Professional Documents
Culture Documents
1976
Introduction
The problem of hydrogen induced
cold cracking in quenched and t e m pered low alloy steels is unlikely to be
resolved without a greater understanding of both the location and the
mechanism of crack initiation and the
metallurgical response of the base
material to the thermal cycle of welding.
A typical e x a m p l e of this cold
cracking problem is the incidence of
cracking at the fusion boundary in the
apparent heat-affected zone in weldm e n t s of H Y - 8 0 , a low c a r b o n ,
quenched and tempered, low alloy
steel.
In g e n e r a l , m o s t i n v e s t i g a t o r s
(Refs. 1-5) agree that the cracking in
HY-80 is predominantly intergranular, at least in the early stages of
propagation. Although the available
evidence suggested that grain b o u n dary segregation is involved in the
cracking, the mechanism by which
the segregation arises had not been
completely resolved.
In a previous investigation at R.P.I..
utilizing special etchants, it was noted
that the fusion boundary of heterogeneous welds in HY-80 was not a
simple fusion line but rather a region
composed of; (1) an unmixed zone of
weld metal which had a composition
essentially that of the base metal and
(2) a partially melted zone (Ref. 6*).
Constitutional liquation of large sulfide inclusions and grain boundary li'Published in this issue, page 260-s
quation were identified in the partially melted zone. Sulfides that dissolved in the partially melted zone
and in the unmixed zone precipitated
in many cases as small globules at
s u b g r a i n and solidification grain
boundaries during the solidification of
the molten material.
Objective
The major objective of this investigation was to correlate the cold
cracking in HY-80 steel with identifiable metallurgical features and the
amount of hydrogen present during
welding
Materials and
Experimental Procedures
Material
Two heats of 2 in. (51 mm.) HY-80
steel plate were used in this study.
The check analyses for these two
heats are listed in Table 1; the tensile
and impact properties are given in
Table 2.
These two particular heats were
selected because of a well d o c u mented difference in their weldability
in spite of a similarity in composition.
It should be noted that Heat No.
72P305 (from here on referred to as
Heat P) has a higher C, Ni, and Cr
content than Heat No. N51755 (from
here or referred to as Heat N).
The weldability of the two heats had
been o r e v i o u s l y d e t e r m i n e d by
means of the cruciform test, in which
Heat P exhibited cracking in 73% of
the weld length in Fillet C, whereas
Heat N exhibited no cracking (Ref. 2).
These heats were part of a series of
12 heats used in a statistical inves-
tigation which showed a fair correlation between the amount of cruciform cracking and the S and Ni c o n tents of the individual heats.
Varestraint Tests of the Weld Metal
The Varestraint Test (Refs. 7, 8)
was used to compare the weld metal
hot cracking sensitivity of E11018G
bead welds made on specimens from
Heats P and N. The purpose of the
tests was to determine whether or not
dilution from the crack sensitive heat
of HY-80 would affect the hot cracking behavior of the weld metal.
For these tests, specimens 1 2 X 2
in. (305 X 51 mm) by 1/2 in. (13 mm)
thick were cut from plates with the 12
in. length parallel to the rolling direction and with the 2 in. width coinciding with the plate thickness. The
specimens were oriented in this
manner so that the bead weld would
be made at the plate center where the
segregation is the highest. All specimens were ground to a thickness of
0.500 0.002 in. (12.70 0.05 mm)
with a 30 (0.75/u) rms surface finish.
cleation of cold cracks could be observed. Two specimen-to-plate orientations were utilized: in one, the b a n d ing was transverse, and in the other,
the banding was parallel to the welding surface. With both orientations, as
shown in Fig. 1, the weld bead location corresponds to the center of the
as-received plate. All 0.5 x 2 in. (12.7
X 51 mm) surfaces were ground parallel, lapped, and rough polished with
600 grit p o l i s h i n g paper prior to
welding.
Pairs of specimens with the same
banding orientation, one from each
heat, were c l a m p e d together between run-off tabs in a vise with the
polished surfaces in contact, as
shown in Fig. 2. E11018G welding
electrodes were deposited with a
stickfeeder utilizing 165 A, 22 V, and
7.5 ipm (190 m m / m i n ) travel speed.
