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Abstract
Ultrapotasslc, peralkahc sdlca-saturated plutons (580 Ma) are widespread in the Cachoelrmha-Salguelro foldbelt, northeastern Brazil They consist of alkali-feldspar syenltes w~th pyroxemte as co-magmatlc inclusions and
syn-plutomc or late-stage dikes Pyroxemte and syemte have the same mineral phases (aeglrme-auglte, m~crocllne,
sphene, apatlte, blue amphibole, magnetite), but only m &fferent proportions Rare inclusions of a "mixed" rock
(about 60% syemte + 40% pyroxenlte m an emuls~on-hke texture) are also present Pyroxenes an the three umts
are all only slightly zoned, slhca-saturated and extremely low m A1203 (0 2-1 4%) Amphiboles are mostly K-rich
rlchterlte, characterized by high $102, low A1203 and TIO2 contents and low Mg#
The three rock types have similar REE chondme-normahzed patterns, wtth negative slopes and lack of Eu anomaly, w~th the total REE m the pyroxemte greater than that &the syemte Trace element patterns for the m~xed rock
are mtermedmte between those for the pyroxemte and syemte Major element partitioning between pyroxenlte and
syemte has the same sense as that one observed between lmmtsclble llqmds m volcanic lavas and trace element
partmonmg ~s similar to the experimentally determined partluon of lmm~soble hqmd pa~rs
The rocks have slmdar high J180 values (avg w r + 8%0SMOW,corrected from p~roxene), high lnltm187Sr/86Sr
ratios (about 0 710), and low 143Nd/144Nd(avg 0 51104)
F~eld and geochemical characteristics m&cate chemical equdlbnum among the three rock t~pes and suggest
llqmd lmm~sc~bdlty between syemte and pyroxemte, the m~xed rock representing the orlgmal magma composlt~on
1. Introduction
286
2. Geological setting
The Trlunfo batholith is one of several elongate syenitlc plutons emplaced within a 200 kmlong zone along the southern boundary of the
Cachoelrlnha-Salgueiro foldbelt (CSF), northeast Brazil (Fig 1 ) The foldbelt, one of the three
segments of the Central Structural Domain of the
Borborema province (Fig 1a), is an elongate belt
of a thick flysh-type sequence of sedimentary and
volcanic rocks metamorphosed to greenschist facies (Cachoelrxnha Group) and greenschist to
amphlbohte facies (Salguelro Group) The CSF,
which developed in the Late Precambrian during
the Braslllano orogeny ( = Pan-African orogeny
in western Africa), is bounded on the north and
south by the Patos and Pernambuco hneaments,
respectively, major strlke-shp systems which are
presumed to extend for hundreds of kilometers
into what is now western Africa
The enormous volume of syn- to late-klne-
[~PHANEROZOIC~OVER
RIUNFO
t '
~'
eER'VA"'~
BORBOREMAPROVINCE
(Central StructuralDomoln)
[~
CRETACEOUSSEDIMENTARY
COVER
BASEMENT ROCKS
GnolssesMigmohtes)
A- Serldo
CACHOEIR1NHAGROUP
(Phylhtes Schists)
PERALKALIC/SHOSHONITICPLUTONS
B- Cachoelnnha Solguelro
[~
ALGUEIROGROUP
(Schists Gnmsses)
[ ~ C A L C ALKALIC PLUTONS
C Rmcho do Ponta[
Fig 1 (right) The Central structural domain m the Borborema province, northeastern Brazil (modified from Santos et al,
1984 ) (left) Slmphfied geological map of the Cachoelrlnha-Salguexro foldbelt emphasizing the main groups of granltoid plutons (modified from Sial and Ferrelra, 1990)
287
iS predominantly composed of rocks with uniform texture and simple mineralogy Much of the
bathohth is composed of equigranular, mediumgrained, leucocratlc alkali-feldspar syenltes, m
which feldspar and chnopyroxene rarely exceed
a few millimeters in size The predominant minerals are perthltlC mxcrocllne and aeglrlne-auglte, with variable amounts of quartz, sphene,
apatlte, blue amphibole (formed at the expense
ofpyroxene) and magnetite Brown mica is present locally
Syenite has very high K20 (up to 12 8 wt %)
