Professional Documents
Culture Documents
Powder Technology
journal homepage: www.elsevier.com/locate/powtec
State Key Laboratory of Multiphase Complex Systems, Institute of Process Engineering, Chinese Academy of Sciences, Beijing 100190, P.R. China
State Key Laboratory of Heavy Oil Processing, China University of Petroleum, Beijing 102249, P.R. China
a r t i c l e
i n f o
Article history:
Received 14 April 2015
Received in revised form 13 July 2015
Accepted 15 July 2015
Available online 22 July 2015
Keywords:
Loop seal
Circulating uidized bed
Numerical simulation
Bubbling uidization
Gas ow
Multiscale
a b s t r a c t
A typical loop seal consists of a supply chamber and a recycle chamber as well as a bottom connection slit in
between. The supply chamber is generally operated in the minimum uidization state, while the recycle chamber
in the bubbling uidization regime. The energy-minimization multi-scale (EMMS) model, as generally used to
calculate interphase drag coefcient in previous simulations of the loop seal, is still open to discussion since it
is based on the concept of particle clusters. So an EMMS bubbling model was developed to model dense gas
solid ow by taking into account the interphase interaction between the emulsion and bubble phases. In this article, a heterogeneity index is calculated from an improved EMMS bubbling model to measure the interphase
drag coefcient and further integrated into the two-uid-model (TFM) approach to simulate the loop seal for a
circulating uidized bed (CFB) system. This index is dependent on supercial gas velocity in bubbling uidization, so a region-specic drag correction scheme is proposed to allow the application of various heterogeneity
index correlations to different zones of the loop seal, since supercial gas velocity may differ much from the
recycle to supply chamber. Several typical cases of drag correction are comparatively investigated by applying
various gas velocities and/or drag models in the recycle and supply chambers, and the optimal one is proven
to be able to reasonably simulate the parametric effects on gas inverse ow in the loop seal.
2015 Elsevier B.V. All rights reserved.
1. Introduction
A loop seal, as one of the most widely used non-mechanical valves in
circulating uidized beds (CFB) or other related processes, serves as a
recycle device allowing the transfer of the solids from the high-pressure
standpipe to the low-pressure riser, but preventing the inverse ow of
the gas from the riser bottom to the standpipe. A typical loop seal
generally consists of a supply chamber and a recycle chamber as well
as a bottom connection opening or slit in between.
A series of experiments were carried out to explore the basic operational principle of the loop seal [110]. Based on these studies, many
empirical or semi-empirical hydrodynamic models were proposed to
predict the performance of the loop seal, but much effort is still needed
to improve the understanding of the design, scale-up, and operation of
the loop seal [11].
A variety of simulation techniques for gassolid ow have been developed to optimize designs and troubleshoot operational problems in
chemical engineering [12,13], but the two-uid-model (TFM) approach
is the most frequently used in practice [14,15]. Traditional TFM approach generally assumes homogeneous conditions inside a control
http://dx.doi.org/10.1016/j.powtec.2015.07.019
0032-5910/ 2015 Elsevier B.V. All rights reserved.
444
on gas bubbles. Taking into account the effects of the above two interactions on the suspension and transporting energy dissipation rate (Nst) in
the system, Liu et al. [24] proposed a new stability condition for gas
solid bubbling uidization to formulate an improved EMMS bubbling
model as follows:
8
< Nst Nst;o Nex;i min
EMMS bubbling model F i X 0 i 1; 2; ; 5
:
U se 0;U si 0
where Nst,0 and Nex,i are the energy dissipation rates due to the interphase slip and the gas bubble expansion, respectively; the ve equations Fi(X) = 0 (i = 1, 2,, 5) describe the force balance and the
material continuity in the system; and supercial slip velocities (Use
and Usi) in the emulsion and interphases should not be smaller than
zero. If assuming no particles in gas bubbles, such a system can be
described by eight structural parameters including e, fb, Uge, Upe, Ub,
ae, ab, and db, among which e, Uge, Upe, and ae refer to the emulsion
phase, and fb, Ub, ab, and db to the bubble phase. So, the constitutive
and main closure equations for the EMMS bubbling model can be summarized in Tables 2 and 3, respectively. By utilizing a two-dimensional
optimization method, this model can be numerically solved without
introducing bubble-specic empirical correlations such as for bubble diameter and bubble acceleration. More details on the EMMS bubbling
model can be found in the previous literatures [24,29].
