Atomic Structure

Level 1
Q No: 1
The specific charge of a proton is 9.6 107C kg1, then for an -particle it will be
(1) 2.4 107C kg1
(2) 4.8 107C kg1
(3) 19.2 107C kg1
(4) 38.4 107C kg1
Correct Answer: 2 Status: unattempted
Mass of particle 4 mass of proton
Q No: 2
If a proton and deutron is projected towards the same nucleus, with the same momentum,
the ratio of their distances of closest approach is
(1) 1 : 1
(2) 1 : 2
(3) 1 : 4
(4) None of these
[X]
Distance of closest approach (rmin) is calculated by
where q1 and q2 are charge on the particle striked and target nucleus.
(q1 and q2 are same for both proton and deutron, as charge on proton and
deutron is same and target nucleus is same)
Q No: 3
A 1k-W radio transmitter operates at a frequency of 880 Hz. How many photons per
second does it emit
(1) 1.71 1021
(2) 1.71 1033
(3) 6.02 1023
(4) 2.85 1026
[X]
Total energy released = nhv
Q No: 4
n => Number of photons
A gas absorbs a photon of 300 nm and then re-emitts two photons. One photon has a
wavelength 600 nm. The wavelength of second photon is
(1) 300 nm
(2) 400 nm
(3) 500 nm
(4) 600 nm
[X]
E = E1 + E2
E => energy of absorbed photon
E1 & E2 => energies of emitted photons
Q No: 5
Radiations of frequency, v, are incident on a photosensitive metal. The maximum kinetic
energy of photoelectrons is E. When the frequency of the incident radiations is doubled,
what is the maximum kinetic energy of the photoelectrons?
(1) 2E
(2) E/2
(3) E + hv
(4) E hv
[X]
E = hv E => energy of photon
hv = hv0 + (K.E.)max
hv0 => work function of Metal
(K.E.)max => Maximum K.E. of ejected electron.
hv = hv0 + E
when v is doubled
2 hv = hv0 + E'
E' => maximum K.E. of photon electron at frequency 2v.
hv = hv0 + E
2 hv = hv0 + E'
E' = 2 hv hv0
(work function of metal (hv0) will be same)