and K20/Na20 ratios (up to 6 3), leading to
their classification as ultrapotasslc, as defined by
Foley et al (1987) The syenltes do not match
one of the criteria (MgO> 3 wt %) for ultrapotasslc characterization as defined by Foley et al
(1987) Nevertheless, the term ultrapotasslc ~s
maintained because Foley and co-authors also
termed ultrapotasslc the most differentiated
members (trachytes) of some ultrapotassxc
suites, which have Mg-numbers similar to those
of the Tnunfo rocks
Late-stage, finer-grained syenltlC and pegmatitlC dikes are locally found cutting the Trlunfo
syenite Despite their different grain size and dike
nature, they have the same mineralogy as the host
syenltes (K-feldspar + aegirlne-augxte)
Numerous pyroxenite inclusions occur
throughout the bathohth. Most are oval-shaped
with their lengths, which ranges from a few centimeters to one meter, paralleling the flow fohatlon of the host syenite. They have about the same
grain size as the host syenite, against which they
have sharp contacts They consist mostly of euhedral to subhedral aeglrine-auglte, sphene and
apatlte Blue amphibole occurs infrequently replacing pyroxene along rims Mxcrochne and interstitial quartz, although rare, occur in some
samples
t~
L~
Fig 2 (A) Pyroxenlte inclusion in the Tnunfo syenite, with sharp contacts and smooth outhnes, (B,C) syn-plutonlc pyroxemte
dikes, (D) late-stage pyroxemte dike Spikes of dike material invade the host syemte, (E) mixed rock inclusion in the syenite
showing emulsion-like texture, suggestive of its splitting into syemtlc (light) and pyroxemtlc (dark) magmas, as shown in (F)
291
Table 1
Representative chemical compositions and mineral formulae of pyroxene of the Trlunfo bathohth, northeastern Brazil Proportions of ferric and ferrous iron were estxmated based on the method by Lmdsley and Anderson ( 1973 )
sample
pomt
SiO 2
T10-~
A1203
FeOt
MgO
CaO
Na20
K20
MnO
Total
TRF-28
PTR-28
MTR-28
52 40
0 20
0 60
17 50
7 90
15 80
5 10
0 30
99 80
52 50
0 50
0 40
15 80
9 20
16 50
4 60
0 30
99 80
52 60
0 20
0 20
18 I0
8 50
16 40
5 00
0 03
0 40
99 73
53 30
0 40
0 50
14 80
10 00
14 70
4 40
0 03
0 30
100 13
53 50
0 40
0 40
15 60
10 10
15 70
4 30
0 02
0 30
100 32
54 20
0 20
0 60
12 80
11 70
17 60
3 30
0 03
0 20
100 63
2 04
2 03
2 03
2 04
2 03
$1
A1TM
Sum
2 03
.
2 03
AIw
Fe 3+
T1
Mg
Fe 2
Sum
Fe 2+
Mn
Ca
Na
Sum
2 02
2 02
2 04
.
2 04
0 03
0 33
0 01
0 46
0 17
1 00
0 02
0 34
0 01
0 53
0 10
1 00
0 01
0 34
0 01
0 49
0 15
1 00
0 02
0 29
0 01
0 57
0 11
1 00
0 02
0 28
0 01
0 57
0 12
1 00
0 02
0 20
0 01
0 65
0 12
1 00
0 07
0 01
0 66
0 38
1 12
0 07
0 01
0 68
0 34
1 10
0 10
0 01
0 61
0 37
1 09
0 07
0 01
0 67
0 33
1 08
0 10
0 01
0 64
0 32
1 07
0 08
0 01
0 71
0 24
1 04
2 03
.
lte a n d s y e n i t e r e s p o n d e d p l a s t i c a l l y d u r i n g
intrusion,
( 4 ) T h e t e x t u r e o f t h e i n c l u s i o n is u n i f o r m l y
g r a n u l a r w i t h s o m e a l i g n m e n t o f p y r o x e n e crystals p a r a l l e l to t h e flow f o h a t i o n ,
(5) The mineral assemblage of the inclusions
is t h e s a m e as t h a t o f t h e h o s t s y e n i t e , b u t t h e
p r o p o r t i o n s o f t h e m i n e r a l s differ,
( 6 ) I n m o s t cases, t h e t w o m a g m a s h a v e retamed their identity with almost no mechanical
mixing or chemical diffusion,
(7) No quench textures of the inclusions are
o b s e r v e d a l o n g t h e m a r g i n s M o r e o v e r , a p a t l t e is
n o t a c l c u l a r in t h e p y r o x e n l t e , b u t f o r m s large
e u h e d r a l c r y s t a l s a b o u t t h e s a m e size as t h o s e o f
the clinopyroxene
T h e p r e s e n c e o f p y r o x e n l t e also as s y n - p l u -
292
Q (Wo,En, Fs)
AEGIRINE
.