With the eight structural parameters in the EMMS bubbling model
to be determined under the given operating conditions, a so-called
structure-dependent drag coefcient (bubble) in gassolid bubbling
uidization can be expressed as
bubble
2g
p g 1 e 1f b g ae
U slip
In gassolid bubbling uidization, the interphase interaction between the continuous and discrete phases can be represented as the
normal pressure stress and the tangential drag force of dense emulsion
WenYu
1 g
3
C D0
g U slip 2:65
g
4
dp
Table 1
Governing equations and constitutive relations for the TFM model.
Mass and momentum conservation equations
n
!
The mass conservative equation for phase q (q = g, s): t q q q q v q 0
!
!
!
! !
The momentum conservative equation for phase q (q = g, s): t q q v q q q v q v q q P q R pq q q F q
n
p1
KTGF theory
The granular temperature: s 13 v0 s 2
The granular temperature conservative equation: 32
s s s
t
i
!
!
s s v s s ps I s : v s ks s s ls
121e2ss g 0;ss
!
p
where ps I s : v s is the generation of energy by the solid stress tensor, ks s is the diffusion of energy, s is the collisional dissipation of energy, s
d
s
th
th
s 2s 3=2
s , and ls = 3lss is the energy exchange between the l uid or solid phase and the s solid phase.
The solid pressure: Ps = sss + 2s(1 + ess)2s g0,sss
h
i
1 1
where g0,ss is the radial distribution function expressed by g 0;ss 1 s = s; ;max 3 .
q
The solid bulk viscosity: s 43 s s ds g 0;ss 1 ess s
p h
q
i2
10s dp s
The solid shear viscosity: s 45 2s s ds g 0;ss 1 ess s 961e
1 45 g 0;ss s 1 ess s
ss g
0;ss
2s g
2
g dp
1:75
s g
dp
jvuj; g b 0:8;
WenYu 34 C D
s g
dp
jvuj 2:65
; g 0:8
g
Rep b 1000
jvujd
with Rep g p
g
Rep 1000
445
Table 2
Constitutive equations for the EMMS bubbling model.
Equation
Mathematical expression
e
2
3
4 C Di db f b U si f b e g g ab 0
g
3
C
1
f b 1e U 2se 34 C Di de f b U 2si 1 f b 1e p g g
4 De dp
b
ae 0
Ug Uge(1 fb) Ub fb = 0
Up Upe(1 fb) = 0
g = (1 fb)e + fb
Nst
p g 1 f b gae f b gab
U ge
p
1 f b
2
f
fb
p g 1bf g ab U b 34 Hs 1
Kgdb U g min
s
p
b
Table 3
Main closure equations for the EMMS bubbling model.
Parameter
Emulsion phase
Interphase
CDe = CDe04.7
e
446
Fig. 2. Computational domain: (1) space diagram of the loop seal and the standpipe; (2) front view and geometric sizes of the loop seal and the standpipe.
three mesh scales, which implies that the numerical accuracy for solids
concentration in the loop seal has not been improved signicantly
when increasing the mesh resolution. Therefore, all hexahedron meshes
in the following simulations will be generated at the scale of 10 mm in
order to achieve sufcient numerical accuracy but avoid large computational cost.
Table 4
Physical properties of gas and particles.
Item
3
Density (kg/m )
Viscosity (Pa.s)
Diameter (m)
Restitution coefcient ()
Maximum packing limit ()
Minimum uidization velocity (m/s)
Gas
Particles
1.225
1.7894e-5
/
/
/
/
2460
/
80.0
0.90
0.63
0.006
models. As listed in Table 6, the Gidaspow model is rstly used to calculate interphase drag force with the adoption of the laminar and turbulent assumptions in schemes a and b, respectively, while the EMMS
bubbling model is utilized to modify interphase drag force with incorporating the laminar ow and k--kp-p turbulence models in schemes c
and d, respectively.
