Professional Documents
Culture Documents
Owner:
TRUenergy Tallawarra Pty Ltd
Contractor:
ALSTOM Power Limited
Revision History
Rev.
Revision Date
Created by
Checked by
Approved by
Description
Replaces
TWA/00/M/PG--------/DM/001
Responsible dept.
Created by
Checked by
Approved by
Format
PEE3
Schultz A.
Koerner J.
Koerner J.
A4
Originator
Document Type
Document Status
abcd
Electronically released
Title, Subtitle
Identification number
Turbo-Systems /
Power Environment
System Manual
Closed Cooling Water System
1AHA054179
Rev.
Date
Lang.
Sheet
21.11.2006
en
1/1
Copyright
All rights reserved
Copyright 2006 ALSTOM (Switzerland) Ltd.
CH-5401 Baden, Brown Boveri Strasse 7
Printed in Switzerland
We reserve all rights in this document and in the information contained herein. Reproduction, use or
disclosure to third parties without express authority is strictly forbidden.
This work, including all parts thereof, is protected by copyright. Any use of it beyond the narrow
restrictions of the copyright law without prior approval of ALSTOM (Switzerland) Ltd., CH-5401 Baden is
prohibited and subject to punishment under the applicable law.
The above pertains in particular to reproduction, translation, microfilming, and electronic data processing.
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Table of Contents
1.
2.
3.
4.
Introduction .........................................................................................................................................................15
1.1.
Purpose............................................................................................................................................................15
1.2.
1.2.1.
1.2.2.
2.2.
System Description............................................................................................................................................21
3.1.
Overview..........................................................................................................................................................21
3.2.
Components ....................................................................................................................................................21
3.3.
Normal Operation............................................................................................................................................21
Operation .............................................................................................................................................................24
4.1.
4.1.1.
4.1.2.
4.2.
4.2.1.
Cleaning ..................................................................................................................................25
4.2.2.
4.2.3.
4.2.4.
4.3.
Start-up ............................................................................................................................................................31
4.3.1.
System Start-Up......................................................................................................................31
4.3.2.
4.4.
Shut-down........................................................................................................................................................32
4.4.1.
4.4.2.
4.5.
Proper Operation.............................................................................................................................................32
4.5.1.
4.5.2.
4.5.3.
Freeze Protection....................................................................................................................33
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Table of Contents
4.5.4.
Temperature ........................................................................................................................... 33
4.5.5.
Pressure ................................................................................................................................. 33
4.5.6.
4.5.7.
4.5.8.
CCW Pumps........................................................................................................................... 34
4.5.9.
4.5.10.
CCW Intercooler water/air fans PGD11 to 16AC001/AN001 ...Error! Bookmark not defined.
4.5.11.
H2 Gas Separation.................................................................................................................. 35
4.5.12.
4.5.13.
4.5.14.
CCW Intercooler water/air and where applicable peak cooling air humidification
system with local control and remote signal exchange to DCSError! Bookmark not defined.
4.6.
4.7.
4.7.1.
4.7.2.
4.7.3.
Standby .................................................................................................................................. 35
4.7.4.
4.7.5.
4.7.6.
4.8.
5.
4.8.1.
General ................................................................................................................................... 37
4.8.2.
CCW Pump............................................................................................................................. 37
4.8.3.
4.8.4.
4.8.5.
4.8.6.
4.8.7.
Maintenance ........................................................................................................................................................39
5.1.
5.2.
System-related Maintenance..........................................................................................................................39
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5.2.1.
5.2.2.
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Table of Contents
6.
Appendices..........................................................................................................................................................40
6.1.
6.2.
6.3.
Alarm List.........................................................................................................................................................42
6.4.
6.5.
6.6.
6.7.
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Table of Contents
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List of Tables
Table 1
Table 2
Table 4
Table 5
Table 6
Table 7
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List of Tables
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List of Figures
Figure 1
Figure 2
Figure 3
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List of Figures
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System Manual
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Title
Contents
Introduction
Safety Instructions
System Description
Operation
Maintenance
Appendices
Table 1
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Preface
DANGER
Type/Source of Hazard
Hazard consequences
Steps to avoid the hazard.