High hydrogen welds (~30 ppm diffusible H) were made by wiping damp
electrodes with a thin film of lubricating oil and also applying a few
drops of oil to the surface of the specimens to be welded. The oil was
necessary because preliminary tests
E IIOI8G
WELDING
ELECTRODE
PAIRS OF HY 8 0
BEAM SPECIMENS
ORIENTATION OF
BANDING
Fig. 2 Schematic illustration showing the welding of cold cracking test specimens
Furnace
practice
72P305
Open
hearth
Electric
N51755
Mn
Si
Ni
Cr
Mo
0.18
0.30
0.018
0.013
0.20
2.99
1.68
0.41
0.13
0.28
0.011
0.011
0.31
2.50
1.49
0.40
Aluminum
sol
insol
0.022
0.024
0.056
0.037
Total 0 2 ,
ppm
0.003
0.007
100
0.009
0.014
95
Al 2 0 3
Oxides
MnO
Si02
Nitrogen in
Nitrides
Cr
72P305
N51755
55
185
23
42
18
15
49
110
410
435
Sulfid ss or Oxides
V
Ti
13
20
5
8
Zr
3
5
WELDING RESEARCH S U P P L E M E N T !
277-s
indicated that simply wetting the electrodes did not introduce a sufficient
amount of hydrogen into the welds to
cause cracking or hydrogen bubble
evolution. Low hydrogen welds (~2
ppm diffusible H) were made with
electrodes that were baked at 800 F
(427 C) for 1-1/2 h and used soon
after removal from the baking furnace.
I m m e d i a t e l y after w e l d i n g , the
c o m p o s i t e w e l d m e n t was w a t e r
quenched and transferred rapidly into
a bath of dry ice and acetone (about
- 1 0 5 F) ( - 7 6 C). After quenching,
the composite weldment was removed briefly from the bath in order
to allow separation of the specimens.
This low temperature storage procedure was used in order to minimize the loss of hydrogen from the
specimens. A lower storage temperature, such as available with liquid
nitrogen, was purposely avoided in
order to minimize transformation of
any retained austenite that possibly
would be present in the heat-affected
zone of the specimens.
The preparation of a specimen for
testing consisted of removing it from
the bath, allowing it to warm to room
temperature, then quickly polishing
and etching. The specimen was then
placed in a loading apparatus, detailed in Fig. 3. This loading apparatus stressed the specimen as a simple
beam with a concentrated load at the
center. To observe the evolution of
hydrogen, a film of immersion oil was
spread over the polished surface, and
the loading apparatus, with the specimen inserted, was placed on the
stage of a microscope. The specimen was observed with magnifications up to 250X under bright-field
illumination, before and during
stressing, to note any crack formation, and/or bubble evolution.
Metallographic Examination of
the Fusion Boundary
rT^I
fr^
!|(Q)
0:1
SPECIMEN
(R) I
Heat
Tensile
specimen
0.2%
Y.S.,
ksi
P
N
0.505 in.
0.252 in.
88
83
T.S.,
ksi
Elong.,
108
103
25
27
74
78
Charpy V
energy,
ft-lb
80F
-120F
R.A.,
143
153
121
140
Heat
P
P
P
P
N
N
N
N
ReiHa
content
Banding
to stress
orientation
Bubble
evolution
30
30
2
2
30
30
2
2
Transverse
Parallel
Transverse
Parallel
Transverse
Parallel
Transverse
Parallel
Profuse
Profuse
None
None
Profuse
Profuse
None
None
ppm
ppm
ppm
ppm
ppm
ppm
ppm
ppm
(a) Includes cracks associated with the unmixed zone and/or the partially-melted zone
278-s I S E P T E M B E R
1976
> 1 2 (long)
1-3 (short)
0
0
7-12 (medium)
0
0
0
General Observations
The observations of the welded
specimens from Heats N and P tested
at room temperature in the loading
apparatus are summarized in Table 3.
These o b s e r v a t i o n s revealed the
following general features:
1. None of the specimens from either
Heat N or P welded under low
hydrogen conditions exhibited
hydrogen bubble evolution or cold
cracking.
2. All specimens welded under high
hydrogen conditions exhibited
bubble evolution and some degree of cold cracking in one or
more of three regions: (a) in the
true heat-affected zone, (b) at the
fusion boundary, subsequently
determined to be associated with
the unmixed zone and/or the partially melted zone.
