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UTS TERMODINAMIKA TEKNIK KIMIA 1

Nama : Muhammad Bachtiar


NPM : 1515041010

3,33

Calculate Z and V for ethane at 323.15 K (50C) and 15 bar by the following equations:

(a) The truncated virial equation with the following experimental values of virial coefficients.
(b) The truncated virial equation, with a value of B from the generalized Pitzer correlation.
(c) The Redlich/Kwong equation.
(d) The Soave/Redlich/Kwong equation.
(e) The Peng/Robinson equation.
Diketahui :

T=
P=
B=
C=

323,15
15
-156,7
9650

K
bar

Ditanya : Z & V = . . . . ?

R=

83,14

cm3.bar.mol-1.K-1

cm3.mol-1
cm6.mol-1

Jawab :
(a) Virial Equation

Vi =

R. T
B
C
(1+
+
)
P
V(i 1) V(i 1)2

B
C
+ 2
V V
-156,7
9650
Z= 1+
+
1624,93 (1624,93)2
Z= 1+

Sebagai tebakan awal, digunakan

V0 = Videal =
Iterasi
Ke
0
1
2
3
4

R.T
P

(83,14).(323,15)
15

= 1791,11

Vi (cm3.mol-1)

Error

1791,11
1639,80
1626,38
1625,08
1624,95

9,23E-02
8,25E-03
8,03E-04
7,89E-05

Z = 0,9072
Saat iterasi ke 5, Error 10-4 maka iterasi
dihentikan dan didapat nilai
V = 1624,95 cm3.mol-1 dan Z = 0,9072

(b) Virial Equation, with a Value of B from the Generalized Pitzer correlation
Tc =
Tr =
K (From Appendix B)
305,30
1,06
bar (From Appendix B)
Pc =
Pr =
48,72
0,31
(From
Appendix
B)
=
0,1

B0 = 0,083

0,422
Tr1,6

B0 = -0,302

Z = 1 + B0

Pr
Pr
+ . B1
Tr
Tr

Z = 0,912

B1 = 0,139

0,172
Tr4,2

B1 = 0,004

V=

Z. R. T
P

V = 1633,79

cm3.mol-1

(Tr=T/Tc)
(Pr=P/Pc)

(c) The Redlich/Kwong Equation


Untuk persamaan RK:
= 1
= 0
= 0,42748
= 0,08664

Z = 1 + q
V=

= Tr-0,5 = 0,972
.
= 5,076
q=
. Tr

= .

0,025

Zvirial
(Zvirial + )(virial + )

Z = 0,909

Z. R. T
P

V = 1628,54

(d) The Soave/Redlich/Kwong Equation


Untuk persamaan SRK:
= 1
= 0
= 0,42748
= 0,08664

Z = 1 + q

cm3.mol-1

2
0,5 2
= (1+(0,48508+1,55171-0,15613 )(1-Tr ))
= 0,964
.
q=
= 5,032
. Tr

= .

V=

Pr
=
Tr

Pr
=
Tr

0,025

Zvirial
(Zvirial + )(virial + )

Z = 0,910

Z. R. T
P

V = 1630,35

cm3.mol-1

(e) Peng/Robinson Equation.


Untuk persamaan RK:
= 2,41421
= -0,41421
= 0,45724
= 0,07779

= (1+(0,37464+1,54226-0,26992)(1-Tr0,5))2
= 0,970
.
q=
= 6,034
. Tr

= .

Z = 1 + q
V=

3,34

Z. R. T
P

Pr
=
Tr

Zvirial
(Zvirial + )(virial + )

0,023

Z = 0,893
V = 1599,89

cm3.mol-1

Calculate Z and V for sulfur hexafluoride at 348.15 K (75C) and 15 bar by the following equations:
(a) The truncated virial equation with the following experimental values of virial coefficients:
(b) The truncated virial equation with a value of B from the generalized Pitzer correlation.
(c) The Redlich/Kwong equation.
(d) The Soave/Redlich/Kwong equation.
(e) The Peng/Robinson equation.
For sulfur hexafluoride, TC = 318.7 K, PC = 37.6 bar, VC = 198 cm3.mol-1, and = 0.286.

