Professional Documents
Culture Documents
General Considerations
* Chemical oxidizing agents have long been used to measure the oxygen
demand of sewage and polluted waters.
* Potassium permanganate were used for many years, and the results were
referred to as oxygen consumed from Potassium Permanganate.
* Oxidation by potassium permanganate was highly variable due to strength
of oxidant and with respect too various types of compounds.
* Oxygen consumed values were always less than the 5-day BOD because
of the inability of permanganate to carry the oxidation to particular endpoint
* Potassium dichromate is the most practical oxidizing agent with a silver ion
catalyst in an acid state and refluxed at high temperatures to completely
oxidize organics to carbon dioxide and water.
Calculations
Alternate Procedures: COD test is precise and accurate for samples with
A COD of 50 mg/L or greater. It is important in any modification that the
Volume of sample plus dichromate solution be maintained at 1:1 ratio.
If it is smaller, the oxidizing power of the solution will decrease, while
If it is larger, the blank consumption of dichromate becomes excessive
Inorganic Interferences