Professional Documents
Culture Documents
3,33
Calculate Z and V for ethane at 323.15 K (50C) and 15 bar by the following equations:
(a) The truncated virial equation with the following experimental values of virial coefficients.
(b) The truncated virial equation, with a value of B from the generalized Pitzer correlation.
(c) The Redlich/Kwong equation.
(d) The Soave/Redlich/Kwong equation.
(e) The Peng/Robinson equation.
Diketahui :
T=
P=
B=
C=
323,15
15
-156,7
9650
K
bar
Ditanya : Z & V = . . . . ?
R=
83,14
cm3.bar.mol-1.K-1
cm3.mol-1
cm6.mol-1
Jawab :
(a) Virial Equation
Vi =
R. T
B
C
(1+
+
)
P
V(i 1) V(i 1)2
B
C
+ 2
V V
-156,7
9650
Z= 1+
+
1624,93 (1624,93)2
Z= 1+
V0 = Videal =
Iterasi
Ke
0
1
2
3
4
R.T
P
(83,14).(323,15)
15
= 1791,11
Vi (cm3.mol-1)
Error
1791,11
1639,80
1626,38
1625,08
1624,95
9,23E-02
8,25E-03
8,03E-04
7,89E-05
Z = 0,9072
Saat iterasi ke 5, Error 10-4 maka iterasi
dihentikan dan didapat nilai
V = 1624,95 cm3.mol-1 dan Z = 0,9072
(b) Virial Equation, with a Value of B from the Generalized Pitzer correlation
Tc =
Tr =
K (From Appendix B)
305,30
1,06
bar (From Appendix B)
Pc =
Pr =
48,72
0,31
(From
Appendix
B)
=
0,1
B0 = 0,083
0,422
Tr1,6
B0 = -0,302
Z = 1 + B0
Pr
Pr
+ . B1
Tr
Tr
Z = 0,912
B1 = 0,139
0,172
Tr4,2
B1 = 0,004
V=
Z. R. T
P
V = 1633,79
cm3.mol-1
(Tr=T/Tc)
(Pr=P/Pc)
Z = 1 + q
V=
= Tr-0,5 = 0,972
.
= 5,076
q=
. Tr
= .
0,025
Zvirial
(Zvirial + )(virial + )
Z = 0,909
Z. R. T
P
V = 1628,54
Z = 1 + q
cm3.mol-1
2
0,5 2
= (1+(0,48508+1,55171-0,15613 )(1-Tr ))
= 0,964
.
q=
= 5,032
. Tr
= .
V=
Pr
=
Tr
Pr
=
Tr
0,025
Zvirial
(Zvirial + )(virial + )
Z = 0,910
Z. R. T
P
V = 1630,35
cm3.mol-1
= (1+(0,37464+1,54226-0,26992)(1-Tr0,5))2
= 0,970
.
q=
= 6,034
. Tr
= .
Z = 1 + q
V=
3,34
Z. R. T
P
Pr
=
Tr
Zvirial
(Zvirial + )(virial + )
0,023
Z = 0,893
V = 1599,89
cm3.mol-1
Calculate Z and V for sulfur hexafluoride at 348.15 K (75C) and 15 bar by the following equations:
(a) The truncated virial equation with the following experimental values of virial coefficients:
(b) The truncated virial equation with a value of B from the generalized Pitzer correlation.
(c) The Redlich/Kwong equation.
(d) The Soave/Redlich/Kwong equation.
(e) The Peng/Robinson equation.
For sulfur hexafluoride, TC = 318.7 K, PC = 37.6 bar, VC = 198 cm3.mol-1, and = 0.286.
Diketahui :
T=
P=
B=
C=
R=
348,15
15
-194
15300
83,14
K
bar
Ditanya : Z & V = . . . . ?
cm3.mol-1
cm6.mol-1
cm3.bar.mol-1.K-1
Jawab :
(a) Virial Equation
R. T
B
C
Vi =
(1+
+
)
P
V(i 1) V(i 1)2
Sebagai tebakan awal, digunakan
Vc =
198
cm3.mol-1
Z= 1+
B
C
+
V V2
Z= 1+
-194
15300
+
1624,93 (1624,93)2
Z = 0,4114
Iterasi
Ke
0
1
2
3
4
5
Vi (cm3.mol-1)
Error
198,00
81,27
184,00
78,72
198,91
198,91
1,44E+00
5,58E-01
1,34E+00
6,04E-01
0,00E+00
(b) Virial Equation, with a Value of B from the Generalized Pitzer correlation
Tc =
Tr =
318,70
1,09
K
Pc =
P
=
bar
37,6
0,40
r
0,286
B0 = 0,083
0,422
Tr1,6
Z = 1 + B0
B1 = 0,020
Pr
Pr
+ . B1
Tr
Tr
V=
Z = 0,899
Z. R. T
P
V = 1734,1
Z = 1 + q
0,172
Tr4,2
B1 = 0,139
B0 = -0,283
V=
(Tr=T/Tc)
(Pr=P/Pc)
= Tr-0,5 = 0,957
.