= 2 hv (hv E)
= E + hv
Q No: 6
The speed of an electron in the third orbit of hydrogen atom
(1) 7.28 107 cm sec1
(2) 7.08 107 cm sec1
(3) 7.38 107cm sec1
(4) 7.48 107 cm sec1
[X]
Q No: 7
If x is the velocity of an electron in first Bohrs orbit, what would be the velocity of the
electron in third Bohrs orbit
(1) x/9
(2) x/3
(3) 3x
(4) 9x
[X]
Q No: 8
Ratio of time period of electron in first and second orbit of H-atom would be
(1) 1 : 18
(2) 1 : 8
(3) 1 : 2
(4) 2 : 1
[X]
Q No: 9
For ionising an excited hydrogen atom, the energy required in eV will be
(1) 3.4 or less
(2) More than 13.6
(3) Little less than 13.6
(4) 13.6
[X]
Total energy of electron in nth orbit.
For Ionising excited Hydrogen atom
energy required = E En (n 1)
Q No: 10
Wave number of a spectral line for a given transition is x cm1 for He+, then its value for
Be3+ for the same transition is
(1) 4x cm1
(2) x cm1
(3) x/4 cm1
(4) 2x cm1
[X]
Q No: 11
What is the change in the orbit radius when the electron in the hydrogen atom (Bohr
model) undergoes the first Paschen transition ?
(1) 4.23 1010 m
(2) 0.35 1010 m
(3) 3.7 1010 m
(4) 1.587 1010 m
[X]
For first paschen transition
n1 = 3
n2 = 4
Radius of nth orbit in hydrogen = 0.529 n2
Change in orbit radius = r4 r3
Change in orbit radius = [0.529 (4)2] [0.529 (3)2]
= 3.7 = 3.7 1010 m
Q No: 12
What is the de-broglie wavelength associated with the hydrogen electron in its third orbit
?
(1) 9.96 1010 cm
(2) 9.96 108 cm
(3) 9.96 104 cm
(4) 9.96 108 cm
[X]
Q No: 13
d6 configuration will result in total spin of
(1) 3/2
(2) 1/2
(3) 2
(4) 1
[X]
Total number of unpaired electrons with parallel spin = 4
Q No: 14
If the values of (n + l) is not > 3, then the maximum number of electrons in all the
orbitals would be :
(1) 12
(2) 10
(3) 2
(4) 6
[X]
If (n + l) = 1 , orbital possible
Maximum number of electron
12
is 1 s
is 2 s
is 2p, 3s
in all the orbitals (1s, 2s, 2p, 3s) = 2 + 2 + 6 + 2 =
Q No: 15
The number of electrons in Na, having n + = 3
(1) 4
(2) 6
(3) 7
(4) 8
[X]
Atomic number of Na = 11
If n + l = 3 then n = 2, l = 1 or n = 3, l = 0 (as l n)
Configuration of Na => 1s2 2s2 2p6 3s1
Number of electrons having n = 2, l = 1 (2p) and n = 3, l = 0 (3s) => 7
Q No: 16
The mass number of dispositive Zn ion is 70. The total number of neutrons is
(1) 34
(2) 40
(3) 36
(4) 38
[X]
Atomic number of Zn = 30
During formation of ion, electrons are gained or lost, so no change in the
number of proton or neutrons.
Number of neutrons = Mass number Atomic number
Number of neutrons = 71 30 = 40
Q No: 17
As the orbit number increases, the distance between two consecutive orbit (r 1 = radius of
first orbit)
(1) increases by 2r1
(2) increases by (2n 1)r1, where n is lower orbit number
(3) increases by (2n 1)r1, where n is higher orbit number
(4) remain constant
[X]
Atomic number of Zn = 30
During formation of ion, electrons are gained or lost, so no change in the
number of proton or neutrons.
Number of neutrons = Mass number Atomic number
Number of neutrons = 71 30 = 40
Q No: 18
How many lines in the spectrum will be observed when electrons return from 7th shell to
2nd shell?
(1) 13
(2) 14
(3) 15
(4) 16
[X]
Total number of lines = Total number of different wavelengths emitted
Total number of lines = (n2 n1)
where n2 => higher orbit number
n1 => lower orbit number
Q No: 19
Number of possible spectral lines which may be emitted in bracket series in H atom, if
electron present in 9th excited level returns to ground level, are
(1) 21
(2) 6
(3) 45
(4) 5
[X]
Any line in bracket series is emitted when electron jumps from any higher level
to n = 4.
9th excited state => 10th orbit
Electron is returning from n = 10 to n = 1.
number of possible spectral lines in Brackett series = 6.
Q No: 20
If Hund's rule is followed, magnetic moment of Fe2+, Mn+ and Cr, all having 24
electrons, will be in order
(1) Fe2+ < Mn+ < Cr
(2) Fe2+ < Cr = Mn+
(3) Fe2+ = Mn+ < Cr
(4) Mn2+ = Cr < Fe2+
[X]
Atomic number of Cr = 24
Atomic number of Mn = 25
Atomic number of Re = 26
3d5 4s1
3d5 4s2
3d6 4s2
Outermost configuration of Cr => 3d5 4s1

number of unpaired electron = 6
Outermost configuration of Mn+ => 3d5 4s1
Outermost configuration of Fe +2 => 3d6
Order of magnetic moment = order of number on unpaired electrons.
Level 2
Q No: 1
Electromagnetic radiations having = 310 are subjected to a metal sheet having
work function = 12.8 eV. What will be the velocity of photoelectrons with maximum
Kinetic Energy ?
(1) 0, no emission will occur
(2) 2.18 106 m/s
(3) 2.18 106 m/s
(4) 8.72 106 m/s
[X]
Q No: 2
Light of wavelength strikes a metal surface with intensity X and metal emits Y
electrons per second of average energy Z. What will happen to Y and Z if X is halved ?
(1) Y will be halved and Z will be doubled
(2) Y will be doubled and Z will be halved
(3) Y will be halved and Z will remain the same
(4) Y will remain same and Z will be halved
[X]
(K.E.)max = hv hv0
where (K.E.)max => maximum K.E. of electron emitted
hv => energy of incident photon
hv0 => work function of metal
K.E. depends on frequency (or wavelength), not on intensity.
No. of electron emitted per second depends on intensity of incident radiation (not
on frequency or wavelength)
As intensity is halved ( is same)
Z (average energy) will remain same.
Y (electrons emitted will be halved per second)
Q No: 3
Photo electric emission is observed from a surface for frequencies 1 and 2 of the
incident radiation (1 > 2) if maximum kinetic energies of the photo electrons in the two
cases are in the radio 1 : K, then the threshold frequency is given by :
(1)
(2)
(3)
(4)
Correct Answer: 2
Status: unattempted
[X]
For photo electric effect
hv = hv0 + (K.E.)max
hv0 => work function
hv => energy of incident photon.
When frequency is v1, (K.E.)max = x (let)
When frequency is v2, (K.E.)max = kx
(as the ratio is 1 : k)
hv1 = hv0 + x
hv2 = hv0 + kx
... (i)
... (ii)
Substituting x from equation (i) to equation (ii)

