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Abstract. In the extraction of coal underground, the incubation period is customarily used as a tool, for deciding the size of an underground coal mine panel, so that
coal therein can be extracted within this period without any sign or symptoms of
spontaneous heating. Nevertheless, in compatible geomining conditions, spontaneous
combustion occurs frequently within the proclaimed incubation period of the mine
panel; resulting huge quantities of coal being left un-extracted due to premature
sealing. The aim of the present study is, thereforeto develop and test methods and
technologies for uprising the incubation period of spontaneous combustion of coal in
an underground mine panel. The methods comprise the development of objective
models (equations) for the assessment and evaluation of causative factors playing
signicant roles in abrupt change of incubation period; the rise of temperature due
to, increased rate of oxidation, fragmentation, impact and friction after commencing
of the roof fall; and propagation of re into the interconnected workings. The technologies comprise the development and application of water fog, chemical fog, gel
fog and inert gel fog at various Indian mines, and other methodologies.
Keywords: spontaneous re, incubation period, intervening strata, re spread, chemical fog
1. Introduction
Board and Pillar mining method, in various forms has dominantly (80%) being
practiced in India. In this method, huge quantity of coal (2045%) remains in
the depillared panels as stook, loose coal at the oor, hard coal as intricate part
of the seam either in oor or roof, and beset the problems of spontaneous heating. In fact, while depillaring (with caving) in thick and multi seam, overlaying
strata collapses; naturallydue to geological disturbances, gravitational force,
front abatement pressure, weak or disturb strata behavior and bad roof conditions, and compellinglyin order to avoid the air blast in due course.
When strata collapses, the gravitational potential energy of the falling mass
changes into heat energy by the time collapsed mass subsided through the surface.
* Correspondence should be addressed to: D. D. Tripathi, E-mail: tripathidd@yahoo.com
186
187
Ec is environmental factor. Equation (3) has been solved numerically for finding the
time interval in which spontaneous combustion to be setup, which helps to determine
the fire risk potential of the mine panel.
2.1.2. During Strata Collapses in the Sealed Off Panel. If, roof fall occurs in the
sealed o panel, air below the falling block will be compressed rapidly; resulting,
rise in coal temperature at vulnerable site. However, in reality air below the falling
block never connes in the sealed o panel due to invariant connections of upper
seams and adjacent goal, mostly during extraction of developed pillars. For this
reason, the falling block experiences some degree of air resistance and must be
damped. The equation describing the motion is modeled as follows[5],
Mass acceleration = force on the falling block ) damping force
M du=dt M g P0 P A DF u
DF 1:80 5:105 As 2:0=Z0 ; As ; surface area
188
In the early stage of oxidative heating, heat transfer from source to the
surroundings occurs extremely slowly, therefore system is considered near
adiabatic i.e.,
PV k C;
T T0 fP =P0 g
5
k1=k
The Equations (6) and (8) has been solved numerically; to evaluate the role of
falling height, falling velocity, pressure and temperature, in facilitating coal to re
spontaneously within a sealed o mine panel with respect to time [6].
189
10
11
12
where scripts 1,2,3, ... i are the boundary element of the strata.
Total heat absorbed per unit area by its constituent boundaries is
1=kqc1=2
q dt
13
190
Table l
Materials
Thermal conductivity
Bthu/h/sq./0c/ft
Materials
Thermal conductivity
Bthu/h/sq./0c/ft
0.24
0.18
1.11
0.11
Sand stone
Sand (granular)
Lime stone
Soil dry
1.16
0.13
2.10
0.14
Coal (solid)
Coal (granular)
Shale (solid)
Shale (granular)
191
2. Chemical Fog
i. Recent tests have shown that mixing of endothermic and re retardant chemicals in water can signicantly improved the eectiveness of water in suppressing
and ghting res by rapid cooling, retarding surface oxidations and minimizing
the possibilities of re-ignition. Chemical fog can be sprayed easily at desired
places i.e., overlying goaf, cavity of the two stone pieces and unapproachable
area where heating may apprehend form a long distance 2530 m.