Diketahui :

T=
P=
B=
C=
R=

348,15
15
-194
15300
83,14

K
bar

Ditanya : Z & V = . . . . ?

cm3.mol-1
cm6.mol-1
cm3.bar.mol-1.K-1

Jawab :
(a) Virial Equation
R. T
B
C
Vi =
(1+
+
)
P
V(i 1) V(i 1)2
Sebagai tebakan awal, digunakan
Vc =
198
cm3.mol-1

Z= 1+

B
C
+
V V2

Z= 1+

-194
15300
+
1624,93 (1624,93)2

Z = 0,4114
Iterasi
Ke
0
1
2
3
4
5

Vi (cm3.mol-1)

Error

198,00
81,27
184,00
78,72
198,91
198,91

1,44E+00
5,58E-01
1,34E+00
6,04E-01
0,00E+00

Saat iterasi ke 5, Error = 0, maka iterasi


dihentikan dan didapat nilai
V = 198,91 cm3.mol-1 dan Z = 0,4114

(b) Virial Equation, with a Value of B from the Generalized Pitzer correlation
Tc =
Tr =
318,70
1,09
K
Pc =
P
=
bar
37,6
0,40
r

0,286

B0 = 0,083

0,422
Tr1,6

Z = 1 + B0

B1 = 0,020

Pr
Pr
+ . B1
Tr
Tr

V=

Z = 0,899

Z. R. T
P

V = 1734,1

(c) The Redlich/Kwong Equation


Untuk persamaan RK:
= 1
= 0
= 0,42748
= 0,08664

Z = 1 + q

0,172
Tr4,2

B1 = 0,139

B0 = -0,283

V=

(Tr=T/Tc)
(Pr=P/Pc)

= Tr-0,5 = 0,957
.
= 5,157
q=
. Tr
=.

Pr
= 0,032
Tr

Zvirial
(Zvirial + )(virial + )

Z. R. T
P

(d) The Soave/Redlich/Kwong Equation


Untuk persamaan SRK:
= 1
= 0

cm3.mol-1

Z = 0,965
V = 1861,97

cm3.mol-1

= (1+(0,48508+1,55171-0,156132)(1-Tr0,5))2
= 0,919

=
=

0,42748
0,08664

q=

.
= 4,953
. Tr

= .

Z = 1 + q
V=

Z = 0,968

Z. R. T
P

V = 1867,06

Z = 1 + q

cm3.mol-1

= (1+(0,37464+1,54226-0,26992)(1-Tr0,5))2
= 0,930
q = .
= 5,969
. Tr
=.

3,35

0,032

Zvirial
(Zvirial + )(virial + )

(e) Peng/Robinson Equation.


Untuk persamaan RK:
= 2,41421
= -0,41421
= 0,45724
= 0,07779

V=

Pr
=
Tr

Pr
= 0,028
Tr

Zvirial
(Zvirial + )(virial + )

Z. R. T
P

Z = 0,950
V = 1833,99

cm3.mol-1

Determine Z and V for steam at 523.15 K (250C) and 1800 kPa by the following:
(a) The truncated virial equation with the following experimental values of virial coefficients:
(b) The truncated virial equation with a value of B from the generalized Pitzer correlation.
(c) The steam tables (App. F).
Diketahui :

T=
P=
B=
C=
R=

523,15
18
-152,5
-5800
83,14

K
bar

Ditanya : Z & V = . . . . ?

cm3.mol-1
cm6.mol-1
cm3.bar.mol-1.K-1

Jawab :
(a) Virial Equation
R. T
B
C
Vi =
(1+
+
)
P
V(i 1) V(i 1)2
Sebagai tebakan awal, digunakan
V0 = Videal =
Iterasi
Ke
0
1
2
3
4
5