hv2 = hv0 + k (hv1 hv0)
hv2 khv1 = hv0 khv0
v0(1 k) = v2 kv1
Q No: 4
If the I.P. of Li+2 is 122.4 eV. Find out 6th I.P. of carbon
(1) 122.4 4eV
(2) 122.4 2eV
(3) 122.4 3eV
(4) 122.4 5eV
[X]
I.P. of one electronic species (the amount of energy required to remove the
electron)
= E E1 (as E = 0)
= E1 (E1 is the energy of electron in 1st orbit)
I.P. of one electronic species = E1 =
eV = 13.6 x2 eV
For Li+2 z = 3
For C+5 z = 6
6th I.P. of C = I.P of C+5
For C+5 = 4 122.4 eV
No: 5
If energy difference between the states n = 2 and n = 3 is E eV, in hydrogen atom. The
ionisation potential of H atom is
(1) 3.2 E
(2) 5.6 E
(3) 7.2 E
(4) 13.2 E
[X]
I.P. (of one electronic species) = E E1 = E1
Q No: 6
To ionize an hydrogen atom from its first orbit, 100 unit energy is required. Energy
required to remove an electron from second orbit upto infinite will be
(1) 50 units
(2) 100 units
(3) 25 units
(4) Zero
Correct Answer: 3
Status: unattempted
[X]
Energy required to remove an electron from second orbit = E E2 = E2
Q No: 7
Which of the expression show the kinetic energy of nth Bohr electron ?
(1)
(2)
(3)
(4)
Correct Answer: 1
Status: unattempted
[X]
Q No: 8
The ratio of potential energy of electron in the 3 rd orbit of Li2+ ion to the Kinetic energy
of electron in the 4th orbit of He+ ion should be
(1) 8 : 1
(2) (8) : 1
(3) (16 : 1)
(4) None of these
[X]
total energy of electron in nth orbit
Q No: 9
Rydberg given the equation for all visible radiation in the hydrogen spectrum as
. The value of k in terms of Rydberg constant is
(1) 4R
(2) R/4
(3) 4/R
(4) R
[X]
Q No: 10
A photon was absorbed by a hydrogen atom in its ground state and the electron was
promoted to the fifth orbit. When the excited atom returned to its ground state, visible
and other quanta were emitted. Other quanta are
(1) 2 1
(2) 5 2
(3) 3 1
(4) 4 1
[X]
The transition of electron from n = 5 to n = 1.
Any quantum in visible region is emitted when electron jumps from any higher
level to n = 2.
Since visible and other quanta are emitted i.e., one transmission is n = 5 to n =
2.
During n = 5 to n = 1
If one transition is 5 2
other will be 2 1
Q No: 11
The value of (n2 + n1) and

for He+ ion in atomic spectrum are 4 and 8
respectively. The wavelength of emitted photon when electron jump from n2 to n1 is
(1)
(2)
(3)
(4)
Correct Answer: 3
Status: unattempted
[X]
n2 + n 1 = 4
n1 n2 (if n1 = n2 no photon will be emitted during n 2 n1)
n22 n11 = 8 (given)
By observation
n1 = 1
n2 = 3
Q No: 12
If an atom of hydrogen is excited by 8.4eV then the number of emitted spectrum lines
will be
(1) 4
(2) 2
(3) 3
(4) None of these
[X]
total energy of electron in nth orbit.