WARNING indicates a potentially hazardous situation which, if not avoided, could result in
death or serious injury.
WARNING
Type/Source of Hazard
Hazard consequences
Steps to avoid the hazard.
CAUTION indicates a potentially hazardous situation which, if not avoided, may result in
minor or moderate injury. It may also be used to alert against unsafe practices.
CAUTION
Type/Source of hazard
Hazard consequences
Steps to avoid the hazard.
DAMAGE information not relevant for the safety of personnel but pointing out possible
damage to the machine is depicted as shown below.
CAUTION
Information pointing out possible damages to the Machine.
A General Note contains supplementary information of general interest for the reader.
Note
This is supplementary information for the reader.
READ INSTRUCTIONS means that it is mandatory to read the specific instructions contained
in this manual or in external reference documents.
Read instructions!
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Preface
MANDATORY ACTION symbols are used to point out instructions and information that must
be strictly followed to prevent any risk for personal safety or to avoid machine damage.
General requirement sign
Explanation
MCWS
SCWS
CCWS
DCS
GT
Gas Turbine
ST
Steam Turbine
H2
Air
MCR
KKS
PFUP
P & ID
Table 2
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Preface
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1.
Introduction
1.1.
Purpose
The closed cooling water (CCWS) fulfils the following tasks:
1.2.
Transferring waste heat from various heat sources to the once trough Main (MCWS) &
Secondary (SCWS) cooling water system via the CCW Intercooler water/water.
Keeping the CCW pressure below the GT/ST generator H2 coolers operational gas
pressure.
System Overview
The CCWS is a closed circuit protected with inhibitor against corrosion. The water of the
CCWS is circulated by the CCW pumps (PGC10/20AP001) to the various heat sources. The
heated water is returned to the CCW Intercooler water/water (PGD10/20 AC001) for cooling
down by the MCWS.
Note
For an overview of the CCWS, refer to P & ID 1AHA050085_A
1.2.1.
Main Components
The system consists of the following main components:
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1
1.2
Introduction
System Overview
1.2.2.
Heat Sources
The CCWS provides cooling to the following heat sources:
Sampling coolers for the HRSG boilers and water steam cycle QUL01
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Introduction
System Overview
1
1.2
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2.
Safety Instructions
2.1.
2.2.
CAUTION
Sodium hydroxide (NaOH)
R35: Causes severe burns
Inappropriate handling can cause serious injuries. Is harmful to the
environment.
S26: In case of contact with eyes rinse immediately with plenty of
water and seek medical advice.
S28: After contact with skin wash immediately with plenty of water.
S36/37/39: Wear suitable protective clothing, gloves and eye/face
protection.
S45: In case of accident or if you feel unwell seek medical advice
immediately (show the label where possible).
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Safety Instructions
System-specific Safety Instructions
2
2.2
WARNING
High voltage/Electrical shock
Electric motors and actuators powered with high voltage, inappropriate
handling can cause serious injuries or death.
Keep away from live parts.
Do not remove guards.
Avoid wet surfaces.
Prior to maintenance:
WARNING
Rotating or moving parts
Inappropriate handling can cause serious injuries or death.
Keep away from rotating or moving parts.
Do not remove guards.
Prior to maintenance, take effective measures to prevent rotating or
moving.
Do not modify systems or components.
The instructions of the component suppliers must be adhered to.
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2
2.2
Safety Instructions
System-specific Safety Instructions
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3.
System Description
3.1.
Overview
The CCWS is a closed water circuit. The system is protected with an inhibitor against
corrosion. The CCW pumps to the various heat sources circulate the water of the CCWS.
The heated water is returned to the tube & shell type CCW water/water Intercooler. The hot
water is cooled down by the MCWS&SCWS.
3.2.
Components
CCW pumps (PGC10AP001 and PGC20AP001)
The CCW pumps circulate the cooling water within the CCWS to the various heat sources.
CCW head tank (PGF10BB001):
The CCW head tank provides the necessary buffer volume for thermal expansion and
maintains a constant pressure in the CCWS.
CCWS chemical dosing sluice (PUN90BR002)
The CCWS chemical dosing sluice provides dosing facility for CCWS chemical conditioning.
