
mi

1/ 2

M P
(B) A A
MB PB

1/ 2

M P
(D) A B
MB PA

P M
(C) A B
PB MA

n
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t
spo

s
e
k
u

m
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b

che

P M
(A) A A
PB MB

(A) 180 mm(B)360 mm(C)540 mm(D)720 mm

17. Same mass of CH4 and H2 is taken in container. The
partial pressure caused by H2 is
1
8
1
(A)
(B) (C) (D)1
9
9
2
18. Equal volumes of the gases which do not react
together are enclosed in separate vessels. This
pressures of 100 mm, and 400 mm respectively. If
the two vessels are joined together, then what will be
the pressure of the resulting mixture (temperature
remaining constant)?
(A) 125 mm(B)500mm(C) 1000 mm(D)250 mm
19. The density of air is 0.00130 g/ml. The vapour
density of air will be
(A) 0.0065(B)0.65(C)14.4816(D)14.56
20. Molecular weight of a gas that diffuses twice as
rapidly as the gas will molecular weight 64 is:
(A) 16(B)8(C)64(D)6.4
Level II
1. If P, V, T represent pressure, volume and
temperature of a gas, the correct representation
of Boyles law is
1
(A) V (at constant P)(B)PV = RT
T
1
(C) V (at constant T)(D)PV = nRT
P
2. Five grams each of the following gases at 87C and
750mm pressure are taken. Which of them will have
the leastvolume?(A) HF(B)HCl(C)HBr(D)HI
3. A real gas most closely approaches the behaviour of
an ideal gas at(A)15 atm and 200K(B)1 atm and
273K
(C) 0.5 atm and 500KD)15 atm and 500K
4. Which one of the following statements is true?
(A) The gas equation is not valid at high pressure
and low temperature
(B) The product of pressure and volume of a fixed
amount of gas is independent of temperature
(C) Molecules of different gases have the same
kinetic energy at a give temperature
(D) The gas constant per molecule is called as
Boltzmanns constant
5. Two separate bulbs contain ideal gas A and B. The
density of gas A is twice that of B. The molecular
mass of A is half that of B. The two gases are at the
same temperature. The ratio of pressure A to that of
gas B is:
1
1
(A) 2 (B)
(C)4 (D)
2
4
6. Use of hot air balloons in sports and metrological
observations is an application of
(A)Boyleslaw(B)Kelvinslaw(C)Charleslaw(D)Brown
s law
7. For an ideal gas, the number of moles per litre in
terms of its pressure P, gas constant R and
temperature T is:
PT
P
PT
(A)
(B)PRT (C)
(D)
R
RT
P
8. The Van der Waals equation reduces itself to the
ideal gas equation at
(A) High pressure and low temperature(Blow
pressure and low temperature
(C) low pressure and high temperature(D)high
pressure alone

1/ 2

1/ 2

12. 4.4 gm of a gas at STP occupies a volume of 2.24

litre, the gas can be
(A) O2 (B)CO (C)NO2 (D)CO2
13. A certain sample of gas has a volume of 0.2 litre
measured to 1 atm. Pressure and 0C. At the same
pressure but at 273C, its volume will be
(A) 0.4 litre (B)0.8 litre (C)27.8 litre(D)55.6 litre
14. If the four tubes of a car are fitted to the same
pressure with N2, O2, H2 and Ne separately, then
which one will be filledfirst?(A)N2B)O2(C)H2(D)Ne
15. If pressure becomes double at the same absolute
temperature of 2 litre CO2, then the volume of CO2
becomes(A)2litre(B)4 litre(C)5 litre(d)1 litre
16. A gaseous mixture contains 56g of N2, 44g of CO2
and 16g of CH4. The total pressure of the mixture is
720 mm Hg. The partial pressure of CH4 is:

g
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b
sir.