Professional Documents
Culture Documents
Rev
Date
Description
Author
Sponsor
10/2006
Initial release
RYOS
DCOC
12/2008
September 2006
CWAN
1 of 12
FFS-SU-5221
CONTENTS
1.0
Scope ..........................................................................................................................3
2.0
References ..................................................................................................................3
2.1 ......Purchaser Documents ......................................................................................3
2.2 ......Industry Codes and Standards .........................................................................3
3.0
4.0
5.0
6.0
7.0
8.0
9.0
10.0
Workmanship ...........................................................................................................11
11.0
Safety ........................................................................................................................11
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FFS-SU-5221
SCOPE
1. This specification sets forth the minimum requirements for the manufacture of cast galvanic
aluminum standoff anodes for offshore applications.
2. Any exceptions to this specification requested by the manufacturer shall be stated at the time
of bid.
2.0
REFERENCES
2.1
Purchaser Documents
FFS-DS-5221
2.2
Data Sheet for Aluminum Alloy Anodes for Offshore Platform Cathodic
Protection
A 53
D 1141
TM0190
SPECIFICATION REVIEW
1. Prior to award of the contract for anode manufacture, Purchaser reserves the right to have all
bidders attend a meeting to review the specifications.
2. At this review meeting any exceptions to this specification will be discussed, and production
schedules finalized.
4.0
PHYSICAL SPECIFICATIONS
Except as modified below, the manufacture of anodes shall be in accordance with the most
up-to-date version of NACE RP 0387.
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FFS-SU-5221
Anode Cores
1. The core shall be carbon steel seamless or ERW pipe which is in compliance with the latest
revision of any of the following specifications: ASTM A 106 Grade B, ASTM A 53 Grade B,
or API 5L Grade B PSL1 or PSL2.
2. Cores shall be of the nominal diameter shown on the bid drawings and shall be a single piece
of weldable pipe Schedule 80 or heavier. Core lengths which contain a butt weld shall not be
allowed.
3. Unless otherwise specified, straight pipe cores shall protrude from the end faces of the anode
as shown in Appendix A.
4. The core diameter should not exceed 50 percent of the anode vertical or horizontal centerline
cross section dimension. Additionally, the minimum alloy cover on the anode core shall be
two inches to help minimize casting defects from shrinkage during the manufacturing process.
5. Core pipe shall be new and of prime quality.
a. Each anode core shall be marked with the anodes unique heat and sequence numbers, and
with the manufacturers initials, such that the marking is visible after casting of the anode.
b. For heat-treated anodes, a heat-treatment batch number shall also be marked.
c. These markings shall agree with the mill certificates which will also be provided.
6. Purchaser reserves the right to inspect the pipe core material.
a. Pipe that has been remarked, pipe without markings or pipe with illegible markings will be
rejected.
b. Pipe that is cut prior to inspection by Purchaser or its representatives will be rejected.
7. The anode cores shall be free from oil, grease, rust, foreign matter, sharp corners or anything
likely to compromise the bonding of the aluminum to the core. At the time of casting, the core
pipe condition shall have been blasted and maintained to meet the requirements of
NACE 2/SSPC-SP 10.
8. The core shall be positioned within the anode mold 0.25 inch of the centerline of the casting
cross section. In the finished anode, the core shall be 0.5 inch of the specified location. The
core shall extend through the ends of the anode.
4.2
Casting
1. Each anode shall have been cast in one pour.
2. Intermediate solidifications shall not be acceptable.
4.3
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FFS-SU-5221
Dimensional Tolerance
The anodes shall be cast within the tolerances shown in Table 1.
Table 1:
Casting Tolerances
Anode length:
1/2 inch
Core length:
1/2 inch
1/4 inch
Straightness shall not deviate from the longitudinal axis by more than 1 percent of
nominal anode length.
4.5
Casting Defects
The following casting defects shall result in rejection of the anode:
1. Anode weights or dimensions outside of tolerance.
2. Cold laps not metallurgically bonded to the anode.
3. Shrinkage cavities shall be limited to one face of the anode only and shall not exceed 1/2 inch
in depth for anodes up to 400 pounds net weight or 3/4 inch in depth for anodes exceeding
400 pounds net weight.
4. Cavities, excluding shrinkage cavities on the top cast surface of the anode, which exceed
1/2 inch length or diameter and 1/4 inch deep.
5. Slag or non-metallic inclusions covering more than 1 percent of the anode surface.
6. Any mechanical treatment to the anode such as peening, grinding or filling which may be
construed as an attempt to mask casting defects.