CCW filling valve (PGF01AA003)
The CCW filling valve controls the water supply from the demineralised water supply system
in order to replenish possible water losses in the CCWS.
H2 gas separator tank (18PGM25AT001)
This tank provides the necessary separating volume if H2 is leaking into the CCWS form the
ST/GT generator H2 coolers. The H2 gas separator tank is vented via an open pipe over the
roof.
CCW flushing filter (19PGA09AT001)
The filter provides filtering facility for the CCWS initial cleaning procedures.
Tube & shell type CCW Intercoolers PGD10AC001 and PGD20AC001
The tube & shell water/water CCW Intercoolers transfer the heat from the CCWS to the
MCWS&SCWS.
3.3.
Normal Operation
During normal operation, the following main components are in service:
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3
3.3
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System Description
Normal Operation
One 100% tube & shell type CCW Intercoolers PGD10AC001 or PGD20AC001
All heat source coolers valve open, at design flow, operating at design heat load.
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System Description
Normal Operation
3
3.3
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4.
Operation
4.1.
General Information
4.1.1.
WARNING
High voltage/Electrical shock and Rotating or moving parts
For applicable Instruction, see chapter 2.2.
4.1.2.
4.2.
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Operation
Conditions Prior to Start-up
4.2.1.
4
4.2
Cleaning
Prior to filling of the CCWS the cleaning procedure has to be applied. Observe CCWS
Cleaning Procedure for the cleaning procedure. It is recommended, that the cleaning
procedure is repeated each time after major repair or maintenance activities in the CCWS.
4.2.2.
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4
4.2
Operation
Conditions Prior to Start-up
4.2.3.
Corrosion inhibitor
Observe Operating Instruction Water Chemistry and Supervision for
applied chemicals, required concentration, periodic checks, sampling
requirements, sampling valve locations, handling, safety, drainage
instructions, and discharge limitations.
Inhibitor dosing is only required when the periodic sample analysis taken at sample rack and
analyzed in the laboratory show low CCWS chemical concentration or after the CCWS has
been drained partly or completely.
The following manually applied procedure shall be used to fill small amounts of or top up
chemicals into the CCWS via the dosing sluice:
8. One of the CCW pump PGC10AP001 or PGC20AP001 must be in operation.
9. Close the isolating valves PUN90AA001 and PUN90AA002
10. Open the dosing valve PUN90AA010
11. Open the drain valve PUN90AA202 for draining the sluice content into a bucket or barrel.
12. Close the drain valve PUN90AA202.
13. Open vent valve PUN90AA201.
14. Fill the chemical in the vessel PUN90BB010.
15. Close the dosing valve PUN90AA010
16. Open the isolating valves PUN90AA001 and PUN90AA002 for conditioning the CCWS.
Trapped air is to be released via vent valve PUN90AA201.
17. Close the isolating valves PUN90AA001 and PUN90AA002
18. Analyse the CCWS Inhibitor concentration levels and repeat aforementioned procedure
until target chemical concentration is achieved.
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Operation
Conditions Prior to Start-up
4.2.4.