ii. In the selection of chemicals, many aspects have been considered i.e., cooling
eciency, long and short term eectiveness, eectiveness in various fuel conditions (i.e., coal left in top or bottom section, developed or depillared panels),
problem of corrosion, abrasion, toxicity, cost eectiveness, easy mixing, pumping and storing. Generally, boric acid, sodium chloride, calcium chloride,
di-ammonium phosphate, sodium silicate, limes and dolomite powder (90%
purity) are used in underground mines.
iii. Of note is that in laboratory experiment, the % evaluation of carbon
monoxide (CO) was reduced from 0.33% to 0.16%, when mixed with sodium
silicate solution (2% W/W).
3. Gel Fog
i. The techniques of spraying gel solution (water thickened with sodium silicate
(Na2SiO2) and diammonium phosphate (Nitrogen (N2) 21%; phosphate (P2O5)
53%) proved very use full for preventing self-heating of coal and control of
advancing res; by both, defensive or oensive way. Gel fog has been prepared,
by admixing 10% sol, w/v of sodium silicate and diammonium phosphate in
4:1 ratio. The combination has the desired setting time of 45 min (pH 9), to
avoid the solidication of gel during the operation. The setting time of gel can
be change by changing the compositions.
ii. Gel fog, holds large quantity of water and had proved eective inhibitor
of coal oxidation reactions 150C. Viscous DAP is not toxic, it tends to
give o ammonia when applied to re and stung to eye but not a serious
problem.
iii. In laboratory test, gel formed would initially increase in volume (6% of its
original volume) but shrinks afterwards if left exposed in ambient temperature
for more than 1 week. Coating of gel on coal surfaces would not crack even
with rise in temperature up to around 70C, but may develop hairlines cracks
on prolonged heating above 100C.
iv. In developed, depillaring or depillared panels, gel solution when infused at
high pressure (57 Kg/cm2) by means of fog ghter, forms an impervious coating on coal surfaces/broken coal mass. The coating of gel lasted for at least
1215 months, hence, found suitable for increasing the incubation periods of
spontaneous combustion of coal in mine panel. In all tests, gel fog produced a
somewhat smaller and denser pattern than water fog or chemical fog; hence all
the vulnerable sites can be covered easily.
192
Incline
mine
of
Singareny
193
parting of 37 m [10]. Overlaying III seam was depillared in past, with poor
recovery (40%) in two slices, 2.75 m in top by conventional method and 4.5 m in
bottom by LHDs (Figure 1). During extraction of developed pillars in underlying
IV seam, spontaneous heating occurs frequently after the roof fall within the
proclaimed incubation period. In panel 6F(ii)a, increasing trends of CO were
194
Table 2
Mining Details of Some Panels Under Fire in IV Seam of GDK-9 Incline Mine, Ramagundem area-II, SCCL
S. No.
7F(I)B
14L(ii)
4(ii)
5(ii)
2A
20F(I)
6F(II)a
3.63.9
98 /107
1:5
BC
III Goaf
30.6.96
18.6.97
28.8.96
1820
1.82
0.63
18
26
70
1.10
6.2
9M-20d
5130
18.6.97
3.63.9
78/100
1:5
BC
III Goaf
24.9.94
27.4.95
9.12.94
2050
2.05
0.57
18
20
70
1.20
6.4
4M-12D
11,700
24.4.95
3.6
63/78
1:5
BC
III Goaf
27.1.88
31.8.88
20.9.88
1050
2.32
1.04
18
36
70
1.10
7.3
4M-8D
9000
1.9.88
3.6
66/77
1:5
BC
III Goaf
15.2.89
9.10.. 89
25.8.89
4320
3.20
0.82
18
30
70
0.8
8.0
2Y-4.5M
13,000
7.12.91
3.6
42/59
1:5
BC
III Goaf
27.5.85
12.3.86
1.10.85
5890
5.89
0.92
18
34
70
4.54
4.8
5M-18D
8670
27.3 86
3.6
62/82
1:5
BC
III Goaf
11.9.83
9.9.84
15.12.83
4202
1.23
1.15
18
47
70
3.53
8.2
7Y-10M
9812
18.10.91
4.46
122/135
1:5
B
III Goaf
11.12.97
26.5.98
10.2.98
844
13.3.98
0.844
0.70
18
16
81
Nil
5.2
3M-15-D
10,770
25.5.91
3.6
166/183
1:5
D
III Goaf
23.3.98
31.7.98
28.6.98
1620
30.6.98
1.620
1.0
18
24
75
Nil
5.4
14,710
29.7.98
1.
