SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 1.4 Revision Date: 12/31/2015 Print Date: 05/02/2016 ‘SECTION 1. IDENTIFICATION Product name : AeroShell Oil Diesel Ultra Product code 00107346 Manufacturer or supplier's details Manufacturer/Supplior ‘Shell Oil Products US PO Box 4427 Houston TX. 77210-4427 usa SDS Request (1) 877-276-7285 Customer Service Emergency telephone number Spill Information 877-504-9351 Health Information 877-242-7400 Recommended use of the chemical and restrictions on use Recommended use ‘Synthetic lubricating oil for aircraft diesel engines., For further details consult the AeroShell Book on www.shell.com/aviation, Restrictions on use ‘This product must be used, handled and applied in accord- ance with the requirements of the equipment manufacturer's ‘manuals, bulletins and other documentation. ‘SECTION 2. HAZARDS IDENTIFICATION GHS Classification Not a hazardous substance or mixture GHS Label element Hazard pictograms No Hazard Symbol required Signal word No signal word, Hazard statements PHYSICAL HAZARDS: Not classified as a physical hazard under GHS criteria, HEALTH HAZARDS: Not classified as a health hazard under GHS criteria, ENVIRONMENTAL HAZARDS: Not classified as an environmental hazard under GHS criteria, Precautionary statements Prevention: No precautionary phrases. Response: No precautionary phrases. Storage: ‘No precautionary phrases. Disposal: ‘No precautionary phrases. 1118 ‘Bo000T018761 usSAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 1.4 Revision Date: 12/31/2015 Print Date: 05/02/2016 Other hazards which do not result in classification Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resull- ing in disorders such as oil acnefollculits Used oil may contain harmful impurities. Not classified as flammable but will bum. ‘The classification of this material is based on OSHA HCS 2012 criteria, Under normal conditions of use or in a foreseeable emergency, this product does not meet the definition of a hazardous chemical when evaluated according to the OSHA Hazard Communica tion Standard, 29 CFR 1910.1200. ‘SECTION 3. COMPOSITIONINFORMATION ON INGREDIENTS Chemical nature ‘Synthetic base ol and additives. Highly refined mineral oil The highly refined mineral oll contains <3% (wiv) DMSO- extract, according to IP346. ‘The highly refined mineral ollis only present as additive dilu- ent * contains one or more of the following CAS-numbers: 64742- 583-6, 64742-54-7, 64742-55-8, 64742-56-9, 64742-65-0, 68037-01-4, 72623-86-0, 72623-87-1, 8042-47-5, 848301-69- 9. Hazardous components Chemical Name ‘Synonyms: CASNo. Concentration () ‘Alkaryi amine. 36878-20-3 1-3 Interchangeable low vis~ Not Assigned 0-80 cosity base oil (<20,5 cSt @u0rc)* SECTION 4. FIRST-AID MEASURES General advice Ifinhaled In case of skin contact In case of eye contact, Hf swallowed 216 Not expected to be a health hazard when used under normal conditions. No treatment necessary under normal conditions of use. If symptoms persist, obtain medical advice. : Remove contaminated clothing. Flush exposed area with wa- ‘er and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Flush eye with copious quantities of water. If persistent irritation occurs, obtain medical attention. In general no treatment is necessary unless large quantities: are swallowed, however, get medical advice. a ‘B0000101576% usSAFETY DATA SHEET ‘According to OSHA Hazard Communication Standard, 29 CFR 1910-1200 Version 1.4 Most important symptoms and effects, both acute and delayed Protection of first-alders Immediate medical attention, special treatment Revision Date: 12/31/2015 Print Date: 05/02/2016 il acne/foliculitis signs and symptoms may include formation Of black pustules and spots on the skin of exposed areas, Ingestion may result in nausea, vomiting andlor diarthoea. When administering first aid, ensure that you are wearing the appropriate personal protective equipment according to the incident, inury and surroundings. ‘Treat symptomatically. SECTION 5. FIRE-FIGHTING MEASURES Suitable extinguishing media Unsuitable extinguishing media Specific hazards during fire- fighting ‘Specific extinguishing meth- ods Special protective equipment for firefighters Foam, water spray or fag. Dry chemical powder, carbon diox- ide, sand or earth may be used for small fires only. Do not use water in a jet. Hazardous combustion products may include: ‘A complex mixture of airborne solid and liquid particulates and «gases (smoke). Cartoon monoxide may be evolved if incomplete combustion ‘occurs. Unidentified organic and inorganic compounds. Use extinguishing measures that are appropriate to local ir- cumstances and the surrounding environment. Proper protective equipment including chemical resistant {loves are to be wom; chemical resistant suits indicated if large contact with spilled product is expected. Self-Contained Breathing Apparatus must be wom when approaching a fire in ‘a confined space. Select fie fighter's clothing approved to relevant Standards (e.g. Europe: EN469). SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec tive equipment and emer- ‘gency procedures, Environmental precautions Methods and materials for containment and cleaning up a5 Avoid contact with skin and eyes. Use appropriate containment to avoid environmental contami- nation. Pravent from spreading or entering drains, ditches or rivers by using sand, earth, or otter appropriate barriers. Local authorities should be advised if significant spillages cannot be contained. Slippery when spill, Avoid accidents, clean up immediately. Prevent from spreading by making a barrier with sand, earth ‘or other containment material Reclaim liquid directly or in an absorbent Soak up residue with an absorbent such as clay, sand or other ‘200001015761 usSAFETY DATA SHEET According to OSHA Hazard Communication Standard, 28 CFR 1910.1200 Version 1.4 Revision Date: 12/31/2015 Print Date: 05/02/2016 suitable material and dispose of propery. Additional advice For guidance on selection of personal protective equipment see Chapter 8 of this Safety Data Sheet. For guidance on disposal of spilled material see Chapter 13 of this Safety Data Sheet. ‘SECTION 7. HANDLING AND STORAGE Technical measures Precautions for safe handling Avoidance of contact Product Transfer Storage Recommended storage tem- perature Other data Packaging material Container Advice Use local exhaust ventilation if thera is risk of inhalation of vapours, mists or aerosols. Use the information in this data sheet as input to a risk as- ‘sessment of local circumstances to help determine appropr ate controls for safe handling, storage and disposal of this material ‘Avoid prolonged or repeated contact with skin. ‘Avoid inhaling vapour andior mists. ‘When handling product in drums, safety footwear should be ‘worn and propor handling equipment should be used. Properly dispose of any contaminated rags or cleaning mate- rials in order to provent fires. Strong oxidising agents. This material has the potential to be a stalic accumulator. Proper grounding and bonding procedures should be used during all bulk transfer operations. -30- 50°C Keep container tightly closed and in a cool, well-ventilated place, Use propery labeled and closable containers. Suitable material: For containers or container linings, use mild sleel or high density polyethylene. Unsuitable material: PVC. Polyethylene containers should not be exposed to high tern- peratures because of possible risk of distortion. ‘SECTION 8. EXPOSURE CONTROLS AND PERSONAL PROTECTION Components with workplace control parameters ‘Components CAS-No. Value type | Control parame- | Basis (Form of __| ters / Permissible as Bo000T015761 usSAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 1.4 Revision Date: 12/31/2015 Print Date: 05/02/2016 exposure) | concentration: Oi mist, mineral Not Assigned | TWA ((inhal- [5 mgim3_ US. ACGIH able trac- Threshold tion)) Limit Values (Mist) Smgims ‘OSHA_TRA NS. Biological occupational exposure No biological limit allocated. Monitoring Methods Monitoring ofthe concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure con- trols. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied By a competent person and sam- ples anelysed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or con- tact the supplier. Further national methods may be available. National institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods http:/wuww.edc.goviniosh/ ‘Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods hitp:/erw.osha.gov! Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances hittp:fwurw hse.gov.ukl Institut fir Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany http:/www.dguy.delinhalindexisp institut National de Recherche et de Securié, (INRS), France hitp:/iwww.inrs fdaceuell Engineering measures The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: ‘Adequate ventilation to control airborne concentrations. ‘Where material is heated, sprayed or mist formed, there is 480 minutes where suitable gloves can be identified. For short-termisplash protection we recommend the same, but recognize that suitable gloves offering this level of protection ‘may not be available and in this case a lower breakthrough time maybe acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not ‘a good predictor of glove resistance to a chemical as itis ‘dependent on the exact composition of the glove material. Glove thickness should be typically greator than 0.35 mm depending on