4
4.2
System/Component
Status
KKS number
CCWS
PG
CCW pumps
PGC10AP001
PGC20AP001
PGB91AT001
PGB91BR002
PGB92AT001
PGB92BR002
PGD10AC001
PGD20AC001
Safety valves
PGM11AA011
PGM12AA011
PGL51AA011
PGL61AA011
Safety valves
PGM11AA010
PGM12AA010
PGM21AA010
PGM22AA010
PGM23AA010
PGM24AA010
Make-up valve
PGF01AA003
Instrumentations
various
GH
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4
4.2
Operation
Conditions Prior to Start-up
Valves
Position
KKS number
open
PGL51AA001
PGL51AA002
PGL61AA001
PGL61AA002
open
PGM11AA001
PGM11AA002
PGM12AA001
PGM12AA002
open
PGM21AA001
PGM21AA002
PGM22AA001
PGM22AA002
PGM23AA001
PGM23AA002
PGM24AA001
PGM24AA002
open
PGQ31AA001
PGQ31AA002
open
PGM50AA001
PGM50AA002
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PGM11AA001
PGM12AA001
PGM11AA002
PGM12AA002
open
PGF01AA001
PGF01AA004
open
PGB91AA001
PGA01AA002
PGB92AA001
PGA02AA002
closed
PGA09AA001
PGB90AA201
closed
PUN90AA001
PUN90AA002
PUN90AA010
PUN90AA202
PUN90AA201
Isolation valves
open
PGF50AA050
PGM40AA250
Drain valves
closed
PGA01AA201
PGA02AA201
Vent valve
closed
PGA10AA201
Drain valves
closed
PGA11AA202
PGA12AA202
Vent valves
closed
PGA11AA201
PGA12AA201
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Operation
Conditions Prior to Start-up
Valves
Position
KKS number
Vent valve
closed
PGA20AA201
Drain valve
closed
PGA20AA202
PGB90AA202
Drain valves
closed
PGL51AA201
PGL61AA201
Drain valves
closed
PGM11AA202
PGM12AA202
Vent valves
closed
PGM20AA201
PGM20AA202
PGM21AA209
PGM21AA210
PGM22AA209
PGM22AA210
PGM23AA209
PGM23AA210
PGM24AA209
PGM24AA210
Drain valves
closed
PGM20AA220
PGM25AA220
PGM25AA202
PGM25AA206
PGM21AA201
PGM22AA201
PGM23AA201
PGM24AA201
PGM21AA205
PGM22AA205
PGM23AA205
PGM24AA205
Drain valves
closed
PGQ31AA201
PGQ31AA203
Vent valve
closed
PGM30AA201
PGM39AA201
Drain valves
closed
PGM50AA203
PGM50AA204
Drrain valves
closed
PGM11AA821
PGM12AA821
open
various
closed
various
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4.2
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4
4.2
Operation
Conditions Prior to Start-up
Position
KKS number
Open
Open
PCB21AA001
PCB23AA001
Closed
PCB21AA201
Open
PGA11AA001
Open
PGA11AA002
Closed
Closed
PGD11AA201
PGD11AA202
Closed
Closed
PCB22AA001
PCB24AA001
Open
PGD22AA201
Open
PGA12AA001
Closed
PGA12AA002
Closed
Closed
PGD12AA201
PGD12AA202
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Valve
Position
KKS number
Closed
Closed
PCB21AA001
PCB23AA001
Open
PCB21AA201
Open
PGA11AA001
Closed
PGA11AA002
Closed
Closed
PGD11AA201
PGD11AA202
Open
Open
PCB22AA001
PCB24AA001
Closed
PGD22AA201
Open
PGA12AA001
Open
PGA12AA002
Closed
Closed
PGD12AA201
PGD12AA202
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Operation
Start-up
4.3.
Start-up
4.3.1.
System Start-Up
4
4.3
Start up can only be released after the CCWS and the components are
ready for operation as described in section 4.2 Conditions Prior to Startup on page 24.
The components of the CCWS must bear the following major characteristics:
CCWS filled with water and conditioned with chemicals for corrosion, properly vented,
and all valves in their required position.
Start the CCW pump (PGC10AP001 or PGC20AP001). The CCW pumps should be in
operation before the heat source systems are started/apply heat to the CCWS.
The CCW pumps are controlled by the DCS and started or stopped by the "ON/OFF"
command in the MCR. The pumps are function loop controlled. The CCW pumps must be
operated alternately.
Before start-up of the H2 generator coolers the following
venting/drainage procedure must be applied:
4.3.2.
Check CCWS operation and functions periodically by local walkabouts according to the
requirements in plant supporting documents and suppliers manuals.
Check differential pressure across the CCW pump, which is indicated on local pressure
gauges PGC10CP001, PGC10CP002, PGC20CP001 and PGC20CP002.
CCW Intercoolers
If the CCWS cold temperature (19PGA20CT001) is greater than 40 C to 45 C an alarm
will be given. The operator to check locally and take corrective action as required.
If the CCWS cold temperature (19PGA20CT001) is lower than 5 C to 10C an alarm will
be given. The operator to check locally and take corrective action as required.
