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ABSTRACT
Certain t y p e s of macromolecules a d d e d to water
a n d s a l t s o l u t i o n s flowing in turbulent motion can
reduce t h e pressure gradient. Alternatively, the
volumetric c a p a c i t y of a pipe for t h e s e f l u i d s is
i n c r e a s e d by t h e p r e s e n c e of t h e s e materials.
Examples p r e s e n t e d s h o w that the drag reduction
c a n become significant. Thus, t h e p r e s e n c e of
0.28 p e r c e n t of a gum derivative in a solution of
sodium chloride flowing a t 200 gal/min in a 1.89in. pipe y i e l d s a p r e s s u r e drop which is 0.44 of
t h e single-phase drop measured under t h e s a m e
conditions of turbulent flow; t h e addition of 0.1
p e r c e n t of a vinyl derivative t o a 1-in. w a t e r l i n e
y i e l d s a throughput c a p a c i t y zohich is 1.78 of t h e
s i n g l e p h a s e c a p a c i t y a t t h e same pressure drop.
It is further shown that t h e s e phenomena a r e
d i s t i n c t l y different from previous observations
with other c l a s s e s of non-Nezutonian systems.
There a simple lowering of friction f a c t o r s below
the l e v e l s predicted from t h e r e s i s t a n c e l a w s for
Newtonian f l u i d s is a s s o c i a t e d with a s u p p r e s s i o n
of turbulent motion. A rational p h y s i c a l explanation
f o r drag reduction is advanced. Briefly, the
proposed mechanism is a s t o r a g e by t h e molecular
e l a s t i c elements of the macromolecules i n solution
of t h e k i n e t i c energy of the turbulent motion.
INTRODUCTION
T h i s study w a s inspired by a recent review of
some paradoxical drag reduction phenomena in
turbulent pipe f1ow.l Under very moderate conditions
of turbulent flow, t h e pressure gradient n e c e s s a r y
to pump solutions containing certain s p e c i f i c
kinds of polymers, fibers and metallic s o a p s may
become appreciably lower than that required* to
pump t h e solvent, i.e., water or a low-viscosity
hydrocarbon, under identical flow r a t e s in the same
conduit. A s shown b y our review, t h i s phenomenon
of drag reduction in turbulent duct flow w a s first
noted during t h e second world war, apparently
Original manuscript received in Society of Petroleum
Engineers office Feb. 10, 1964. Revised manuskript received
June 17, 1964. Paper presented at meeting of AIChE in
Houston, Tex., Dec. 5 , 1963.
l ~ e f e r e n c e sgiven at end of paper.
SPE 867
SEPTEMBER, 1964
Materials I n v e s t i g a t e d
Six synthetic and natural polymeric materials,
representing a variety of c e l l u l o s e , vinyl and
natural gum derivatives, were investigated. T h e y
are identified a s follows: c e l l u l o s e I, c e l l u l o s e
11, vinyl I, vinyl 11, gum I and gum 11. D i s t i l l e d
water and 6 and 24 p e r cent solutions of sodium
chloride were u s e d a s solvents.
P I P E FLOW S Y S T E M
POLYMER CONC
a
0
0
loz
-a
CI
IK
4
0
Y
A
to'
, 1 1 1 1 1 1 1
100
10
12
I5
FLOW PROPERTIES OF
POLYMER SOLUTIONS
SOLVENT
n'
0.275
24KNoCI
6%
CELLULOSE 1
0.0358
0.0716
0.143
0.286
0 0358
0.0716
0.275
0.0179
0.0716
0.1433
0.0179
0.844
1.0
0.877
0.797-0.887
0.790
0.798
0.704
0.720
0.631-0.825
0.5059
0.078
0.1787
0.4296-02192
0.3911
0 . 1929
0.5515
0.781
2.525-0945
0.860
0.3105
0 459
0.4820
6 281
19. 5 4
CELLULOSE P
0.143
2i:
dr
1
1 ,
( 1 ,
I I I L
lo2
10'
0286%
o 0.286%
0.286%
NBE M.
