Page 2

Mark Scheme: Teachers version

Class 10th Nov 2015

Syllabus
0620

1 (a)
moles of CH3-CH = CH2 reacted = 1.4/42 = 0.033
[1]
maximum moles of CH3-CH(I)-CH3 that could be formed = 0.033
[1]
maximum mass of 2-iodopropane that could be formed = 5.61 g
[1]
percentage yield 4.0/5.67 x 100 = 70.5%
[1]
(b)
iron + nitric acid iron nitrate + hydrogen
[2]
(c)
number of moles of O2 formed = 0.16/24 = 0.0067/0.00667 or 1/150
number of moles of Pb(NO3)2 in the sample = 0.0133/0.013 or 1/75
mass of one mole of Pb(NO3)2 = 331 g
mass of lead(II) nitrate in the sample = 4.4(1) g
percentage of lead(II) nitrate in sample = 88.3% (allow 8889)
2 (a)
impure copper
[1]
(pure) copper
[1]
(soluble) copper salt or Cu2+
[1]
(b)
Cu - 2e Cu2+ or Cu Cu2+ + 2e
[2]
(c)
(i) cathode
(ii) pure foil: gets further copper deposit/increases in thickness/gets less shiny
[1]
impure foil: copper removed/decreases in thickness/appears cleaner
[1]
3 (a)
(i) Carbon has gained oxygen from iron (III) oxide
[1]
(b)
(i) Carbon monoxide + water carbon dioxide + hydrogen
[2]
(ii) 80
(c)
(i) Chlorine gas
[1]

Paper
4

[4]

[1]

[1]

(ii) Zinc metal

[1]
(d)
Number of moles of LiOh used = 0.062 moles
Number of moles of Li2SO4.H2O = 0.031 moles
Mass of one mole of Li2SO4.H2O = 128 grams
Maximum yield of Li2SO4.H2O = 3.96grams
Percentage yield = 55.6 %

4
Molten potassium iodide

NOT aqueous

[1]

Hydrogen
oxygen
water used up or solution becomes more concentrated or sodium chloride remains
NOT no change
If products are given as hydrogen, chlorine and sodium hydroxide then 2/3

[1]
[1]

Copper
oxygen (and water)
sulfuric acid

[1]
[1]
[1]

accept hydrogen sulfate

aqueous or dilute or concentrated potassium bromide

accept correct formulae
5
(a)

72/24 = 3 and 28/14 = 2

Mg3N2
accept just formula for [2] even with incorrect or no working

[1]

[1]

[1]
[1]

(b) Al4C3 + 12H2O = 4Al(OH)3 + 3CH4

For Al4C3 ONLY [1]

[2]

(c) (i) silicon is limiting reagent

0.07 moles of Si and 25/160 = 0.156 moles of Br2
because 0.14 (2 0.07) < 0.156

[1]
[1]
[1]

(ii) 0.07

[1]

[Total: 8]

6 (a)

1st, 3rd and 4th boxes down ticked (aqueous sodium chloride, copper and graphite)

[3]

(b) Insulator

[1]

(c)

(i) Anode

[1]

(ii) negative electrode: zinc

positive electrode: chlorine

[1]
[1]

(iii) graphite
allow: carbon

[1]

(a)
(i)

The mass of substance containing the same number of fundamental units as there are

atoms in exactly 12 grams of carbon 12

[1]
(ii)
Number of particles found in one mole of a substance.
[1]
(b) 2gm of methane and 8 gm of SO2 contain same number of molecules
[2]
(c)
(i)
Moles of calcium = 0.12 moles
[1]
(ii)
Moles of water = 0.2 moles
[1]
(iii)
Calcium is in excess as 4.8 gm of calcium gives 8.88gm of Ca(OH)2 and 3.6 gm of
water gives
7.4gm og Ca(OH)2
[2]
(v)
0.8 gm of calcium left at the end of the reaction
[1]
8 (a)
(i) Percentage of oxygen = 31.6%
(ii) Number of moles of Ti = 31.6/48 = 0.66
Number of moles of O = 31.6/16 = 1.98
(iii) The simplest whole number ratio for moles of atoms:
Fe : Ti : O
1 1
3
(iv)
Formula is FeTiO3 accept TiFeO3

[1]
[2]
[1]
[1]

(b)
(i) Chemical decomposition produced by passing an electric current through a liquid or solution
containing
ions
[1]
(ii) Anode
[1]
(iii) Hydrogen
[1]
(iv) platinum, inert
[2]
(c)
(i) Alf3
(ii) As2O5
(iii) SiBr4
(iv) Al2O3
[4]