It is of major importance, that after start-up of the H2 generator coolers,
when proper venting has been achieved, the following procedure must
be applied:
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4
4.4
Operation
Shut-down
4.4.
Shut-down
4.4.1.
Normal Shut-down
After the heat load has been taken away from the CCW Intercooler, the following procedure
can be applied:
Shut down the CCW pump in operation as soon as there is no residual heat or continuous
cooling requirement from the CCWS (e.g., from GT/ST generator, oil system/turning gear,
etc.).
In those cases where residual heat and/or early shut down of the CWS / CCW pumps causes
too high CCWS temperature (19PGA20CT001), then periodic manual start/stop of either
MCWS&SCWS pumps and or CCW pumps may be considered as required.
4.4.2.
Immediate Shut-down
In case of immediate shut down, all components can be shut down immediately. For
restrictions see in referenced documents specified elsewhere. For other criteria refer to
section 4.4.1 Normal Shut-down on page 32.
4.5.
Proper Operation
4.5.1.
Hydraulic Balance
The pump head/flow chart in section 6.1 Hydraulic Head/Flow Chart of CCW Pump on page
40 shows the CCW pump curves and the CCWS gradient. The pump head/flow chart
represents the total generated head of the CCW pump at various flows.
The normal operating case applies when one CCW pump is in operation. The head/flow chart
shows the pressure loss in the system against flow. Normal operating condition applies when
the level of the CCW head tank is full one CCW pump operating against one CCW Intercooler
and all the heat source coolers/valves are open.
All values and set points stated in this document are related to the turbine house finish floor
level or to the head tank bottom level. Therefore all level and pressure set points, instruments
and transmitters settings shall be corrected and compensated to the chosen reference level.
4.5.2.
Water Chemistry
The CCWS chemical balance, applied chemicals, required concentration, periodic checks,
sampling requirements, sampling valve locations, handling, safety, drainage instructions, and
discharge limitations are described in the Operating Instruction Water Chemistry and
Supervision and must be observed.
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Operation
Proper Operation
4.5.3.
4
4.5
Freeze Protection
NA
4.5.4.
Temperature
The operational supervision of CCWS temperature is done by DCS. The Operator must take
corrective actions, based on criteria, restrictions, limitations specified elsewhere.
Operation of the CCWS is possible between the following temperature:
60 C
greater than 12 C
less than 60 C
Remark:
The MCWS&SCWS side is Thermo shock treated for biocide control every two weeks for ca.
o
1 hour. During this period, the cold SCWS is increased /maintained up to 42 C respectively
o
the cold CCWS is increased /maintained up to 47 C
High CCWS Water Temperature limits for CCW Intercooler water /water
Where extended periods with high above normal heat input, high MCWS&SCWS water
temperatures, or high ambient air temperatures during either start up, normal plant operation,
shut down, cooling down, thermo shock operation or stand still periods exist, then the
operator must visually supervise and assure by manual action, that the CCWS cold water
temperatures TCCW of less than 40C is maintained.
If TCCW (19PGA20CT001) after CCW Intercooler exceeds 47 C, a hot water alarm will be
given.
The operator personnel must do the following checks or actions:
Check if the heat input from source coolers is too high and take measures.
Check if the MCWS&SCWS flow is too low and if possible throttled condenser outlet
valves.
Check if the CCW pump flow is too low and take measures.
Low CCWS Water Temperature limits for CCW Intercooler water /water
Where extended periods with low heat input and/or low MCWS&SCWS water temperatures
during either start up, normal plant operation, shut down or stand still exist, then the operator
must visually supervise and assure by manual action, that a CCWS cold water temperatures
TCCW of more than 12C is maintained. For MCWS&SCWS water temperature control see
referenced MCWS&SCWS documentation.
4.5.5.
Pressure
Operation of the CCWS is possible up to the following pressure:
Design pressure
6.0 barg
5.5 barg
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4
4.5
Operation
Proper Operation
For the reference of pressure and level set points refer to section 4.5.1 Hydraulic Balance on
page 32.
4.5.6.
4.5.7.