I"
I'
1.31"
1.89"
;02
WT%
CELLULOSE n
CELLULOSE I
GUM TI
GUM I
POLYMER
I
2
3
4
5
6
- LAMINAR
10'
PRESSURE GRADIENT ( P S I 1 1 0 0 0 F T )
TABLE 1
TUBE DIA
0.0179%
0.0179%
0.0179%
0.143 %
K'
0
L
K
u
;
Y
10'
PRESSURE GRADIENT
IP S I / 1000FT)
degradation w a s a l s o encountered in t h e s e s t u d i e s .
Degradation e f f e c t s usually showed up during
the duplicate run procedure described earlier.
However, in t h e c a s e of vinyl I, degradation w a s
s o rapid and i n t e n s e a s to produce an immediate
and continued upward drift in recorded p r e s s u r e
drop a t constant flow rate. Of course, some degradation may already have occurred during the solution
preparation s t a g e . T h e gum derivatives a l s o
showed a tendency to degrade in the p r e s e n c e of high
concentrations of sodium chloride. T h e other
materials studied were definitely s t a b l e . The e f f e c t
of an electrolyte environment on drag reduction
i s illustrated in Fig. 3. Here t h e pumping charact e r i s t i c s of c e l l u l o s e I are compared i n d i s t i l l e d
water and i n a 6 per c e n t solution of sodium
chloride. Note that t h e laminar flow properties
a r e strongly affected by t h e electrolyte. T h e s e
e f f e c t s probably reflect t h e influence of t h e s a l t
on t h e expansion and contraction of t h e molecular
coils.
Some r e s u l t s on solutions of vinyl I1 a r e shown
in Fig. 4. T h i s polymer did not exhibit drag
reduction c h a r a c t e r i s t i c s within t h e region s c a n n e d
a s evidenced by t h e failure of t h e d a t a points to
c r o s s the solvent line. T h i s wholly different
behavior y i e l d s friction f a c t o r s which a r e a l s o
l e s s than t h o s e predicted from t h e r e s i s t a n c e l a w s
for Newtonian fluids. T h e r e s u l t s a r e typical of
the d a t a which form t h e b a s i s of t h e Dodge and
Metzner correlations of friction factor v s Reynolds
number, and illustrate why published correlations
of t h i s kind are not applicable t o t h e prediction of
pumping requirements for fluids exhibiting drag
reduction characteristics.
l * k - '
10'
- '
, ,,J
I+
Drag R a t i o s
FIG. 3
FLOW DIAGRAM ILLUSTRATING P U M P I N G
CHARACTERISTICS O F C E L L U L O S E I - NaC1 SOLU TIONS.
-s
10'
10'
NOTE SOLID LINES DENOTE
SMWTHED FLOW CURVES
FOR WTER IN INDICATED
TUBE SIZE
I
I00
1 1 11111
lo2
PRESSURE GRADIENT ( P S I / 1 0 0 0 F T )
10'
1 1 1 1 1 1
10'
(1) C E L L U L O S E
JI
(2) C E L L U L O S E
R) V I N Y L I
TUBE DIA.:
(4) V I N Y L I[
CONC.:
1.31''
(I) GUM I
0.275%
(21 GUM 11
(3) C E L L U L O S E I
20
40
60
80
100
120
FIG. 5
- DRAG
CELLULOSE I
----EXPERIMENTAL
REGION
----- EXTRAPOLATED REGION
III(/IIIIIIII
20
40
60
80
IW
I20
TUBE D I A :
20
40
1.89"
CONC. : 0 . 2 7 5 %
60
80
00
120
(I)
CELLULOSE
(2)
GUM I
140
I60
180
200
FIG. 8 - DRAG
RATIOS IN 24 P E R
SOLUTIONS.
C E N T NaCl
Capacity
POLYMER CONCENTRATION
(%I
FIG. 9 - E F F E C T O F P O L Y M E R CONCENTRATION
ON HYDRAULIC C A P A C I T Y A T C O N S T A N T P R E S S U R E
GRADIENT.
Proposed Mechanisms
I.