The related simulations are implemented under the preceding typical operating conditions. As shown in Fig. 4a and b, if only the Gidaspow
drag model is adopted in the simulation, solids concentration in the
standpipe almost approaches the maximum packing limit regardless
Table 5
Simulation settings in Fluent.
Space
Time
Pressurevelocity coupling
Momentum discretization
Volume fraction discretization
Granular temperature
Granular viscosity
Granular bulk viscosity
Frictional viscosity
Angle of internal friction
Solids pressure
Frictional pressure
Radial distribution
Time step
Max. iterations per time step
3D
Transient, second-order implicit
Phase-coupled SIMPLE
Second-order upwind
Quick
Second-order upwind
Gidaspow
Lun et al.
Schaeffer
30
Lun et al.
Based KTGF
Lun et al.
0.0005 s
60
447
Table 6
Summary of various modeling schemes.
Modeling scheme
Drag model
Viscous model
a
b
c
d
Gidaspow
Gidaspow
EMMS bubbling
EMMS bubbling
Laminar
Turbulent
Laminar
Turbulent
448
Table 7
Summary of various correction schemes.
Correction scheme
Recycle chamber
Supply chamber
A
B
C
D
Gidaspow (Qsc)
EMMS bubbling (Qsc)
EMMS bubbling (Qsc)
Gidaspow (Qsc)
All related simulations in this section are performed under the preceding typical operating conditions. Fig. 6 presents the snapshots of instantaneous solids concentrations (s) under four drag correction
schemes. It can be found that many bubble-like voids occur in the
whole computational domain if scheme A or B is adopted in the simulation. These voids, however, begin to coalesce with each other in the recycle chamber under either scheme C or D. In this case, the discrete
phase is hard to distinguish from the continuous one in the supply
chamber. This is because the interphase drag force in the recycle chamber is signicantly over-predicted with the specied mesh resolution in
schemes C and D. The former can be attributed to the adopted large gas
ow rate up to Qrc + Qsc in the recycle chamber, while the latter, as
aforementioned, results from the Gidaspow drag model itself.
Fig. 7 depicts the streamline of the gas owing from the bottom inclined entrance of the loop seal. Regardless of scheme B or C, it is only
through the adjacent region to the internal bafe that a large part of
Qsc is carried into the recycle chamber and nally into the riser bottom
by the circulated particles. This simulation result is consistent with the
fact that the gas tends to choose a path with minimal resistance in a
gas uidized bed. That is, this part of gas ow contributes little to the
uidization of most particles in the recycle chamber, implying that the
calculated supercial gas velocity in the recycle chamber from Qrc,
as in scheme B, is much closer to actual situation than that from
Qrc + Qsc in scheme C.
Axial proles of cross-sectional average solids concentrations (as) in
the recycle and supply chambers simulated by using various correction
schemes are shown in Fig. 8. In the recycle chamber, the simulation
using scheme A predicts a higher solids concentration than that using
reference scheme D because of the corrected drag force in this chamber,
which whereas leads to the reverse variation of solids concentration in
the supply chamber due to the constraints of the mass and pressure
balances in the computational domain. If scheme B is used in the simulation, a slightly increased solids concentration in the whole computational domain but a decreased expansion rate in the supply chamber
can be obtained in comparison with the simulation using scheme A.
This can be attributed to the decreased heterogeneity index calculated
Fig. 7. Streamline of the gas owing from the bottom inclined entrance of the loop seal
under schemes B and C.
from the EMMS bubbling drag model in the supply chamber. The simulation using scheme C predicts a much lower solids concentration in the
recycle chamber but a rather higher one in the supply chamber than
that using scheme B, because a too large gas ow rate of Qrc + Qsc
leads to a signicantly increased interphase drag force in the recycle
chamber even if the EMMS bubbling drag model is adopted in the
simulation.