CCW Pumps
The CCW pumps PGC10AP001 and PGC20AP001 are used to circulate water through the
CCWS, heat source coolers, and the CCW Intercooler. During normal operation only one of
the two CCW pumps shall be in operation. For more detailed information of this components,
consult the Operation & Maintenance Manual of the supplier.
For limited rare and short term events (10 to 20 times of ca. 15 minutes), manually initiated,
supervised, and terminated parallel operation of both CCW pumps is possible for CCWS
cleaning process and flushing.
The CCW pumps are controlled by the plant DCS.
During CCW pump operation, it must be assured that the CCW pump is continuously running
within acceptable pressure and flow ranges without exceeding the operating limits as
indicated in section 6.1 Hydraulic Head/Flow Chart of CCW Pump on page 40.
4.5.8.
An alarm will be given if the level in the CCW head tank measured with PGF10CL003
reaches MIN2.
The CCW pumps are switched off for protection if the level in the CCW head tank
measured with PGF10CL002 reaches MIN1 and the level measured with PGF10CL003
reaches MIN2.
An alarm will be given if both CCW pumps are operated parallel for more than 5 minutes.
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Operation
Inadmissible Operation
4.5.9.
4
4.6
H2 Gas Separation
In order to prevent dangerous concentration of H2 gas in CCWS a H2 gas separator is
installed. The H2 gas separator is fitted with a vent pipe routed over the building roof.
4.6.
Inadmissible Operation
The following operation modes are not permitted:
Any CCW pump operation against too many closed valves or continuous operation
outside pump acceptable operating range as indicated in section 6.1 Hydraulic
Head/Flow Chart of CCW Pump on page 40
Any CCW pump operation against not open suction or discharge valve
4.7.
4.7.1.
Failure of Component
Failure and alarms of component controlled by the local control system will be indicated in the
MCR via DCS. For component failures and trouble shooting, refer to the relevant sections of
the suppliers instructions. Local checks, repairs, resetting, etc. are required within time frame
according to the relevant sections of the suppliers instructions.
4.7.2.
Long-term Shut-downs
For long term outages the instructions and the measures for long-term shutdowns of the
subsystem and the individual components must be observed. Refer to the relevant sections
of the suppliers instructions.
4.7.3.
Standby
The standby of individual components is defined in the referenced subsystem and component
operating instructions. This is an essential condition for operational standby of the system.
The standby CCW Intercooler water/water is isolated by its inlet/outlet valve and drained on
MCWS&SCWS side as mentioned in section 4.7.6 Methods of Preservation for Isolated CCW
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4
4.7
Operation
Other Operation Modes
Intercoolers on page 36.The CCW medium side remains filled and only the CCW Intercooler
outlet valve is closed.
4.7.4.
4.7.5.
4.7.6.
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Major Component Data
4.8.
4.8.1.
General
4.8.2.
4.8.3.
700
kPa
60
30 to 80
m3
CCW Pump
Configuration/duty:
2 x 100
620
m3/h
29
mWC
approx. 100
4.8.5.
kW
Configuration/duty:
2 x 100
620
m3/h
1002
m3/h
7.5
MW
33
28
0.49
bar
0.27
kPa
4.8.4.
4
4.8
Configuration:
1 x 100
Net volume:
m3
H2 Gas Separator
Configuration:
1 x 100
Net volume:
2.5
m3
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4
4.8
Operation
Major Component Data
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5.
Maintenance
5.1.
Prior to executing any maintenance work you must have read and
understood the safety instructions in chapter 2 of this manual.
Operational readiness of the system components is to be maintained by adhering to the
relevant operation & maintenance documentation supplied by the supplier, and must be
consulted before operation or maintenance begins.
5.2.
5.2.1.
System-related Maintenance
System Drainage
If inspection, maintenance, repair, or replacement require a partial or complete CCWS source
coolers or CCW Intercoolers drainage, then opening of the CCWS pipe section or component
drain and vent valves can do this.
It is not allowed to drain the chemically conditioned CCWS direct to the
waste water system. All drains from chemically conditioned CCWS must
be collected for external disposal. Disposal rules and regulations must
be observed. Follow Operating Instruction Water Chemistry and
Supervision.
5.2.2.
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6
6.1
Appendices
Hydraulic Head/Flow Chart of CCW Pump
Blank page
6.
