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MULTIPLE CHOICE.
Choose the one alternative that best completes the statement or answers the question.
1) Which of the following compounds will be most soluble in ethanol (CH3CH2OH)?
A) acetone (CH3COCH3)
B) ethylene glycol (HOCH2CH2OH)
C) trimethylamine (N(CH3)3)
D) hexane (CH3CH2CH2CH2CH2CH3)
E) None of these compounds should be soluble in ethanol.
1)
2)
3) The phrase "like dissolves like" refers to the fact that ________.
A) polar solvents dissolve nonpolar solutes and vice versa
B) solvents can only dissolve solutes of similar molar mass
C) condensed phases can only dissolve other condensed phases
D) gases can only dissolve other gases
E) polar solvents dissolve polar solutes and nonpolar solvents dissolve nonpolar
solutes
3)
4)
5) How many moles of KF are contained in 102 mL of 0.135 m KF aqueous solution? The
density of the solution is 1.22 g/mL.
A) 3.99 10-2 mol KF
B) 1.67 10-2 mol KF
C) 2.32 10-2 mol KF
D) 4.31 10-2 mol KF
E) 3.29 10-2 mol KF
5)
CHEM 1212
6)
7) Commercial grade HCl solutions are typically 39.0% (by mass) HCl in water.
Determine the molarity of the HCl, if the solution has a density of 1.20 g/mL (Mwt HCl
= 36.46 g/mol).
A) 7.79 M
B) 9.35 M
C) 13.9 M
D) 10.7 M
E) 12.8 M
7)
8) A 4.55 L sample of water and salt contains 0.115 g of sodium ions. Determine the
concentration of sodium ions in ppm if the density of the solution is 1.00 g/mL.
A) 12.7 ppm
B) 25.3 ppm
C) 52.3 ppm
D) 36.5 ppm
E) 13.2 ppm
8)
9) To make a 0.500 M solution, one could take 0.500 moles of solute and add
A) enough solvent to make 1.00 L of solution.
B) 1.00 kg of solvent.
C) 1.00 L of solvent.
D) enough solvent to make 1.00 kg of solution.
9)
10) The concentration of CO2 in a soft drink bottled with a partial pressure of CO2 of 4.0
atm over the liquid at 25 C is 1.2 10-1 M. The Henry's law constant for CO2 at this
10)
temperature is ________.
A) 2.3 10-2 mol/L-atm
B) 3.0 10-2 mol/L-atm
C) 5.6 10-3 mol/L-atm
D) 4.5 10-3 mol/L-atm
E) More information is needed to solve the problem.
11) Determine the freezing point depression of a solution that contains 30.7 g glycerin
(C3H8O3, Mwt= 92.09 g/mol) in 376 mL of water. Some possibly useful constants for
water are Kf = 1.86C/m , Kb = 0.512C/m and density =1.00g/mL
A) 3.33C
B) 1.65C
C) 0.654C
D) 0.887C
E) -3.33C
11)
CHEM 1212
12) Which of the following aqueous solutions will have the lowest freezing point?
A) 0.010 m Na2CO3
B) 0.035 m CH3CH2OH
C) 0.015 m BaCl2
12)
D) 0.010 m K Br
13) Given the following balanced equation, determine the rate of reaction with respect to
[NOCl].
13)
1 [NOCl]
2
t
B) Rate = -
1 [NOCl]
2
t
C) Rate = -
1 [NO]
2 t
D) Rate = -
2 [NOCl]
t
14)
15) What is the overall order of the following reaction, given the rate law?
15)
1
order
2
B) 3rd order
C) 0th order
D) 2nd order
E) 1st order
CHEM 1212
16) Given the following balanced equation, if the rate of Cl2 loss is 4.24 10-2 M/s, what
is the rate of formation of NOCl?
16)
17)
A)
1 [H2O]
6
t
B)
1 [NO2]
4
t
C) -
1 [NH3]
4
t
D) -
1 [O2]
7
t
18)
CHEM 1212
19) Which of the following statements is true about the reaction 2A B + C which is first
order in A and first order overall?
A) The rate of the reaction will decrease at higher concentrations of B and C.
B) The rate of formation of B is the same as the rate of reaction of A.
C) The rate of formation of C is twice the rate of reaction of A.
D) The rate of the reaction is independent of A.
E) The initial rate doubles with doubling of initial concentration of A.
19)
20) Determine the rate law and the value of k for the following reaction using the data
provided.
20)
[O2]i (M)
0.0055
0.0110
0.0055
21)
22) The first-order decomposition of cyclopropane has a rate constant of 6.7 x 10-4 s-1. If
the initial concentration of cyclopropane is 1.33 M, what is the concentration of
cyclopropane after 644 s?
A) 0.15 M
B) 0.94 M
C) 0.86 M
D) 0.43 M
E) 0.67 M
22)
23) The second-order decomposition of HI has a rate constant of 1.80 x 10-3 M-1s-1. How
much HI remains after 27.3 s if the initial concentration of HI is 4.78 M?
A) 4.55 M
B) 2.39 M
C) 3.87 M
D) 2.20 M
E) 0.258 M
23)
CHEM 1212
24)
25) Which one of the following graphs shows the correct relationship between
concentration and time for a reaction that is second order in [A]?
A)
25)
B)
C)
D)
E)
Answer Key
Testname: EXAM 2 W15 1212
B
2) B
3) E
4) A
5) B
6) E
7) E
8) B
9) A
10) B
11) B
12) C
13) A
14) C
15) D
16) B
17) E
18) C
19) E
20) E
21) E
22) C
23) C
24) C
25) E
1)