2.
3.
4.
5.
6.
7.
8.
9.
10.
11.
12.
13.
14.
15.
16.
17.
18.
19.
20.
Panel details
195
196
Coal Characteristics, DSC Thermo Gram, Calorific Value, CPT and IPT
Value of Coal Samples Collected from IV-A Seam of Rajnagar RO
Colliery SECL
Proximate
analysis %
Moisture
VM
Ash
FC
Distribution of
sulphur %
5.32
34.22
13.51
46.95
Pyretic
Sulphate
Organic
0.11
0.14
0.09
56.67C
85.19C
)86.55 Jg)1
Crossing/
ignition
point
temperature
in C
CPT
IPT
144
162
Caloric value
Kcal/Kg
6520
197
Figure 4. Depicting the CPT and IPT value of coal samples collected
from the running panel/IV-A seam of Rajnagar R.O. Colliery SECL.
normalized value )86.55 Jg)1, indicate least heat absorbing capacity of coal. Also,
onset value 56.67C and peak value 85.19C indicates presence of moisture in coal
matrix. In view of that, coal is least susceptible to spontaneous heating.
198
The extrinsic mining parameters are also not much favorable to initiate the
spontaneous heating or re. In conclusion, only instantaneous conditions like
sluggish ventilation, crushing of coal; rapid oxidation due to heavy roof fall initiates the spontaneous heating impulsively and unpredictably. Therefore, it has been
recommended that water fog should be infused periodically after the roof falls in
the depillaring panels.
Acknowledgments
Author is thankful to the referee for his pain taking eorts in reviewing the manuscript and director CMRI for his kind permission to publish the paper. The members of Mine Fire Laboratory are appreciated for their co-operations.
References
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IBH, Rotterdam
2. D.D. Tripathi and S.K. Sen, Prediction of Fire StatusA New Approach to an Old
Problem, Coal International, 1996, p. 118
3. A.J. Pickention, Heat Sources Evaluation Determination of Heat Stress and Heat
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4. J.B. Stott, Thesis in the University of Canterbury, 1971
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International Mine Ventilation. Congress Reno, Nevada, 1980
6. McPherson M.J. (1995) The Adiabatic Compression of Air by Large Fall of Roof SME
7th US Symposium on Mine Ventilation, Lexington, Kentucky
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Impacts, John Wiley and Sons, New York
8. Carslaw H.S., Jaeger J.C. (1959) Conduction of Heat in Solid; Second edition, Oxford
University press, London
9. Y. Miron, Gel Sealant for Mitigation of Spontaneous Heating in Coalmines. USBM,
RI-9585, 1995
10. Design of Economic Methods for Fire Safe Extraction of Coal Pillars at GDK-9 Incline
Mine of SCCL & Advice There O; Central Mining Research Institute Project Report
No. MS/GC/68/9899, 1999
11. Studying the incubation period of IV-A seam of Rajnagar R.O. Colliery of Hasdeo
Area SECL and advice thereof; Central Mining Research Institute- Project Report,
GC/MS/87/02-03, 2003