Fig. 9 shows the variation of Hb with time when various drag correction schemes are utilized in the simulation. It can be seen that the simulation using scheme B has a much higher accuracy than the other
schemes and successfully predicts the experimental Hb indicated by a
dashed line in the gure. As listed in Table 8, average solids concentrations (s,rc, s,sc, and s,sp) in the recycle chamber, the supply chamber,
and the standpipe are determined from the measured pressure drops
across these three domains, respectively [13]. It can be found from the
table that only using scheme B does the simulated average solids concentration show a high accuracy with relative error less than about
2.0% in the three different regions including the recycle chamber and
449
supply chamber as well as the standpipe. All these phenomena consolidate that scheme B has a signicant advantage over the other schemes
for the simulation of the loop seal with high solids concentrations. So,
this scheme will be used to investigate the parametric effects on gas
inverse ow in the loop seal.
5. Parametric effects on gas inverse ow in the loop seal
A little gas inverse ow rate (Qsp) in the loop seal helps to maintain
the normal operation of the standpipe, which, however, should not be
too large to reach a high separation efciency of the cyclone. As a result,
it is generally preferred that a large part of loop seal gas ow (Qrc + Qsc)
is carried into the riser bottom by the circulated particles. In this section,
the effects of inuential parameters, such as Qrc, Qsc, Pb, and Im on gas inverse ow are numerically studied in detail by varying corresponding
parameter value under the typical operating conditions.
The ratio in Table 9, as an index to gas inverse ow in the loop seal,
denotes the percentage of Qsp to the sum of Qrc and Qsc. It is clear that gas
inverse ow in the loop seal is suppressed to a low level under the typical operating conditions of Qrc = 5 m3/h, Qsc = 5 m3/h, Pb = 12.5 kPa,
and Im = 65 kg. Increasing Qsc and/or Pb or decreasing Qrc and/or Im may
Table 8
Comparison between the simulated and experimental average solids concentrations in the
different domains under various correction schemes.
Drag
correction
scheme
A
B
C
D
s,rc
s,sc
lead to a signicant increment of Qsp. Specially, at Im = 55 kg, the pressure head provided by the standpipe and supply chamber is even not
sufcient to counteract the resistance from the bottom slit and recycle
chamber as well as back pressure, leading to a very large gas inverse
percentage up to 34.4% and even zero solid circulation in the loop seal.
These simulation results are consistent with our experimental observations, indicating the rationality of the adopted numerical scheme.
An internal bafe is generally employed to divide the loop seal into
the recycle and supply chambers with a connection passage at the bottom. The inclination angle of the bafe may signicantly affect particle
circulation and gas ow in the loop seal. As shown in Figs. 10, 11, and
12, the effects of the introduced particles at the bottom side of the
standpipe on the concentration and pressure elds in the computational
domain are insignicant and only conned to the adjacent region to the
entrance under the investigated operating conditions. The simulated
particle bed height in the standpipe gradually increases from case i to
iii with an obvious decrement of solids concentration in this domain.
This simulation result indicates that the percentage of gas inverse ow
s,sp
Exp.
()
Cal.
()
Err.
(%)
Exp.
()
Cal.
()
Err.
(%)
Exp.
()
Cal.
()
Err.
(%)
0.502
0.506
0.511
0.493
0.487
0.80
1.79
1.79
2.99
0.556
0.548
0.557
0.571
0.566
1.44
0.18
2.70
1.80
0.566
0.553
0.564
0.606
0.609
2.30
0.35
7.07
7.60
Table 9
Parametric effects on gas inverse ow in the loop seal.
Parameter
3
Qrc (m /h)
Qsc (m3/h)
Pb (kPa)
Im (kg)
Value
Qsp (m3/h)
Ratio (%)
5.0
7.5
10.0
5.0
7.5
10.0
12.5
13.0
13.5
55.0
65.0
70.0
1.321
0.993
0.742
1.321
1.984
2.712
1.321
1.558
1.932
3.436
1.321
0.924
13.2
7.95
4.94
13.2
15.9
18.1
13.2
15.6
19.3
34.4
13.2
9.24
450
Uge, Upe supercial gas and particle velocities in the emulsion phase,
m/s
Umf
minimum uidization velocity, m/s
Up
supercial particle velocity, m/s
Use, Usi supercial slip velocities in the emulsion and interphases, m/s
Uslip
supercial gassolid slip velocity, m/s
gradually increases from case i to iii under the tested operating conditions.