= 5,157
q=
. Tr
=.
Pr
= 0,032
Tr
Zvirial
(Zvirial + )(virial + )
Z. R. T
P
cm3.mol-1
Z = 0,965
V = 1861,97
cm3.mol-1
= (1+(0,48508+1,55171-0,156132)(1-Tr0,5))2
= 0,919
=
=
0,42748
0,08664
q=
.
= 4,953
. Tr
= .
Z = 1 + q
V=
Z = 0,968
Z. R. T
P
V = 1867,06
Z = 1 + q
cm3.mol-1
= (1+(0,37464+1,54226-0,26992)(1-Tr0,5))2
= 0,930
q = .
= 5,969
. Tr
=.
3,35
0,032
Zvirial
(Zvirial + )(virial + )
V=
Pr
=
Tr
Pr
= 0,028
Tr
Zvirial
(Zvirial + )(virial + )
Z. R. T
P
Z = 0,950
V = 1833,99
cm3.mol-1
Determine Z and V for steam at 523.15 K (250C) and 1800 kPa by the following:
(a) The truncated virial equation with the following experimental values of virial coefficients:
(b) The truncated virial equation with a value of B from the generalized Pitzer correlation.
(c) The steam tables (App. F).
Diketahui :
T=
P=
B=
C=
R=
523,15
18
-152,5
-5800
83,14
K
bar
Ditanya : Z & V = . . . . ?
cm3.mol-1
cm6.mol-1
cm3.bar.mol-1.K-1
Jawab :
(a) Virial Equation
R. T
B
C
Vi =
(1+
+
)
P
V(i 1) V(i 1)2
Sebagai tebakan awal, digunakan
V0 = Videal =
Iterasi
Ke
0
1
2
3
4
5
R.T
P
(83,14).(523,15)
18
Vi (cm3.mol-1)
2416,37
2261,47
2250,69
2249,88
2249,82
2249,82
= 2416,37
Error
6,85E-02
4,79E-03
3,59E-04
2,70E-05
0,00E+00
B
C
+ 2
V V
-152,5
5800
Z= 1+
+
2249,82 (2249,82)2
Z= 1+
Z = 0,9311
Saat iterasi ke 5, Error = 0, maka iterasi
dihentikan dan didapat nilai
V = 2249,82 cm3.mol-1 dan Z = 0,9311
(b) Virial Equation, with a Value of B from the Generalized Pitzer correlation
Tc =
Tr =
318,70
1,64
K
Pc =
Pr =
bar
37,6
0,48
0,286
B0 = 0,083
0,422
Tr1,6
B1 = 0,139
B0 = -0,108
Z = 1 + B0
(Tr=T/Tc)
(Pr=P/Pc)
Pr
Pr
+ . B1
Tr
Tr
0,172
Tr4,2
B1 = 0,118
V=
Z = 0,978
Z. R. T
P
V = 2363,99
cm3.mol-1
3,38
Calculate the molar volume of saturated liquid and the molar volume of saturated vapor
by the Redlich/Kwong equation for one of the following and compare results with values
found by suitable generalized correlations.
(a) Propane at 313.15 K(40C) where PSat = 13.71 bar.
(b) Propane at 323.15 K(50C) where PSat = 17.16 bar.
(c) Propane at 333.15 K(60C) where PSat = 21.22 bar.
(d) Propane at 343.15 K(70C) where PSat = 25.94 bar.
(e) n-Butane at 373.15 K(100oC) where PSat = 15.41 bar.
(f) n-Butane at 383.15 K(110oC) where PSat = 18.66 bar.
(g) n-Butane at 393.15 K(120C) where PSat = 22.38 bar.
(h) n-Butane at 403.15 K(130C) where PSat = 26.59bar.
(i) Isobutane at 363.15 K(90C) where PSat = 16.54bar.
(o) Isobutane at 373.15 K(100oC) where PSat = 20.03 bar.
(k) Isobutane at 383.15 K(110oC) where PSat = 24.01 bar.
(I) Isobutane at 393.15 K(120C) where PSat = 28.53 bar.
(m) Chlorine at 333.15 K(60C) where PSat = 18.21 bar.
(n) Chlorine at 343.15 K(70C) where PSat = 22.49 bar.