7. Longitudinal cracks exceeding 1/8 inches wide and 6 inches length.
8. Transverse cracks greater than 3/16 inch wide at the surface of the anode.
9. Transverse cracks which extend around more than two complete adjacent surfaces of the
anode.
10. Cracks that intersect or can be projected to intersect in such a manner that loss of anode could
result.
4.6
Marking
1. The following information shall be metal stamped in letters 1/8 inch high or greater onto the
aluminum anode end:
a. heat number
b. anode number (pouring sequence)
c. manufacturers initials
2. Order number or other identification (such as color code), if specified, to distinguish anode
sizes or alloys supplied by manufacturer shall also be marked onto each anode core in such a
way as to remain visible through to the installation stage.
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CHEMICAL COMPOSITION
5.1
Composition
FFS-SU-5221
The alloy used in the manufacture of the anodes shall be in accordance with the requirements of
this specification and shall comply with the Purchaser approved anode chemistry described in
Table 2.
Table 2:
ELEMENT
Minimum
(% by wt)
Maximum
(% by wt)
Zinc (Zn)
4.75
5.75
Indium (In)
0.016
0.025
0.08
0.12
Iron (Fe)
0.06
Copper (Cu)
0.003
Cadmium (Cd)
0.002
0.02 each
Tin (Sn)
Silicon (Si)
Other
elements1
5.2
0.05
Balance
Balance
Testing
It is the anode manufacturers responsibility to conduct all testing and inspections as specified
herein. Purchaser, or a representative of its choice, may witness all and any phases of testing and
inspection.
5.2.1
Methods
The following methods of chemical assay are acceptable:
1. atomic absorption
2. optical emission spectrometer
3. inductively coupled plasma
5.2.2
Equipment Calibration
1. The method and calibration standards used to calibrate the chemical assay equipment
must be available for review by Purchaser, or a representative of its choice.
2. Purchaser reserves the right to provide calibration standards for the chemical assay
equipment and have the equipment calibrated to those standards without cost to
Purchaser.
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FFS-SU-5221
Sampling Frequency
1. Samples for chemical assay analysis shall be collected at three intervals for each heat,
or each batch of heats representing 5 tons of produced alloy.
2. Samples shall be taken from the start, middle, and end of pour.
3. The chemical composition of all three samples shall be tested and recorded.
4. Test samples and test data are to be retained by the manufacturer for 5 years from the
date of anode delivery.
5.2.4
Acceptance Criteria
1. All samples must show chemical composition within the limits of the specification.
2. If any sample falls outside the specification, two additional samples cut from the
anodes produced in that heat may be retested.
3. If both these cut samples are within the specification, all anodes in the heat shall be
accepted, if either of these cut samples are out of specification, all anodes in the heat
shall be rejected.
6.0
ELECTROCHEMICAL SPECIFICATIONS
6.1
Electrochemical Requirements
1. This section covers the minimum electrochemical performance requirements for the alloy and
the methods for testing.
2. The manufacturer shall submit their own published specifications, at the time of bid
presentation, for the following:
a. closed circuit potential (vs. SCE)
b. alloy energy capacity (amp-hrs/lb)
3. If the manufacturers specifications claim superior performance (i.e., more negative open
circuit potential or greater current capacity), then the manufacturers values shall apply.
4. Manufacturers values are subject to approval by Purchaser.
6.2
Accepting Values
The closed-circuit potential of the alloy shall meet the minimum criteria shown in Table 3.
Table 3:
Minimum Criteria
Alloy
Al-Zn-In
September 2006
Current Capacity
(A-hr/lb)
(A-hr/kg)
Minimum
Average
Minimum
Minimum
-1.030
-1.080
1136
2500
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FFS-SU-5221
Test Procedures
1. One sample shall be tested from each heat, or each batch of melts representing 5 tons
of produced alloy. The sample shall be representative of the finished anode material
and shall be drawn from the middle of the pour.
2. For each heat, a middle of pour sample shall be collected then stamped with the heat
number and manufacturer identity. These samples shall be provided to Purchaser at
the time of anode delivery along with all required documentation prior to payment
(see Section 5.2 of this specification).
3. The hydrogen evolution method shall not be used to qualify anodes unless otherwise
specified.
4. Tests shall be performed with a constant current density of 4 mA/in2 impressed onto
the sample from a constant current power supply.
5. Tests may be performed on either cut or as-cast surfaces. All test surfaces shall
receive a pretreatment per NACE TM 0190.