the glove make and model {f material is handled such that it could be splashed into eyes, protective eyewear Is recommended. ‘Skin protection is not ordinarily required beyond standard ‘work clothes. Iis good practice to wear chemical resistant gloves. Personal protective equipment (PPE) should meet recom- mended national standards. Check with PPE supplier. Environmental exposure controls General advice Take appropriate measures to fulfll the requirements of rele- ars Bo000TOTS TET usSAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 1.4 Revision Date: 12/31/2015. Print Date: 05/02/2016 vant environmental protection legislation. Avoid contamination of the environment by following advice given in Chapter 6. If necessary, prevent undissolved material from being dis- charged to waste water. Waste water should be treated in a municipal or industrial waste water treatment plant before sischarge to surface water. Local guidelines on emission limits for volatile substances must be observed for the discharge of exhaust air containing vapour. ‘SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Colour Odour Odour Threshold pH pour point Initia! boiling point and boiling range Flash point Evaporation rate Flammability (solid, gas) Upper explosion limit Lower explosion limit Vapour pressure Relative vapour density Relative density, Density ‘Solubilty(ies) Water solubility Solubility in other solvents Partition coefficient: n- Liquid at room temperature. : amber Slight hydrocarbon Data not available Not applicable -39°C |-38 “FMethod: ASTM D97 > 280 °C | 536 "Festimated value(s) 215°C /419 °F Method: ASTM D9 Data not available + Data not available Typical 10 %(V) Typical 1 %(V) <0.5 Pa (20°C /68 "F) estimated value(s) > testimated value(s) 0.840 (15 °C / 59 °F) + B40 kgim3 (15.0 °C /59.0 °F) Method: ASTM D1298 or D4052 negligible Data not available Pow: > 6(based on information on similar products) 7116 ‘BOD0OTOTETET us‘SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910-1200 Version 1.4 e Revision Date: 12/31/2015 Print Date: 05/02/2016 octanoliwater Auto-ignition temperature > 320°C 1608 °F Viscosity Viscosity, dynamic Viscosity, kinematic, Explosive properties Oxidizing properties Conductivity Decomposition temperature Data not avaitable + 68.2 mm2is (40.0 °C / 104.0 °F) Method: ASTM D445 42.2 mm2ts (100 °C /212 °F) Method: ASTM D445, Not classified Data not available + This material is not expected to be a static accumulator. + Data not available ‘SECTION 10. STABILITY AND REACTIVITY Reactivity Chemical stability Possibility of hazardous reac- tions, Conditions to avoid Incompatible materials Hazardous decomposition products ‘The product does not pose any further reactivity hazards in addition to those listed in the following sub-paragraph. Stable, 2 Reacts with strong oxidising agents. : Extremes of temperature and direct sunlight. Strong oxidising agents. Hazardous decomposition products are not expected to form during normal storage. SECTION 11. TOXICOLOGICAL INFORMATION Basis for assessment Information given is based on data on the components and the toxicology of similar products. Unless indicated otherwise, the dala presented is representative of the product as a whole, rather than for individual component(s). likely routes of exposure ‘Skin and eye contact are the primary routes of exposure although exposure may occur following accidental ingestion, Acute toxicity ais ‘s0000T OTB 76T usSAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 910.1200 Version 1.4. Revision Date: 12/31/2015 Print Date: 05/02/2016 Product: ‘Acute oral toxicity LD80 (rat): > 5,000 mg/kg Remarks: Expected to be of low toxicity Acute inhalation toxicity Remarks: Not considered to be an inhalation hazard under normal conditions of use. Acute dermal toxicity LDS0 (Rabbit): > 5,000 mg/kg Remarks: Expected to be of low toxicity Skin corrosionvirritation Product: Remarks: Expected to be slightly irritating... Prolonged or repeated skin contact without proper cleaning can clog the pores of the skin resulting in disorders such as oil acnetfollicultis. Serious eye damageleye irritation Product: Remarks: Expected to be slightly irritating, Respiratory or skin sensitisation Product: Remarks: Not expected to be a skin sensitiser. Germ cell mutagenicity Product: Remarks: Not considered a mutagenic hazard. Carcinogenicity Product: Remarks: Not expected to be carcinogenic. IARC. No component of this product present at levels greater than or ‘equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH No component ofthis product present at levels greater than or ‘equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH, OsHA No component ofthis product present at levels greater than or ‘equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP ‘No component ofthis product present at levels greater than or ‘equal to 0.1% is identified as a known or anticipated carcinogen by NTP. 9148 ~-so0001015767 usSAFETY DATA SHEET According to OSHA Hazard Communication Standard, 20 CFR 1910.1200 Version 1.4 Reproductive toxicity Product: ‘STOT- single exposure Product: Revision Date: 12/31/2015 Print Date: 05/02/2016 Remarks: Not expected to impair fertility., Not expected to be a developmental toxicant. Remarks: Not expected to be a hazard. STOT - repeated exposure Product: Remarks: Not expected to be a hazard. Aspiration toxicity Product: Not considered an aspiration hazard. Further information Product: Remarks: Used oils may contain harmful impurities that have accumulated during use. The con- centration of such impurities will depend on use and they may present risks to health and the. environment on disposal., ALL used oil should be handled with caution and skin contact avoided as far as possible. Remarks: Continuous contact with used engine oils has caused skin cancer in animal tests. Remarks: Slightly inrtating to respiratory system. ‘SECTION 12. ECOLOGICAL INFORMATION Basis for assessment Ecotoxicity Product: Toxicity to fish (Acute toxici- y) Ecotoxicolagical data have not been determined specifically for this product. Information given is based on a knowledge of the components and the ecotoxicology of simitar products. Unless indicated otherwise, the data presented is representa- tive of the product as a whole, rather than for individual com- ponent(s).(LL/EL/ILSO expressed as the nominal amount of product required to prepare aqueous test extract). Remarks: Expected to be practically non toxic: LUELIILSO > 100 maf 70115 300001015761 usSAFETY DATA SHEET ‘According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 4.4 Revision Date: 12/31/2015 Print Date: 05/02/2016 Toxicity to daphnia and other aquatic invertebrates (Acute toxicity) Toxicity to algae (Acute tox- icity) Toxicity to fish (Chronic tox- icity) Toxicity to daphnia and other aquatic Invertebrates (Chron ie toxicity) Toxicity to bacteria (Acute toxicity) Persistence and degradability Product: Biodegradability Bioaccumulative potential Product, Bioaccumulation Mobility in soll Product: Mobility Other adverse effects no data available Remarks: Expected to be practically non toxic: LUELALSO > 100 mg! Remarks: Expected to be practically non toxic: LUELIILS0 > 100 maf Remarks: Data not available Remarks: Data not available Remarks: Data not available : Remarks: Expected to be nat readily biodegradable. Major constituents are expected to be inherently biodegrada- ble, but contains components that may persist in the environ- ment. + Remarks: Contains components with the potential to bioac- cumulate. Remarks: Liquid under most environmental conditions. Ifitenters soi, it will adsorb to soll partides and will not be mobile. Remarks: Floats on water. Product: ‘Additional ecological infor- Product is a mixture of non-volatile components, which are not ‘mation expected to be released to air in any significant quantities. Not expected to have ozone depletion potential, photochemi cal ozone creation potential or global warming potential Poorly soluble mixture. May cause physical fouling of aquatic organisms. WS 800001015761 us‘SAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 910.1200 Version 1.4 Revision Date: 12/31/2015 Print Date: 05/02/2016. ‘SECTION 13. DISPOSAL CONSIDERATIONS. Disposal methods Waste from residues +: Waste product should not be allowed to contaminate soil or ‘ground water, or be disposed of into the environment. Waste, spills or used product is dangerous waste. Disposal should be in accordance with applicable regional, ‘rational, and local laws and regulations. Local regulations may be more stringent than regional or na- tional requirements and must be complied with, Contaminated packaging = Diispose in accordance with prevailing regulations, preferably toa recognized collector or contractor. The competence of the collector or contractor should be established beforehand. Disposal should be in accordance with applicable regional, national, and local laws and regulations. ‘SECTION 14. TRANSPORT INFORMATION National Regulations US Department of Transportation Classification (49 CFR Parts 171-180) Not regulated as a dangerous good International Regulation IATA-DGR Not regulated as a dangerous good IMDG-Code Not regulated as a dangerous good ‘Transport in bulk according to Annex Il of MARPOL 73/78 and the IBC Code Pollution category Not applicable Ship type Not applicable Product name ‘Not applicable ‘Special precautions, Not applicable Special precautions for user Remarks ‘Special Precautions: Refer