\,Ae
Fig 3 Compositional variation of chnopyroxenes of the T n u n f o bathohth m the J d - Q - A e diagram F~elds and nomenclature
from M o n m o t o ( 19 8 8 ) Asterisk = syenite, square = pyroxenlte, trmngle = mixed rock
tonic and late-stage dikes argues for contemporaneous nature of the two hqulds Most pyroxenlte dikes are up to 4 m long and up to 20 cm wide
and within them pyroxene grains have random
orientation Generally the flow foliation of the
host syenite is oblique to the strike of the dikes
but does not cut the dike itself Locally, the dikes
are disrupted and offset, but their terminations
are smooth (Fig 2b, c) Composite dikes having
pyroxenitlc margins and coarse-grained syenltlC
cores are also common (Fig 2d) Altogether,
these field relations are suggestive of two contemporaneous liquids (e g Rogers and Bird,,
1987, Vernon, 1983)
Furthermore, a "mixed" rock found in some
exposures suggests that these two liquids had a
common parental magma This rock has an ocellar-hke texture, with spherical mihmeter-sized
syenite ocelh surrounded by pyroxenlte This
texture could be interpreted as an "emulsion", a
mixture of small irregular drops of one liquid in
the other (Fig 2e, f )
It has been noted that unmlxlng initiates with
separation of rounded globules of one phase in a
293
Table 2
Representative chemical compositions and mineral formulae of amphiboles of the Trlunfo bathohth, northeastern Brazil Proportions of ferric and ferrous iron were estimated based on the method by Robinson et al (1982)
sample
pomt
S10 2
TIO2
A1203
FeO t
MgO
CaO
Na20
K20
MnO
total
S1
AITM
Sum
A1vx
Cr
T1
Fe 3+
Mg
Fe z+
Sum
Fe 2+
Mn
Ca
Na
Sum
Na
K
Sum
TRF-28
PTR-28
MTR-28
52 40
0 70
1 80
12 70
1600
6 00
5 40
2 60
0 30
97 90
52 60
0 80
1 60
13 00
1550
6 00
5 40
2 30
0 40
97 60
56 40
0 04
0 20
8 90
1870
5 60
5 20
1 70
0 50
97 24
56 10
0 06
0 20
10 00
1760
5 70
5 80
1 50
0 50
97 46
55 30
0 20
0 60
8 90
1830
6 00
4 90
2 30
0 40
96 90
55 80
0 20
0 50
9 70
1800
5 90
5 50
2 20
0 40
98 20
7 66
0 34
8 O0
0 07
008
3 48
1 37
5 00
011
0 04
0 94
0 91
2 00
0 63
0 48
1 11
7 69
0 31
8 O0
0 01
0 01
013
3 39
1 46
5 00
0 05
0 94
1 01
2 00
0 51
0 43
094
8 05
8 05
0 04
0 01
8 04
8 04
0 03
0 01
027
3 77
0 92
5 00
001
0 06
0 88
1 05
2 00
0 56
0 28
084
7 95
0 05
8 O0
0 06
0 01
0 02
028
3 93
0 70
5 00
009
0 93
0 98
2 00
0 40
0 42
082
7 96
0 04
8 O0
0 05
0 02
011
3 83
0 99
5 00
005
0 05
0 91
0 99
2 00
0 53
0 40
093
023
3 98
0 75
5 00
008
0 06
0 85
1 01
2 00
0 44
0 30
074
pale-green cores and darker green rims The zoning is characterized by enrichment toward the rim
i n F e 3 + and Na and depletion in Ca and Mg The
pyroxene is slhca-saturated, with extremely low
A1 content (0 2-1 4%), and is a calcxc-sodlc aegmne-auglte according to Morlmoto's (1988)
nomenclature (Fig 3)
Amphibole in the three rock types is late-stage,