131"
VINYL
1 (0.143% WT.1
FIG. 10 - F R I C T I O N F A C T O R C O R R E L A T I O N S F O R P U R E L Y VISCOUS F L U I D S .
S E P T E M B E R , 196.2
where:
W L Y Y R : CELLULOSE
II
COWCj 0.275 X
CELLULOSE II
0.278
0.143
T U E DIA
1'
lo0
*I
1 1 ,111
10'
I ,,,mi
IO1
1 1 1 1
lo1
FIG.
% (WT.)
SYSTEM
&UM
oCELLULOSE
OVINYL
FIG. 14
II
II
SOLVENT
_L
0.286
d.w.
0.77
0.143
d.w
NONE
- G R A P H I C A L METHOD F O R DETERMINING
BOUNDARY L A Y E R C O E F F I C I E N T S .
1,
IP
a tube of length L )
observed p r e s s u r e gradient for solvent
observed p r e s s u r e gradient for polymer
solution
parameter in
n'
he
flow r a t e
<
effective s l i p velocity
boundary
Eq. 7
us
layer
coefficient,
defined b y
fluid d e n s i t y
s h e a r s t r e s s a t r a d i u s ' r of tube
rw = s h e a r s t r e s s e v a l u a t e d a t wall of tube
ACKNOWLEDGMENT
I wish t o thank R. F. Burdyn, W. R. F o s t e r and
G. C. Wallick for t h e benefit of their helpful
criticisms and advice. T h e permission of Socony
Mobil Oil Co., Inc. to publish t h i s material is a l s o
gratefully acknowledged.
N(n9
C(n )'
NOMENCLATURE
dimensionless function of flow behavior
index
dimensionless function of flow behavior
index
i n s i d e diameter of tube
f(r)
s h e a r rate at r a d i u s r of tube
f(rw)
REFERENCES
Savins, J. G.: "Some Comments on Pumping Requirements for Non-Newtonian Fluids", l o u r . Inst. Petr.
(1961) Vol. 47, 329.
Toms, B. A.: "Some Observations on t h e Flow of
Linear Polymer Solutions Through Straight T u b e s
a t Large Reynolds Numbers, Proc., F i r s t International
Congress on Rheology, Scheveningen (1949) 135.
Oldroyd, J. G.: "A Suggested Method of Detecting
Wall-Effects in Turbulent F l o w through Tubes",
Proc., F i r s t International Congress on Rheology,
Scheveningen (1949) 130.
Agoston, G. A., et aE.:L'Flow of Gasoline Thickened
by Napalm", Ind. Engr. Chem. (1954) Vol. 46, 1017.
Bundrant, C. 0. and Matthews, T. A.: "Friction L o s s
of Fracturing Fluids", P a p e r 531-G presented a t
30th Annual F a l l Meeting (Petr. Branch) AIME,
New Orleans (Oct. 2-5, 1955).
Robertson, A. A. and Mason, S. G.: "The Flow
Characteristics
of Dilute F i b e r Suspensions'*,
TAPPI (1957) Vol. 40, 326.
Ousterhout, R. S. and Hall, C. D., Jr.: "Reduction
of Friction L o s s in Fracturing Operations", Jour.
P e t . Tech. (1960) Vol. XIII, 217.
Daily, J. W. a n d Bugliarello, G.: " B a s i c Data for
Dilute F i b e r Suspensions i n Uniform Flow with
Shear", TAPPI (1961) Vol. 44, 497.
Lummus, J. L., Anderson, D. B. and Fox, J. E.,
Jr.: "New T y p e of Mud R e d u c e s Drilling Costs",
World Oil (1962) Vol. 154, 68.
Mysels, K. J.: Flow of Thickened Fluids, U . S.
P a t e n t No. 2,492,173 (1947).
Dever, C. D., Harbour, R. J. and Seifert, W. F.:
16.
17.
18.
19.
20.
21.
22.
23.
24.
25.
26.
27.
28.
29.
30.
31.
32.
33.
34.
35.
36.
37.
38.
39.
40.
41.