3. The observed cracking in the high
h y d r o g e n s p e c i m e n s was p r i marily delayed in nature. In other
words, the cracks generally initiated shortly after application of
the load and extended with time,
accompanied by steady and/or intermittent hydrogen bubble evolution. The bubble evolution confirmed the association of hydrogen with delayed cracking.
4. Under similar welding conditions,
the degree of cracking in Heat N
specimens was always less than in
Heat P specimens.
5. Cracking in the true heat-affected
zone in both heats of HY-80 appeared to be nucleated by sulfide
inclusions.
6. Most of the cracks, both at the f u sion boundary and in the true heataffected zone, appeared to propagate along light etching alloy-rich
bands of the base metal.
7. In the specimens welded under
high hydrogen welding conditions
with the rolling direction oriented
parallel to the direction of the principal stress, the cracks were generally shorter and less likely to be
nucleated within the fusion b o u n dary than were those in specimens w e l d e d with the rolling
direction transverse to the stress
direction.
8. Cold cracks associated with the
DATA
OBTAINE
FROM
GROUNOAND POUSHEO
SURFACE
600
" 8
00
" 4
00
JJ
<&/
300
IOO
MY BO. MEAT
_
Mo M M T l U
I
0 50
PERCENT AUGMENTED
O 73
STRAIN
Composite Region
Unmixed Zone
Partially-Melted zone
True Heat-Affected zone
Fig. 6 A transverse section showing a fusion boundary crack in a Varestraint test
specimen from Heat P strained 2%. Nital and sodium bisulfite procedure: X300, reduced
24%
WELDING RESEARCH S U P P L E M E N T I 279-s
Fig. 7 Schematic illustration of the probable mechanism producing the intermittent bursts of hydrogen observed during
delayed cracking
Sulfide Inclusion
X2100, reduced
280-s I S E P T E M B E R
61%
1976
lei to the stress direction, true heataffected zone cracking was virtually
eliminated. Heat N had no cracks and
Heat P had two cracks. One of these
cracks in Heat P is shown in Fig. 11
after repolishing and etching with the
two-stage procedure. Note that both
ends of the crack were arrested in a
dark etching band, which suggests
that cracks become severely blunted
upon entering relatively tough, alloylean bands. The low incidence of
cracking with the parallel orientation
results from the fact that the elongated sulfides, being parallel to the
stress direction, are less effective as
stress raisers and thus crack nucleation is considerably reduced or essentially eliminated.
Cracking Associated With
the Fusion Boundary
30 minutes
1 hour
1976
Conclusions
1. The following conclusions pertain to Varestraint tests of the weld
metal produced in HY-80 steel with
E11018G electrodes:
a. Hot cracking in the composite
region of bead welds deposited
with E11018G electrodes is extremely irregular and is not readily evaluated quantitatively.
b. The large difference in weldability
between the two heats of HY-80
did not influence the hot cracking
behavior of the composite region
of the weld metal produced in the
Varestraint test.
2. The following conclusions pertain to cold cracking tests of HY-80:
a. The cold cracking test procedure
used in this investigation is an excellent method for investigating
the nucleation and propagation of
cold cracks in low alloy steels.
b. Hydrogen is necessary for the
p r o p a g a t i o n of c r a c k s and
appears to be the catalyst for the
nucleation of the cracking.
c. Hot microcracking in the unmixed
zone at alloy-rich locations is a
valid but probably infrequent
mechanism of crack nucleation in
rich-analysis heats of HY-80. However, the presence of hydrogen is
required for the propagation of
such microcracks.
d. Cold cracking occurs preferentially in alloy-rich bands in the true
heat-affected zone and adjacent to
the weld interface.
e. Cold cracking in the true heataffected zone was almost exclusively nucleated by elongated sulfide inclusions.
f. Cold cracking in the partially
melted zone can be nucleated by
liquated grain boundaries and by
small precipitated sulfides in constitutionally liquated regions.
3. The following conclusions pertain to the observed location of the
cracks in the sample from the cruciform test specimen:
a. A considerable length of the crack
under fillet weld C traversed the
unmixed zone and the partially
melted zone, indicating that it is
inaccurate to assume that cracking
in the cruciform test is simply heataffected-zone cracking.
b. The existence and nature of the
unmixed zone and the partially
melted zone may provide an explanation for the correlation between the cold cracking susceptibility as measured by the cruciform test and the hot cracking susceptibility as measured by the
Varestraint test.