replaces aegmne-auglte either along rims or
cleavages and fractures It is characterized by
h i g h S102, lOW A 1 2 0 3 and T 1 0 2 contents, and low
Mg/Fe* ratios (Table 2) K20 content IS relatively h i g h (most values 2 wt %) filling 43-56%
of total alkali in the A-site of the amphibole
structure They are mostly K-rich rlchterite, according to the classification ofLeake ( 1978 )
294
Table 3
Representative bulk rock major element analyses and CIPW norms from rocks of the Tnunfo bathohth, northeastern Brazil
Oxide
TRF-01
TRF-I 1
TRF-28
TRF-31
PTR-02
PTR-11
PTR-28
MTR-28
61 10
0 59
15 40
2 20
1 00
0 87
2 70
2 40
12 80
0 32
0 48
< 0 05
011
0 13
100 15
59 60
0 46
14 90
3 10
1 15
1 10
2 60
3 80
11 60
0 28
0 51
< 0 05
015
0 18
99 78
59 00
0 41
13 10
3 00
2 20
2 30
4 80
2 60
10 40
0 77
0 45
0 65
015
0 11
99 94
57 60
0 65
12 80
3 50
1 56
2 50
5 30
3 30
10 70
0 87
0 55
0 10
045
003
99 91
50 00
2 20
0 78
10 30
8 20
5 80
16 00
4 10
0 32
1 10
0 08
0 20
029
027
100 22
52 40
1 80
3 30
9 80
5 40
7 80
11 00
4 60
2 20
0 46
0 15
0 20
042
0 16
100 07
49 50
1 50
0 75
11 70
4 10
7 90
16 80
4 90
0 23
1 50
0 01
0 20
042
006
99 44
56 00
0 34
8 60
5 80
2 90
4 30
9 80
3 20
6 50
1 20
0 57
0 40
004
0 10
99 94
1 16
82 72
76 12
495
1 65
6 40
1 20
.
4 70
1 63
146
.
.
126
78 24
69 32
505
3 87
9 07
2 33
186
71 43
1 33
67 28
301
17 82
61 88
955
8 74
0 62
.
7 83
4 21
1 33
0 82
0 56
0 38
.
.
63 21
909
7 16
301
1 90
224
.
28 77
-
11 10
3 45
1 37
147
.
7 96
5 14
0 05
3 26
097
1 24
0 48
143
46 82
38 71
811
-
(wt%)
S~O2
T102
A1203
Fe203
FeO
MgO
CaO
Na20
K20
P205
BaO
CO2
H20+
H20-Total
al
d i
q
or
ab
lc
ne
ac
ns
ks
dl-dl
&-hd
hy-en
hy-fs
fo
ta
wo
mt
hm
iI
ap
cc
.
5 98
2 57
026
.
.
.
0
6
10
2
.
13
3
0
-
63
44
25
39
13 07
475
.
.
28 51
0 47
.
33
34
09
31 35
22 44
247
061
30 49
10 41
4 70
1 84
0 49
0 21
-
16 89
32 67
9 16
0 26
0 12
0 23
0 12
001
1 13
0 88
0 78
1 25
4 20
3 44
0 65
0 76
-
0 67
-
1 84
149
2 09
-
2 62
046
1 10
046
0 55
-
2 87
082
295
Table 4
Representative bulk rock trace element analyses of rocks from the Trlunfo bathohth, northeastern Brazd
Element
( ppm )
TRF-11
TRF-28
TRF-31
PTR-02
PTR-28
MTR-28
Nb
Y
Rb
Sr
Zr
Ba
Th
Ta
La
Ce
Nd
Sm
Eu
Gd
Dv
Ho
Er
Yb
Lu
REE
Eu/Eu*
< 20
< 10
240
750
27
5100
nd
nd
33 29
56 50
27 85
6 64
1 18
3 68
1 83
036
0 85
0 59
0 16
132 93
0 66
24
44
250
970
160
4000
<15
<15
53 25
112 90
55 75
9 80
2 14
6 21
4 13
068
1 49
1 34
0 19
247 88
0 78
32
40
270
1350
142
5500
415
<15
72 80
139 60
72 30
17 50
3 30
10 80
6 10
100
2 20
1 60
0 22
327 42
0 72
34
170
20
740
290
700
<15
<15
134 30
326 00
173 30
34 80
7 94
23 66
17 32
311
7 66
6 10
0 86
735 05
0 80
33
52
< 10
2360
250
1070
<15
<15
108 50
246 70
133 00
25 23
5 65
16 20
10 79
198
4 58
3 87
0 66
557 16
0 85
20
40
140
1000
210
5700
<15
<15
76 92
163 50
78 03
13 27
3 13
8 78
5 09
090
2 04
1 73
0 30
353 69
0 83
296
o
0E
cC
'/
0
L~
X
o,
001
S,
A'I
I<
TI
Fes* Fez* Mg
Co
No