Minimum energy required for excitation => E 2 E1
Since the atom is excited by 8.4 eV which is less than the minimum energy
required for excitation
=> excitation will not take place i.e., no spectral line will be emitted.
Q No: 13
If there are six energy levels in Hatom, then the number of lines its emission spectrum
in ultra violet region will be
(1) 6
(2) 5
(3) 4
(4) 3
[X]
Different line is spectrum are obtained in emission spectrum due to emission of
radiations different wavelengths.
Ultra-violet regions means Lyman series.
Any line in UV region will be formed when electron jumps from any higher level
to n = 1.
Hence 5 lines will be there in UV region.
Q No: 14
Check the correctness of the statements about the Bohr model of hydrogen atom
(i) The acceleration of the electron in the n = 2 orbit is more than that in the n = 1 orbit
(ii) The angular momentum of the electron in the n = 2 orbit is more than that in the n =
1 orbit
(iii) The kinetic energy of electron in the n = 2 orbit is less than in the n = 1 orbit. Mark
(1) if all the statements are correct
(2) if only (i) and (ii) are correct
(3) if only (ii) and (iii) are correct
(4) if only (i) and (iii) are correct
[X]
While revolving in a particular Bohr's orbit electron moves with a constant speed.
Angular momentum of electron in nth orbit (mvr) =
Kinetic energy of electron in nth orbit = 13.6
As n increases, angular momentum increases.
eV
as n increases, K.E. decreases

Hence only (ii) and (iii) are correct.
Q No: 15
An electron, a proton and an alpha particle have kinetic energies of 16E, 4E and E
respectively. What is the qualitative order of their de Broglie wavelengths?
(1) e > p =
(2) p = > e
(3) p > e >
(4) < e p
[X]
m > mp > me
m = 4mp >>> me
Q No: 16
Uncertainty in position and momentum are equal. Uncertainty in velocity is
(1)
(2)
(3) Both
(4)
Correct Answer: 4
Status: unattempted
[X]
Q No: 17
If elements with principal quantum number n > 4 is not allowed in nature, the number of
possible elements would be
(1) 60
(2) 32
(3) 64
(4) 50
[X]
Q No: 18
Two Particles A and B are in motion. Wave length related to A is 5.0 10 8 m. If the
momentum of B is Half of A, then what will be the wavelength of B
(1) 2.5 108 m
(2) 1.25 108 m
(3) 1.0 107 m
(4) 1.0 108 m
[X]
Q No: 19
Magnetic moment of X3+ ion of 3d series is

BM. What is atomic number of X3+ ?
(1) 25
(2) 26
(3) 27
(4) 28
[X]
Since number of outer electrons of x+3 = 5

hence number of outer electrons in x = 8
The element X must have 8 outer electrons i.e., its outermost configuration
should be 3d64s2 which is Fe, atomic number 26.
Q No: 20
The energy required to break one mole of ClCl bonds in Cl 2 is 242 kJ mol 1. The
longest wavelength of light capable of breaking a single ClCl

(1) 594 nm
(2) 640 nm
(3) 700 nm
(4) 494 nm
Level 3
Q No: 1
What transition in the hydrogen spectrum would have the same wavelength as the
Balmer transition, n = 4 to n = 2 of He+ spectrum.
(1) n1 = 1, n2 = 2
(2) n1 = 2, n2 = 1
(3) n2 = 1, n1 = 2
(4) n1 = 3, n2 = 5
[X]
Energy of photon should be same in both cases
Now manipulate for EH = EHe+
Q No: 2
The shortest wavelength of He atom in Balmer series is x, then longest wavelength in the
Paschene series of Li+2 is
(1)
(2)
(3)
(4)
Correct Answer: 2
Status: unattempted
[X]
Shortest wavelength of Balmer series.