6. Tests shall be performed in a quiescent room temperature air-exposed test solution
conforming to ASTM D 1141. Test solution pH and temperature shall be recorded
daily and the solution shall be changed if the pH falls outside the range 49.
7. Potential values shall be recorded using a laboratory grade saturated calomel reference
electrode fitted with a Luggin probe, in conjunction with a high input impedance
digital voltmeter. Several readings, distributed over the sample surface, shall be
observed with the Luggin probe 1 millimeter from the anode surface, and the
minimum and average values shall be recorded.
8. A single test shall be run using a single sample for 14 days.
9. Anode potentials shall be measured at the beginning and end of an 8 hour working
day, after the initial 24 hour period and until the 14th day of monitoring.
10. The minimum and average of the readings for each sample must meet those specified
in Table 3.
11. No anodes will be shipped until the conclusion of the current capacity test, unless
otherwise approved in writing by Purchaser.
6.2.3
Test Accuracy
1. One SCE reference electrode shall be designated the primary reference, and shall not
be used for routine potential measurements.
2. Before each set of anode potential measurements, the secondary reference electrode
used for routine measurements shall be checked against the primary reference and the
potential difference recorded.
3. If the secondary reference shows a discrepancy of more than 5 mV to the primary
reference, it shall be discarded.
4. If more than one secondary reference fails this test, it may be necessary to replace the
primary reference with a new, unused SCE reference electrode.
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FFS-SU-5221
Acceptance Criteria
1. Energy capacity, determined by mass loss, shall meet a minimum of 1136 A-hrs/lb.
2. If the manufacturers standard specifications are indicative of higher values, then
those values will apply.
3. The minimum value stated applies to each independent heat.
6.3.2
where:
C = alloy capacity (A-hrs/lb)
I = current passed (amperes)
T = test duration (hours)
Wi = initial sample weight (grams)
Wf = final sample weight (grams)
3. Current Time (Coulombs) shall be determined by placing a copper coulometer in the
circuit.
a. Coulometer weights shall be reported with the sample weights.
b. Data from a digital coulometer will be accepted provided it is reported in the test
results.
6.3.3
7.0
7.1
General
1. The anode manufacturer is responsible for conducting all testing and inspections as specified
herein.
2. Purchaser, or a representative of its choice, may witness all and any phases of the testing and
inspection.
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FFS-SU-5221
Reports
1. All inspection and testing documentation shall be submitted to Purchaser and/or its designated
representative. Submission of satisfactory test documentation is a condition for shipment
release.
2. Documentation (to be retained by the manufacturer for five years) required for each heat and
for inspection and testing in accordance with this specification shall include, but not be limited
to, the following:
a. purchase order number
b. manufacturers name
c. pipe core mill certification
d. heat number, sequence number, and number of anodes per heat
e. alloy name
f.
j.
heat and sequence numbers of each rejected anode and reason for rejection
8.1
Packaging
1. Anodes shall be packed in bundles after inspection.
2. Anodes shall be adequately fastened to withstand all reasonable shipping and handling without
damage.
8.2
Shipping
1. Qualified anodes shall be shipped to the designated job site specified on the purchase order.
2. Care shall be taken to prevent the possibility of interchange with non-qualified anodes.
3. The bill of lading must clearly show the number of anodes shipped and their respective heat
and sequence identification numbers.
9.0
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FFS-SU-5221
WORKMANSHIP
Workmanship shall be in accordance with the Technical Requirements and with the requirement
that specialized tasks such as welding structural steel shall be accomplished only by suitably
qualified and certified personnel.
11.0
SAFETY
Safety shall be in accordance with the requirement that the Contractor shall select equipment and
employ installation methods that will ensure safe installation and operation of the Cathodic
Protection system.
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FFS-SU-5221
45q CORE
Approximate
Anode Gross
Weight
45o
Straight
(lb)
(lb)
450
430
A
(in)
96
B
(in)
95
C
(in)
6
725
930
860
96
95
93/4
93/4
108
1115
1350
1285
120
119
95/8
111/2
Alloy
Net
Weight
(lb)
385
830
1060
1000
G
1
120
119
Approximate Dimensions
D
E
F
H
(in)
(in)
(in)
(in)
1
3
7 /2
6 /4
108 140
9 /4
9 /16
(min)
(in)
12
Core2
(in)
2
156
12
132
182
12
132
182
12
These dimensions are approximate. The anode pour depth (and therefore top width) may be adjusted slightly to meet the critical Alloy
Net Weight specification.
2
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