R.T
P

(83,14).(523,15)
18

Vi (cm3.mol-1)
2416,37
2261,47
2250,69
2249,88
2249,82
2249,82

= 2416,37

Error

6,85E-02
4,79E-03
3,59E-04
2,70E-05
0,00E+00

B
C
+ 2
V V
-152,5
5800
Z= 1+
+
2249,82 (2249,82)2
Z= 1+

Z = 0,9311
Saat iterasi ke 5, Error = 0, maka iterasi
dihentikan dan didapat nilai
V = 2249,82 cm3.mol-1 dan Z = 0,9311

(b) Virial Equation, with a Value of B from the Generalized Pitzer correlation
Tc =
Tr =
318,70
1,64
K
Pc =
Pr =
bar
37,6
0,48

0,286

B0 = 0,083

0,422
Tr1,6

B1 = 0,139

B0 = -0,108

Z = 1 + B0

(Tr=T/Tc)
(Pr=P/Pc)

Pr
Pr
+ . B1
Tr
Tr

0,172
Tr4,2

B1 = 0,118

V=

Z = 0,978

Z. R. T
P

V = 2363,99

cm3.mol-1

(c) The steam tables (App. F).


Dari steam table diperoleh data Volume spesifik steam pada suhu 523,15 K dan 1800 kPa
Vsp =
124,99
cm3.gram-1
BMsteam =
18
gram.mol-1
Jadi, Volume molar steam adalah:
Vm = Vsp . BMsteam =
2249,82 cm3.mol-1
Maka:
B
C
Z= 1+ + 2
Z = 0,93107
V V

3,38

Calculate the molar volume of saturated liquid and the molar volume of saturated vapor
by the Redlich/Kwong equation for one of the following and compare results with values
found by suitable generalized correlations.
(a) Propane at 313.15 K(40C) where PSat = 13.71 bar.
(b) Propane at 323.15 K(50C) where PSat = 17.16 bar.
(c) Propane at 333.15 K(60C) where PSat = 21.22 bar.
(d) Propane at 343.15 K(70C) where PSat = 25.94 bar.
(e) n-Butane at 373.15 K(100oC) where PSat = 15.41 bar.
(f) n-Butane at 383.15 K(110oC) where PSat = 18.66 bar.
(g) n-Butane at 393.15 K(120C) where PSat = 22.38 bar.
(h) n-Butane at 403.15 K(130C) where PSat = 26.59bar.
(i) Isobutane at 363.15 K(90C) where PSat = 16.54bar.
(o) Isobutane at 373.15 K(100oC) where PSat = 20.03 bar.
(k) Isobutane at 383.15 K(110oC) where PSat = 24.01 bar.
(I) Isobutane at 393.15 K(120C) where PSat = 28.53 bar.
(m) Chlorine at 333.15 K(60C) where PSat = 18.21 bar.
(n) Chlorine at 343.15 K(70C) where PSat = 22.49 bar.
(0) Chlorine at 353.15 K(80C) where PSat = 27.43 bar.
(p) Chlorine at 363.15 K(90C) where PSat = 33.08 bar.
(q) Sulfur dioxide at 353.15 K(80C) where PSat = 18.66 bar.
(r) Sulfur dioxide at 363.15 K(90oC) where PSat = 23.31 bar.
(s) Sulfur dioxide at 373.15 K(l00C) where PSat = 28.74bar.
(t) Sulfur dioxide at 383.15 K(110C) where PSat = 35.01 bar.