Tnunfo syenite and pyroxenite are characterized by overall enrichment in REE relative to
chondrlte abundance, with greater enrichment in
the pyroxenlte (up to about 1000 ppm) relative
to syenite (up to 370 ppm) They have similar
chondrite-normahzed REE patterns with negative, almost parallel slopes, laclong significant Eu
anomaly (Fig 8) The REE data further refute
any model involving fractlonatlon or partial
melting, which, in either case, yields increasing
enrichment in more felslc members The opposite case is observed here Moreover, the mixed
rock, with REE concentrations between the average concentrations of the two end-members,
has a general pattern similar to the patterns for
the other rocks, which is compatible with
unmlxing
6 3 Oxygen tsotopes
Whole rock and mineral separates were analyzed at the Stable Isotope Laboratory of the Department of Geology, University of Georgia
(USA), using fluorine as reagent Isotopic values are reported in permll relative to SMOW, and
displayed in Table 4
Whole-rock samples analyzed have a broad
range of JlS O values, between + 1 8 and + 9 6,
indicating that they cannot be primary magmatlc values In order to estimate the original
isotopic values, the j180 of chnopyroxene was
used, because in the absence of modal quartz, this
phase is one of the most resistant minerals to '80
exchange To calculate magmatic values, a wholerock/chnopyroxene J ' 8 0
fractlonatlon of
+0.25%0 was assumed (Taylor et al, 1979,
1984)
The corrected isotopic compositions are remarkably uniform with a total J~80 range from
297
FeOt + T)O2+
Na20 K20 *
StO2
AI203 + MgO
Fig 5 Analyses of the T n u n f o syemte and pyroxemte plotted in the S 1 0 2 ( N a z O + K 2 0 + M g O + A 1 2 0 3 ) ( FeO t + ZlO2 + CaO + P205 ) (wt %) diagram The immiscibility field is from Roedder ( 195 l, in Phllpotts, 1982 ), for the system
fayahte-leuclte-sxhca circle = syenite, dot = pyroxenxte
I0-
~12
~IOIK
L~
X
r~
(,.)
o
r'r"
,t
OI
ox6_
~......--~
(D
Sm
Yb
"K-
L.U
M "~
2-
ool
B~ Rb
Lo c.
s'r N. sm z.
~ T,
Fig 6 Element concentrations in syemte (circle) and pyroxenite (asterisk) normalized to the corresponding concentrations in the mixed rock, from site 28 (samples TRF-28,
PTR28 and MTR-28, Table 4)
o
oo
o'~
,~
,'s
2'o
2'~
3'o
3'5
4'o
PYROXENITE / S Y E N I T E
298
Table 5
for pyroxene
Sample
w r 180
Qz
K-spar
TRF-01
TRF-03
TRF-04
TRF-05
TRF-11
TRF-13
TRF-14
TRF-18
TRF-19
TRF-21
TRF-22
TRF-27
TRF-31
TRF-35
TRF-41
TRF-47
TRF-57
PTRF-28
TRF-28C
MTR-28
6 8
52
6 8
9 1
94
79
78
4 1
32
74
9 6
8 7
9 5
17
7 7
76
8 1
.
.
.
-
.
.
.
.
.
.
.
8 3
78
80
7 8
80
80
82
80
82
6
8
8
7
8
7
6
8
8
8
8
8
Syenite
Syenite
Syenite
Syenite
Syenite
S :enlte
S :enlte
S,enlte
S :enlte
S ,enite
S :emte
S :enlte
S :enite
S enlte
S ,enite
S :enite
S :enite
P 'roxemte (enclave)
P : o x e m t e (late dike)
M i x e d rock
2 2
.
.
.
.
-12
.
