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CHAPTER 15
QUALITATIVE ANALYSIS (TEST FOR IONS)
15.1
Introduction
Most ions have chemical characteristics that can be used for their confirmatory tests.
Metallic Lithium
Sodium Potassium Calcium
ion
(Li+)
(Na+)
(K+)
(Ca2+)
Flame
Deep red Golden
Lilac
Brick
colour or carmine yellow
red
Copper (II)
(Cu2+)
Bluish
green
Barium
(Ba2+)
Apple
green
Metallic ion
Test
3+
Fe
Hydrogen ion;
H+
hydroxide solution to a
solution of the substance.
Chloride ion;
Cl-
Bromide ion;
Br-
by ammonia solution
Iodide ion; I-
by ammonia solution
Add aqueous barium
chloride to the solution of
the substance followed by
dilute hydrochloric acid.
Add aqueos barium
chloride to the solution of
the substance followed by
dilute hydrochloric acid.
Sulphate ion;
SO42Sulphite ion;
SO32-
Hydroxide ion;
OH-
Oxygen; (O2) /
Colourless
Chlorine; (Cl2) /
greenish yellow
Hydrogen chloride;
(HCl) / colourless
but fumes in moist
air
Ammonia; (NH3) /
colourless
Nitrogen dioxide;
(NO2) / brown
Hydrogen sulphide;
(H2S) / colourless
Carbon monoxide;
(CO) / Colourless
Splint relights
Sulphur dioxide;
(SO2) / colourless
Nitrogen monoxide;
(NO) / Colourless
Turns brown
2NO(g) + O2(g) 2NO2(g)