Diketahui :
Ditanya : V (liquid) = . . . . ?
3
-1 -1
R= 83,14 cm .bar.mol .K
V (vapor) = . . . . ?
Untuk persamaan RK:
Z
= 1
Zliquid = 1 + q
(Z + )( + )
= 0
(1 + Z)
= 0,42748
Zvapor = + Z + Z +

= 0,08664
Jawab:
(a)
Propane

(b)
Propane

(c)
Propane

(d)
Propane

(e)
n-Butane

(f)
n-Butane

(g)
n-Butane

(h)
n-Butane

T (K)
313,15

1,087
T (K)
323,15

1,070
T (K)
333,15

1,054
T (K)
343,15

1,038
T (K)
373,15

1,067
T (K)
383,15

1,053
T (K)
393,15

1,040
T (K)
403,15

1,027

Tc

Tr

PC

Pr

P (bar)
13,71
Zliquid

369,8
q
6,332

0,847

42,48
Vliquid

0,323
Zvapor

Vvapor

0,03302

0,824

1565,10

0,196

372,53

PC

Pr

P (bar)
17,16
Zliquid

42,48
Vliquid

0,404
Zvapor

Vvapor
332,30

Tc

Tr

369,8
q
6,040

0,874
0,040

0,799

1250,22

0,212

Tc

Tr

PC

Pr

369,8
q
5,770

0,901

P (bar)
21,22
Zliquid

42,48
Vliquid

0,500
Zvapor

Vvapor

0,048

0,771

1007,00

0,230

299,79

Tc

Tr

PC

Pr

369,8
q
5,520

0,928

P (bar)
25,94
Zliquid

42,48
Vliquid

0,611
Zvapor

Vvapor

0,057

0,743

817,53

0,249

273,32

Tc

Tr

PC

Pr

425,1
q
5,999

0,878

P (bar)
15,41
Zliquid

36,96
Vliquid

0,417
Zvapor

Vvapor

0,041

0,795

1599,86

0,215

432,23

Tc

Tr

PC

Pr

425,1
q
5,766

0,901

P (bar)
18,66
Zliquid

36,96
Vliquid

0,505
Zvapor

Vvapor

0,049

0,769

1313,39

0,230

393,28

Tc

Tr

PC

Pr

425,1
q
5,547

0,925

P (bar)
22,98
Zliquid

36,96
Vliquid

0,622
Zvapor

Vvapor

0,058

0,736

1047,19

0,249

354,19

Tc

Tr

Pr

0,948

P (bar)
26,59
Zliquid

PC

425,1
q
5,342

36,96
Vliquid

0,719
Zvapor

Vvapor

0,066

0,716

902,70

0,265

334,31

3,43

To a good approximation, what is the molar volume of ethanol vapor at 753.15 K (480C)
and 6000 kPa? How does this result compare with the ideal-gas value?
Diketahui :

T=
P=
R=

753,15
6000 kPa =
83,14

Tc =
Pc =

513,90
61,48

0,645

Ditanya : Vm = . . . . ?

K
60

bar

cm3.bar.mol-1.K-1

Jawab :

B0 = 0,083

0,422
Tr1,6

B1 = 0,139

B0 = -0,146

Z = 1 + B0

Tr =
Pr =

K
bar

1,47
0,98

(Tr=T/Tc)
(Pr=P/Pc)

0,172
Tr4,2

B1 = 0,104

Pr
Pr
+ . B1
Tr
Tr

Z = 0,948

V=

Z. R. T
P

V = 989,02

cm3.mol-1

Untuk gas ideal :


R. T
Videal =
P
Videal =

1043,61

cm3.mol-1

3,44

A 0.35 m3 vessel is used to store liquid propane at its vapor pressure. Safety considerations
dictate that at a temperature of 320 K the liquid must occupy no more than 80% of the total
volume of the vessel. For these conditions, determine the mass of vapor and the mass of liquid
in the vessel. At 320 K, the vapor pressure of propane is 16.0 bar.

3,59

Determine a good estimate for the compressibility factor Z of saturated hydrogen vapor at 25 K
and 3.213 bar. For comparison, an experimental value is Z = 0.7757.

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