Energy should be maximum for shortest & vice versa.
Q No: 3
Given H for the process Li(g) Li +3(g) + 3e is 19800 kJ/mole and IE1 for Li is 520
then IE2 and IE3 of Li+ are respectively (approx, value)
(1) 7505, 11775
(2) 520, 19280
(3) 11775, 19280
(4) Data insufficient
[X]
Check the given data IE1 = 520 and IE1 + IE2 + IE3 = 19800
Use IE3 > IE2 > IE1
After emission of 2e Li2+ becomes H+ like species.
So IE3 can be calculated from here.
Q No: 4
Three energy levels P, Q, R of a certain atom are such that E P < EQ < ER. If 1, 2 and 3
are the wave length of radiation corresponding to transition R Q ; Q P and R P
respectively. The correct relationship between 1, 2 and 3 is
(1) 1 + 2 = 3
(2)
(3)
(4)
Correct Answer: 2
Status: unattempted
[X]
Draw energy diagram
Use E3 = E1 + E2 from above diagram.
Q No: 5
The value of (n2 + n1) and

for He+ ion in atomic spectrum are 4 and 8
respectively. The wavelength of emitted photon when electron jump from n2 to n1 is
(1)
(2)
(3)
(4)
Correct Answer: 3
Status: unattempted
[X]
Q No: 6
Number of possible spectral lines which may be emitted in bracket series in H atom, if
electrons present in 9th excited level returns to ground level, are
(1) 21
(2) 6
(3) 45
(4) 5
[X]
Q No: 7
The longest wavelength of He+ in Paschen series is "m", then shortest wavelength of Be +3
in Paschen series is (in terms of m) :
(1)
(2)
(3)
(4)
Correct Answer: 4
Status: unattempted
[X]
Longest wavelength means minimum energy & vice versa.
For He+
Divide (1) by (2)
Q No: 8
Electromagnetic radiations having = 310 are subjected to a metal sheet having

work function = 12.8 eV. What will be the velocity of photoelectrons with maximum
Kinetic Energy.
(1) 0, no emission will occur
(2) 2.18 106 m/s
(3) 2.18 106 m/s
(4) 8.72 106 m/s
[X]
Energy of incident photon E =
KEmax = Eincident
Use KEmax = mv2
No: 9
Choose the correct statement among the following
(1) Radial distribution function (24r2 dr) give probability at a particular distance
along one chosen direction
(2) 2(r) give probability density at a particular distance over a spherical surface
(3) For 's' orbitals (r) () () = (x, y, z) is independent of and
(4) '2p' orbital with quantum numbers. n = 2, = 1, m = 0, also shows angular
dependence
Correct Answer: 3,4 Status: unattempted
2 represent probability density at a point while 2 4r2 dr represents over a

surface.
Wave function for s is independent of and
2p orbital shows angular dependency.
Q No: 10
Correct statement(s) regarding 3Py orbital is/are
(1) Angular part of wave function is independent of angles ( and )
(2) No. of maxima when a curve is plotted between 4r2R2(r) vs r are '2'
(3) 'xz' plane acts as nodal plane
(4) Magnetic quantum number must be '1'
[X]
Correct Answer: 2,3
Status: unattempted
[X]
For 3Py angular wave function depend on and .

On 4r2 R2(r) Vs r for 3Py two maximum will appear.
For Py xz plane is nodal plane.
11. Select the correct curve(s) :

