Professional Documents
Culture Documents
Mechanical processes
wear
Chemical processes
oxidation
electrochemical
corrosion
polymer
degradation
combinations
and
synergies
Resources
Callister chapter 17 (6th edition)
chapter 18 (5th edition)
J.C. Scully: Fundamentals of corrosion
(Pergamon Press, 1966 (1st edition), 1975
(2nd edition))
300 GJ/tonne
Al ingot
base metals
Gold
Platinum
Silver
Copper
Lead
Tin
Nickel
Iron
Zinc
Aluminium
Magnesium
Sodium
(based on standard
electrode potentials)
metal
air
Oxidation: examples
Aluminium: oxide film is of high quality protects
underlying metal
Magnesium: low-quality oxide film, with cracks and
pores high oxidation rates
Stainless steel: contains Cr, which forms protective
and highly adherent Cr2O3 film
etc etc
Direct losses
Indirect losses
plant shutdown
loss of product e.g. in pipes
loss of efficiency
contamination of product
prevention measures
e-
e-
M2+
e-
eM2+
2H+ +2e
H2
2H2O + O2 + 4e
e-
eM2+
4OH
Corrosion cell
M
e-
M2+
econductive solution
(electrolyte)
M2+
e-
M2+ + 2e
M (reduction reaction)
and
Reactivity of metals
noble metals
base metals
Metal
Standard
electrode
potential
Gold
+1.4
Platinum
+1.2
Copper
+0.34
Iron
-0.44
Aluminium
-1.7
Magnesium
-2.3
Sodium
-2.7
low reactivity
high reactivity
and
_
2H+ + 2e
H2 (reduction reaction)
H2
ee-
Reactivity of metals
noble metals
base metals
Metal
Standard
electrode
potential
Gold
+1.4
Platinum
+1.2
Copper
+0.34
Iron
-0.44
Aluminium
-1.7
Magnesium
-2.3
Sodium
-2.7
oxygen reduction
hydrogen evolution
metal
electrolyte
Corrosion types
Uniform corrosion
Oxidation and reduction reactions
occur randomly across whole
surface.
Corrosion process is predictable and
unproblematic.
Localised corrosion
Oxidation reaction concentrated at one
area of surface.
Major problem, because component can
fail without warning and even at low
overall corrosion rates.
Crevice corrosion
Occurs in water when oxygen content varies across component
surface e.g. in crevices around mechanical joints or under dirt.
metal dissolution
cathodic reaction
Pitting corrosion
Similar to crevice corrosion.
Arises from local breakdown in protective oxide film
for aluminium, stainless steel
_
Pitting promoted by presence of Cl ions.
cathodic reaction
metal dissolution
problem
cathodic reaction
Galvanic corrosion
Occurs when dissimilar metals are in electrical contact e.g.
steel screws in brass component, copper and steel tubing in
radiator
metal
dissolution
Fe
_
e
Brass
cathodic
reaction
Fe
Brass
Cathodic protection
Aim is to bring potential below standard electrode potential
_
prevent anodic reaction (M
M2+ + 2e )
Connect to external dc power source
Connect to more reactive metal (sacrificial anode)
steel pipe
coated Cu
wire
Mg anode
Polymer degradation
Behaviour highly specific to individual polymer
General trends:
Resistant to attack by acids, alkalis and salt water
oxygen
UV light
heat
ozone
x-rays
partial dissolution /
evaporation
bond rupture (scission)
cross-linking
discoloration
surface cracking
embrittlement
loss