This is also the reason why the internal bafe is set to incline toward the
supply chamber of the loop seal in this research.
6. Conclusions
A structure-dependent drag coefcient calculated from an improved
energy-minimization multi-scale (EMMS) bubbling drag model is integrated into the two-uid-model (TFM) approach, in order to simulate
dense gassolid ow in the loop seal for a circulating uidized bed
(CFB). The EMMS bubbling scheme enables detailed heterogeneous
structures to be captured in the loop seal without consideration of turbulence in the gas and solid phases. A region-specic drag correction
scheme is proposed to allow the application of various drag coefcient
correlations to different zones of the loop seal, so as to address the effect
of the variation of supercial gas velocity on the interphase drag coefcient. In the recycle and supply chambers of the loop seal, the drag coefcients should be calculated from the EMMS bubbling drag model at
their respective supercial gas velocities. By incorporating with the
TFM approach, the EMMS-based region-specic drag correction scheme
enables the reasonable prediction of the parametric effects on gas inverse ow in the loop seal with an inclined internal bafe.
Nomenclature
ae, ab
acceleration of the emulsion particles and the gas bubbles,
m/s2
CD0
drag coefcient for a single particle or bubble
CDe, CDi effective drag coefcients in the emulsion and interphases
db
bubble diameter, m
dp
particle diameter, m
fb
volume fraction of bubble phase
H
height, m
Hb
total particle bed height in the supply chamber and the
standpipe, m
Hd
heterogeneity index
Im
solid inventory, kg
Nex,i
energy dissipation rate due to the gas bubble expansion,
m2/s3
Nst
suspension and transporting energy dissipation rate, m2/s3
Nst,0
energy dissipation rate due to the interphase slip, m2/s3
Pb
back pressure, kPa
Qrc
gas ow rate at the horizontal entrance, m3/h
Qsc
gas ow rate at the inclined entrance, m3/h
Qsp
gas inverse ow rate, m3/h
Re
Reynolds number
Ub
gas bubble velocity, m/s
Ug
supercial gas velocity, m/s
Greek Letters
average density of the emulsion phase, kg/m3
e
g
gas density, kg/m3
p
particle density, kg/m3
bubble
drag coefcient calculated from the EMMS bubbling model
as
cross-sectional average solids concentration
e
voidage in the emulsion phase
g
voidage
s
solids concentration
s,rc
average solids concentration in the recycle chamber
s,sc
average solids concentration in the supply chamber
s,sp
average solids concentration in the standpipe
Acknowledgment
We would like to thank nancial supports from the Strategic
Priority Research Program of the Chinese Academy of Sciences
(No. XDA07080400) and the Natural Science Foundation of China
(Nos. 21376244 and 91334107).
References
[1] L. Cheng, P. Basu, Effect of pressure on loop seal operation for a pressurized circulating uidized bed, Powder Technol. 103 (1999) 203211.
[2] S. Kim, W. Namkung, S. Kim, Solids ow characteristics in loop-seal of a circulating
uidized bed, Korean J. Chem. Eng. 16 (1999) 8288.
[3] P. Basu, L. Cheng, An analysis of loop seal operations in a circulating uidized bed,
Chem. Eng. Res. Des. 78 (2000) 991998.
[4] S.W. Kim, S.D. Kim, Effects of particle properties on solids recycle in loop-seal of a
circulating uidized bed, Powder Technol. 124 (2002) 7684.
[5] E. Botsio, P. Basu, Experimental investigation into the hydrodynamics of ow of
solids through a loop seal recycle chamber, Can. J. Chem. Eng. 83 (2005) 554558.
[6] E.R. Monazam, L.J. Shadle, J.S. Mei, Impact of the circulating uidized bed riser on the
performance of a loop seal non-mechanical valve, Ind. Eng. Chem. Res. 46 (2007)
18431850.
[7] P. Basu, J. Butler, Studies on the operation of loop-seal in circulating uidized bed
boilers, Appl. Energy 86 (2009) 17231731.