If v = velocity of electron in Bohr's orbit
r = Radius of electron in Bohr's orbit
P.E. = Potential energy of electron in Bohr's orbit
K.E. = Kinetic energy of electron in Bohr's orbit.
1
)
2
)
3
)
4
)
[X]
Q No: 12
Which is / are correct statement.
(1) The difference in angular momentum associated with the electron present in
consecutive orbits of H-atom is (n 1)
(2) Energy difference between energy levels will be changed if, P.E. at infinity assigned
value other than zero
(3) Frequency of spectral line in a H-atom is in the order of (2 1) < (3 1) < (4 1)
(4) On moving away from the nucleus, kinetic energy of electron decreases
Correct Answer: 3,4 Status: unattempted
[X]
From radial function determine number of radial node.
R(r) = K1 (polynomial)n11
1 = 0, n 1 1 = 2
n=2
[X]
As value of n increases energy difference decreases.
Q No: 13
It is a data sufficiency problem in which it is to be decided on the basis of given
statements whether the given question can be answered or not. No matter whether the
answer
is
yes
or
no.
Question
:
Is
the
orbital
of
hydrogen
atom
3p x?
Statement-1 : The radial function of the orbital is R(r) =
Statement-2 : The orbital has 1 radial node and 0 angular node.
(1) Statement (1) alone is sufficient.
(2) Statement (2) alone is sufficient.
(3) Both together is sufficient.
(4) Neither is sufficient.
[X]
1 = 0, n 1 1 = 2
n=2
Q No: 14
Column I and column II contain data on Schrondinger Wave Mechanical model, where
symbols have their usual meanings.Match the columns.
Column I
Column II
P 4S
Q 5px
C (, ) = K (independent of and )
D atleast one angular node is present
R 3s
S 6dxy
(1) A-P
(2) A-Q
(3) A-R
(4) A-S
(5) B-P
(6) B-Q
(7) B-R
(8) B-S
(9) C-P
(10) C-Q
(11) C-R
(12) C-S
(13) D-P
(14) D-Q
(15) D-R
(16) D-S
Correct Answer: 1,5,6,8,9,11,14,16
Status: unattempted
[X]
1 = 0, n 1 1 = 2
n=2
Q No: 15
The French physicist Louis de Broglie in 1924 postulated that matter, like radiation,
should exhibit a dual behaviour. He proposed the following relationship between the
wavelength of a material particle, its linear momentum p and planck constant h.
The de Broglie relation implies that the wavelength of a particle should decreases as its
velocity increases. It also implies that for a given velocity heavier particles should have
shorter wavelength than lighter particles. The waves associated with particles in motion
are called matter waves or de Broglie waves. These waves differ from the
electromagnetic
waves
as
they
(i)
have
lower
velocities
(ii)
have
no
electrical
and
magnetic
fields
and
(iii)
are
not
emitted
by
the
particle
under
consideration.
The experimental confirmation of the de Broglie relation was obtained when Davisson
and Germer, in 1927, observed that a beam of electrons is diffracted by a nickel crystal.
As diffraction is a characteristic property of waves, hence the beam of electron behaves
as
a
wave,
as
proposed
by
de
Broglie.
Werner Heisenberg considered the limits of how precisely we can measure properties of
an electron or other microscopic particle like electron. He determined that there is a
fundamental limit of how closely we can measure both position and momentum. The
more accurately we measure the momentum of a particle, the less accurately we can
determine its position. The converse is also true. This is summed up in what we now call
the "Heisenberg uncertainty principle: It is impossible to determine simultaneously and
precisely both the momentum and position of a particle. The product of uncertainty in
the position, x and the uncertainty in the momentum (mv) must be greater than or
equal to
.i.e.
The correct order of wavelength of Hydrogen ( 1H1), Deuterium (1H2) and Tritium (1H3)
moving with same kinetic energy is
(1) H > D > T
(2) H = D = T
(3) H < D < T
(4) H < D > T
[X]
mT > mD > MH
H > D > T
Q No: 16
electromagnetic
waves
as
they
(i)
have
lower
velocities
(ii)
have
no
electrical
and
magnetic
fields
and
(iii)
are
not
emitted
by
the
particle
under
consideration.
as
a
wave,
as
proposed
by
de
Broglie.
equal to
.i.e.
The transition, so that the de-Broglie wavelength of electron becomes 3 times of its
initial value in He+ ion will be
(1) 2 5
(2) 3 2
(3) 2 6
(4) 1 2
[X]
Q No: 17
electromagnetic
waves
as
they
(i)
have
lower
velocities
(ii)
have
no
electrical
and
magnetic
fields
and
(iii)
are
not
emitted
by
the
particle
under
consideration.
as
a
wave,
as
proposed
by
de
Broglie.
equal to
.i.e.
If the uncertainty in velocity and position is same, then the uncertainty in momentum
will be
(1)
(2)
(3)
(4)
Correct Answer: 1
Status: unattempted
[X]
Q No: 18
The only electron in the hydrogen atom resides under ordinary conditions on the first
orbit. When energy is supplied, the electron moves to higher energy orbit depending on
the amount of energy absorbed. When this electron returns to any of the lower orbits, it
emits energy. Lyman series is formed when the electron returns to the lowest orbit while
Balmer series is formed when the electron returns to second orbit. Similarly, Paschen,
Brackett and Pfund series are formed when electron returns to the third, fourth and fifth
orbits
from
higher
energy
orbits
respectively.
Maximum number of lines produced when an electron jumps from nth level to ground
level is equal to
. For example, in the case of n = 4, number of lines produced is
6. (4 3, 4 2, 4 1, 3 2, 3 1, 2 1). When an electron returns from n 2 to n1
state, the number of lines in the spectrum will be equal to
.
If the electron comes back from energy level having energy E 2 to energy level having
energy E1, then the difference may be expressed in terms of energy of photon as :
Since h and c are constants, E corresponds to definite energy; thus each transition from
one energy level to another will produce a light of definite wavelength. This is actually
observed
as
a
line
in
the
spectrum
of
hydrogen
atom.
Wave number of line is given by the formula