8 1
rock type
95
89
.
w r *~80
CPX
6
2
3
9
0
9
9
5
5
2
2
1
67
69
Table 6
R b - S r isotope data for rocks o f t h e T r l u n f o b a t h o h t h , n o r t h e a s t e r n Brazil Except for the T r l u n f o syenites, all m m a l ratios were
calculated a s s u m i n g t h e s a m e age as for the T n u n f o syenltes
Sample
Rb(ppm)
Sr(ppm)
Rb/Sr
87Rb/S6Sr
875r/86Sr
875r/86Sr),
Rock type
TRF-12
TRF-13
TRF-14
TRF-22
TRF-25
TRF-31
PTRF-28
282
322
343
238
255
371
7
676
649
597
1401
895
1936
3306
0
0
0
0
0
0
0
1 20891
1 43659
1 66006
0 49171
0 82586
0 55539
0 00637
0
0
0
0
0
0
0
0
0
0
0
0
0
0
Syenite
Syenite
Syemte
Syenite
Syenite
Syenite
Pyroxenite
5
6
0
2
5
8
3
2
7
7
7
2
8
8
42
50
57
17
28
19
00
71966
72144
72359
71383
71658
71397
71014
7096
7095
7098
7097
7097
7093
7101
Table 7
S m - N d isotope d a t a for rocks o f t h e T n u n f o bathollth, n o r t h e a s t e r n Brazil T h e initial 143Nd/144Nda n d N d were c o m p u t e d
a s s u m i n g a 600 M a age, relative to a chondrltlC reservoir with present-day values o f 143Nd/144Nd=0 51264 a n d 147Sm/
144Nd=0 1966
Sample
Sm
(ppm)
Nd
(ppm)
1475m/144Nd
143Nd/la4Nd
eNd
TRF-II
TRF-12
TRF-22
TRF-25
PTR-54
4
7
20
12
13
25
40
108
63
62
0
0
0
0
0
0
0
0
0
0
-15
- 15
- 15
-17
-16
80
95
90
00
20
3
3
4
0
8
1146
0939
1168
1155
1265
511504
511454
511524
511440
511538
9
3
7
2
1
TCHUR
(Ma)
TDM
(Ma)
2104
1756
2124
2246
2381
2382
2027
2405
2507
2654
299
6 4 Rubtdtum-stronttum
n e o d y m t u m tsotopes
JO0
1 iio:i:i::
,
LO
Ce
NdSm
EuGd
Dy
HoEr
Yb
t
0730
572
andsamartum-
Me
(87Sr/a6Sr)l
709B
0 725
0720
~0
a0
715
07tO
O 705
0 700
O0
04
oa
~2
Ja
zo
24
a7Rb / 86 S r
Fig 9 Rb-Sr lsochronfor syemtesandpyroxenlte(Y-axissample) oftheTrmnfobathohth
300
form 87Sr/86Sr ratio, around 0 710, based primarily on the pyroxenite samples, which have
higher Mg number, CaO and Sr contents (i e
least susceptible to Sr isotopic contamination)
At 583 Ma lmtial 143Nd/144Nd ratios for the
Triunfo syenite and pyroxenlte are very uniform, lying in a narrow range from 0.510999 to
0 511086, further supportive of a co-magmatic
relation of both rock types The S m / N d ratios
are also very uniform, about 0.19, lower than the
ratio for C H U R ( = 0 31, DePaolo, 1988), and
compatible with a LILE-enrlched source
Regarding that (a) pyroxenlte magmas are
usually believed to be mantle derived, (b) the
presence of mica pyroxenlte xenohths in these
syenltes (Ferrelra and Sial, 1994) originated
from the mantle source, as elsewhere (e g Lloyd
et al, 1987), and that (c) most authors (e g
Foley et al, 1987) consider ultrapotassic magmas derived from enriched mantle source, one
rules out the continental crust as the source for
the magma under consideration, eNd values relative to a chondrltic reservoir are all strongly
negative (ca - 15 to - 18), implying an old,
LREE-enrlched source for these rocks Therefore, one considers that the data are suggestive
of magma production within the ancient continental hthospherlc mantle Nd model age, relative to chondnt~c reservoir, averages 2 1 Ga, and
thus indicates an Early Proterozolc age for the
generation of the old, enriched-mantle domain
Dr R V Fodor for his assistance. An earlier versxon of the manuscript was reviewed by Dr L
Anderson, and substantial improvement was
made as a result of the thoughtful criticism of Dr.
A R Philpotts
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