to Chapter 7, Handling & Storage, for special precautions which a user needs to be aware of or ‘needs to comply with in connection with transport. Additional Information : MARPOL Annex 1 rules apply for bulk shipments by sea, ‘SECTION 15. REGULATORY INFORMATION OSHA Hazards : No OSHA Hazards 800001015761 us “asSAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910.1200 Version 1.4 Revision Date: 12/31/2015 Print Date: 05/02/2016 EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity ‘This material does not contain any components with a CERCLA RQ., Shall classifies this material ‘as an “oll” under the CERCLA Petroleum Exclusion, therefore releases to the environment are not reportable under CERCLA. ‘SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards No SARA Hazards SARA 302 ‘No chemicals in this material are subject to the reporting requirements of SARA Title Il, Section 302. SARA 313 2 This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title Ill, Section 313, Clean Water Act This product does not contain any Hazardous Chemicals listed under the U.S, CleanWater Act, Section 311, Table 117.3, Pennsylvania Right To Know Distiates (petroleum), hydrotreated heavy 64742-54-7 paraffinic Distilates (petroleum), hydrotreated heavy 64742-54-7, paraffinic Distilates (petroleum), solvent-dewaxed 6 4742-65-0 heavy paraffinic baseol - unspecified 72628-87-1 California Prop 65 This product does not contain any chemicals known to State of Califomia to cause cancer, birth defects, or any other re~ productive harm, ‘The components of this product are reported in the following inventories: EINECS All components listed or polymer exempt. TSCA All components listed. pst + All components listed. SECTION 16. OTHER INFORMATION Further information NFPA Rating (Health, Fire, Reac- 0. 1,0 tivity) ‘A vertical bar (| in the left margin indicates an amendment from the previous version. ‘Abbreviations and Acronyms = The standard abbreviations and acronyms used in this docu- ‘ment can be looked up in reference literature (e.9. scientific dictionaries) and/or websites, 13/15 ~ 800001015761 usSAFETY DATA SHEET According to OSHA Hazard Communication Standard, 29 CFR 1910-1200 Version 1.4 Revision Date: 12/31/2015, Print Date: 05/02/2016. ACGIH = American Conference of Governmental Industrial Hygienists: ADR = European Agreement concerning the International Carriage of Dangerous Goods by Road AICS = Australian Inventory of Chemical Substances BEL = Biological exposure limits BTEX = Benzene, Toluene, Ethylbenzene, Xylenes CEFIC = European Chemical Industry Council CLP = Classification Packaging and Labelling Deutsches Institut fur Normung Derived Minimal Effect Level “uropean Commission lective Concentration fifty ECETOC = European Center on Ecotoxicology and Toxicolo- gy Of Chemicals European Chemicals Agency ‘The European inventory of Existing Commercial Chemical Substances Hfective Loading fity lapanese Existing and New Chemical Substances GHS = Globally Harmonised System of Classification and Labelling of Chemicals iterational Agency for Research on Cancer Intemational Air Transport Association Inhibitory Concentration fity Inhibitory Level fity IMDG = International Maritime Dangerous Goods INV = Chinese Chemicals Inventory IP346 = Institute of Petroleum test method N° 346 for the determination of polycyclic aromatics DMSO-extractables KECI = Korea Existing Chemicals Inventory C50 = Lethal Concentration fity LD50 = Lethal Dose fifty per cent LUELIL = Lethal Loading/Effective Loading/inhibitory loading LL50 = Lethal Loading fy MARPOL = Intemational Convention for the Prevention of Pollution From Ships NOECINOEL = No Observed Effect Concentration / No Ob- served Effect Level (OE_HPV = Ocoupational Exposure - High Production Volume PBT = Persistent, Bioaccumulative and Toxic PICCS = Philippine Inventory of Chemicals and Chemical ‘Substances PNEC = Pradicted No Effect Concentration REACH = Registration Evaluation And Authorisation Of Chemicals RID = Regulations Relating to Intemational Carriage of Dan- sgerous Goods by Rall 74118 ‘800001015761 usSAFETY DATA SHEET ‘According to OSHA Hazard Communication Standard, 29 CFR 4910.1200 Version 1.4 Revision Date: 12/31/2015 Print Date: 05/02/2016 ‘SKIN_DES = Skin Designation ‘STEL= Short term exposure limit TRA = Targeted Risk Assessment TSCA = US Toxic Substances Control Act TWA = Time-Weighted Average \vPVB = very Persistent and very Bloaccumulative Revision Data 12/31/2015 ‘This information is based on our current knowledge and is intended to describe the product for the purposes of health, safety and environmental requirements only. t should not therefore be construed as guaranteeing any specific propery ofthe product. ers ‘B0000T018761 us