References
1. Doty, W. D. and Grotke, G. E., "Some
Composite Region
Unmixed Zone
Partially-Melted
Zone
True Heat-Affected
Zone
}*!' l
'-- \ S
Composite Region
Unmixed zone
Partially-Melted
Zone
True Heat-Affected
Zone
Fig. 15 Views along the macrocrack under fillet weld Con a transverse section of a cruciform test specimen of HY-80. Ammonium persulfate etchant. (a) A digression of the crack
path into the unmixed zone, (b) Crack branches into the unmixed and partially
melted
zones. X250, reduced 31%
O b s e r v a t i o n s on the W e l d a b i l i t y of
Q u e n c h e d and T e m p e r e d High Yield
Strength Alloy Steels," Conference Proceedings, U.S. Navy Bureau of Ships,
Washington, D . C , 34 to 67, March 21 and
22, 1960.
2. Rathbone, A. M. and Gross, J. H.,
"Factors Influencing Heat-Affected Zone
Cracking of HY-80 Steel Weldments,"
Technical Report 56.02-001(4), U.S. Steel
Corp., Applied Res. Lab., Monroeville, Pa.,
June (1962).
3. Masubuchi, K. and Martin, D. C ,
"The Mechanism of Cracking in HY-80
Steel Weldments," Welding Journal, 41(8),
Aug. 1962, Research Suppl., 375-s to
384-s.
4. Griffin. R. J.. "Cold Cracking in the
H e a t - A f f e c t e d Z o n e of HY-80 W e l d e d
Joints." Bureau Ships Journal, 5, 9 to 17
(1959).
5. Emmanuel, G. N., Young, D. E. and
Spahr, G. L., "The Metallurgy of Heat-Affected Zones in HY-80 High Strength
Steel," Metals Engineering Quarterly, 1(3),
82 to 97 (1961).
6. Savage, W. F., Nippes, E. F. and
Szekeres, E. S., "A Study of Weld-Interface Phenomena in a Low Alloy Steel."
Welding Journal, 55(9), Sept. 1976, Research Suppl., 260-s to 268-s.
7. Savage, W. F. and Lundin, C. D.,
"The Varestraint Test," Welding
Journal,
44(10), Oct. 1965, Research Suppl., 433-s
to 442-s.
8. Savage, W. F. and Lundin, C. D.,
"Application of Varestraint Technique to
the Study of Weldability," Welding Journal,
45(11). Nov. 1966, Research Suppl., 497-s
to 503-s.
9. Granjon, H. P., 1961 A d a m s Lecture:
"Studies on Cracking of and Transformation in Steels During Welding," Welding
Journal,
4 1 ( 1 ) , J a n . 1962, R e s e a r c h
Suppl., 1-s to 11-s.
10. Bell, J. R., "A Study of the Relationship of Microsegregation to Cracking in
C o n s t r u c t i o n a l Alloy S t e e l s , " Master's
Thesis, Rensselaer Polytechnic Institute,
Troy, New York (1966).
11. Elsea, A. R. and Fletcher, E. E.,
" H y d r o g e n Induced Delayed Brittle
Failures of High Strength Steels," Defense
Metals Information Center Report 199.
Battelle Memorial Institute, Columbus,
Ohio, January 20, 1964.
12. Rathbone, A. M., Connor, L. P. and
Gross, J. H., "Weldability of a High Toughness Alloy Plate Steel With a Minimum
Yield Strength of 140 KSI," Welding Journal, 43(12), Dec. 1964, Research Suppl.,
551-s to 563-s.
13. Randall, M. D Monroe, R. D. and
Rieppel, P. J., "Causes of Microcracking
and Microporosity in Ultra-High Strength
Steel Weld Metal." Welding Journal. 41(5),
May 1962, Research Suppl., 193-s to
206-s.
14. Boniszewski, R. and Baker, R. G.,
"Burning and Hot Testing in the Weld
Heat-Affected Zone of Ferritic Steel," Journal of the Iron and Steel Institute, 202(11),
921 to 928 (1964).
15. Boneszewski, T. and Moreton, J.,
"Effect of Micro-Voids and Manganese
Sulphide Inclusions in Steel on Hydrogen
Evolution and E m b r i t t l e m e n t , "
British
Welding Journal. 14(6), 321 to 336 (1967).
WELDING RESEARCH
SUPPLEMENT
I 283-S
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1976