(0) Chlorine at 353.15 K(80C) where PSat = 27.43 bar.
(p) Chlorine at 363.15 K(90C) where PSat = 33.08 bar.
(q) Sulfur dioxide at 353.15 K(80C) where PSat = 18.66 bar.
(r) Sulfur dioxide at 363.15 K(90oC) where PSat = 23.31 bar.
(s) Sulfur dioxide at 373.15 K(l00C) where PSat = 28.74bar.
(t) Sulfur dioxide at 383.15 K(110C) where PSat = 35.01 bar.
Diketahui :
Ditanya : V (liquid) = . . . . ?
3
-1 -1
R= 83,14 cm .bar.mol .K
V (vapor) = . . . . ?
Untuk persamaan RK:
Z
= 1
Zliquid = 1 + q
(Z + )( + )
= 0
(1 + Z)
= 0,42748
Zvapor = + Z + Z +
= 0,08664
Jawab:
(a)
Propane
(b)
Propane
(c)
Propane
(d)
Propane
(e)
n-Butane
(f)
n-Butane
(g)
n-Butane
(h)
n-Butane
T (K)
313,15
1,087
T (K)
323,15
1,070
T (K)
333,15
1,054
T (K)
343,15
1,038
T (K)
373,15
1,067
T (K)
383,15
1,053
T (K)
393,15
1,040
T (K)
403,15
1,027
Tc
Tr
PC
Pr
P (bar)
13,71
Zliquid
369,8
q
6,332
0,847
42,48
Vliquid
0,323
Zvapor
Vvapor
0,03302
0,824
1565,10
0,196
372,53
PC
Pr
P (bar)
17,16
Zliquid
42,48
Vliquid
0,404
Zvapor
Vvapor
332,30
Tc
Tr
369,8
q
6,040
0,874
0,040
0,799
1250,22
0,212
Tc
Tr
PC
Pr
369,8
q
5,770
0,901
P (bar)
21,22
Zliquid
42,48
Vliquid
0,500
Zvapor
Vvapor
0,048
0,771
1007,00
0,230
299,79
Tc
Tr
PC
Pr
369,8
q
5,520
0,928
P (bar)
25,94
Zliquid
42,48
Vliquid
0,611
Zvapor
Vvapor
0,057
0,743
817,53
0,249
273,32
Tc
Tr
PC
Pr
425,1
q
5,999
0,878
P (bar)
15,41
Zliquid
36,96
Vliquid
0,417
Zvapor
Vvapor
0,041
0,795
1599,86
0,215
432,23
Tc
Tr
PC
Pr
425,1
q
5,766
0,901
P (bar)
18,66
Zliquid
36,96
Vliquid
0,505
Zvapor
Vvapor
0,049
0,769
1313,39
0,230
393,28
Tc
Tr
PC
Pr
425,1
q
5,547
0,925
P (bar)
22,98
Zliquid
36,96
Vliquid
0,622
Zvapor
Vvapor
0,058
0,736
1047,19
0,249
354,19
Tc
Tr
Pr
0,948
P (bar)
26,59
Zliquid
PC
425,1
q
5,342
36,96
Vliquid
0,719
Zvapor
Vvapor
0,066
0,716
902,70
0,265
334,31
3,43
To a good approximation, what is the molar volume of ethanol vapor at 753.15 K (480C)
and 6000 kPa? How does this result compare with the ideal-gas value?
Diketahui :
T=
P=
R=
753,15
6000 kPa =
83,14
Tc =
Pc =
513,90
61,48
0,645
Ditanya : Vm = . . . . ?
K
60
bar
cm3.bar.mol-1.K-1
Jawab :
B0 = 0,083
0,422
Tr1,6
B1 = 0,139
B0 = -0,146
Z = 1 + B0
Tr =
Pr =
K
bar
1,47
0,98
(Tr=T/Tc)
(Pr=P/Pc)
0,172
Tr4,2
B1 = 0,104
Pr
Pr
+ . B1
Tr
Tr
Z = 0,948
V=
Z. R. T
P
V = 989,02
cm3.mol-1
1043,61
cm3.mol-1
3,44
A 0.35 m3 vessel is used to store liquid propane at its vapor pressure. Safety considerations
dictate that at a temperature of 320 K the liquid must occupy no more than 80% of the total
volume of the vessel. For these conditions, determine the mass of vapor and the mass of liquid
in the vessel. At 320 K, the vapor pressure of propane is 16.0 bar.
3,59
Determine a good estimate for the compressibility factor Z of saturated hydrogen vapor at 25 K
and 3.213 bar. For comparison, an experimental value is Z = 0.7757.