Appendices
6.1.
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Figure 1
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Index
6.2.
Alarm List
KKS
Code
Description
Actions
PGF10CL001
>MAX1
L HEAD TK CCW
PGF10CL002
<MIN1
L HEAD TK CCW
PGF10CL003
<MIN2
L HEAD TK CCW
PGA20CT001
>MAX1
PGA20CT001
<MIN1
Table 3
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6.3.
19PUN90BR002
Operating Data:
Medium:
700 kPa
60 C
Figure 2
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Index
6.4.
Source cooler
KKS no.
ST Generator H2 coolers
ST H2 cooled Generator
brush gear cooler
ST Generator H2 seal oil coolers
GT Generator Air coolers and
lubrication oil cooler
Sample coolers W/S cycle
HP Feedwater Pump coolers
Condenser water box
evacuation system coolers
Cooler
configuration
(*)
Coolers in
@
operation
Total
Flow (*)
No x %
(*)
MKA13AC100 to AC400
MKB40AC001
4 x 25
1 x 100
4 x 25
1 x 100
MKW25/26AC001
MKP10
2 x 100
1 x 100
1 x100
3 x 50
2 x 100%
QUL01
LAC50/60/70AC001
{MAJ61/62AC001}
Total heat
load (*)
Differential
Pressure at
@ flow
m3/h
kW
kPa
379.08
20.16
4550
85
900
50
1 x 100
1 x 100
26
108
75
2010
50
210
1 x100
2 x50
1 x 100%
15.9
36
2.16
196
150
8
50
100
500
588.74
7079
+ appr.
5%
+ appr.
6%
618.18
7503.74
Total calculated
summarised CCWS flow
Approx. surplus margin
CCWS/Equipment
Design Parameters
(*) Note: All the above mentioned 3 x 50% coolers, have constant parallel flow, while heat load is applied to 2 x50% cooler only.
All the above mentioned 2 x 100% coolers, have constant parallel flow, while heat load is applied to 1 x 100% cooler only.
Table 4
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6.5.
Title
1AHA050085
P & ID CCWS PG
1AHA050297
1AHA054184_A
1AHA
1AHA
1AHA
Orifice list PG
1AHA
1AHA050587
various
Table 5
6.6.
Title
1AHA054180
1AHA049957
1AHA
1AHA 050360
1AHA
1AHA 050364
Table 6
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Index
6.7.
Catalog
Numbers:
Synonyms:
Caustic soda
Company Identification:
Acros Organics
One Reagent Lane
Fair Lawn, NJ 07410
800-ACROS-01
+32 14 57 52 11
+32 14 57 52 99
201-796-7100
800-424-9300
703-527-3887
Water
35
50 231-791-2
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Risk Phrases:
35
Section 3 - Hazards Identification
EMERGENCY OVERVIEW
Causes severe burns.
Skin:
Causes skin burns. May cause deep, penetrating ulcers of the skin.
Ingestion: Causes gastrointestinal tract burns. Causes severe pain, nausea, vomiting,
diarrhea, and shock. May cause corrosion and permanent tissue destruction
of the esophagus and digestive tract.
Inhalation: Irritation may lead to chemical pneumonitis and pulmonary edema. Causes
severe irritation of upper respiratory tract with coughing, burns, breathing
difficulty, and possible coma. Causes chemical burns to the respiratory
tract.
Chronic:
Eyes:
Skin:
Get medical aid immediately. Immediately flush skin with plenty of water
for at least 15 minutes while removing contaminated clothing and shoes.
Discard contaminated clothing in a manner which limits further
exposure.
Ingestion:
Inhalation:
Get medical aid immediately. Remove from exposure and move to fresh
air immediately. If not breathing, give artificial respiration. If breathing
is difficult, give oxygen.
Notes to
Physician:
As in any fire, wear a self-contained breathing apparatus in pressuredemand, MSHA/NIOSH (approved or equivalent), and full protective
gear. May react with metals and lead to the formation of flammable
hydrogen gas.