.
where R is a Rydberg's constant (R = 1.1 107 m1)
The energy photon emitted corresponding to transition n = 3 to n = 1 is [h = 6 1034 Jsec.]
(1) 1.76 1018 J
(2) 1.98 1018 J
(3) 1.76 1017 J
(4) None of these
[X]
E = 6 1034 3 108 1.1 107
Q No: 19
orbits
from
higher
energy
orbits
respectively.
level is equal to
.
observed
as
a
line
in
the
spectrum
of
hydrogen
atom.
.
7
1
where R is a Rydberg's constant (R = 1.1 10 m )
In a collection of H-atom, electrons make transition from 5 th excited state to 2nd excited
state then maximum number of different types of photons observed are

(1) 3
(2) 4
(3) 6
(4) 15
[X]
NA
Q No: 20
orbits
from
higher
energy
orbits
respectively.
level is equal to
.
observed
as
a
line
in
the
spectrum
of
hydrogen
atom.
.
The difference in the wavelength of the 1st line of Lyman series and 2nd line of Balmer
series in a hydrogen atom is
(1)
(2)
(3)
(4) None
Correct Answer: 2
Status: unattempted
[X]
Q No: 21
orbits
from
higher
energy
orbits
respectively.
level is equal to
.
observed
as
a
line
in
the
spectrum
of
hydrogen
atom.
Wave
number
of
line
is
given
by
the
formula

The wave number of electromagnetic radiation emitted during the transition of electron
in between two levels of Li2+ ion whose principal quantum numbers sum is 4 and
difference is 2 is
(1) 3.5 R
(2) 4 R
(3) 8 R
(4) (8/9) R
[X]

Atomic Structure

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Atomic Structure

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Level 1

Mass of particle 4 mass of proton

Distance of closest approach (rmin) is calculated by

Total energy released = nhv

n => Number of photons

(work function of metal (hv0) will be same)

Total number of unpaired electrons with parallel spin = 4

number of possible spectral lines in Brackett series = 6.

Outermost configuration of Cr => 3d5 4s1

Substituting x from equation (i) to equation (ii)

I.P. of one electronic species = E1 =

For C+5 = 4 122.4 eV

I.P. (of one electronic species) = E E1 = E1

Energy required to remove an electron from second orbit = E E2 = E2

total energy of electron in nth orbit

The value of (n2 + n1) and

total energy of electron in nth orbit.

Hence 5 lines will be there in UV region.

as n increases, K.E. decreases

Magnetic moment of X3+ ion of 3d series is

Since number of outer electrons of x+3 = 5

longest wavelength of light capable of breaking a single ClCl

Now manipulate for EH = EHe+

Shortest wavelength of Balmer series.

Draw energy diagram

Use E3 = E1 + E2 from above diagram.

The value of (n2 + n1) and

Longest wavelength means minimum energy & vice versa.

Divide (1) by (2)

Electromagnetic radiations having = 310 are subjected to a metal sheet having

2 represent probability density at a point while 2 4r2 dr represents over a

Correct Answer: 2,3

For 3Py angular wave function depend on and .

11. Select the correct curve(s) :

As value of n increases energy difference decreases.

Wave number of line is given by the formula

E = 6 1034 3 108 1.1 107

state then maximum number of different types of photons observed are

where R is a Rydberg's constant (R = 1.1 107 m1)

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