[8] M.M. Yazdanpanah, A. Forret, T. Gauthier, A. Delebarre, An experimental investigation of loop-seal operation in an interconnected circulating uidized bed system,
Powder Technol. 237 (2013) 266275.
[9] X. Wang, X. Wu, F. Lei, J. Lei, Y. Xiao, 3D full-loop simulation and experimental verication of gassolid ow hydrodynamics in a dense circulating uidized bed,
Particuology 16 (2014) 218226.
[10] P. Bareschino, R. Solimene, R. Chirone, P. Salatino, Gas and solid ow patterns in the
loop-seal of a circulating uidized bed, Powder Technol. 264 (2014) 197202.
[11] C. Li, H. Li, Q. Zhu, A hydrodynamic model of loop-seal for a circulating uidized bed,
Powder Technol. 252 (2014) 1419.
[12] M. Syamlal, C. Guenther, A. Cugini, W. Ge, W. Wang, N. Yang, J. Li, Computational science: enabling technology development, Chem. Eng. Prog. 107 (1) (2011) 2329.
[13] X. Liu, L. Guo, Z. Xia, B. Lu, M. Zhao, F. Meng, Z. Li, J. Li, Harnessing the power of
virtual reality, Chem. Eng. Prog. 108 (2012) 2833.
[14] S. Sundaresan, Reections on mathematical models and simulation of gas-particle
ows, in: T.M. Knowlton (Ed.), Tenth International Conference on Circulating Fluidized Beds and Fluidization Technology CFB-10, Sunriver 2011, pp. 2140.
[15] A. Nikolopoulos, N. Nikolopoulos, A. Charitos, P. Grammelis, E. Kakaras, A.R. Bidwe,
G. Varela, High-resolution 3-D full-loop simulation of a CFB carbonator cold
model, Chem. Eng. Sci. 90 (2013) 137150.
[16] D. Gidaspow, Multiphase ow and uidization: continuum and kinetic theory
descriptions, Academic Press, San Diego, 1994.
[17] W. Ge, W. Wang, W. Dong, J. Wang, B. Lu, Q. Xiong, J. Li, Meso-scale structurea
challenge of computational uid dynamics for circulating uidized bed risers, Proceedings of the Ninth International Conference on Circulating Fluidized Beds, Hamburg 2008, pp. 1937.
[18] Q. Wang, H. Yang, P. Wang, J. Lu, Q. Liu, H. Zhang, L. Wei, M. Zhang, Application of
CPFD method in the simulation of a circulating uidized bed with a loop seal, part
IDetermination of modeling parameters, Powder Technol. 253 (2014) 814821.
[19] Q. Wang, H. Yang, P. Wang, J. Lu, Q. Liu, H. Zhang, L. Wei, M. Zhang, Application of
CPFD method in the simulation of a circulating uidized bed with a loop seal Part
IIInvestigation of solids circulation, Powder Technol. 253 (2014) 822828.
451
[26] S. Ergun, Fluid ow through packed columns, Chem. Eng. Prog. 48 (1952) 8994.
[27] C.Y. Wen, Y.H. Yu, Mechanics of uidization, Chem. Eng. Prog. Symp. Ser. 62 (1966)
100111.
[28] J. Ding, D. Gidaspow, A bubbling uidization model using kinetic theory of granular
ow, AIChE J 36 (1990) 523538.
[29] X. Liu, S. Hu, Y. Jiang, J. Li, Extension and application of energy-minimization multiscale (EMMS) theory for full-loop hydrodynamic modeling of complex gassolid reactors, Chem. Eng. J. 278 (2015) 492503.
[30] N. Yang, W. Wang, W. Ge, J. Li, CFD simulation of concurrent-up gassolid ow in
circulating uidized beds with structure-dependent drag coefcient, Chem. Eng. J.
96 (2003) 7180.
[31] A.R. Coughtrie, D.J. Borman, P.A. Sleigh, Effects of turbulence modelling on prediction of ow characteristics in a bench-scale anaerobic gas-lift digester, Bioresour.
Technol. 138 (2013) 297306.