Extinguishing
Media:
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Index
Information:
Spills/Leaks:
Handling: Wash thoroughly after handling. Use with adequate ventilation. Do not allow
water to get into the container because of violent reaction. Do not breathe
dust, vapor, mist, or gas. Do not get in eyes, on skin, or on clothing. Use
only in a chemical fume hood.
Storage:
Store in a cool, dry place. Store in a tightly closed container. Store in a cool,
dry, well-ventilated area away from incompatible substances. Corrosives
area. Store under an inert atmosphere.
Section 8 - Exposure Controls, Personal Protection
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash
facility and a safety shower. Use adequate ventilation to keep airborne
concentrations low. Use adequate general or local exhaust ventilation to keep
airborne concentrations below the permissible exposure limits.
Exposure Limits
CAS# 1310-73-2:
United Kingdom, WEL - STEL: 2 mg/m3 STEL
United States OSHA: 2 mg/m3 TWA
Belgium - TWA: 2 mg/m3 VLE
France - VME: 2 mg/m3 VME
Germany: 2 mg/m3 TWA (inhalable fraction)
Japan: 2 mg/m3 Ceiling
Malaysia: 2 mg/m3 Ceiling
Spain: 2 mg/m3 VLA-EC
CAS# 7732-18-5:
Skin:
Clothing:
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Conditions to Avoid:
Incompatibilities with
Other Materials
Hazardous
Decomposition Products
Sodium oxide.
Hazardous
Polymerization
LD50/LC50:
RTECS:
CAS# 1310-73-2: Draize test, rabbit, eye: 400 ug Mild;
Draize test, rabbit, eye: 1% Severe;
Draize test, rabbit, eye: 50 ug/24H Severe;
Draize test, rabbit, eye: 1 mg/24H Severe;
Draize test, rabbit, skin: 500 mg/24H Severe;
.
RTECS:
CAS# 7732-18-5: Oral, rat: LD50 = >90 mL/kg;
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Index
.
Other:
Carcinogenicity: Sodium hydroxide - Not listed as a carcinogen by ACGIH, IARC, NTP,
or CA Prop 65.
Water - Not listed as a carcinogen by ACGIH, IARC, NTP, or CA Prop
65.
Other:
Not available
Section 13 - Disposal Considerations
Dispose of in a manner consistent with federal, state, and local regulations.
Section 14 - Transport Information
Shipping
Name:
Hazard
Class:
UN Number:
Packing
Group:
IATA
SODIUM HYDROXIDE
SOLUTION
8
IMO
SODIUM HYDROXIDE
SOLUTION
8
RID/ADR
SODIUM HYDROXIDE
SOLUTION
8
1824
II
1824
II
1824
II
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Index
A
abbreviations and acronyms, 13
alarm list, 42
B
block identification, 13
C
CAUTION
explanation, 12
CCW heat exchangers
proper operation, 35
standby, 36
CCW pumps
parallel operation, 34
proper operation, 34
CCW SYS
check up actions after start-up, 31
chemical conditioning, 26
cleaning procedure, 25
conditions prior to start-up, 31
conditions prior to start-up, 31
functions of main components, 21
initial filling, 25
long-term shutdowns, 36
normal operation, 21
normal shut-down, 32
chemical balance, 32
component failures, 35
compulsory reading, 11
copyright, 2
D
DAMAGE
explanation, 12
DANGER
explanation, 12
documents and diagrams from connected
systems, 45
drainage, 39
F
H
heat sources
connected to CCW SYS, 16
design and operating data, 44
high cold water temperatures, 33
hot water alarm, 33
hydraulic balance, 32
I
immediate shut down, 32
inadmissible operation, 35
isolated heat source coolers, 36
K
KKS prefix number, 13
M
main components, 15
MANDATORY ACTION
explanation, 13
manual preparation prior to start-up, 27
O
operational readiness, 39
outages, 36
R
read instructions
explanation, 13
refilling procedure, 39
related documents and diagrams, 45
S
safety instructions, 18
standby of components, 36
system pressure, 34
system tasks, 15
T
target audience, 11
TN04/0297, 18
general note
explanation, 12
user audience, 11
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Index
V
visual inspection, 39
W
explanation, 12
water chemistry, 32
water level, 34
water temperature, 33
WARNING
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